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RESEARCH PAPER · Inorganic Chemistry · 2011

Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3– Anion

Zhenbo Cao, Yinchao Yue, Jiyong Yao, Zheshuai Lin, Ran He, Zhanggui Hu

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Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3– AnionOriginalHalogens1ChemInform Abstract: Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3‐ Anion.0A New Mixed Halide, Cs2HgI2Cl2: Molecular Engineering for a New Nonlinear Optical Material in the Infrared Region145Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP32Incorporating different secondary building units of {Bi 2 }, {Bi 8 } and {Bi 10 } to construct diversity of luminescent bismuth–organic frameworks22A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681Hg2Br3I: a new mixed halide nonlinear optical material in the infrared region28K4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates18Syntheses, crystal structures and magnetic properties of three new silver manganese(ii) or manganese(iii) mixed metal iodates10Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response26ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Hydrothermal preparation, structure and characterizations of noncentrosymmetric LiZnO(IO3)6Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates33Ab initio calculation of structural, electronic and optical properties of Hg(IO3)27Synthesis, structure and photoluminescence properties of amine-templated open-framework bismuth sulfates9A 2 BiI 5 O 15 (A = K + or Rb + ): two new promising nonlinear optical materials containing [I 3 O 9 ] 3− bridging anionic groups62Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation121Investigation of the second-order nonlinear optical properties of Cs2TeMo3O12 single crystal31α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)24Synthesis, crystal structure and optical properties of two new layered cadmium iodates: Cd(IO3)X (X=Cl, OH)13Hydrothermal synthesis of C3N4/BiOIO3 heterostructures with enhanced photocatalytic properties74Bi 2 Te(IO 3 )O 5 Cl: a novel polar iodate oxychloride exhibiting a second-order nonlinear optical response29BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions36Recent advances on second-order NLO materials based on metal iodates328Strong IR NLO Material Ba4MGa4Se10Cl2: Highly Improved Laser Damage Threshold via Dual Ion Substitution Synergy97Structures, Thermal Behaviors, and Luminescent Properties of Anhydrous Lanthanum Iodate Polymorphs26Pb17O8Cl18: A Promising IR Nonlinear Optical Material with Large Laser Damage Threshold Synthesized in an Open System223KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate7RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold124Synthesis, structure, and characterization of two new bismuth(III) selenite/tellurite nitrates: [(Bi3O2)(SeO3)2](NO3) and [Bi(TeO3)](NO3)22Bi 2 O(XO 4 )(IO 3 ) 2 (X = S, Se, Cr): Three-dimensional frameworks containing [Bi 4 O 2 ] 8+ clusters19Recent achievements on middle and far-infrared second-order nonlinear optical materials433A new cerium iodate infrared nonlinear optical material with a large second-harmonic generation response30Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6K 8 Ce 2 I 18 O 53 : a novel potassium cerium( iv ) iodate with enhanced visible light driven photocatalytic activity resulting from polar zero dimensional [Ce(IO 3 ) 8 ] 4− units14Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response121Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials5ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap36M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups15Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy36Bi 2 (IO 3 )(IO 6 ): First combination of [IO 3 ] − and [IO 6 ] 5− anions in three-dimensional framework9Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Second-order nonlinear optical crystals with mixed anions250Lead‐Based Organic Frameworks (Pb‐MOFs): Structural, Luminescence and Adsorption Aspects23A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions138A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer18Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 