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RESEARCH PAPER · Chemistry - A European Journal · 2014

Q 18 Mg 6 (B 5 O 10 ) 3 (B 7 O 14 ) 2 F (Q=Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological Structures

Zheng Wang, Min Zhang, Xin Su, Shilie Pan, Zhihua Yang, Hui Zhang, Lu Liu

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Q 18 Mg 6 (B 5 O 10 ) 3 (B 7 O 14 ) 2 F (Q=Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological StructuresOriginalNa 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13ChemInform Abstract: Q18Mg6(B5O10)3 (B7O14)2F (Q: Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological Structures.0Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical Properties79Ba2B6O11, a Member of the BaO‐B2O3 Family, Featuring a Layer Framework19New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7KMg6(P2O7)2P3O10: A novel phosphate with two distinct anions22Synthesis, crystal structure and characterizations of a new red phosphor K 3 EuB 6 O 1229K5Ba10(BO3)8F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure43Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates31Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units33Two New Octaborates Constructed of Two Different Sub-clusters and Supported by Metal Complexes11Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks4A novel supramolecular magnesoborate framework with snowflake-like channels built by unprecedented huge B 69 cluster cages66Syntheses, crystal structures and characterization of three alkaline metal borates7The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Two Phosphates: Noncentrosymmetric Cs6Mg6(PO3)18 and Centrosymmetric Cs2MgZn2(P2O7)255The new metal complex templated polyoxoborate(s) (POB(s)) structures. Synthesis, structural characterization, and hydrogen storage capacities13Two New Copper Borates with Mesoscale Cubic Supramolecular Cages Assembled from {Cu4@B20} Clusters27A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures36An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units56Borates A Novel Twofold Interpenetrating 3D Diamondoid Borate Framework Constructed from B 4 and B 5 Clusters15Li3.366Mg0.317B2O5: The first pyroborate in the Li2O-MgO-B2O3 system1BaLiZn3B3O9: a Mixed‐Cation KBe2BO3F2‐Type Zinc‐Borate with a (LiZn3B3O9)∞ Network9Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11The structure and classification of complex borates43BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge38Crystal structure and pale-yellow emitting properties of K3Gd1–xDyxB6O12solid solutions2Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units8An Uncommon Hypervalent Fluorooxosilicophosphate5Syntheses and structures of a new 2D layered borate and a novel 3D porous-layered aluminoborate17Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups12Borates: A Rich Source for Optical Materials1090Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups10From β‐Na2B6O10 to Na3AlB8O15 and Na3Al2B7O15: Structural Tuning of Anionic‐Group Architectures by Substitution of [BO4] by [AlO4] Covalent Tetrahedra10Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB18Rearrangement of [B2O5] Dimers within [B7O14] Clusters Enables Enhanced Optical Anisotropy in Li3Cs6Al2B14O28F4Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence9Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges9

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  1. Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra

    RSC Advances · 2015-01-01

    Chunyan Bai, Shujuan Han, Shilie Pan, Bingbing Zhang, Yun Mo Yang, Lin Li, Zhihua Yang

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  2. ChemInform Abstract: Q18Mg6(B5O10)3 (B7O14)2F (Q: Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological Structures.

    ChemInform · 2015-03-26

    Zheng Wang, Min Zhang, Xin Su, Shilie Pan, Zhihua Yang, Hui Zhang, Lu Liu

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  3. Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical Properties

    Chemistry of Materials · 2015-06-04

    Hongwei Yu, Hongping Wu, Qun Jing, Zhihua Yang, P. Shiv Halasyamani, Shilie Pan

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  4. Ba2B6O11, a Member of the BaO‐B2O3 Family, Featuring a Layer Framework

    European Journal of Inorganic Chemistry · 2015-06-24

    Lili Liu, Yun Mo Yang, Xiaoyu Dong, Lei Chen, Shujuan Han, Shilie Pan

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  5. New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method

    Dalton Transactions · 2016-01-01

    Yun Mo Yang, Xiaoyu Dong, Shilie Pan

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  6. KMg6(P2O7)2P3O10: A novel phosphate with two distinct anions

