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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2019

Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands

Zi‐Jian Li, Shangyao Guo, Huangjie Lu, Yongjia Xu, Zenghui Yue, Linhong Weng, Xiaofeng Guo, Jian Hung Lin, Jian‐Qiang Wang

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Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligandsOriginalUltrastable Thorium Metal–Organic Frameworks for Efficient Iodine Adsorption162Mesoporous Zeolitic Imidazolate Framework-67 Nanocrystals on Siliceous Mesocellular Foams for Capturing Radioactive Iodine69Boosting the Iodine Adsorption and Radioresistance of Th‐UiO‐66 MOFs via Aromatic Substitution118Decisive Role of 5f-Orbital Covalence in the Structure and Stability of Pentavalent Transuranic Oxo [M6O8] Clusters11Tuning of the Network Dimensionality and Photoluminescent Properties in Homo- and Heteroleptic Lanthanide Coordination Polymers21Emergence of a thorium–organic framework as a radiation attenuator for selective X-ray dosimetry20Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications928Synthesis, Characterization, and Solid-State Structural Chemistry of Uranium(IV) Aliphatic Dicarboxylates7Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption35Effect of land use changes on non-carcinogenic health risks due to nitrate exposure to drinking groundwater38Structural Evolution from Noninterpenetrated to Interpenetrated Thorium–Organic Frameworks Exhibiting High Propyne Storage19An Azobenzene-Modified Photoresponsive Thorium–Organic Framework: Monitoring and Quantitative Analysis of Reversible trans–cis Photoisomerization30Study of colloidal sol-gel transition for the synthesis of actinide oxides materials with controlled and organized nanoporosity0An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters50Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks9SAXS study of the formation and structure of polynuclear thorium(IV) colloids and thorium dioxide nanoparticles12Cobalt Formate, a Functional MOF: Electrocatalytic Water Oxidation1Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture24Progress in solid state and coordination chemistry of actinides in China5Extremely Stable Thorium‐MOF Assembly of Tetraphenylethylene Derivative With Tunable AIE Property and Highly Selective Detection of Nitro Aromatic Compounds28Cluster‐Based Crystalline Materials for Iodine Capture30Topological control of metal–organic frameworks toward highly sensitive and selective detection of chromate and dichromate32Selective Crystallization of a Highly Radiation-Resistant Isonicotinic Acid-Based Metal–Organic Framework as a Primary Actinide Waste Form23Unveiling the Structure–Modulator Relationships in Thorium-Based Metal–Organic Framework Crystallization18Adsorption and Detection of Iodine Species by a Thorium-Based Metal–Organic Framework46Catalysis for the hydrogenation of nitroaromatics by highly dispersed palladium nanoparticles anchored on a resorcin[4]arene-based metal–organic dimer containing amino groups7Designed assembly of heterometallic cluster organic frameworks based on Th6 cluster14Elucidating trends in synthesis and structural periodicity in a series of tetravalent actinide–oxo hexamers8Computational Explorations of Th4+ First Hydrolysis Reaction Constants: Insights from Ab Initio Molecular Dynamics and Density Functional Theory Calculations0Crystallographic Evidence for Formation of M 6 O 8 /M 6 O 9 f-Element Clusters in Hydrolysis Reactions6M6O8 metal oxo clusters: A key structural motif across the periodic table8A bifunctional ligand-based metal-organic framework with rich aromatic pores and open O donor sites for selective C2H6/C2H4 separation2Emergence of Radiochromic Metal–Organic Frameworks for Information Encryption via Dual-Stimuli Responses3

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  1. Ultrastable Thorium Metal–Organic Frameworks for Efficient Iodine Adsorption

    Inorganic Chemistry · 2020-03-13

    Zi‐Jian Li, Zenghui Yue, Yu Ju, Xiaoling Wu, Yiming Ren, Shaofei Wang, Yongxin Li, Zhi‐Hui Zhang, Xiaofeng Guo, Jian Hung Lin, Jian‐Qiang Wang

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  2. Mesoporous Zeolitic Imidazolate Framework-67 Nanocrystals on Siliceous Mesocellular Foams for Capturing Radioactive Iodine

    ACS Applied Nano Materials · 2020-05-08

    Le Chen, Jun-Yan Qian, Dandan Zhu, Song Yang, Jian Hung Lin, Mingyang He, Zhi‐Hui Zhang, Qun Chen

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  3. Boosting the Iodine Adsorption and Radioresistance of Th‐UiO‐66 MOFs via Aromatic Substitution

    Chemistry - A European Journal · 2020-09-22

    Zi‐Jian Li, Yu Ju, Huangjie Lu, Xiaoling Wu, Xinle Yu, Yongxin Li, Xiaowei Wu, Zhi‐Hui Zhang, Jian Hung Lin, Yuan Qian, Mingyang He, Jian‐Qiang Wang

