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RESEARCH PAPER · Inorganic Chemistry · 2019

Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic Framework

Peng Li, Subhadip Goswami, Ken‐ichi Otake, Xingjie Wang, Zhijie Chen, Sylvia L. Hanna, Omar K. Farha

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Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic FrameworkOriginalTetranuclear oxido-bridged thorium( iv ) clusters obtained using tridentate Schiff bases18Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )14Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials40A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability50Design and construction of a 2D PbII coordination polymer as a multi-response luminescent sensor for Fe3+, Cr2O72−, and TNP13From Thorium to Plutonium: Trends in Actinide(IV) Chloride Structural Chemistry27Monomeric and Trimeric Thorium Chlorides Isolated from Acidic Aqueous Solution18Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands34A mixed-ligand strategy regulates thorium-based MOFs55Oligonuclear Actinoid Complexes with Schiff Bases as Ligands—Older Achievements and Recent Progress52Mononuclear to Polynuclear UIV Structural Units: Effects of Reaction Conditions on U‐Furoate Phase Formation23Reticular exploration of uranium-based metal—organic frameworks with hexacarboxylate building units37Ultrastable Thorium Metal–Organic Frameworks for Efficient Iodine Adsorption162Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-6660From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates2Rational Design of a Uranyl Metal–Organic Framework for the Capture and Colorimetric Detection of Organic Dyes22Porous framework materials for singlet oxygen generation99Metal–Organic Frameworks Based on Group 3 and 4 Metals140Auxiliary Ligand-Dependent Adaptive Regulation of Uranyl Coordination in Mixed-Ligand Uranyl Compounds of Flexible Biphenyltetracarboxylic Acid16Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks65Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene10Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption35Structural Evolution from Noninterpenetrated to Interpenetrated Thorium–Organic Frameworks Exhibiting High Propyne Storage19An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Pentanuclear Thorium(IV) Coordination Cluster from the Use of Di(2-pyridyl) Ketone7Porous porphyrin-based metal-organic frameworks: synthesis, structure, sorption properties and application prospects36State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization20Mechanism-Guided Design of Metal–Organic Framework Composites for Selective Photooxidation of a Mustard Gas Simulant under Solvent-Free Conditions67Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters50Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks9Carboxylato Bridged Cyclic SBUs as Robust Features in a Series of Cu(II) Coordination Polymers and Halogen···Halogen Interactions in Crystal Packing11Constructing dual-functional porphyrin-based thorium metal-organic framework toward photocatalytic uranium(VI) reduction integrated with organic oxidation28Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene3Achieving High Photo/Thermocatalytic Product Selectivity and Conversion via Thorium Clusters with Switchable Functional Ligands87Synthesis of Thorium Dioxide Nanocrystals by Pyrolysis of a Thorium‐based Metal‐organic Framework4Tailored Persistent Radical‐containing Heterotrimetal‐Organic Framework for Boosting Efficiency of Visible/NIR Light‐driven Photocatalytic CO 2 Reduction47Thermally Induced Orderly Alignment of Porphyrin Photoactive Motifs in Metal–Organic Frameworks for Boosting Photocatalytic CO2 Reduction152Friends or Foes: Fundamental Principles of Th-Organic Scaffold Chemistry Using Zr-Analogs as a Guide22Capture of Iodine in Vapor and Solution Phases by a Th-Based Metal–Organic Framework18Functionalized Thorium‐Based Metal‐Organic Frameworks for the Photocatalytic Oxidation of 1, 5‐Dihydroxynaphthalene1Integrating Uranyl Complexes into Porous Organic Cages for Enhanced Photocatalytic Oxidation of A Mustard‐Gas Simulant2Metal–Organic Frameworks for Gaseous Pollutant Management: From Capture to Neutralization and Reutilization25Democratizing AI‐Enhanced Experimental Optimization: An Accessible Workflow for Chemists0

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  1. Tetranuclear oxido-bridged thorium( iv ) clusters obtained using tridentate Schiff bases

    Dalton Transactions · 2019-01-01

    Sokratis T. Tsantis, Aimilia Lagou-Rekka, Konstantis F. Konidaris, Catherine P. Raptopoulou, Vlasoula Bekiari, Vassilis Psycharis, Spyros P. Perlepes

