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RESEARCH PAPER · Inorganic Chemistry · 2025

Rb 7 PbY 2 (B 5 O 10 ) 3 : A Noncentrosymmetric Rare-Earth Borate Nonlinear Optical Crystal with [B 5 O 10 ] Unit

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Rb 7 PbY 2 (B 5 O 10 ) 3 : A Noncentrosymmetric Rare-Earth Borate Nonlinear Optical Crystal with [B 5 O 10 ] UnitOriginalSynthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups3Halide Ion-Directed Symmetry Control in π-Conjugated Molecular Crystals6Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations2Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20[C(NH2)3]Pb(C2O4)Cl·H2O: A halogen- and lone-pair-tuned UV crystal with large birefringence originated from cooperative π-conjugation6Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties3A New Short-Wavelength UV NLO Material based on Dual Alkaline-Earth Metal Borophosphate with 1D Helical Anionic Chains0BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution0Rb7.5Ln2.5B15O30 (Ln = Gd and Eu): All-in-One Noncentrosymmetric Pentaborates with Strong Second-Harmonic Generation and Efficient Luminescence0Two scandium borate UV NLO crystals designed through chemical element substitution1[Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units1Structural and luminescence analysis of Li+/Na+ co-doped K7 CaGd2 (B5 O10)3:Tb3+ phosphors with enhanced green emission and thermal stability6(C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence0Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1Research advances in rare-earth nonlinear optical crystalline materials in 20250MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence0

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  1. Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups

    Dalton Transactions · 2025-01-01

    Yixin Song, Hongwei Yu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  2. Halide Ion-Directed Symmetry Control in π-Conjugated Molecular Crystals

    Inorganic Chemistry · 2025-06-17

    Yu Zhang, Han Luo, Shunke Zhang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  3. Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations

    Inorganic Chemistry · 2025-08-14

    Yuquan Feng, Zhiguo Zhong, Shuyang Chen, Sujuan Jin, Zhaohui Meng, Hongwei Wang

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  4. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

    Coordination Chemistry Reviews · 2025-08-26

    Bailin Chen, Shuai An, Xueling Hou, Shilie Pan

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  5. [C(NH2)3]Pb(C2O4)Cl·H2O: A halogen- and lone-pair-tuned UV crystal with large birefringence originated from cooperative π-conjugation

    Journal of Molecular Structure · 2025-09-08

    Chao Ma, Yu-Ming Pan, Pei Feng Han, Meihong Duan

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  6. Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties

    The Journal of Physical Chemistry Letters · 2025-12-26

    Zi-Xuan Zhao, Wei Chen, Hui‐Yan Zhao, Mengjiao Xu, Chao He, Qi Wei, Guo-Ming Wang

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  7. A New Short-Wavelength UV NLO Material based on Dual Alkaline-Earth Metal Borophosphate with 1D Helical Anionic Chains

    SSRN Electronic Journal · 2026-01-01

    Zhiguo Zhong, Yu-Quan Feng, Jing Li

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  8. BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution

    Chemical Communications · 2026-01-01

    Zheng-Yu Yang, C. Z. Chen, Bing-Wei Miao, Yi‐Lei Lv, Wenfeng Zhou, Ming‐Yang Cao, Ru‐Ling Tang

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  9. Rb7.5Ln2.5B15O30 (Ln = Gd and Eu): All-in-One Noncentrosymmetric Pentaborates with Strong Second-Harmonic Generation and Efficient Luminescence

    SSRN Electronic Journal · 2026-01-01

    S. D. Lee, Yunseung Kuk, Congcong Jin, Wei Zeng, Kang Min Ok

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  10. Two scandium borate UV NLO crystals designed through chemical element substitution

    Chemical Communications · 2026-01-01

    Zelong Liu, Huijian Zhao, Longyun Xu, Ning Jia, Ning Ye, Zhanggui Hu, Conggang Li

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  11. [Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units

    Inorganic Chemistry · 2026-01-07

    Yuquan Feng, Dongqin Bi, K. C. Liu, Shuyang Chen, Limin Gao, Zhaohui Meng

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  12. Structural and luminescence analysis of Li+/Na+ co-doped K7 CaGd2 (B5 O10)3:Tb3+ phosphors with enhanced green emission and thermal stability

    Materials Research Bulletin · 2026-01-14

    Sabriye Yuşan, Mustafa Burak Çoban, Umit Hüseyin Kaynar, İkbal Gözde Kaptanoğlu, Abeer S. Altowyan, Jabir Wali Hakami, H. Aydın, Elçin Ekdal Karalı, A. Canımoğlu, N. Can

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  13. (C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence

    Inorganic Chemistry · 2026-01-26

    Zeqiao Yin, Yue Zhang, Yongpan Lin, Xuehua Dong, Yuqiao Zhou, Daojiang Gao, Ling Huang, Liling Cao

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  14. Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency

    Inorganic Chemistry · 2026-02-05

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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  15. Research advances in rare-earth nonlinear optical crystalline materials in 2025

    Journal of Rare Earths · 2026-07-21

    Tiantian He, Dandan Zhou, Fang Kong, Jianggao Mao

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  16. MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence

    Crystal Growth & Design · 2026-10-02

    Yaozu Li, Chao Wei, Wenjing Zhang, Huiyi Zhang, Bo Zhao, Bingbing Zhang, Ying Wang

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