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  4. Decisive Role of 5f-Orbital Covalence in the Structure and Stability of Pentavalent Transuranic Oxo [M6O8] Clusters

    Inorganic Chemistry · 2020-12-08

    Shu‐Xian Hu, Peng Zhang, Erli Lu, Ping Zhang

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  5. Tuning of the Network Dimensionality and Photoluminescent Properties in Homo- and Heteroleptic Lanthanide Coordination Polymers

    Inorganic Chemistry · 2020-12-15

    Zhaofa Zheng, Huangjie Lu, Yumin Wang, Hongliang Bao, Zi‐Jian Li, Guoping Xiao, Jian Hung Lin, Yuan Qian, Jian‐Qiang Wang

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  6. Emergence of a thorium–organic framework as a radiation attenuator for selective X-ray dosimetry

    Chemical Communications · 2021-01-01

    Zhaofa Zheng, Huangjie Lu, Xiaofeng Guo, Zhengyang Zhou, Yumin Wang, Zi‐Jian Li, Guoping Xiao, Yuan Qian, Jian Hung Lin, Jian‐Qiang Wang

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  7. Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

    Chemical Reviews · 2021-02-25

    Gouri Chakraborty, In‐Hyeok Park, Raghavender Medishetty, Jagadese J. Vittal

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  8. Synthesis, Characterization, and Solid-State Structural Chemistry of Uranium(IV) Aliphatic Dicarboxylates

    Crystal Growth & Design · 2021-03-15

    Aphra V. Murray, Jennifer N. Wacker, Jeffery A. Bertke, Karah E. Knope

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  9. Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption

    Inorganic Chemistry · 2021-03-19

    Yu Ju, Zi‐Jian Li, Huangjie Lu, Zhengyang Zhou, Yongxin Li, Xiaoling Wu, Xiaofeng Guo, Yuan Qian, Zhi‐Hui Zhang, Jian Hung Lin, Jian‐Qiang Wang, Ming‐Yang He

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  10. Effect of land use changes on non-carcinogenic health risks due to nitrate exposure to drinking groundwater

    Environmental Science and Pollution Research · 2021-04-01

    Ahmad Badeenezhad, Majid Radfard, Fariba Abbasi, Anna Jurado, Mehdi Bozorginia, Mahrokh Jalili, Hamed Soleimani

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  11. Structural Evolution from Noninterpenetrated to Interpenetrated Thorium–Organic Frameworks Exhibiting High Propyne Storage

    Inorganic Chemistry · 2021-04-12

    Yuan-Bo Wu, Cheng Xiong, Qing‐Yan Liu, Jianguo Ma, Feng Luo, Yu‐Ling Wang

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  12. An Azobenzene-Modified Photoresponsive Thorium–Organic Framework: Monitoring and Quantitative Analysis of Reversible trans–cis Photoisomerization

    Inorganic Chemistry · 2021-06-07

    Jun‐shan Geng, Kang Liu, Yuanyuan Liang, Jipan Yu, Kong‐Qiu Hu, Lihua Yuan, Wen Feng, Zhifang Chai, Lei Mei, Wei‐Qun Shi

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  13. Study of colloidal sol-gel transition for the synthesis of actinide oxides materials with controlled and organized nanoporosity

    Unknown journal · 2021-07-02

    Zijie Lu

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  14. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

    Coordination Chemistry Reviews · 2021-07-07

    Kai Lv, Sebastian Fichter, Mei Gu, Juliane März, Moritz Schmidt

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  15. Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters

    Dalton Transactions · 2022-01-01

    Zi‐Jian Li, Xiaofeng Guo, Jie Qiu, Huangjie Lu, Jian‐Qiang Wang, Jian Hung Lin

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  16. Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks

    CrystEngComm · 2022-01-01

    Megan C. Wasson, Haomiao Xie, Xingjie Wang, Joshua S. Duncan, Omar K. Farha

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  17. SAXS study of the formation and structure of polynuclear thorium(IV) colloids and thorium dioxide nanoparticles

    Journal of Synchrotron Radiation · 2022-01-18

    Baihui Zhai, Qiang Tian, Na Li, Minhao Yan, Mark Julian Henderson

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  18. Cobalt Formate, a Functional MOF: Electrocatalytic Water Oxidation

    Journal of Molecular and Engineering Materials · 2022-03-01

    Athira Ravi, Rajendar Nasani, Samar K. Das

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  19. Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture

    Inorganic Chemistry · 2022-06-14

    Ashley M. Hastings, Debmalya Ray, Sylvia L. Hanna, WooSeok Jeong, Zhijie Chen, Allen G. Oliver, Laura Gagliardi, Omar K. Farha, Amy E. Hixon

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  20. Progress in solid state and coordination chemistry of actinides in China

    Radiochimica Acta · 2022-09-20

    Kai Li, Wei Liu, Hailong Zhang, Liwei Cheng, Yugang Zhang, Yaxing Wang, Ning Chen, Congqing Zhu, Zhifang Chai, Shuao Wang

