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RESEARCH PAPER · Inorganic Chemistry · 2013

Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates

Chao Huang, Chun‐Li Hu, Xiang Xu, Bing‐Ping Yang, Jiang‐Gao Mao

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Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) IodatesOriginalChemInform Abstract: Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates.0Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge50Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Role of Acentric Displacements on the Crystal Structure and Second-Harmonic Generating Properties of RbPbCO3F and CsPbCO3F90(3 + 1)-Dimensional commensurately modulated structure and photoluminescence properties of diborate KSbOB 2 O 513Recent advances on second-order NLO materials based on metal iodates328Ba2B6O11, a Member of the BaO‐B2O3 Family, Featuring a Layer Framework19K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units18New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33Two tartratoborates with hybrid anionic groups from unusual condensation reactions9Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials5M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)9Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6Synthesis and Magnetic Properties of the KCu(IO3)3 Compound with [CuO5]∞ Chains7A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates7New polymorphism for BaTi(IO 3 ) 6 with two polymorphs crystallizing in the same space group11A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units28Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons15K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations33BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups2Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds37C(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups13A new polar alkaline earth–rare earth iodate: Ba 2 Ce(IO 3 ) 8 (H 2 O)10A review on the advancements in the characterization of the high-pressure properties of iodates44(NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence22LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution20From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap1

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  1. ChemInform Abstract: Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates.

    ChemInform · 2013-11-14

    Chao Huang, Chun‐Li Hu, Xiang Xu, Bing‐Ping Yang, Jiang‐Gao Mao

    Read original paper ↗ ·

  2. Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge

    Dalton Transactions · 2014-01-01

    Lili Liu, Xin Su, Yun Mo Yang, Shilie Pan, Xiaoyu Dong, Shujuan Han, Min Zhang, Jing Kang, Zhihua Yang

    Read original paper ↗ ·

  3. Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)

    Inorganic Chemistry · 2014-01-15

    Xiang Xu, Bing‐Ping Yang, Chao Huang, Jiang‐Gao Mao

    Read original paper ↗ ·

  4. α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion

    Chemistry of Materials · 2014-04-25

    Xiang Xu, Chun‐Li Hu, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

    Read original paper ↗ ·

  5. Role of Acentric Displacements on the Crystal Structure and Second-Harmonic Generating Properties of RbPbCO3F and CsPbCO3F

    Inorganic Chemistry · 2014-05-27

    T. Thao Tran, P. Shiv Halasyamani, James M. Rondinelli

    Read original paper ↗ ·

  6. (3 + 1)-Dimensional commensurately modulated structure and photoluminescence properties of diborate KSbOB 2 O 5

    Dalton Transactions · 2015-01-01

    Dan Zhao, Ronghua Zhang, Feifei Li, Juan Yang, Bingguo Liu, Yun-Chang Fan

    Read original paper ↗ ·

  7. Recent advances on second-order NLO materials based on metal iodates

    Coordination Chemistry Reviews · 2015-01-25

    Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  8. Ba2B6O11, a Member of the BaO‐B2O3 Family, Featuring a Layer Framework

    European Journal of Inorganic Chemistry · 2015-06-24

    Lili Liu, Yun Mo Yang, Xiaoyu Dong, Lei Chen, Shujuan Han, Shilie Pan

    Read original paper ↗ ·

  9. K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units

    Chemistry - A European Journal · 2016-01-07

    Xiang Xu, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  10. New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)

    Inorganic Chemistry · 2016-02-05

    Bing‐Ping Yang, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

    Read original paper ↗ ·

  11. Two tartratoborates with hybrid anionic groups from unusual condensation reactions

    Dalton Transactions · 2017-01-01

    Dong Yan, Fei‐Fei Mao, Tingting Ruan, Jiang‐Gao Mao

    Read original paper ↗ ·

  12. Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials

    Inorganic Chemistry · 2017-06-02

    Bing‐Ping Yang, Chun‐Li Hu, Fei‐Fei Mao, Xiang Xu, Jiang‐Gao Mao

    Read original paper ↗ ·

  13. M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates

    Crystal Growth & Design · 2017-08-16

    Tong-Ying Chang, Bing‐Ping Yang, Chun‐Li Hu, Dong Yan, Jiang‐Gao Mao

    Read original paper ↗ ·

  14. Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)

