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RESEARCH PAPER · Inorganic Chemistry · 2012

Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units

Yunjing Shi, Shilie Pan, Xiaoyu Dong, Ying Wang, Min Zhang, Fangfang Zhang, Zhongxiang Zhou

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Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion UnitsOriginalChemInform Abstract: Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero‐Dimensional Anion Units.0Syntheses, crystal structures of a series of novel alkali metal or alkaline earth metal phosphites21Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O836Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Ba2Cd(B3O6)2: A Congruent‐Melting Compound with Isolated B3O6 Units8Special ∞1[OPb2] Chains and ∞1[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb2(O4Pb8)(BO3)3Br3 and Pb2(O8Pb12)(BO3)2Br614Noncentrosymmetric Cubic CsCdBO3 with Bichromophore23Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion8Electron-Vibrational Interaction in the 5d States of Eu2+Ions in Sr6-xEuxBP5O20(x = 0.01-0.15)12K 7 B 2 P 5 O 19 : a novel alkali metal borophosphate with zero dimensional [B 2 P 5 O 19 ] 7− anionic units23Structural insights for the design of new borate–phosphates: synthesis, crystal structure and optical properties of Pb 4 O(BO 3 )(PO 4 ) and Bi 4 O 3 (BO 3 )(PO 4 )36β-BaGa[B 4 O 8 (OH)](H 2 O) and Ba 4 Ga[B 10 O 18 (OH) 5 ](H 2 O): new barium galloborates featuring unusual [B 4 O 8 (OH)] 5− and [B 10 O 18 (OH) 5 ] 11− clusters26Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate–Phosphate LiPb4(BO3)(PO4)215The interaction between cations and anionic groups inducing SHG enhancement in a series of apatite-like crystals: A first-principles study23The crystal structure of Li 2 B 3 PO 8 with the 2D-linkage of BO 3 , BO 4 and PO 4 groups22Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer8Planar Cu2(ppz)2 Dimers as SBUs for Diverse Polyoxometalate-Based Metal Organic Frameworks6Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O1616ACdCO 3 F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction61Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13Three Alkali Metal Lead Orthophosphates – Syntheses, Crystal Structures and Properties of APbPO4 (A = K, Rb, Cs)20Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Cd3[B2P4O14(OH)4]: A 3D Open‐Framework Cadmium Borophosphate with Unique Twisted 8‐Ring Channels1Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups279Series of SHG Materials Based on Lanthanide Borate–Acetate Mixed Anion Compounds39Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Iron Borophosphate as a Potential Cathode for Lithium- and Sodium-Ion Batteries29K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures42New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates57New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10Synthesis and characterization of CsSrCO 3 F – a beryllium-free new deep-ultraviolet nonlinear optical material34Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8A Cubic Non-Centrosymmetric Mixed-Valence Iron Borophosphate–Phosphite6New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33The Flexibility of P2O7 Dimers in Soft Structures: M2CdP2O7 (M = Rb, Cs)13Syntheses, structural and characterizations of a new anhydrous mixed-metal phosphate1Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity38Syntheses of six and twelve membered borophosphate ring structure with nonlinear optical activity12A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response384Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge69Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations85Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations1Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response23Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units16(H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates12Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures36Open-Framework Manganese(II) and Cobalt(II) Borophosphates with Helical Chains: Structures, Magnetic, and Luminescent Properties25Crystal growth, physical properties and computational insights of semi-organic non-linear optical crystal diphenylguanidinium perchlorate grown by conventional solvent evaporation method26Insights of BO 3 –PO 4 replacement for the design and synthesis of a new borate–phosphate with unique 1∞[Zn 4 BO 11 ] chains and two new phosphates16A novel selenoalkenyl-isoxazole based donor–acceptor nonlinear optical material14Synthesis of Iron Phosphate and Their Composites for Lithium/Sodium Ion Batteries33Synthesis, crystal structure and characterizations of a new diphosphate Rb2CaP2O719Combination of d 10 -cations and fluorine anion as active participants to design novel borate/carbonate nonlinear optical materials24Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge14A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)336From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals26KNa 4 B 2 P 3 O 13 : A Deep-Ultraviolet Transparent Borophosphate Exhibiting Second-Harmonic Generation Response26Synthesis, characterization and theoretical calculation of a noncentrosymmetric compound, Cs0.92B0.92Si5.08O122CsBP 2 O 6 (OH) 2 : a second-order NLO material with a unique borophosphate anionic partial structure and strong SHG effect10Ultraviolet nonlinear optical crystal: (NH4)ZnPO47Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units28Efficient degradation of reactive brilliant red on the first open-framework borate-rich cadmium borophosphate8Three polar indium phosphites exhibiting diverse structural networks and SHG-activity9Structure and Characterization of K2Na3B2P3O13, a New Nonlinear Optical Borophosphate with One-Dimensional Chain Structure and Short Ultraviolet Cutoff Edge13Isomeric Cd(NH4)2(PO3F)2·2H2O: Solution concentration-driven elimination of antiparallel dipole-dipole interaction generating an SHG β phase12Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates8Organometallic hexa-aqua magnesium hydrogen maleate third-order nonlinear optical crystal for NLO and optoelectronic device applications2A2Cd(PO3)4 (A = K, Rb, Cs): Series of cadmium polyphosphates with infinite 1[(PO3)4]ꝏ chains and deep ultraviolet transparency windows2A new strategy of getting accurate refractive index dispersion curves using first-principles sum-over-states method jointed by density functional perturbation theory2Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations2Syntheses, structural characterization, and nonlinear optical properties of mixed alkaline/alkaline earth metal borophosphates1Enhanced Ion-Exchange Properties of a Complex Microporous Uranyl Borophosphate0A New Short-Wavelength UV NLO Material based on Dual Alkaline-Earth Metal Borophosphate with 1D Helical Anionic Chains0[Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units1Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance0

