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RESEARCH PAPER · Chemistry - A European Journal · 2019

A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability

Korey Prescott Carter, J. August Ridenour, Mark Kalaj, Christopher L. Cahill

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A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical StabilityOriginalTime-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )14A Double-Walled Thorium-Based Metal–Organic Framework as a Promising Dual-Function Absorbent for Efficiently Capturing Iodine and Dyes54Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands34A Double-Walled Porous Metal–Organic Framework as a Highly Efficient Catalyst for Chemical Fixation of CO2 with Epoxides46Disappearing Polymorphs in Metal–Organic Framework Chemistry: Unexpected Stabilization of a Layered Polymorph over an Interpenetrated Three‐Dimensional Structure in Mercury Imidazolate35A mixed-ligand strategy regulates thorium-based MOFs55Occurrence of polyoxouranium motifs in uranyl organic networks constructed by using silicon-centered carboxylate linkers: structures, spectroscopy and computation11In-situ synthetic modified metal-organic framework (MZIF-8) as an interlayer of the composite membranes for ethanol dehydration36Ultrastable Thorium Metal–Organic Frameworks for Efficient Iodine Adsorption162Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-6660Design and Assembly of a Hierarchically Micro- and Mesoporous MOF as a Highly Efficient Heterogeneous Catalyst for Knoevenagel Condensation Reaction52From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates2Rational Design of a Uranyl Metal–Organic Framework for the Capture and Colorimetric Detection of Organic Dyes22Recent Advances on Metal‐Organic Frameworks in the Conversion of Carbon Dioxide67Metal–Organic Frameworks Based on Group 3 and 4 Metals140Metal-organic frameworks as a versatile platform for radionuclide management163“Turn-on” fluorescent sensor for Th4+ in aqueous media based on a combination of PET-AIE effect22Linker Substituents Control the Thermodynamic Stability in Metal–Organic Frameworks56Potassium Ions Induced Framework Interpenetration for Enhancing the Stability of Uranium-Based Porphyrin MOF with Visible-Light-Driven Photocatalytic Activity68A cationic thorium–organic framework with triple single-crystal-to-single-crystal transformation peculiarities for ultrasensitive anion recognition29Simplifying and expanding the scope of boron imidazolate framework (BIF) synthesis using mechanochemistry12Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene10Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption35Versatility vs stability. Are the assets of metal–organic frameworks deployable in aqueous acidic and basic media?83An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Unusual Metal–Organic Framework Topology and Radiation Resistance through Neptunyl Coordination Chemistry32Synthesis, characterization and biocompatibility of guar gum-benzoic acid39Enhanced Xe/Kr separation via the pore size confinement effect of a microporous thorium-based metal–organic framework9Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters50Syntheses, crystal structures, and luminescence properties of three cadmium coordination polymers assembled from a semi-rigid tetracarboxylate ligand2Encapsulation of Polymetallic Oxygen Clusters in a Mesoporous/Microporous Thorium-Based Porphyrin Metal–Organic Framework for Enhanced Photocatalytic CO2 Reduction38Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture24A comprehensive overview of carbon dioxide capture: From materials, methods to industrial status68A dual-functional 3D cerium MOF heterogeneous catalyst for catalysing Knoevenagel condensation and cyanosilylation14Fabrication of a Cd( ii ) metal–organic framework as a dual functional material: efficient iodine capture and selective adsorption of a cationic dye24Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids2Integrating Metal Complex Units and Redox Sites into Thorium‐Based Metal–Organic Frameworks for Selective Photocatalytic Oxidation of Sulfides37Experimental and Theoretical Evaluation of the Thermodynamics of the Carbonation Reaction of ZIF-8 and Its Close-Packed Polymorph with Carbon Dioxide4Expanding the Transuranic Metal–Organic Framework Portfolio: The Optical Properties of Americium(III) MOF-7613ZIF-67-Based Triboelectric Nanogenerator Fabricated Through EHD Printing: Performance Evaluation as an Energy Harvesting Device and Its Pressure-Sensing Application12Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials18Pioneering radiation dosimetry and photothermal conversion in a photochromic and radiochromic thorium cluster13Direct Imaging of Co‐CUK‐1 Framework with H2O Guests1Carbon Quantum Dot‐Encapsulated Metal–Organic Framework Hybrids as Multifunctional Fluorescent Sensors for Oral Disease Biomarker Detection16A Zn-based MOF with honeycomb topology for highly efficient iodine uptake from vapor and liquid phases: synthesis, crystal structure, topology and dual-phase sorption performance4Metal-Organic Frameworks Constructed by Functional Flexible Carboxylates: Structures and Properties0Programmable Atomic Composition through Transmetalation for Isostructural Multimetallic Metal–Organic Frameworks0Construction of an Amino-Functionalized Thorium MOF for Bifunctional Catalysis toward CO2 Cycloaddition and N-Formylation0Photoinduced Electronic Modulation in a Thorium Cluster: Enabling Dual Radiation Sensing and Photothermal Conversion0