1217Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds16TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)9HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Synthesis and Crystal Structure of a New Iodate (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 Analogous to Sr[IO3]22Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6SrI3O9H: A new alkaline earth metal iodate with two different anionic units using mild aqua-solution method8Synthesis and Magnetic Properties of the KCu(IO3)3 Compound with [CuO5]∞ Chains7(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior92(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior11Mixed lone-pair and mixed anion compounds: Pb3(SeO3)(HSeO3)Br3, Pb3(SeO3)(OH)Br3, CdPb8(SeO3)4Cl4Br6 and RbBi(SeO3)F218A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates7Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material20From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides36Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance17Synthesis and Characterization of Two New Second Harmonic Generation Active Iodates: K3Sc(IO3)6 and KSc(IO3)3Cl9K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence24Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50Synthesis of Bi5O7I-MoO3 photocatalyst via simultaneous calcination of BiOI and MoS2 for visible light degradation of ibuprofen60Crystal growth, characterization and theoretical studies of the noncentrosymmetric compound Al3(IO3)9·(HIO3)6·18H2O4Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Barium fluoroiodate crystals with a large band gap and birefringence22SrTi(IO 3 ) 6 ·2H 2 O and SrSn(IO 3 ) 6 : distinct arrangements of lone pair electrons leading to large birefringences11Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups18Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10Hydrothermal Synthesis of New Iodates Ln2(IO3)3(IO4) (Ln = La, Nd, Pr) Containing the Tetraoxoiodate(V) Anion: Creation of Luminescence Properties by Doping with Eu, Dy, and Tb5Chemical substitution – oriented design of a new polar PbFIO3 achieving a balance between large second-harmonic generation response and wide band gap16BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups2Mg(H 2 O) 6 [(IO 2 (OH)) 2 (IO 3 )] 2 : a new iodate with a very large band gap and optical anisotropy14Pressure-Induced Phase Transition and Band-Gap Decrease in Semiconducting Na3bi(Io3)68Polar lanthanide copper iodates LnCu(IO3)5 (Ln = La, Ce, Pr, and Nd): Synthesis, crystal structure and characterization6One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response29General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates15Synthesis and Crystal Structure of Fluoride K2(Ta0.9I0.1)F7 with the Micro-Isomorphic Substitution in the Ta Cationic Position0AIO3·H6TeO6 (A = NH4+, Rb+): Two telluric acid and iodate Co-crystalline compounds with second harmonic generation response4Enhancement of birefringence and refractive index dispersion optimization from iodates to fluorooxoiodates1Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure6Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20Three novel iridium (III) complexes containing double chiral atoms for organic light‐emitting diodes5Tuning the Alkyl Chain of Nitrilotriacetamide for Selectively Extracting Trivalent Am over Eu Ions18An experimental look into efficient quaternary Bi5O7I/Bi(IO3)3/Bi2(IO4) (IO3)3/BiOIO3 photocatalytic composite10(H3O)Li2(IO3)3: crystal structure and IR spectrum0Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)64Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)60Samarium Hydrogen Iodate, Sm(IO3)3·HIO3: Synthesis and Characterization0SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap8Construction of efficient Pb( ii ) carboxylate catalysts for the oxygen and hydrogen evolution reactions2Symmetry Breaking via Anion-Molecule Synergy: Fluorine and Crystalline Water Directed Construction of Noncentrosymmetric Sr(IO2F2)2·2H2O0From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap1IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F20