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  1. ChemInform Abstract: Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero‐Dimensional Anion Units.

    ChemInform · 2013-01-01

    Yunjing Shi, Shilie Pan, Xiaoyu Dong, Ying Wang, Min Zhang, Fangfang Zhang, Zhongxiang Zhou

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  2. Syntheses, crystal structures of a series of novel alkali metal or alkaline earth metal phosphites

    CrystEngComm · 2013-01-01

    Xi-Jia Wang, Jian‐Han Zhang, Jun‐Ling Song, Fang Kong, Jiang‐Gao Mao

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  3. Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O8

    CrystEngComm · 2013-01-01

    Ying Wang, Shilie Pan, Min Zhang, Shujuan Han, Xin Su, Lingyun Dong

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  4. Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response

    Inorganic Chemistry · 2013-04-05

    Bing‐Ping Yang, Chun‐Li Hu, Xiang Xu, Chao Huang, Jiang‐Gao Mao

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  5. Ba2Cd(B3O6)2: A Congruent‐Melting Compound with Isolated B3O6 Units

    Zeitschrift für anorganische und allgemeine Chemie · 2013-04-26

    Xiaoyu Dong, Liang Cui, Yunjing Shi, Shilie Pan, Zhongxiang Zhou, Zhihua Yang, Bingbing Zhang, Xiangzhan Jiang, Yun Mo Yang, Zhaohui Chen, Zhenjun Huang

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  6. Special ∞1[OPb2] Chains and ∞1[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb2(O4Pb8)(BO3)3Br3 and Pb2(O8Pb12)(BO3)2Br6

    Inorganic Chemistry · 2013-09-19

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Xiaoyu Dong, Shujuan Han, Min Zhang

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  7. Noncentrosymmetric Cubic CsCdBO3 with Bichromophore

    European Journal of Inorganic Chemistry · 2013-10-02

    Hongwei Yu, Hongping Wu, Shilie Pan, Bingbing Zhang, Ming Wen, Zhihua Yang, Hongyi Li, Xiangzhan Jiang

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  8. Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block

    Journal of Materials Chemistry C · 2013-10-23

    Fangyuan Zhang, Fangyuan Zhang, Qun Jing, Fangfang Zhang, Fangfang Zhang, Shilie Pan, Zhihua Yang, Jian Wei Han, Min Zhang, Shujuan Han

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  9. BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion

    CrystEngComm · 2014-01-01

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Qiang Bian, Zhihua Yang, Hongping Wu, Min Zhang

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  10. Electron-Vibrational Interaction in the 5d States of Eu2+Ions in Sr6-xEuxBP5O20(x = 0.01-0.15)

    ECS Journal of Solid State Science and Technology · 2014-01-01

    Dejian Hou, C.-G. Ma, Hongbin Liang, M.G. Brik

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  11. K 7 B 2 P 5 O 19 : a novel alkali metal borophosphate with zero dimensional [B 2 P 5 O 19 ] 7− anionic units

    CrystEngComm · 2014-01-01

    Ying Wang, Shilie Pan, Shujuan Han, Bingbing Zhang, Lingyun Dong, Min Zhang, Zhihua Yang

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  12. Structural insights for the design of new borate–phosphates: synthesis, crystal structure and optical properties of Pb 4 O(BO 3 )(PO 4 ) and Bi 4 O 3 (BO 3 )(PO 4 )

    Dalton Transactions · 2014-01-01

    Ying Wang, Shilie Pan, Shengshi Huang, Lingyun Dong, Min Zhang, Shujuan Han, Xian Wang

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  13. β-BaGa[B 4 O 8 (OH)](H 2 O) and Ba 4 Ga[B 10 O 18 (OH) 5 ](H 2 O): new barium galloborates featuring unusual [B 4 O 8 (OH)] 5− and [B 10 O 18 (OH) 5 ] 11− clusters

    RSC Advances · 2014-01-01

    Hui Yang, Chun‐Li Hu, Jun‐Ling Song, Jiang‐Gao Mao

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  14. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

