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RESEARCH PAPER · Journal of Materials Chemistry C · 2013

Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response

Hongyi Li, Hongping Wu, Xin Su, Hongwei Yu, Shilie Pan, Zhihua Yang, Yi Lu, Jian Wei Han, Kenneth Reinhard Poeppelmeier

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Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation responseOriginalSynthesis, crystal structure, and optical properties of a new lead barium borate, PbBa 2 (B 3 O 6 ) 217Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Synthesis and Crystal Structure of the Iron(III) Oxotellurate(IV) Phosphate Oxide Chloride Fe11(TeO3)2(TeO4)3(PO4)2O4Cl36An outstanding second-harmonic generation material BiB 2 O 4 F: exploiting the electron-withdrawing ability of fluorine92PbGa 4 S 7 : a wide-gap nonlinear optical material91Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)30Synthesis and optical properties of the first lead borate bromide with isolated BO 3 groups: Pb 2 Ba 3 (BO 3 ) 3 Br26A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular Units287A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular Units59Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67The lone-pairs enhanced birefringence and SHG response: A DFT investigation on M2B5O9Cl (M=Sr, Ba, and Pb)47Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups279Linear optical and thermo-physical properties of polar K3B6O10Cl crystal21K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures42Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials341Alkali metal–alkaline earth metal borate crystal LiBa 3 (OH)(B 9 O 16 )[B(OH) 4 ] as a new deep-UV nonlinear optical material34Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates8New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)8Ba 3 FeS 4 Br: A 0D Iron‐Based Chalcohalide with Unusual Magnetic Properties9Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations85Experimental and ab initio studies of two UV nonlinear optical materials15KB(PO 4 )F: a novel acentric deep-ultraviolet material43The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13Pb 2 BO 3 Br: a novel nonlinear optical lead borate bromine with a KBBF-type structure exhibiting strong nonlinear optical response113A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses103Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals256The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation14Second-order nonlinear optical crystals with mixed anions251Synthesis and Characterization of the First Tin Fluoride Borate Sn3[B3O7]F with Second Harmonic Generation Response28The structure and classification of complex borates43A UV Transmittable NLO crystal Hydrofluoric Acid Mixed Sulphamic acid (FASA) : Synthesis, Growth and Characterization0CO(NH 2 ) 2 ·NH 4 Cl: an ultraviolet birefringent material with conjugated CO groups16Serendipitous formation and characterization of K2[Pd(NO3)4]·2HNO33Synthesis and Characterization of the Tin Iodide Borate Sn3[B3O7]I13Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data8[O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains6PbSrSiO 4 : a new ultraviolet nonlinear optical material with a strong second harmonic generation response and moderate birefringence37PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material121Sr5[BO2(OH)]3(OH)3F: First hydroxyborate fluoride with the [BO2(OH)]2− unit2Synthesis, Structure, and Characterization of d0 Transition-Metal Iodate: BaTi(IO3)6·0.5H2O12AB 11 O 16 (OH) 2 (A = K and Cs): interpenetrating 2D layers with large birefringence7Borates: A Rich Source for Optical Materials1097Ba 2.5 Pb 1.5 B 12 O 22 : structural transformation from a centrosymmetric to a noncentrosymmetric space group by introducing Pb into Ba 2 B 6 O 117Improving sensitivity and resolution in solid-state nuclear magnetic resonance0Noncentrosymmetric Tetrel Pnictides RuSi4P4 and IrSi3P3: Nonlinear Optical Materials with Outstanding Laser Damage Threshold47Thermal anomalies and phase transitions in Pb2Sc2Si2O9 and Pb2In2Si2O91CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy28Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra20A Cation-Driven Approach toward Deep-Ultraviolet Nonlinear Optical Materials17SYNTHESIS AND CRYSTAL STRUCTURE OF TWO NEW TETRAFLUOROBORATE CRYSTALLOHYDRATES M(BF4)2·3H2O, M = Sr, Ba2Synthesis, crystal and electronic structures, linear and nonlinear optical properties, and photocurrent response of oxyhalides CeHaVIO 4 (Ha = Cl, Br; VI = Mo, W)10Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl24Exploration of the structure, electronic and optical properties of AB 2(PO3)5 polyphosphates: a first-principle approach3Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )1Na 2 SnSO 4 F 2 : an ultraviolet-transparent sulfate crystal with large birefringence driven by stereochemically active tin( ii )1A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials1

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  1. Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa 2 (B 3 O 6 ) 2

    Journal of Alloys and Compounds · 2014-07-05

    Hongyi Li, Lingyun Dong, Yi Lu, Shilie Pan, Xiaoquan Lu, Hongwei Yu, Hongping Wu, Xin Su, Zhihua Yang