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  21. Extremely Stable Thorium‐MOF Assembly of Tetraphenylethylene Derivative With Tunable AIE Property and Highly Selective Detection of Nitro Aromatic Compounds

    Advanced Materials Interfaces · 2022-09-22

    Qing Lin Guan, Fen Xu, Yao Xiao, Zi-Xin You, Feng‐Ying Bai, Yong‐Heng Xing

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  22. Cluster‐Based Crystalline Materials for Iodine Capture

    Chemistry - A European Journal · 2022-09-30

    San‐Tai Wang, Yajie Liu, Cheng‐Yang Zhang, Fan Yang, Wei‐Hui Fang, Jian Zhang

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  23. Topological control of metal–organic frameworks toward highly sensitive and selective detection of chromate and dichromate

    Inorganic Chemistry Frontiers · 2023-01-01

    Zi‐Jian Li, Yu Ju, Xiaoling Wu, Xiaoyun Li, Jie Qiu, Yongxin Li, Zhi‐Hui Zhang, Ming‐Yang He, Linjuan Zhang, Jian‐Qiang Wang, Jian Hung Lin

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  24. Selective Crystallization of a Highly Radiation-Resistant Isonicotinic Acid-Based Metal–Organic Framework as a Primary Actinide Waste Form

    ACS Materials Letters · 2023-01-17

    Kai Lv, Michael Patzschke, Juliane März, Elena Bazarkina, Kristina O. Kvashnina, Moritz Schmidt

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  25. Unveiling the Structure–Modulator Relationships in Thorium-Based Metal–Organic Framework Crystallization

    Inorganic Chemistry · 2023-03-24

    Shujing Hou, Fusheng Liu, Haomiao Xie, Sylvia L. Hanna, Karam B. Idrees, Chenghui Zhang, Xingjie Wang, Yongwei Chen, Peng Li, Omar K. Farha

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  26. Adsorption and Detection of Iodine Species by a Thorium-Based Metal–Organic Framework

    Inorganic Chemistry · 2023-05-15

    Yu Ju, Zi‐Jian Li, Jie Qiu, Xiaoyun Li, Junpu Yang, Zhi‐Hui Zhang, Ming‐Yang He, Jian‐Qiang Wang, Jian Hung Lin

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  27. Catalysis for the hydrogenation of nitroaromatics by highly dispersed palladium nanoparticles anchored on a resorcin[4]arene-based metal–organic dimer containing amino groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Fei-Fei Wang, Wei Hua Jiang, Wen‐Yuan Pei, Jian‐Fang Ma

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  28. Designed assembly of heterometallic cluster organic frameworks based on Th6 cluster

    Chinese Chemical Letters · 2024-02-13

    Xiang‐he Kong, Xiaoli Liao, Zhenkun Huang, Lei Mei, Hongqing Wang, Kong‐Qiu Hu, Wei‐Qun Shi

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  29. Elucidating trends in synthesis and structural periodicity in a series of tetravalent actinide–oxo hexamers

    CrystEngComm · 2024-12-13

    Thomas L. McCusker, Nicole A. Vanagas, Jennifer E. S. Szymanowski, Robert G. Surbella, Jeffery A. Bertke, Ana Arteaga, Karah E. Knope

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  30. Computational Explorations of Th4+ First Hydrolysis Reaction Constants: Insights from Ab Initio Molecular Dynamics and Density Functional Theory Calculations

    The Journal of Physical Chemistry A · 2025-01-16

    Yang He, Chang‐Yi Tian, Shiru Wei, Zongchang Han, Han‐Shi Hu, Jun Li

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  31. Crystallographic Evidence for Formation of M 6 O 8 /M 6 O 9 f-Element Clusters in Hydrolysis Reactions

    Crystal Growth & Design · 2025-03-18

    Ethan A. Hiti, Geetha Bolla, Robin Don Rogers

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  32. M6O8 metal oxo clusters: A key structural motif across the periodic table

    Coordination Chemistry Reviews · 2025-08-12

    Ajmal Roshan Unniram Parambil, Jikson Pulparayil Mathew, Muhammed Jibin Parammal, Jonathan De Roo

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  33. A bifunctional ligand-based metal-organic framework with rich aromatic pores and open O donor sites for selective C2H6/C2H4 separation

    Journal of Molecular Structure · 2025-12-16

    Di-Ming Chen, Xue-Jing Zhang, Dong-Ying Shi, Lin Han

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  34. Emergence of Radiochromic Metal–Organic Frameworks for Information Encryption via Dual-Stimuli Responses

    JACS Au · 2026-01-19

    Huangjie Lu, Jialu Chen, Junpu Yang, Jingqi Ma, Chun Wang, Junfeng Qian, Zhi‐Hui Zhang, Qun Chen, Ming-Yang He, Jian Hung Lin

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