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RESEARCH PAPER · Inorganic Chemistry · 2017

Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77

Maierhaba Abudoureheman, Shujuan Han, Ying Wang, Qiong Liu, Zhihua Yang, Shilie Pan

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Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77OriginalK 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block19Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates42LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge20Pb8M(BO3)6 (M = Mg, Ca): Two new borates with large birefringence activated by the ∞[Pb8B6O18]2- double layers6A new alkaline-earth metal borate SrB3O4(OH)3·H2O with UV cutoff edge below 190 nm7The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges16Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block18Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges0Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions98LiK[B5O8(OH)]·1.5H2O: A novel lithium borate with nonlinear optical property11Four new deep ultraviolet borates with isolated B12O24 groups: Synthesis, structure, and optical properties9RbB 11 O 16 (OH) 2 : First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System5β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound6Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions21Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways5Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196Li4Ca2B8O16: A Borate with a Unique Fundamental Building Block and a Short Cutoff Edge14BaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase19Synthesis, crystal structure and theoretical calculations of two rare-earth borates with DUV cut-off edges6The First Mixed Calcium Zinc Borate with a Flexible [B8O17] Fundamental Building Block and Short UV Cutoff Edge7K2Na3[{B6O10(OH)}{B3O4(OH)3}] ⋅ H2O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear‐Optical Property20Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer11Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB18Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge8Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure6Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups8FBB-directed open framework evolution in alkali metal borates: Synthesis and structure property relationships of NaRb2B9O150

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  1. K 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block

    Dalton Transactions · 2018-01-01

    Dequan Jiang, Ying Wang, Bingbing Zhang, Guopeng Han, Zhihua Yang, Shilie Pan

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  2. Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)

    Dalton Transactions · 2018-01-01

    Ruijiao Chen, Xiaowen Wu, Zhi Su

    Read original paper ↗ ·

  3. Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates

    Inorganic Chemistry · 2018-01-25

    Shao-Chen Zhi, Yuelin Wang, Li Quan Sun, Jian‐Wen Cheng, Guo‐Yu Yang

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  4. LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge

    Inorganic Chemistry · 2018-02-14

    Yun Mo Yang, Qingrong Kong, Zhihua Yang, Shilie Pan

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  5. Pb8M(BO3)6 (M = Mg, Ca): Two new borates with large birefringence activated by the ∞[Pb8B6O18]2- double layers

    Journal of Alloys and Compounds · 2018-02-22

    Chen Zhou, Hui Zhang, Jianian Cheng, Hongyi Li, Sadeh Beysen

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  6. A new alkaline-earth metal borate SrB3O4(OH)3·H2O with UV cutoff edge below 190 nm

    Inorganic Chemistry Communications · 2018-04-05

    Hongjun Zhou, Li‐Xian Chang, Yanhui Zhang, Li Wang, Mohamedally Kurmoo

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  7. The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges

    Chemistry - A European Journal · 2018-08-07

    Ruru Ma, Yun Mo Yang, Cong Hu, Zhihua Yang, Shilie Pan

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  8. Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block

    Inorganic Chemistry Frontiers · 2019-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhizhong Zhang, Zhihua Yang, Shilie Pan

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  9. Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges

    New Journal of Chemistry · 2019-01-01

    Shuaishuai Hu, Zhi Su

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  10. Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

    Inorganic Chemistry · 2019-01-14

    Jianhao Huang, Congcong Jin, Pei-Li Xu, Pifu Gong, Zheshuai Lin, Jian‐Wen Cheng, Guo‐Yu Yang

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  11. LiK[B5O8(OH)]·1.5H2O: A novel lithium borate with nonlinear optical property

    Inorganic Chemistry Communications · 2019-02-23

    Xuyan Li, Guo‐Yu Yang

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  12. Four new deep ultraviolet borates with isolated B12O24 groups: Synthesis, structure, and optical properties

    Journal of Solid State Chemistry · 2019-02-28

    Tuohetijiang Baiheti, Shujuan Han, B. Bashir, Zhihua Yang, Y. Wang, Hongwei Yu, Shilie Pan