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  2. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

    Inorganic Chemistry · 2014-08-07

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  3. Synthesis and Crystal Structure of the Iron(III) Oxotellurate(IV) Phosphate Oxide Chloride Fe11(TeO3)2(TeO4)3(PO4)2O4Cl3

    Zeitschrift für anorganische und allgemeine Chemie · 2014-09-12

    Iwan Zimmermann, Mats Johnsson

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  4. An outstanding second-harmonic generation material BiB 2 O 4 F: exploiting the electron-withdrawing ability of fluorine

    Inorganic Chemistry Frontiers · 2014-12-26

    Rihong Cong, Ying Wang, Lei Kang, Zhengyang Zhou, Zheshuai Lin, Tao Yang

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  5. PbGa 4 S 7 : a wide-gap nonlinear optical material

    Journal of Materials Chemistry C · 2015-01-01

    Xiaoshuang Li, Lei Kang, Chao Li, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  6. Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)

    Journal of Materials Chemistry C · 2015-01-01

    Hyung Gu Kim, Jae Soo Yoo, Kang Min Ok

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  7. Synthesis and optical properties of the first lead borate bromide with isolated BO 3 groups: Pb 2 Ba 3 (BO 3 ) 3 Br

    Dalton Transactions · 2015-01-01

    Qun Jing, Xiaoyu Dong, Zhihua Yang, Shilie Pan

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  8. A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular Units

    Angewandte Chemie International Edition · 2015-01-28

    Jun‐Ling Song, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

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  9. A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular Units

    Angewandte Chemie · 2015-02-04

    Jun‐Ling Song, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

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  10. Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra

    Inorganic Chemistry · 2015-04-02

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  11. The lone-pairs enhanced birefringence and SHG response: A DFT investigation on M2B5O9Cl (M=Sr, Ba, and Pb)

    Chemical Physics · 2015-04-06

    Qun Jing, Xiaoyu Dong, Xinglong Chen, Zhihua Yang, Shilie Pan, Lei Chen

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  12. Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups

    Journal of the American Chemical Society · 2015-07-06

    Xiaoyu Dong, Qun Jing, Yunjing Shi, Zhihua Yang, Shilie Pan, Kenneth Reinhard Poeppelmeier, Joshua Young, James M. Rondinelli

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  13. Linear optical and thermo-physical properties of polar K3B6O10Cl crystal

    Journal of Materiomics · 2015-07-14

    Hongping Wu, Hongwei Yu, Zhihua Yang, Jian Wei Han, Kui Wu, Shilie Pan

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  14. K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures

    Inorganic Chemistry · 2015-10-21

    Yuan Hua Lin, Chun‐Li Hu, Jiang‐Gao Mao

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  15. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

    Ying Wang, Shilie Pan

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  16. Alkali metal–alkaline earth metal borate crystal LiBa 3 (OH)(B 9 O 16 )[B(OH) 4 ] as a new deep-UV nonlinear optical material

    Journal of Materials Chemistry C · 2016-01-01

    Chao Wu, Jun‐Ling Song, Longhua Li, Mark Graeme Humphrey, Chi Zhang

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  17. Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates

    Elsevier eBooks · 2016-01-01

    Shilie Pan, Y. Wang, Kenneth Reinhard Poeppelmeier

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  18. New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method

    Dalton Transactions · 2016-01-01

    Yun Mo Yang, Xiaoyu Dong, Shilie Pan

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  19. Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains

    RSC Advances · 2016-01-01

    Xuefei Wang, Fangfang Zhang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  20. Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)

    Journal of Alloys and Compounds · 2016-02-24

    Hongil Jo, Jae Soo Yoo, Kang Min Ok

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  21. Ba 3 FeS 4 Br: A 0D Iron‐Based Chalcohalide with Unusual Magnetic Properties

    European Journal of Inorganic Chemistry · 2016-03-01

    Xiaoshuang Li, Chao Li, Lei Kang, Yuxiao Wu, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  22. Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations

    Inorganic Chemistry · 2016-11-09

    Yuquan Feng, Hui‐Tao Fan, Zhiguo Zhong, Hongwei Wang, Dongfang Qiu

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  23. Experimental and ab initio studies of two UV nonlinear optical materials

    RSC Advances · 2017-01-01

    Juanjuan Lu, Guoqiang Q. Shi, Hongping Wu, Ming Wen, Dianwei Hou, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  24. KB(PO 4 )F: a novel acentric deep-ultraviolet material