    Inorganic Chemistry · 2018-03-06

    Leyan Nian, Kui Wu, Guijie He, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  15. Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O

    Inorganic Chemistry · 2018-07-19

    Yahui Li, Hongping Wu, Bingbing Zhang, Zhihua Yang, Guopeng Han, Shilie Pan

    Read original paper ↗ ·

  16. TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)

    Chinese Journal of Physics · 2019-02-22

    Soraya Belhadj, Brahim Lagoun, Mohamed B. Taouti, Salah Khenchoul, Ali Benghia, Djamel Benbertal

    Read original paper ↗ ·

  17. Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses

    Chemistry of Materials · 2019-03-29

    Yahui Li, Guopeng Han, Hongwei Yu, Hao Li, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  18. Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties

    ChemistrySelect · 2019-08-06

    Qi Wu, Xian Liu, Siran Xu, Hongbing Pi, Yanjun Li

    Read original paper ↗ ·

  19. Synthesis and Magnetic Properties of the KCu(IO3)3 Compound with [CuO5]∞ Chains

    ACS Omega · 2019-08-30

    Eleni Mitoudi Vagourdi, Julia Rienmüller, P. Lemmens, V. P. Gnezdilov, Reinhard Karl Kremer, Mats Johnsson

    Read original paper ↗ ·

  20. A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates

    Dalton Transactions · 2020-01-01

    Jian‐Han Zhang, Qi Wu, Wen-Zhong Lai

    Read original paper ↗ ·

  21. New polymorphism for BaTi(IO 3 ) 6 with two polymorphs crystallizing in the same space group

    Dalton Transactions · 2020-01-01

    Zhen Qian, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  22. A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs

    Coordination Chemistry Reviews · 2020-05-25

    Kui Wu, Ya Feng Yang, Lihua Gao

    Read original paper ↗ ·

  23. Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units

    Chemical Communications · 2021-01-01

    Mengmeng Ding, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  24. Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons

    Inorganic Chemistry Frontiers · 2021-01-01

    Akun Liang, Plácida Rodríguez-Hernández, Alfonso Muñoz, Saqib Rahman, Alfredo Segura, Daniel Errandonea

    Read original paper ↗ ·

  25. K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations

    Chemical Science · 2021-12-06

    Jin Chen, Chun‐Li Hu, Yilin Li, Yan Chen, Qianqian Chen, Jiang‐Gao Mao

    Read original paper ↗ ·

  26. BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups

    New Journal of Chemistry · 2022-01-01

    Wenjuan Ma, Jianlong Huang, Bin Dai, Feng Yu

    Read original paper ↗ ·

  27. Noncentrosymmetric (C3H7N6)6(H2PO4)4(HPO4)·4H2O and Centrosymmetric (C3H7N6)2SO4·2H2O: Exploration of Acentric Structure by Combining Planar and Tetrahedral Motifs via Hydrogen Bonds

    Inorganic Chemistry · 2022-06-16

    Shu‐Fang Li, Liang Hu, Yao Ma, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Dong Yan

    Read original paper ↗ ·

  28. C(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups

    Journal of Solid State Chemistry · 2022-08-28

    Dong Yan, Yao Ma, Ru‐Ling Tang, Liang Hu, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Shu‐Fang Li

    Read original paper ↗ ·

  29. A new polar alkaline earth–rare earth iodate: Ba 2 Ce(IO 3 ) 8 (H 2 O)

    Dalton Transactions · 2023-01-01

    Xueying Zhang, Xiaohan Zhang, Bing‐Ping Yang, Jiang‐Gao Mao

    Read original paper ↗ ·

  30. A review on the advancements in the characterization of the high-pressure properties of iodates

    Progress in Materials Science · 2023-03-01

    Akun Liang, Robin Turnbull, Daniel Errandonea

    Read original paper ↗ ·

  31. (NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence

    Small · 2023-07-25

    Nan Ma, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  32. LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution

    Small · 2023-09-07

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

    Read original paper ↗ ·

  33. From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap

    Inorganic Chemistry Frontiers · 2026-01-01

    Xue-Ying Zhang, Peng-Fei Chen, Bing‐Ping Yang, Jiang‐Gao Mao

    Read original paper ↗ ·
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