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  2. Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )

    RSC Advances · 2019-01-01

    Maxime Dufaye, Nicolas P. Martin, Sylvain Duval, Christophe Volkringer, Atsushi Ikeda‐Ohno, Thierry Loiseau

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  3. Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials

    ACS Applied Nano Materials · 2019-03-15

    Peng Li, Xingjie Wang, Ken‐ichi Otake, Jiafei Lyu, Sylvia L. Hanna, Timur İslamoğlu, Omar K. Farha

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  4. A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability

    Chemistry - A European Journal · 2019-04-10

    Korey Prescott Carter, J. August Ridenour, Mark Kalaj, Christopher L. Cahill

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  5. Design and construction of a 2D PbII coordination polymer as a multi-response luminescent sensor for Fe3+, Cr2O72−, and TNP

    Journal of Molecular Structure · 2019-05-12

    Chaolin Miao

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  6. From Thorium to Plutonium: Trends in Actinide(IV) Chloride Structural Chemistry

    Inorganic Chemistry · 2019-07-12

    Jennifer N. Wacker, Sae Young Han, Aphra V. Murray, Nicole A. Vanagas, Jeffery A. Bertke, Joseph M. Sperling, Robert G. Surbella, Karah E. Knope

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  7. Monomeric and Trimeric Thorium Chlorides Isolated from Acidic Aqueous Solution

    Inorganic Chemistry · 2019-07-29

    Jennifer N. Wacker, Monica Vasiliu, Ian Colliard, R. Lee Ayscue, Sae Young Han, Jeffery A. Bertke, May Nyman, David A. Dixon, Karah E. Knope

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  8. Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands

    Inorganic Chemistry Frontiers · 2019-10-29

    Zi‐Jian Li, Shangyao Guo, Huangjie Lu, Yongjia Xu, Zenghui Yue, Linhong Weng, Xiaofeng Guo, Jian Hung Lin, Jian‐Qiang Wang

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  9. A mixed-ligand strategy regulates thorium-based MOFs

    Dalton Transactions · 2019-12-19

    Zhi‐wei Huang, Kong‐Qiu Hu, Lei Mei, Xiang‐he Kong, Jipan Yu, Kang Liu, Li-wen Zeng, Zhifang Chai, Wei‐Qun Shi

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  10. Oligonuclear Actinoid Complexes with Schiff Bases as Ligands—Older Achievements and Recent Progress

    International Journal of Molecular Sciences · 2020-01-15

    Sokratis T. Tsantis, Demetrios I. Tzimopoulos, Małgorzata Hołyńska, Spyros P. Perlepes

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  11. Mononuclear to Polynuclear UIV Structural Units: Effects of Reaction Conditions on U‐Furoate Phase Formation

    Chemistry - A European Journal · 2020-01-30

    Nicole A. Vanagas, Robert F. Higgins, Jennifer N. Wacker, Dane Romar C. Asuigui, Evan Warzecha, Stosh A. Kozimor, Sarah L. Stoll, Eric J. Schelter, Jeffery A. Bertke, Karah E. Knope

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  12. Reticular exploration of uranium-based metal—organic frameworks with hexacarboxylate building units

    Nano Research · 2020-02-28

    Zhijie Chen, Penghao Li, Xuan Zhang, Mohammad Rasel Mian, Xingjie Wang, Peng Li, Zhichang Liu, M. O’Keeffe, James Fraser Stoddart, Omar K. Farha

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  13. Ultrastable Thorium Metal–Organic Frameworks for Efficient Iodine Adsorption

    Inorganic Chemistry · 2020-03-13

    Zi‐Jian Li, Zenghui Yue, Yu Ju, Xiaoling Wu, Yiming Ren, Shaofei Wang, Yongxin Li, Zhi‐Hui Zhang, Xiaofeng Guo, Jian Hung Lin, Jian‐Qiang Wang

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  14. Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-66

    Journal of the American Chemical Society · 2020-04-26

    Ashley M. Hastings, Debmalya Ray, WooSeok Jeong, Laura Gagliardi, Omar K. Farha, Amy E. Hixon

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  15. From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates

    European Journal of Inorganic Chemistry · 2020-06-19

    Aphra V. Murray, Nicole A. Vanagas, Jennifer N. Wacker, Jeffery A. Bertke, Karah E. Knope

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  16. Rational Design of a Uranyl Metal–Organic Framework for the Capture and Colorimetric Detection of Organic Dyes

    Chemistry - A European Journal · 2020-07-18

    Robert G. Surbella, Korey Prescott Carter, Trevor D. Lohrey, Dallas D. Reilly, Mark Kalaj, Bruce K. McNamara, Jon M. Schwantes, Rebecca J. Abergel

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  17. Porous framework materials for singlet oxygen generation

    Coordination Chemistry Reviews · 2020-08-17

    Jan Hynek, Mandeep Kaur Chahal, Daniel T. Payne, Jan Labuta, Jonathan P. Hill

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  18. Metal–Organic Frameworks Based on Group 3 and 4 Metals

    Advanced Materials · 2020-09-09

    Liang Feng, Jiandong Pang, Ping She, Jia‐Luo Li, Jun‐Sheng Qin, Dong‐Ying Du, Hong-Cai “Joe” Zhou

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  19. Auxiliary Ligand-Dependent Adaptive Regulation of Uranyl Coordination in Mixed-Ligand Uranyl Compounds of Flexible Biphenyltetracarboxylic Acid

    Inorganic Chemistry · 2020-11-13

    Junfeng Qian, Wen-Jiang Tian, Song Yang, Zhonghua Sun, Le Chen, Mei-Jun Wei, Zhong Wu, Ming‐Yang He, Zhi‐Hui Zhang, Lei Mei

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  20. Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks

    Chemical Science · 2021-01-01

    Corey R. Martin, Gabrielle A. Leith, Natalia B. Shustova

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  21. Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

    RSC Advances · 2021-01-01

    Ting Yu, Zhenghua Qian, Lin Li, Xiaoling Wu, Hui He, Yanbo Qiao, Ye Guoan

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  22. Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption

    Inorganic Chemistry · 2021-03-19

    Yu Ju, Zi‐Jian Li, Huangjie Lu, Zhengyang Zhou, Yongxin Li, Xiaoling Wu, Xiaofeng Guo, Yuan Qian, Zhi‐Hui Zhang, Jian Hung Lin, Jian‐Qiang Wang, Ming‐Yang He

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  23. Structural Evolution from Noninterpenetrated to Interpenetrated Thorium–Organic Frameworks Exhibiting High Propyne Storage

    Inorganic Chemistry · 2021-04-12

    Yuan-Bo Wu, Cheng Xiong, Qing‐Yan Liu, Jianguo Ma, Feng Luo, Yu‐Ling Wang

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  24. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

    Coordination Chemistry Reviews · 2021-07-07

    Kai Lv, Sebastian Fichter, Mei Gu, Juliane März, Moritz Schmidt

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  25. Pentanuclear Thorium(IV) Coordination Cluster from the Use of Di(2-pyridyl) Ketone

    Inorganic Chemistry · 2021-08-05

    Sokratis T. Tsantis, Panagiota Danelli, Demetrios I. Tzimopoulos, Catherine P. Raptopoulou, Vassilis Psycharis, Spyros P. Perlepes

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  26. Porous porphyrin-based metal-organic frameworks: synthesis, structure, sorption properties and application prospects

    Russian Chemical Reviews · 2021-11-23

    Yulia G. Gorbunova, Yulia Yu. Enakieva, Marina V. Volostnykh, Anna А. Sinelshchikova, Inna A. Abdulaeva, Kirill P. Birin, Aslan Yu. Tsivadze

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  27. State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization

    Journal of Hazardous Materials · 2021-11-25

    Yezi Hu, Zewen Shen, Bingfeng Li, Xiaoli Tan, Bing Han, Zhuoyu Ji, Jianjun Wang, Guixia Zhao, Xiangke Wang

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  28. Mechanism-Guided Design of Metal–Organic Framework Composites for Selective Photooxidation of a Mustard Gas Simulant under Solvent-Free Conditions

    ACS Catalysis · 2021-12-16

    Yajiao Hao, Edgar K. Papazyan, Yong Ba, Yangyang Liu

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  29. Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters

    Dalton Transactions · 2022-01-01

    Zi‐Jian Li, Xiaofeng Guo, Jie Qiu, Huangjie Lu, Jian‐Qiang Wang, Jian Hung Lin

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  30. Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks

    CrystEngComm · 2022-01-01

    Megan C. Wasson, Haomiao Xie, Xingjie Wang, Joshua S. Duncan, Omar K. Farha

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  31. Carboxylato Bridged Cyclic SBUs as Robust Features in a Series of Cu(II) Coordination Polymers and Halogen···Halogen Interactions in Crystal Packing

    Crystal Growth & Design · 2022-01-03

    Sanobar Naaz, Bhaswati Debnath, Sakhiul Islam, Samim Khan, Faruk Ahmed, Basudeb Dutta, Atish Dipankar Jana, Mohammad Hedayetullah Mir

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  32. Constructing dual-functional porphyrin-based thorium metal-organic framework toward photocatalytic uranium(VI) reduction integrated with organic oxidation

    Science China Chemistry · 2022-07-21

    Zhi Yue Gao, Yue Wang, Yuzhi Lin, Zhijian Zheng, Yao Liu, Qiqi Jing, Feng Luo

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  33. Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene

    Royal Society Open Science · 2022-08-01

    Lin Li, Ting Yu, Zhenghua Qian, Xiaoling Wu, Hui He, Ye Guoan, Yanbo Qiao

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  34. Achieving High Photo/Thermocatalytic Product Selectivity and Conversion via Thorium Clusters with Switchable Functional Ligands

    Journal of the American Chemical Society · 2022-10-03

    Qian Niu, Qing Huang, Tao‐Yuan Yu, Jiang Liu, Jingwen Shi, Long‐Zhang Dong, Shun‐Li Li, Ya‐Qian Lan

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  35. Synthesis of Thorium Dioxide Nanocrystals by Pyrolysis of a Thorium‐based Metal‐organic Framework

    ChemistrySelect · 2022-10-19

    Ting Yu, Zhenghua Qian, Lin Li, Zonghui Lu, Bin Li, Qiang Zhang, Xiaofeng Liu, Hui He, Yanbo Qiao, Ye Guoan

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  36. Tailored Persistent Radical‐containing Heterotrimetal‐Organic Framework for Boosting Efficiency of Visible/NIR Light‐driven Photocatalytic CO 2 Reduction

    Advanced Functional Materials · 2022-12-21

    Kong‐Qiu Hu, Zhiwei Huang, Xiao‐Bo Li, Yi Cheng, Xiang‐he Kong, Lei Mei, Li‐Wen Zeng, Zhi‐Hui Zhang, Jipan Yu, John K. Gibson, Zhifang Chai, Hui‐Zhong Kou, Wei‐Qun Shi

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  37. Thermally Induced Orderly Alignment of Porphyrin Photoactive Motifs in Metal–Organic Frameworks for Boosting Photocatalytic CO2 Reduction

    Journal of the American Chemical Society · 2023-08-02

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  38. Friends or Foes: Fundamental Principles of Th-Organic Scaffold Chemistry Using Zr-Analogs as a Guide

    Journal of the American Chemical Society · 2024-04-22

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  39. Capture of Iodine in Vapor and Solution Phases by a Th-Based Metal–Organic Framework

    Inorganic Chemistry · 2024-09-23

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  40. Functionalized Thorium‐Based Metal‐Organic Frameworks for the Photocatalytic Oxidation of 1, 5‐Dihydroxynaphthalene

    Chemistry - A European Journal · 2025-03-11

    Hui Ling Zhou, Ran‐Wei Zhang, Xiao‐Yue Pan, Shiyan Ai, Zi‐Wei Cui, Pengfei Wu, Qing Huang, Dan Bi Tian

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  41. Integrating Uranyl Complexes into Porous Organic Cages for Enhanced Photocatalytic Oxidation of A Mustard‐Gas Simulant

    European Journal of Inorganic Chemistry · 2025-04-24

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  42. Metal–Organic Frameworks for Gaseous Pollutant Management: From Capture to Neutralization and Reutilization

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  43. Democratizing AI‐Enhanced Experimental Optimization: An Accessible Workflow for Chemists

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