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RESEARCH PAPER · Coordination Chemistry Reviews · 2021

An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

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An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to applicationOriginalUranyl ion complexes with 2,2′:6′,2′′-terpyridine-4′-carboxylate. Interpenetration of networks involving “expanded ligands”10Unusual Metal–Organic Framework Topology and Radiation Resistance through Neptunyl Coordination Chemistry32Cellulose–metal organic frameworks (CelloMOFs) hybrid materials and their multifaceted Applications: A review341High-energy resolution X-ray spectroscopy at actinide M 4,5 and ligand K edges: what we know, what we want to know, and what we can know77Versatile monometallic coordination polymers constructed from 4,4′-thiobis(methylene)bibenzoic acid and 1,10-phenanthroline. Synthesis, structure, magnetic and luminescence properties3Preparation of modified zirconium-based metal-organic frameworks (Zr-MOFs) supported metals and recent application in environment: A review and perspectives143Uranyl Ion Coordination by Benzene‐1,2,3‐tricarboxylate: Building Chains and Networks from Binuclear Bricks1Electrospun metal–organic framework based nanofibers for energy storage and environmental applications: current approaches and challenges84UoC-3: A Metal–Organic Framework with an Anionic Framework Based on Uranyl UO22+ Nodes and Partly Fluorinated Benzene-1,3,5-Tribenzoate Linkers221,2,4-Triazolyl-4-acetate: a ditopic ligand combining soft and hard donor sites in homometallic (Ag I ) and heterometallic (Ag I /U VI ) coordination polymers8Covalency in actinide( iv ) hexachlorides in relation to the chlorine K-edge X-ray absorption structure40Enhancing photosensitivity via the assembly of a uranyl coordination polymer8Luminometric dosimetry of X-ray radiation by a zwitterionic uranium coordination polymer5Plumbing the uncertainties of solvothermal synthesis involving uranyl ion carboxylate complexes9Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters50Recent advances in uranium-containing polyoxometalates59Varied role of organic carboxylate dizwitterions and anionic donors in mixed-ligand uranyl ion coordination polymers14Contrasting Networks and Entanglements in Uranyl Ion Complexes with Adipic and trans,trans-Muconic Acids7MOFs with 12-Coordinate 5f-Block Metal Centers41Multiple aspects of chirality in coordination polymers formed by the uranyl ion with (1R,3S)-(+)-camphorate ligands1Preparation of rGO/Ni2ZnS4 and high-performance asymmetric supercapacitors with GO/ZIF-8 template11Varying Structure‐Directing Anions in Uranyl Ion Complexes with Ni(2,2′ : 6′,2′′‐terpyridine‐4′‐carboxylate)212Metal–Organic Framework-Based Materials for Adsorption and Detection of Uranium(VI) from Aqueous Solution138Ni(2,2′:6′,2″-Terpyridine-4′-carboxylate)2 Zwitterions and Carboxylate Polyanions in Mixed-Ligand Uranyl Ion Complexes with a Wide Range of Topologies17Highlighting Recent Crystalline Engineering Aspects of Luminescent Coordination Polymers Based on F-Elements and Ditopic Aliphatic Ligands5Comparative Analysis of Mononuclear 1:1 and 2:1 Tetravalent Actinide (U, Th, Np) Complexes: Crystal Structure, Spectroscopy, and Electrochemistry10Metal–organic frameworks and derived materials as photocatalysts for water splitting and carbon dioxide reduction207The effectiveness of silver nanoparticles as a clean-up material for water polluted with bacteria DNA conveying antibiotics resistance genes: Effect of different molar concentrations and competing ions24Carboxymethyl cellulose-coated HKUST-1 for baclofen drug delivery in vitro20The Chemistry and Applications of Metal–Organic Frameworks (MOFs) as Industrial Enzyme Immobilization Systems138Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene3Capture Instead of Release: Defect-Modulated Radionuclide Leaching Kinetics in Metal–Organic