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RESEARCH PAPER · Inorganic Chemistry · 2016

Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates

Miriding Mutailipu, Min Zhang, Xiaoyu Dong, Yanna Chen, Shilie Pan

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Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the PentaboratesOriginalBa n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units33ChemInform Abstract: Effects of the Orientation of [B5O11]7‐ Fundamental Building Blocks on Layered Structures Based on the Pentaborates.0The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response121Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36]9– Fundamental Building Blocks36Structural Insights into Borates with an Anion‐Templated Open‐Framework Configuration: Asymmetric K2BaB16O26 versus Centrosymmetric K3CsB20O32 and Na2M2NB18O30 (M=Rb, Cs; N=Ba, Pb)26Fabrication of highly efficient mesoporous NaBiO 3 /ZnO nanocomposites for recyclable photocatalytic degradation of organic pollutants18MBaYB 6 O 12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges42K 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block19The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges16Growth, Crystal Structures, and Characteristics of Li 5 ASrMB 12 O 24 (A = Zn, Mg; M = Al, Ga) with [MB 12 O 24 ] Frameworks12Ba 3 B 10 O 17 F 2 ·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement17Mg(H 2 O) 6 B 4 O 5 (OH) 4 (H 2 O) 3 : a new hydrated borate with a short DUV cutoff edge9Two alkali calcium borates exhibiting second harmonic generation and deep-UV cutoff edges3NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates14Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups12From BaAl 2 (BO 3 ) 2 O to SnAl 2 (BO 3 ) 2 F 2 : structure transformation based on ion regulation3Synthesis and characterization of three new rare-earth orthoborates: Ba 2 MgY 2 (BO 3 ) 4 , Ba 2 CdY 2 (BO 3 ) 4 , and Ba 2 CdSc(BO 3 ) 310Gadolinium-Rich Borate Gd 17.33 (BO 3 ) 4 (B 2 O 5 ) 2 O 16 Exhibiting a Magnetocaloric Effect24Borates: A Rich Source for Optical Materials1089Li3La2(BO3)3 and Li1.75Na1.25La2(BO3)3: A Great Enhancement in Birefringence Induced by Optimal Arrangement of π-Conjugated [BO3] Units28Pb 2 Al 2 B 3 O 8 F 3 : structure and properties of a new fluoroaluminoborate with non-traditional chain-like B 3 O 8 groups4Topological Features of A+B2+[B5O9] Layered Pentaborates: Structural Changes in NaSr[B5O9] at High Temperatures or Why KCa[B5O9] Is Unstable?4Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window62Design of New Borates with Deep Ultraviolet Transparency Inspired by the Flexibility of Unusual Triple-Layered Frameworks3Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks15Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F211K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O3Zero Liquid Discharge of Recirculating Cooling Water via Polyborate-Assisted Electrodialysis0The First Silver Lead Borate, AgPb[B5O9]0

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  1. Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units

    Inorganic Chemistry Frontiers · 2016-12-01

    Miriding Mutailipu, Xin Su, Min Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  2. ChemInform Abstract: Effects of the Orientation of [B5O11]7‐ Fundamental Building Blocks on Layered Structures Based on the Pentaborates.

    ChemInform · 2016-12-01

    Miriding Mutailipu, Min Zhang, Xiaoyu Dong, Yanna Chen, Shilie Pan

    Read original paper ↗ ·

  3. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges

    Dalton Transactions · 2017-01-01

    Miriding Mutailipu, Min Zhang, Yanna Chen, Xiaoquan Lu, Shilie Pan

    Read original paper ↗ ·

  4. Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response

    Chemistry of Materials · 2017-01-23

    Min Zhang, Xin Su, Miriding Mutailipu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  5. Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36]9– Fundamental Building Blocks

    Inorganic Chemistry · 2017-04-24

    Miriding Mutailipu, Min Zhang, Xin Su, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  6. Structural Insights into Borates with an Anion‐Templated Open‐Framework Configuration: Asymmetric K2BaB16O26 versus Centrosymmetric K3CsB20O32 and Na2M2NB18O30 (M=Rb, Cs; N=Ba, Pb)

    Chemistry - A European Journal · 2017-07-21

    Miriding Mutailipu, Min Zhang, Xin Su, Zhihua Yang, Yanna Chen, Shilie Pan

    Read original paper ↗ ·

  7. Fabrication of highly efficient mesoporous NaBiO 3 /ZnO nanocomposites for recyclable photocatalytic degradation of organic pollutants

    Optik · 2017-10-02

    Sekar Selvarajan, Ayyadurai Suganthi, Muthuramalingam Rajarajan, M.M. Shrividhya

    Read original paper ↗ ·

  8. MBaYB 6 O 12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges

    Dalton Transactions · 2017-11-30

    Xinglong Chen, Fangfang Zhang, Yunjing Shi, Yanzhou Sun, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  9. K 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block

    Dalton Transactions · 2018-01-01

    Dequan Jiang, Ying Wang, Bingbing Zhang, Guopeng Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  10. The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges

    Chemistry - A European Journal · 2018-08-07

    Ruru Ma, Yun Mo Yang, Cong Hu, Zhihua Yang, Shilie Pan

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  11. Growth, Crystal Structures, and Characteristics of Li 5 ASrMB 12 O 24 (A = Zn, Mg; M = Al, Ga) with [MB 12 O 24 ] Frameworks