    Dalton Transactions · 2017-01-01

    Jihong Jiang, Lin-Chuan Zhang, Ya‐Xi Huang, Zhimei Sun, Yuanming Pan, Jin‐Xiao Mi

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  25. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges

    Dalton Transactions · 2017-01-01

    Miriding Mutailipu, Min Zhang, Yanna Chen, Xiaoquan Lu, Shilie Pan

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  26. Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation

    Inorganic Chemistry Frontiers · 2018-01-01

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  27. Pb 2 BO 3 Br: a novel nonlinear optical lead borate bromine with a KBBF-type structure exhibiting strong nonlinear optical response

    Inorganic Chemistry Frontiers · 2018-01-01

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  28. A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses

    Chemistry of Materials · 2018-03-08

    Zhiqing Xie, Miriding Mutailipu, Guijie He, Guopeng Han, Ying Wang, Zhihua Yang, Min Zhang, Shilie Pan

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  29. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

    Coordination Chemistry Reviews · 2018-03-15

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  30. The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation

    Journal of Solid State Chemistry · 2018-04-26

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  31. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

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  32. Synthesis and Characterization of the First Tin Fluoride Borate Sn3[B3O7]F with Second Harmonic Generation Response

    Chemistry - A European Journal · 2018-08-07

    Sandra Schönegger, Stephan G. Jantz, Andreas Saxer, Lkhamsuren Bayarjargal, Björn Winkler, Florian Pielnhofer, Henning A. Höppe, Hubert Huppertz

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  33. The structure and classification of complex borates

    Russian Chemical Reviews · 2018-10-25

    Anastasiya P. Topnikova, Elena L. Belokoneva

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  34. A UV Transmittable NLO crystal Hydrofluoric Acid Mixed Sulphamic acid (FASA) : Synthesis, Growth and Characterization

    International Journal of Scientific Research in Science and Technology · 2018-12-12

    Y. Samson, S. Anbarasu, Madhu Rajkumar, P. Ajith, D. Prem Anand

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  35. CO(NH 2 ) 2 ·NH 4 Cl: an ultraviolet birefringent material with conjugated CO groups

    CrystEngComm · 2019-01-01

    Wang Ya, Jian Wei Han, Abudukadi Tudi, Zhizhong Zhang, Zhihua Yang, Shilie Pan

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  36. Serendipitous formation and characterization of K2[Pd(NO3)4]·2HNO3

    Zeitschrift für Naturforschung B · 2019-03-21

    Michael Zoller, Jörn Bruns, Günter Heymann, Klaus Wurst, Hubert Huppertz

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  37. Synthesis and Characterization of the Tin Iodide Borate Sn3[B3O7]I

    Inorganic Chemistry · 2019-04-09

    Sandra Schönegger, Florian Pielnhofer, Andreas Saxer, Klaus Wurst, Hubert Huppertz

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  38. Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data

    Journal of Solid State Chemistry · 2019-04-29

    Carlos Alberto López, E. Bâati, María Teresa Fernández-Díaz, Felix O. Saouma, Joon Ik Jang, J. A. Alonso

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  39. [O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains

    Dalton Transactions · 2020-01-01

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  40. PbSrSiO 4 : a new ultraviolet nonlinear optical material with a strong second harmonic generation response and moderate birefringence

    Chemical Communications · 2020-01-01

    Shutong Jiang, Jinjie Zhou, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  41. PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material

    Chemistry of Materials · 2020-02-11

    Shujuan Han, Miriding Mutailipu, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  42. Sr5[BO2(OH)]3(OH)3F: First hydroxyborate fluoride with the [BO2(OH)]2− unit

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  43. Synthesis, Structure, and Characterization of d0 Transition-Metal Iodate: BaTi(IO3)6·0.5H2O

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  44. AB 11 O 16 (OH) 2 (A = K and Cs): interpenetrating 2D layers with large birefringence

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  45. Borates: A Rich Source for Optical Materials

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  46. Ba 2.5 Pb 1.5 B 12 O 22 : structural transformation from a centrosymmetric to a noncentrosymmetric space group by introducing Pb into Ba 2 B 6 O 11

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  47. Improving sensitivity and resolution in solid-state nuclear magnetic resonance

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  48. Noncentrosymmetric Tetrel Pnictides RuSi4P4 and IrSi3P3: Nonlinear Optical Materials with Outstanding Laser Damage Threshold

    Advanced Functional Materials · 2021-02-17

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  49. Thermal anomalies and phase transitions in Pb2Sc2Si2O9 and Pb2In2Si2O9

    Zeitschrift für Kristallographie - Crystalline Materials · 2021-10-19

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  50. CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy

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