Frameworks35Anionic uranyl ion complexes with pyrazinetetracarboxylate: Influence of structure-directing cations1Zwitterionic and Anionic Polycarboxylates as Coligands in Uranyl Ion Complexes, and Their Influence on Periodicity and Topology19Energetic Systematics of Metal–Organic Frameworks: A Case Study of Al(III)-Trimesate MOF Isomers16Crystalline Molecular Assemblies of Complexes Showing Eightfold Coordinated Niobium(IV) Dodecahedral Geometry in the Pyridine-Dicarboxylic Acid System2Progress in solid state and coordination chemistry of actinides in China5Achieving High Photo/Thermocatalytic Product Selectivity and Conversion via Thorium Clusters with Switchable Functional Ligands87Electrospun Metal–Organic Framework Nanofiber Membranes for Energy Storage and Environmental Protection98Effective adsorbent for the removal of bisphenol A from water: MOF-derived carbon21Unconventional Pathways to Carbide Phase Synthesis via Thermal Decomposition of UI4(1,4-dioxane)26Development of an intelligent heterojunction fenton catalyst for chemodynamic/starvation synergistic cancer therapy40Rare radioisotopes at the ready0f‐block MOFs: A Pathway to Heterometallic Transuranics29f‐block MOFs: A Pathway to Heterometallic Transuranics1A Comprehensive Review on Zeolite Chemistry for Catalytic Conversion of Biomass/Waste into Green Fuels39Two protons masquerading as a metal ion? Anionic coordination polymers of uranyl ion and tetrahydrofurantetracarboxylate with protonated or metal-complexed azamacrocyclic cations1A ratiometric radio-photoluminescence dosimeter based on a radical excimer for X-ray detection8A robust thorium–organic framework as a bifunctional platform for iodine adsorption and Cr( vi ) sensitization9A UOF based on a cyclotriphosphazene skeleton: fluorescence sensing of different substituted aldehydes and NACs18Energy–structure–property relationships in uranium metal–organic frameworks32Ligand competition on uranyl ion: further examples of zwitterionic vs. anionic carboxylate coordination9Modulating the coordination microenvironment of uranyl compounds to enhance photocatalytic CO 2 reduction21Nanotubule inclusion in the channels formed by a six-fold interpenetrated, triperiodic framework7Oligozwitterions in coordination polymers and frameworks – a structural view14Post-synthetic linker installation: an unprecedented strategy to enhance iodine adsorption in metal–organic frameworks17Recent progress in anion exchange membranes (AEMs) in water electrolysis: synthesis, physio-chemical analysis, properties, and applications90The Capture Performance of An-Mof for Fission Gases: Insight from Dft and Aimd Calculations0Topological control of metal–organic frameworks toward highly sensitive and selective detection of chromate and dichromate32Triple-armed aliphatic tricarboxylic acids as sources of ligands for uranyl ion: influence of bridgehead functionalization4Selective Crystallization of a Highly Radiation-Resistant Isonicotinic Acid-Based Metal–Organic Framework as a Primary Actinide Waste Form23Oxidatively Doped Tetrathiafulvalene-Based Metal–Organic Frameworks for High Specific Energy of Supercapatteries14Flexible Aliphatic Diammonioacetates as Zwitterionic Ligands in UO22+ Complexes: Diverse Topologies and Interpenetrated Structures15Unveiling Structural Diversity of Uranyl Compounds of Aprotic 4,4′-Bipyridine N,N′-Dioxide Bearing O-Donors8A Tetravalent Plutonium Organic Framework Containing [ Pu2O16 ] Dimers as Secondary Building Units: Synthesis, Structure, and Radiation Stability9MOFs for desulfurization of fuel oil: Recent advances and future insights40Unveiling the Structure–Modulator Relationships in Thorium-Based Metal–Organic Framework Crystallization18Insight into the Structural and Emissive Behavior of a Three‐Dimensional Americium(III) Formate Coordination Polymer10A Joint Study of Experimental and Computational Chemistry to Probe the Effect of Coordination Modes on the Luminescence of