    Inorganic Chemistry · 2018-12-31

    Huimin Song, Naizheng Wang, Xingxing Jiang, Ying Fu, Yunfei Li, Wang Liu, Zheshuai Lin, Jiyong Yao, Guochun Zhang

    Read original paper ↗ ·

  12. Ba 3 B 10 O 17 F 2 ·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement

    Chemical Communications · 2019-01-01

    Yahui Li, Hongwei Yu, Guopeng Han, Hao Li, Zhihua Yang, Shilie Pan

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  13. Mg(H 2 O) 6 B 4 O 5 (OH) 4 (H 2 O) 3 : a new hydrated borate with a short DUV cutoff edge

    Dalton Transactions · 2019-01-01

    Ya Wang, Jian Wei Han, Fengjiao Guo, Shichao Cheng, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  14. Two alkali calcium borates exhibiting second harmonic generation and deep-UV cutoff edges

    New Journal of Chemistry · 2019-01-01

    Peng Rong Ren, Yun Mo Yang, Hao Li, Zhihua Yang, Shilie Pan

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  15. NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates

    Inorganic Chemistry · 2019-03-04

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Sujuan Yu, Shilie Pan

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  16. Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups

    Inorganic Chemistry · 2019-12-26

    Ya Wang, Jian Wei Han, Junben Huang, Zhihua Yang, Shilie Pan

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  17. From BaAl 2 (BO 3 ) 2 O to SnAl 2 (BO 3 ) 2 F 2 : structure transformation based on ion regulation

    New Journal of Chemistry · 2020-01-01

    Ya Wang, Jian Wei Han, Junben Huang, Zhihua Yang, Shuzhao Huang, Shilie Pan

    Read original paper ↗ ·

  18. Synthesis and characterization of three new rare-earth orthoborates: Ba 2 MgY 2 (BO 3 ) 4 , Ba 2 CdY 2 (BO 3 ) 4 , and Ba 2 CdSc(BO 3 ) 3

    Dalton Transactions · 2020-01-01

    Runqing Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  19. Gadolinium-Rich Borate Gd 17.33 (BO 3 ) 4 (B 2 O 5 ) 2 O 16 Exhibiting a Magnetocaloric Effect

    Inorganic Chemistry · 2020-07-10

    Huimin Song, Naizheng Wang, Wang Liu, Jingcheng Feng, Jun Shen, Wei Dai, Zheshuai Lin, Jiyong Yao, Guochun Zhang

    Read original paper ↗ ·

  20. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  21. Li3La2(BO3)3 and Li1.75Na1.25La2(BO3)3: A Great Enhancement in Birefringence Induced by Optimal Arrangement of π-Conjugated [BO3] Units

    Inorganic Chemistry · 2021-07-30

    Xuping Shi, Wenbin Zhang, Wenbing Cai, Shujuan Han, Zhihua Yang, Shilie Pan

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  22. Pb 2 Al 2 B 3 O 8 F 3 : structure and properties of a new fluoroaluminoborate with non-traditional chain-like B 3 O 8 groups

    Dalton Transactions · 2022-01-01

    Bao Jiang, Shan Shu, Zhihua Yang, Fangfang Zhang, Min Zhang, Shilie Pan

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  23. Topological Features of A+B2+[B5O9] Layered Pentaborates: Structural Changes in NaSr[B5O9] at High Temperatures or Why KCa[B5O9] Is Unstable?

    Crystal Growth & Design · 2022-01-03

    Sergey N. Volkov, Sergey M. Aksenov, Valentina A. Yukhno, Р. С. Бубнова, Alexey V. Povolotskiy, M. Yu. Arsent’ev, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya

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  24. Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window

    Science China Chemistry · 2022-03-10

    Yanhui Zhang, Fuming Li, Rong Yang, Yun Mo Yang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  25. Design of New Borates with Deep Ultraviolet Transparency Inspired by the Flexibility of Unusual Triple-Layered Frameworks

    Crystal Growth & Design · 2022-06-13

    Yidan Chen, Tinghao Tong, Da‐Wei Fu

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  26. Ultraviolet Crystal with Strong Optical Nonlinearity by Creating Halogen-Centered Secondary Building Blocks

    Chemistry of Materials · 2023-07-06

    Xuping Shi, Abudukadi Tudi, Minqiang Gai, Zhihua Yang, Shujuan Han, Shilie Pan

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  27. Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F2

    Inorganic Chemistry · 2023-07-26

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Changyou Liu, Xifa Long, Yun Mo Yang

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  28. K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response

    New Journal of Chemistry · 2024-01-01

    Aihaimaitijiang Ababaikeri, Xueting Pan, Xueling Hou, Jian Wei Han

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  29. Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O

    Dalton Transactions · 2024-01-01

    Xiaojing Li, Luyong Zhang, Fuming Li, Zhihua Yang, Xueling Hou, Fangfang Zhang

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  30. Zero Liquid Discharge of Recirculating Cooling Water via Polyborate-Assisted Electrodialysis

    SSRN Electronic Journal · 2026-01-01

    Dong Guo, Ma Du, Yuansheng Pei, Li’an Hou

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  31. The First Silver Lead Borate, AgPb[B5O9]

    Journal of Chemical Crystallography · 2026-07-30

    V. E. Kireev, D. O. Charkin, Yu.O. Kopylova, A. N. Gosteva, M. Yu. Arsent’ev, Kompanchenko A.A., M.G. Krzhizhanovskaya, S. N. Volkov, Sergey M. Aksenov

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