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  13. RbB 11 O 16 (OH) 2 : First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System

    ChemistrySelect · 2019-03-26

    Shuaishuai Hu, Shuwei Li, Zhi Su

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  14. β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

    Chemistry - A European Journal · 2019-06-18

    Shujuan Han, Chunmei Huang, Abudukadi Tudi, Shuaishuai Hu, Zhihua Yang, Shilie Pan

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  15. K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound

    ChemistrySelect · 2019-09-17

    Shuzhao Huang, Chen Zhou, Shichao Cheng, Feng Yu

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  16. Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions

    Dalton Transactions · 2019-10-27

    Ru‐Ling Tang, Chun‐Li Hu, Jianghe Feng, Zhi Gang Fang, Yan Chen, Fang Kong, Jiang‐Gao Mao

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  17. Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways

    Dalton Transactions · 2020-01-01

    Mengmeng Ding, Jingjing Xu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  18. Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 19

    New Journal of Chemistry · 2020-01-01

    Xiaowen Niu, Li Wang

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  19. Li4Ca2B8O16: A Borate with a Unique Fundamental Building Block and a Short Cutoff Edge

    Inorganic Chemistry · 2020-06-01

    Peng Rong Ren, Yun Mo Yang, Ming Wen, Hao Li, Zhihua Yang, Shilie Pan

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  20. BaB 4 O 5 F 4 with reversible phase transition featuring unprecedented fundamental building blocks of [B 16 O 21 F 16 ] in the α -phase and [B 4 O 6 F 4 ] in the β -phase

    Chemical Communications · 2021-01-01

    Wenbin Zhang, Siru Guo, Shujuan Han, Liying Wang, Xin Hua Zhou, Zhihua Yang, Shilie Pan

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  21. Synthesis, crystal structure and theoretical calculations of two rare-earth borates with DUV cut-off edges

    New Journal of Chemistry · 2021-01-01

    Qin Ma, Tinghao Tong, Zhi Su

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  22. The First Mixed Calcium Zinc Borate with a Flexible [B8O17] Fundamental Building Block and Short UV Cutoff Edge

    Chemistry - A European Journal · 2021-06-21

    Wenbin Zhang, Siru Guo, Shujuan Han, Zhihua Yang, Shilie Pan

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  23. K2Na3[{B6O10(OH)}{B3O4(OH)3}] ⋅ H2O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear‐Optical Property

    Chemistry - An Asian Journal · 2021-08-23

    Chong‐An Chen, Qi–Ming Qiu, Guo‐Yu Yang

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  24. Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer

    Dalton Transactions · 2021-12-01

    Chengfa Wu, Zilong Chen, Jianbang Chen, Zhihua Yang, Fangfang Zhang, Hongsheng Shi, Shilie Pan

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  25. Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB

    Inorganic Chemistry Frontiers · 2022-01-01

    Feixiang Wang, Yun Mo Yang, Congcong Jin, Shilie Pan

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  26. Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Zhikang Chen, Kewang Zhang, Bei Zhang, Jun Zhang

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  27. Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Jianlong Huang, Chengfa Wu, Jianbang Chen, Zhiyong Guo, Wenjuan Ma, Feng Yu, Bin Dai

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  28. Two Ultraviolet Optical Crystals K6B12O19F4 and K12B28O48: The Effects of Metal Cations Size and the F Ions on the Structure

    Inorganic Chemistry · 2023-05-09

    Shuzhao Huang, Liang Zhu, Ivan A. Kruglov, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  29. Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups

    ACS Omega · 2023-06-02

    Yu Dang, Jingdong Yan, Xueling Hou, Hongsheng Shi

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  30. FBB-directed open framework evolution in alkali metal borates: Synthesis and structure property relationships of NaRb2B9O15

    Journal of Molecular Structure · 2026-10-03

    Mengyang Jiao, Jiaxing Wei, Jianji Yao, Xifa Long, Yun Yang

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