Uranyl‐Organic Coordination Polymers6Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids2Adsorption and Detection of Iodine Species by a Thorium-Based Metal–Organic Framework46Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy21Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy0Fluorescence detection platform of metal-organic frameworks for biomarkers146Mixed 5 f configuration in americium trichloride: Dynamical mean‐field theory combined with density functional theory study1Synthetic Control of Thorium Metal‐Organic Frameworks for Sequencing and Sensing of Radioiodine Species20Experimental Investigation of Thermodynamic Stabilization in Boron Imidazolate Frameworks (BIFs) Synthesized by Mechanochemistry6Th6-Based Multicomponent Heterometallic Metal–Organic Frameworks Featuring 6,12-Connected Topology for Iodine Adsorption18Understanding the sorption behavior of tri, tetra and hexavalent f cations on metal–organic framework (MOF), ZIF-67: experimental and theoretical investigation10Application of metal-organic skeletons and cellulose composites in nanomedicine16The capture performance of An-MOF for fission gases: Insight from DFT and AIMD calculations6Fine‐Tuning X‐Ray Sensitivity in Organic–Inorganic Hybrids via an Unprecedented Mixed‐Ligand Strategy12Hydrogen-bonded organic frameworks (HOFs): Multifunctional material on analytical monitoring79Highly sensitive and selective detection of chromate and dichromate by a luminescent thorium metal-organic framework5Radiation‐Responsive Metal–Organic Frameworks: Fundamentals and Applications36Expanding the Transuranic Metal–Organic Framework Portfolio: The Optical Properties of Americium(III) MOF-76134-(Ammoniomethyl)benzoate, a protic zwitterionic bifunctional linker in uranyl ion carboxylate complexes5Antibacterial, antibiofilm, and antioxidant activities of two novel metal–organic frameworks (MOFs) based on 4,6-diamino-2-pyrimidinethiol with Zn and Co metal ions as coordination polymers82Temperature induced single-crystal to single-crystal transformation of uranium azide complexes6Uranyl ion coordination polymers with the dibenzobarrelene-based rac - and ( R , R )- trans -9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylate ligands41,1ʹ-Dimethyl-4,4ʹ-bipyridinium as a multivalent structure-directing counterion to anionic uranyl ion polycarboxylate complexes9Designed assembly of heterometallic cluster organic frameworks based on Th6 cluster14Recent progress in ZIF nanocomposite materials for wastewater pollutant in aqueous solution: A mini-review26Recent progress in separation of technetium-99 from spent nuclear fuel and radioactive waste. Challenges and prospects55Rational design and synthesis of a uranyl-organic hybrid for X-ray scintillation4Uranyl‐Organic Framework as Hydrogen Atom Transfer Catalyst for Visible‐Light‐Driven Heterogeneous Hydroacylation of Azodicarboxylates8Bifunctional ligands in uranyl chemistry: Metalloligands and zwitterions26Perrhenate anion encapsulation in a uranyl ion–zwitterionic dicarboxylate coordination polymer4Consistent Second-Order Treatment of Spin–Orbit Coupling and Dynamic Correlation in Quasidegenerate N-Electron Valence Perturbation Theory12Unraveling the role of coordinated water in the capture of americium and toxic gases by an ultrastable uranyl phosphonate framework12Efficient and selective H2O2 production through uranyl-assisted photocatalytic oxygen reduction reaction process in a uranium-organic framework20Single‐crystal‐to‐single‐crystal transformation of a two‐dimensional noninterpenetrated layer to a microporous three‐dimensional fourfold interpenetrated MOF triggered by DMF3Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials18Constructing Functional Radiation-Resistant Thorium Clusters for Catalytic Redox Reactions31Thorium Cluster Synthesized by a Solvent-Free Flux Approach: The Richest Coordination Diversity and Application Exploration5Photocatalytic Hydrogen Peroxide