    Inorganic Chemistry Communications · 2016-02-08

    Yaoguo Shen, Siyuan Zeng, Yingying Xu, Sijie Liu, Sasa Wang, Zhenyue Wu, Sangen Zhao, Junhua Luo

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  7. Synthesis, crystal structure and characterizations of a new red phosphor K 3 EuB 6 O 12

    Materials Chemistry and Physics · 2016-07-16

    Dan Zhao, Fa‐Xue Ma, Zhiqiang Wu, Lei Zhang, Wei Wei, Juan Yang, Rong‐Hua Zhang, Pengfei Chen, Shan-Xuan Wu

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  8. K5Ba10(BO3)8F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure

    The Journal of Physical Chemistry C · 2016-08-01

    Lili Liu, Yun Mo Yang, Qun Jing, Xiaoyu Dong, Zhihua Yang, Shilie Pan, Kui Wu

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  9. Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates

    Inorganic Chemistry · 2016-09-26

    Miriding Mutailipu, Min Zhang, Xiaoyu Dong, Yanna Chen, Shilie Pan

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  10. Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units

    Inorganic Chemistry Frontiers · 2016-12-01

    Miriding Mutailipu, Xin Su, Min Zhang, Zhihua Yang, Shilie Pan

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  11. Two New Octaborates Constructed of Two Different Sub-clusters and Supported by Metal Complexes

    Journal of Cluster Science · 2016-12-17

    Rui Pan, Chong‐An Chen, Bai‐Feng Yang, Guo‐Yu Yang

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  12. Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks

    Journal of Cluster Science · 2016-12-29

    Pei-Li Xu, Congcong Jin, Tingting Deng, Er-Rong Wang, Jian‐Wen Cheng

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  13. A novel supramolecular magnesoborate framework with snowflake-like channels built by unprecedented huge B 69 cluster cages

    Chemical Communications · 2017-01-01

    Jia-Jia Wang, Guo‐Yu Yang

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  14. Syntheses, crystal structures and characterization of three alkaline metal borates

    CrystEngComm · 2017-01-01

    Sambasivam Sangaraju, Lili Liu, Yun Mo Yang, Guopeng Han, Beenish Bashir, Zhihua Yang, Shilie Pan

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  15. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges

    Dalton Transactions · 2017-01-01

    Miriding Mutailipu, Min Zhang, Yanna Chen, Xiaoquan Lu, Shilie Pan

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  16. Two Phosphates: Noncentrosymmetric Cs6Mg6(PO3)18 and Centrosymmetric Cs2MgZn2(P2O7)2

    Inorganic Chemistry · 2017-01-03

    Yi-Gang Chen, Meiling Xing, Pengfei Liu, Yao Guo, Nan Qing Yang, Xian‐Ming Zhang

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  17. The new metal complex templated polyoxoborate(s) (POB(s)) structures. Synthesis, structural characterization, and hydrogen storage capacities

    Journal of Molecular Structure · 2017-01-08

    Dursun Ali Köse, Ömer Yurdakul, Onur Şahın, Zeynel Öztürk

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  18. Two New Copper Borates with Mesoscale Cubic Supramolecular Cages Assembled from {Cu4@B20} Clusters

    Chemistry - A European Journal · 2017-01-12

    Jiajia Wang, Qi Wei, Bai‐Feng Yang, Guo‐Yu Yang

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  19. A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures

    Inorganic Chemistry · 2017-03-15

    Maierhaba Abudoureheman, Shujuan Han, Ying Wang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  20. An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

    Inorganic Chemistry · 2017-06-07

    Er-Rong Wang, Jianhao Huang, Sujuan Yu, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  21. Borates A Novel Twofold Interpenetrating 3D Diamondoid Borate Framework Constructed from B 4 and B 5 Clusters

    ChemistrySelect · 2017-07-03

    Jiajia Wang, Qi Wei, Guo‐Yu Yang

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  22. Li3.366Mg0.317B2O5: The first pyroborate in the Li2O-MgO-B2O3 system

