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RESEARCH PAPER · Journal of Materials Chemistry C · 2022

CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy

Yuchen Yan, Jiahao Jiao, Chenchen Tu, Min Zhang, Zhihua Yang, Shilie Pan

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CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategyOriginalA pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses12Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties26Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation7Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses20Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials24The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 485The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)47Two Chiral YbIII Enantiomeric Pairs with Distinct Enantiomerically Pure N-Donor Ligands Presenting Significant Differences in Photoluminescence, Circularly Polarized Luminescence, and Second-Harmonic Generation30Structural Motif Cosubstitution Strategy for Designing Fluoroaluminoborate with the Sr2Be2B2O7-Type Double-Layered Structure14Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges9“One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra8[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect60Ca 3 Al 2 B 8 O 18 : borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO 4 ] units7CsAlB 3 O 6 Cl: the rational construction of a KBBF-type structure with aligned 2 ∞ [AlB 3 O 6 Cl] layers via introducing unprecedented [AlO 3 Cl] tetrahedra5Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Review on birefringence in borates based on birefringence-active functional groups and arrangements57NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission3LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs10K 2 SO 4 (NH 3 SO 3 ) 2 and Cs 2 SO 4 (NH 3 SO 3 ) 3 : two deep-UV transparent sulfamate-sulfates with moderate birefringence2Crystal Chemistry of Silver Borates with Salt Inclusion Structure2Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships13Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy16Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20Study of Cleavage Fracture Strength of Cation-Tuned Yttrium Calcium Oxyborate Crystals0Navigating the Landscape of Next-Generation Nonlinear Optical Materials Discovery: Opportunities and Challenges Driven by Artificial Intelligence4Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units0

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  1. A pair of ionic 1D Cu( ii ) chain enantiomers simultaneously displaying large second- and third-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Congli Gao, Zhiqiang Zhang, Bing Su, Xi-Li Li

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  2. Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties

    Chemical Communications · 2023-01-01

    Ziqi Chen, Fuming Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  3. Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation

    Materials Today Chemistry · 2023-01-01

    Huanhuan Cheng, Z. Li, Fromenteze Zhang, Zhihua Yang, Shilie Pan

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  4. Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Zhiqiang Zhang, Congli Gao, Fengcai Li, Xi-Li Li

    Read original paper ↗ ·

  5. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

    Inorganic Chemistry · 2023-01-18

    Feixiang Wang, Mengfan Wu, Zhihua Yang, Xifa Long, Yun Mo Yang, Shilie Pan

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  6. Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-02-03

    Hongkang Su, Ziting Yan, Xueling Hou, Min Zhang

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  7. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 4

    Angewandte Chemie International Edition · 2023-02-27

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  8. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)4

    Angewandte Chemie · 2023-02-27

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  9. Two Chiral YbIII Enantiomeric Pairs with Distinct Enantiomerically Pure N-Donor Ligands Presenting Significant Differences in Photoluminescence, Circularly Polarized Luminescence, and Second-Harmonic Generation

    Inorganic Chemistry · 2023-02-27

    Xi-Li Li, Ailing Wang, Yanan Li, Congli Gao, Minghui Cui, Hong‐Ping Xiao, Liming Zhou

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  10. Structural Motif Cosubstitution Strategy for Designing Fluoroaluminoborate with the Sr2Be2B2O7-Type Double-Layered Structure

    Inorganic Chemistry · 2023-03-03

    Jiahao Jiao, Abudukadi Tudi, Ziting Yan, Min Zhang

    Read original paper ↗ ·

  11. Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures

    Chemistry of Materials · 2023-07-07

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Fangfang Zhang, Zilong Chen, Xueling Hou, Zhihua Yang, Shilie Pan

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  12. Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges

    Dalton Transactions · 2023-12-07

    Hongkang Su, Jiahao Jiao, Shi‐Bin Wang, Donghai An, Min Zhang

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  13. “One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra

    Journal of Materials Chemistry C · 2024-01-01

    Haoran Wang, Jiahao Jiao, Abudukadi Tudi, Shilie Pan, Min Zhang

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  14. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

    Chemical Science · 2024-01-01

    Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  15. Ca 3 Al 2 B 8 O 18 : borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO 4 ] units

    Chemical Communications · 2024-01-01

    Ziting Yan, Dongdong Chu, Zhihua Yang, Shilie Pan, Min Zhang

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  16. CsAlB 3 O 6 Cl: the rational construction of a KBBF-type structure with aligned 2 ∞ [AlB 3 O 6 Cl] layers via introducing unprecedented [AlO 3 Cl] tetrahedra

    Chemical Communications · 2024-01-01

    Haoran Liu, Jiahao Jiao, Abudukadi Tudi, Qing‐Yu Liu, Zhihua Yang, Shilie Pan, Min Zhang

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  17. Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates

    Chemical Society Reviews · 2024-01-01

    Ziting Yan, Jinbin Fan, Shilie Pan, Min Zhang

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  18. Review on birefringence in borates based on birefringence-active functional groups and arrangements

    Science China Chemistry · 2024-06-14

    Qianzhen Zhang, Ran An, Zhihua Yang, Xifa Long, Shilie Pan, Yun Mo Yang

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  19. NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission

    Crystal Research and Technology · 2024-07-19

    Luyong Zhang, Shibin Wang, Zhencheng Wu, Xueling Hou, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  20. LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs

    Inorganic Chemistry · 2024-08-21

    Ziting Yan, Jinbin Fan, Dongdong Chu, Zhihua Yang, Juanjuan Lu, Shilie Pan, Min Zhang

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  21. K 2 SO 4 (NH 3 SO 3 ) 2 and Cs 2 SO 4 (NH 3 SO 3 ) 3 : two deep-UV transparent sulfamate-sulfates with moderate birefringence

    Dalton Transactions · 2025-01-01

    Yun Ji, Huili Zhang, Xin Wen, Jindong Chen, Guangsai Yang, Yuchen Yan, Guang Peng, Ning Ye

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  22. Crystal Chemistry of Silver Borates with Salt Inclusion Structure

    Crystallography Reports · 2025-04-01

    S. N. Volkov, Dmitri O. Charkin, Sergey M. Aksenov, A. M. Banaru, Yu.O. Kopylova, Р. С. Бубнова

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  23. Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships

    Coordination Chemistry Reviews · 2025-04-06

    Junben Huang, Chenglong Zhang, Siying Chen, Ailijiang Abudurusuli

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  24. Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy

    Laser & Photonics Review · 2025-04-10

    Piao Tang, Xin Wen, Yuchen Yan, Cao Xue, Jindong Chen, Chensheng Lin, Min Luo, Ning Ye, Guang Peng

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  25. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

    Coordination Chemistry Reviews · 2025-08-26

    Bailin Chen, Shuai An, Xueling Hou, Shilie Pan

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  26. Study of Cleavage Fracture Strength of Cation-Tuned Yttrium Calcium Oxyborate Crystals

    Crystal Growth & Design · 2025-09-25

    Chengkai Ren, Weirong Chen, Yafei Qin, Xiaoniu Tu, Shuai Wang, Sheng Wang, Kainan Xiong, Yanqing Zheng

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  27. Navigating the Landscape of Next-Generation Nonlinear Optical Materials Discovery: Opportunities and Challenges Driven by Artificial Intelligence

    Accounts of Materials Research · 2025-12-30

    Ran An, Dongdong Chu, Congwei Xie, Shilie Pan, Zhihua Yang

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  28. Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units

    Inorganic Chemistry Frontiers · 2026-01-01

    Yucheng Hao, Qiuhui Zhang, Haoran Yu, Xikai Miu, Simin Cai, Xinnan Li, Fengshan Yu, Yuan Lin, Mingyang Cao

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