    Crystal Growth & Design · 2014-03-13

    Shujuan Han, Ying Wang, Shilie Pan, Xiaoyu Dong, Hongping Wu, Jian Wei Han, Yun Mo Yang, Hongwei Yu, Chunyan Bai

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  15. The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate–Phosphate LiPb4(BO3)(PO4)2

    European Journal of Inorganic Chemistry · 2014-07-09

    Shengshi Huang, Hongwei Yu, Jian Wei Han, Shilie Pan, Qun Jing, Ying Wang, Lingyun Dong, Hongping Wu, Zhihua Yang, Xian Wang

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  16. The interaction between cations and anionic groups inducing SHG enhancement in a series of apatite-like crystals: A first-principles study

    Journal of Solid State Chemistry · 2014-07-28

    Qun Jing, Xiaoyu Dong, Zhihua Yang, Shilie Pan, Bingbing Zhang, Xuchu Huang, Mingwei Chen

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  17. The crystal structure of Li 2 B 3 PO 8 with the 2D-linkage of BO 3 , BO 4 and PO 4 groups

    Dalton Transactions · 2014-08-06

    Toru Hasegawa, Hisanori Yamane

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  18. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework

    Inorganic Chemistry · 2014-09-26

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  19. Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer

    New Journal of Chemistry · 2014-09-30

    Xiangzhan Jiang, Yun Mo Yang, Shilie Pan, Jian Wei Han, Xiaoyu Dong, Fangyuan Zhang, Hongwei Yu, Ying Wang

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  20. Planar Cu2(ppz)2 Dimers as SBUs for Diverse Polyoxometalate-Based Metal Organic Frameworks

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    Zhikai Qi, Jun‐Liang Liu, Juan‐Juan Hou, Minmin Liu, Xian‐Ming Zhang

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  21. Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O16

    Materials Research Bulletin · 2014-11-25

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Xiaoxia Nina Lin, Shujuan Han

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  22. ACdCO 3 F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction

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    Guohong Zou, Gnu Nam, Hyung Gu Kim, Hongil Jo, Tae‐Soo You, Kang Min Ok

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  23. Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra

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  24. Three Alkali Metal Lead Orthophosphates – Syntheses, Crystal Structures and Properties of APbPO4 (A = K, Rb, Cs)

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  25. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

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  26. Cd3[B2P4O14(OH)4]: A 3D Open‐Framework Cadmium Borophosphate with Unique Twisted 8‐Ring Channels

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  27. Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups

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  28. Series of SHG Materials Based on Lanthanide Borate–Acetate Mixed Anion Compounds

    Inorganic Chemistry · 2015-07-21

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  29. Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)3

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  30. Iron Borophosphate as a Potential Cathode for Lithium- and Sodium-Ion Batteries

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  31. K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures

    Inorganic Chemistry · 2015-10-21

    Yuan Hua Lin, Chun‐Li Hu, Jiang‐Gao Mao

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  32. New Developments in the Synthesis, Structure, and Applications of Borophosphates and Metalloborophosphates

    Crystal Growth & Design · 2015-10-30

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  33. New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion

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  34. Synthesis and characterization of CsSrCO 3 F – a beryllium-free new deep-ultraviolet nonlinear optical material

    New Journal of Chemistry · 2015-12-22

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  35. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

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  36. Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains

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    Xuefei Wang, Fangfang Zhang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  37. A Cubic Non-Centrosymmetric Mixed-Valence Iron Borophosphate–Phosphite

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  38. New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)

    Inorganic Chemistry · 2016-02-05

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  39. The Flexibility of P2O7 Dimers in Soft Structures: M2CdP2O7 (M = Rb, Cs)

    European Journal of Inorganic Chemistry · 2016-04-20

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  40. Syntheses, structural and characterizations of a new anhydrous mixed-metal phosphate

    Inorganica Chimica Acta · 2016-04-29

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  41. Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity

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  42. Syntheses of six and twelve membered borophosphate ring structure with nonlinear optical activity

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  43. A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response

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  44. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

    Angewandte Chemie International Edition · 2016-08-24

    Guohong Zou, Chensheng Lin, Hongil Jo, Gnu Nam, Tae‐Soo You, Kang Min Ok

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  45. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

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  46. Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge

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  47. Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations

    Inorganic Chemistry · 2016-11-09

    Yuquan Feng, Hui‐Tao Fan, Zhiguo Zhong, Hongwei Wang, Dongfang Qiu

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  48. Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations

    CrystEngComm · 2017-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Xiao-Ni Yao, Xian‐Ming Zhang

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  49. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response

    Dalton Transactions · 2017-01-01

    Chao Wu, Longhua Li, Gang Yang, Jun‐Ling Song, Bing Yan, Mark Graeme Humphrey, Long Zhang, Jianda Shao, Chi Zhang

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  50. Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units

    New Journal of Chemistry · 2017-01-01

    Ruru Ma, Yun Mo Yang, Shilie Pan, Yanzhou Sun, Zhihua Yang

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