    Inorganic Chemistry Communications · 2018-05-17

    Chen Zhou, Jianian Cheng, Hongyi Li, Sadeh Beysen

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  23. BaLiZn3B3O9: a Mixed‐Cation KBe2BO3F2‐Type Zinc‐Borate with a (LiZn3B3O9)∞ Network

    European Journal of Inorganic Chemistry · 2018-06-20

    Meihong Duan, Mingjun Xia, Rukang K. Li

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  24. Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations

    Chemistry - A European Journal · 2018-09-19

    Yanna Chen, Min Zhang, Cong Hu, Hongping Wu, Zhihua Yang, Shilie Pan

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  25. The structure and classification of complex borates

    Russian Chemical Reviews · 2018-10-25

    Anastasiya P. Topnikova, Elena L. Belokoneva

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  26. BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge

    Chemistry - A European Journal · 2019-04-01

    Chunmei Huang, Fangfang Zhang, Hao Li, Zhihua Yang, Haohai Yu, Shilie Pan

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  27. Crystal structure and pale-yellow emitting properties of K3Gd1–xDyxB6O12solid solutions

    Acta Crystallographica Section C Structural Chemistry · 2019-10-04

    Rui-Juan Zhang, Jian-Chao Shi, Dan-Dan Zhao, Xiao-Yang Han, Ling Deng, Xiao-Qi Cui, Dan Zhao

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  28. Pb 3 Ba 3 Zn 6 (BO 3 ) 8 and α-BaZn 2 (BO 3 ) 2 : new members of the zincoborates containing two different dimensional Zn–O units

    Inorganic Chemistry Frontiers · 2019-10-09

    Xiaobo Pan, Hongping Wu, Shichao Cheng, Zhengping Wang

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  29. An Uncommon Hypervalent Fluorooxosilicophosphate

    Chemistry - An Asian Journal · 2019-10-17

    Qingran Ding, Sangen Zhao, Han Xiao, Yanqiang Li, Shuai Liu, Lina Li, Chunsen Li, Yusong Wang, Maochun Hong, Junhua Luo

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  30. Syntheses and structures of a new 2D layered borate and a novel 3D porous-layered aluminoborate

    Dalton Transactions · 2019-11-07

    Chong‐An Chen, Rui Pan, Guo‐Yu Yang

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  31. Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups

    Inorganic Chemistry · 2019-12-26

    Ya Wang, Jian Wei Han, Junben Huang, Zhihua Yang, Shilie Pan

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  32. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

    Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  33. Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups

    Inorganic Chemistry · 2020-12-29

    Siru Guo, Wen-Bin Zhang, Min Zhang, Zhihua Yang, Shilie Pan

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  34. From β‐Na2B6O10 to Na3AlB8O15 and Na3Al2B7O15: Structural Tuning of Anionic‐Group Architectures by Substitution of [BO4] by [AlO4] Covalent Tetrahedra

    Chemistry - A European Journal · 2021-11-24

    Jiahao Jiao, Wenqi Jin, Min Zhang, Zhiyong Guo, Zhihua Yang, Shilie Pan

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  35. Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB

    Inorganic Chemistry Frontiers · 2022-01-01

    Feixiang Wang, Yun Mo Yang, Congcong Jin, Shilie Pan

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  36. Rearrangement of [B2O5] Dimers within [B7O14] Clusters Enables Enhanced Optical Anisotropy in Li3Cs6Al2B14O28F

    Inorganic Chemistry · 2022-07-27

    Xingqi Li, Dongdong Chu, Wenqi Jin, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  37. Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-09-04

    Qianzhen Zhang, Ran An, Abudukadi Tudi, Zhihua Yang, Xifa Long, Yun Mo Yang

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  38. Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2023-09-08

    Yunjie Bai, Xinyue Wang, Hongbo Huang, Danyang Dou, Cheng Chen, Bingbing Zhang, Ying Wang

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  39. Rb 3 MgB 5 O 10 and LiBaAl(BO 3 ) 2 : covalent tetrahedra MO 4 -containing borates with deep-ultraviolet cutoff edges

    Dalton Transactions · 2023-12-07

    Hongkang Su, Jiahao Jiao, Shi‐Bin Wang, Donghai An, Min Zhang

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