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  1. Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )

    RSC Advances · 2019-01-01

    Maxime Dufaye, Nicolas P. Martin, Sylvain Duval, Christophe Volkringer, Atsushi Ikeda‐Ohno, Thierry Loiseau

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  2. A Double-Walled Thorium-Based Metal–Organic Framework as a Promising Dual-Function Absorbent for Efficiently Capturing Iodine and Dyes

    Crystal Growth & Design · 2019-08-13

    Na Zhang, Lixian Sun, Yong‐Heng Xing, Feng‐Ying Bai

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  3. Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands

    Inorganic Chemistry Frontiers · 2019-10-29

    Zi‐Jian Li, Shangyao Guo, Huangjie Lu, Yongjia Xu, Zenghui Yue, Linhong Weng, Xiaofeng Guo, Jian Hung Lin, Jian‐Qiang Wang

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  4. A Double-Walled Porous Metal–Organic Framework as a Highly Efficient Catalyst for Chemical Fixation of CO2 with Epoxides

    Inorganic Chemistry · 2019-11-08

    Qianqian Zhu, Wenwen Zhang, Hanwen Zhang, Ye Yuan, Rongrong Yuan, Fuxing Sun, Hongming He

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  5. Disappearing Polymorphs in Metal–Organic Framework Chemistry: Unexpected Stabilization of a Layered Polymorph over an Interpenetrated Three‐Dimensional Structure in Mercury Imidazolate

    Chemistry - A European Journal · 2019-11-22

    Isaiah R. Speight, Igor Huskić, Mihails Arhangelskis, Hatem M. Titi, Robin S. Stein, Timothy P. Hanusa, Tomislav Friščić

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  6. A mixed-ligand strategy regulates thorium-based MOFs

    Dalton Transactions · 2019-12-19

    Zhi‐wei Huang, Kong‐Qiu Hu, Lei Mei, Xiang‐he Kong, Jipan Yu, Kang Liu, Li-wen Zeng, Zhifang Chai, Wei‐Qun Shi

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  7. Occurrence of polyoxouranium motifs in uranyl organic networks constructed by using silicon-centered carboxylate linkers: structures, spectroscopy and computation

    Dalton Transactions · 2020-01-01

    Chao Liu, Xin-Xue Yang, Shuai Niu, Xiao‐Yi Yi, Qing‐Jiang Pan

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  8. In-situ synthetic modified metal-organic framework (MZIF-8) as an interlayer of the composite membranes for ethanol dehydration

    Journal of Membrane Science · 2020-02-03

    Xin Zhang, Feng-Yi Cheng, Haizhen Zhang, Zhen‐Liang Xu, Shuangmei Xue, Xiao‐Hua Ma, Xinru Xu

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  9. Ultrastable Thorium Metal–Organic Frameworks for Efficient Iodine Adsorption

    Inorganic Chemistry · 2020-03-13

    Zi‐Jian Li, Zenghui Yue, Yu Ju, Xiaoling Wu, Yiming Ren, Shaofei Wang, Yongxin Li, Zhi‐Hui Zhang, Xiaofeng Guo, Jian Hung Lin, Jian‐Qiang Wang

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  10. Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-66

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  11. Design and Assembly of a Hierarchically Micro- and Mesoporous MOF as a Highly Efficient Heterogeneous Catalyst for Knoevenagel Condensation Reaction

    Crystal Growth & Design · 2020-06-09

    Kun Peng Cai, Wenjun Tan, Nian Zhao, Hongming He

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  12. From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates

    European Journal of Inorganic Chemistry · 2020-06-19

    Aphra V. Murray, Nicole A. Vanagas, Jennifer N. Wacker, Jeffery A. Bertke, Karah E. Knope

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  13. Rational Design of a Uranyl Metal–Organic Framework for the Capture and Colorimetric Detection of Organic Dyes

    Chemistry - A European Journal · 2020-07-18

    Robert G. Surbella, Korey Prescott Carter, Trevor D. Lohrey, Dallas D. Reilly, Mark Kalaj, Bruce K. McNamara, Jon M. Schwantes, Rebecca J. Abergel

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  14. Recent Advances on Metal‐Organic Frameworks in the Conversion of Carbon Dioxide

    Chinese Journal of Chemistry · 2020-09-06

    Xiongli Liu, Jinli Li, Na Li, Baiyan Li, Xian‐He Bu

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  15. Metal–Organic Frameworks Based on Group 3 and 4 Metals

    Advanced Materials · 2020-09-09

    Liang Feng, Jiandong Pang, Ping She, Jia‐Luo Li, Jun‐Sheng Qin, Dong‐Ying Du, Hong-Cai “Joe” Zhou