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  1. Halogens

    Annual Reports Section A (Inorganic Chemistry) · 2012-01-01

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  2. ChemInform Abstract: Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3‐ Anion.

    ChemInform · 2012-01-27

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  3. A New Mixed Halide, Cs2HgI2Cl2: Molecular Engineering for a New Nonlinear Optical Material in the Infrared Region

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  4. Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP

    European Journal of Inorganic Chemistry · 2012-08-23

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  5. Incorporating different secondary building units of {Bi 2 }, {Bi 8 } and {Bi 10 } to construct diversity of luminescent bismuth–organic frameworks

    Dalton Transactions · 2012-10-12

    Xiaoping Zhang, Han‐Rui Tian, Gu-Fan Yan, Ying Su, Yun‐Long Feng, Jian‐Wen Cheng

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  6. A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO6

    Journal of Materials Chemistry C · 2013-01-01

    Sangen Zhao, Xingxing Jiang, Ran He, Shuquan Zhang, Zhihua Sun, Junhua Luo, Zheshuai Lin, Maochun Hong

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  7. Hg2Br3I: a new mixed halide nonlinear optical material in the infrared region

    CrystEngComm · 2013-01-01

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  8. K4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates

    CrystEngComm · 2013-01-01

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  9. Syntheses, crystal structures and magnetic properties of three new silver manganese(ii) or manganese(iii) mixed metal iodates

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  10. Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response

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  11. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

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  12. New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)

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    Eun Pyo Lee, Seung Yoon Song, Dong Woo Lee, Kang Min Ok

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  13. Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response

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  14. Hydrothermal preparation, structure and characterizations of noncentrosymmetric LiZnO(IO3)

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  15. Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates

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  16. Ab initio calculation of structural, electronic and optical properties of Hg(IO3)2

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  17. Synthesis, structure and photoluminescence properties of amine-templated open-framework bismuth sulfates

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  18. A 2 BiI 5 O 15 (A = K + or Rb + ): two new promising nonlinear optical materials containing [I 3 O 9 ] 3− bridging anionic groups

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  19. Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)

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  20. A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation

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  21. Investigation of the second-order nonlinear optical properties of Cs2TeMo3O12 single crystal

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  22. α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion

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  23. Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)

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  24. Synthesis, crystal structure and optical properties of two new layered cadmium iodates: Cd(IO3)X (X=Cl, OH)

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  25. Hydrothermal synthesis of C3N4/BiOIO3 heterostructures with enhanced photocatalytic properties

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  26. Bi 2 Te(IO 3 )O 5 Cl: a novel polar iodate oxychloride exhibiting a second-order nonlinear optical response

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  27. BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions

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  28. Recent advances on second-order NLO materials based on metal iodates

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  29. Strong IR NLO Material Ba4MGa4Se10Cl2: Highly Improved Laser Damage Threshold via Dual Ion Substitution Synergy

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  30. Structures, Thermal Behaviors, and Luminescent Properties of Anhydrous Lanthanum Iodate Polymorphs

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  31. Pb17O8Cl18: A Promising IR Nonlinear Optical Material with Large Laser Damage Threshold Synthesized in an Open System

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  32. KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate

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  33. RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold

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  34. Synthesis, structure, and characterization of two new bismuth(III) selenite/tellurite nitrates: [(Bi3O2)(SeO3)2](NO3) and [Bi(TeO3)](NO3)

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  35. Bi 2 O(XO 4 )(IO 3 ) 2 (X = S, Se, Cr): Three-dimensional frameworks containing [Bi 4 O 2 ] 8+ clusters

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  36. Recent achievements on middle and far-infrared second-order nonlinear optical materials

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  37. A new cerium iodate infrared nonlinear optical material with a large second-harmonic generation response

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  38. Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )

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  39. K 8 Ce 2 I 18 O 53 : a novel potassium cerium( iv ) iodate with enhanced visible light driven photocatalytic activity resulting from polar zero dimensional [Ce(IO 3 ) 8 ] 4− units

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  40. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

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  41. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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  42. Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response

    Chemistry of Materials · 2017-01-23

    Min Zhang, Xin Su, Miriding Mutailipu, Zhihua Yang, Shilie Pan

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  43. Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials

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  44. ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap

    Angewandte Chemie International Edition · 2017-06-20

    Hongming Liu, Qi Wu, Xingxing Jiang, Zheshuai Lin, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  45. ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap

    Angewandte Chemie · 2017-06-20

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  46. M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates

    Crystal Growth & Design · 2017-08-16

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  47. Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion

    Inorganic Chemistry · 2017-11-09

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  48. Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups

    Journal of Materials Science · 2017-11-13

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  49. Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy

    Dalton Transactions · 2018-01-01

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  50. Bi 2 (IO 3 )(IO 6 ): First combination of [IO 3 ] − and [IO 6 ] 5− anions in three-dimensional framework

    Solid State Sciences · 2018-02-02

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