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  16. Metal-organic frameworks as a versatile platform for radionuclide management

    Coordination Chemistry Reviews · 2020-09-15

    Kangwoo Jin, Byeongchan Lee, Jinhee Park

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  17. “Turn-on” fluorescent sensor for Th4+ in aqueous media based on a combination of PET-AIE effect

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2020-11-14

    Shibing Chen, Shengjie Jiang, Hongyu Guo, Fafu Yang

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  18. Linker Substituents Control the Thermodynamic Stability in Metal–Organic Frameworks

    Journal of the American Chemical Society · 2020-12-16

    Novendra Novendra, Joseph M. Marrett, Athanassios D. Katsenis, Hatem M. Titi, Mihails Arhangelskis, Tomislav Friščić, Alexandra Navrotsky

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  19. Potassium Ions Induced Framework Interpenetration for Enhancing the Stability of Uranium-Based Porphyrin MOF with Visible-Light-Driven Photocatalytic Activity

    Inorganic Chemistry · 2020-12-31

    Zhi‐wei Huang, Kong‐Qiu Hu, Lei Mei, Cui Wang, Yanmei Chen, Wangsuo Wu, Zhifang Chai, Wei‐Qun Shi

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  20. A cationic thorium–organic framework with triple single-crystal-to-single-crystal transformation peculiarities for ultrasensitive anion recognition

    Chemical Science · 2021-01-01

    Zi‐Jian Li, Min Lei, Hongliang Bao, Yu Ju, Huangjie Lu, Yongxin Li, Zhi‐Hui Zhang, Xiaofeng Guo, Yuan Qian, Ming‐Yang He, Jian‐Qiang Wang, Wei Liu, Jian Hung Lin

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  21. Simplifying and expanding the scope of boron imidazolate framework (BIF) synthesis using mechanochemistry

    Chemical Science · 2021-01-01

    Cameron B. Lennox, Jean‐Louis Do, Joshua G. Crew, Mihails Arhangelskis, Hatem M. Titi, Ashlee J. Howarth, Omar K. Farha, Tomislav Friščić

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  22. Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

    RSC Advances · 2021-01-01

    Ting Yu, Zhenghua Qian, Lin Li, Xiaoling Wu, Hui He, Yanbo Qiao, Ye Guoan

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  23. Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption

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  24. Versatility vs stability. Are the assets of metal–organic frameworks deployable in aqueous acidic and basic media?

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  25. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

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    Kai Lv, Sebastian Fichter, Mei Gu, Juliane März, Moritz Schmidt

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  26. Unusual Metal–Organic Framework Topology and Radiation Resistance through Neptunyl Coordination Chemistry

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  27. Synthesis, characterization and biocompatibility of guar gum-benzoic acid

    International Journal of Biological Macromolecules · 2021-12-01

    Trung‐Anh Le, Yong Guo, Junnian Zhou, Jiaqi Yan, Hongbo Zhang, Tan‐Phat Huynh

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  28. Enhanced Xe/Kr separation via the pore size confinement effect of a microporous thorium-based metal–organic framework

    Dalton Transactions · 2022-01-01

    Pinhong Mi, Lixi Chen, Xiaoqi Li, Xia Wang, Guodong Li, Liwei Cheng, Junhao Lu, Hailong Zhang, Yanlong Wang, Shuao Wang

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  29. Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters

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    Zi‐Jian Li, Xiaofeng Guo, Jie Qiu, Huangjie Lu, Jian‐Qiang Wang, Jian Hung Lin

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  30. Syntheses, crystal structures, and luminescence properties of three cadmium coordination polymers assembled from a semi-rigid tetracarboxylate ligand

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    Wei Yang, Baoqiu Yu, Hailong Wang

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  31. Encapsulation of Polymetallic Oxygen Clusters in a Mesoporous/Microporous Thorium-Based Porphyrin Metal–Organic Framework for Enhanced Photocatalytic CO2 Reduction

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    Zhi‐wei Huang, Kong‐Qiu Hu, Lei Mei, Degao Wang, Jing-Yang Wang, Wangsuo Wu, Zhifang Chai, Wei‐Qun Shi

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  32. Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture

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  33. A comprehensive overview of carbon dioxide capture: From materials, methods to industrial status

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  34. A dual-functional 3D cerium MOF heterogeneous catalyst for catalysing Knoevenagel condensation and cyanosilylation

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  35. Fabrication of a Cd( ii ) metal–organic framework as a dual functional material: efficient iodine capture and selective adsorption of a cationic dye

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  37. Integrating Metal Complex Units and Redox Sites into Thorium‐Based Metal–Organic Frameworks for Selective Photocatalytic Oxidation of Sulfides

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  39. Expanding the Transuranic Metal–Organic Framework Portfolio: The Optical Properties of Americium(III) MOF-76

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