Production by a Mixed Ligand-Functionalized Uranyl–Organic Framework8High photoluminescence quantum yield of a uranyl ion complex with the hemi-zwitterion 1,3-bis(carboxylatomethyl)-1H-benzimidazol-3-ium2Exploring Energy-Density Relationships in Uranyl nun-Topology MOFs and Their Topological Isomers2Structural Design of Zinc-Directed Heterometallic Uranyl Organic Frameworks: Multifunction Detection of Cr 2 O 7 2– and Metamitron Contaminants from Water12Synthesis of crystalline uranyl ion coordination polymers with zwitterionic carboxylate ligands: comparing solvothermal and ambient conditions1Recent development towards the novel applications and future prospects for cellulose-metal organic framework hybrid materials: a review14Emerging metal-organic framework-based photocatalysts for solar-driven fuel production63Uranyl‐Nickel(II) Cation‐Cation Interaction in a Triperiodic Framework with cis‐1,2‐Cyclohexanedicarboxylate and Isonicotinate Ligands1Insights into Structural Diversity and Morphotropic Evolution in A4Th(WO4)4 (A=Li, Na, K, Rb and Cs) Family0A uranyl-based luminescent dosimeter for ultralow-dose tracking of UV and X-ray radiation2A uranyl-based metal–organic framework featuring an eight-connected U 4 L 2 cage for guest capture2Electrospun Zif-67 and Lignin Co-Modified Cellulose Based Hierarchical Porous N-Doped Carbon Materials for High-Performance Supercapacitors0Emergence of a bismuth-based metal–organic framework as an X-ray scintillator3From separation to photothermal conversion: selective crystallization of thorium from lanthanides7Tuning N-donor coordination and assembly structures in uranyl compounds of carboxylate ligands with divergent vinyl pyridine groups1What goes on in sub-critical solvothermal synthesis of metal ion complexes?2Pioneering radiation dosimetry and photothermal conversion in a photochromic and radiochromic thorium cluster13Technetium ‐ The Unknown Center of the Periodic Table11Highly efficient separation of high-valent actinide ions from lanthanides via fractional crystallization1Electrospun ZIF-67 and lignin co-modified cellulose based hierarchical porous N-doped carbon materials for high-performance supercapacitors12Identical Metal–Organic Frameworks with Distinct Colors: The Role of Modulator in Directing Photophysical Properties3Enhanced Photocatalytic Efficiency and Structural Stability of Uranyl-Organic Coordination Polymers via the Semirigid Ligand6Facile solvothermal fabrication of cobalt-metal–organic framework (Co-MOF)-based electrode material for supercapacitor devices8Emergence of acidity modulation as a new strategy for eliciting stable radicals in multi-stimuli-responsive metal-oxo clusters5Electronic structures and gas adsorption behaviors of 12–coordinated Th (U)–based metal–organic frameworks0Facile interface engineering of MXenes via CTAB intercalation for rapid and selective uranium capture from complex salt lake brines2Interactions of early actinides with biologically-relevant organic molecules including carboxylates, amino acids and proteins2Ultra-violet and electron beam irradiation as an effective approach for design of Ln( iii ) and Am( iii ) MOFs0Metal-organic frameworks for nuclear waste remediation: A review of cutting-edge advances and applications12Photoinduced Formation of Heterobiradical Species in Crystalline Uranyl–Organic Frameworks Incorporating Cucurbit[8]uril-Viologen [3]Pseudorotaxane1Engineering Dual‐Active N and O Sites in Covalent Organic Frameworks for Ultrahigh and Selective Thorium Removal0Radiation effects on metal-organic frameworks (MOFs) for nuclear environmental chemistry: A review1A Host–Guest Uranium-Based Luminescent MOF for the Sensitive Recognition of Acetone in Water0Programmable Atomic Composition through Transmetalation for Isostructural Multimetallic Metal–Organic Frameworks0A One-Dimensional Thorium-Containing Arsenotungstate for the Synthesis of 2,3-Dihydroquinazolinones0Functional Bi‐MOFs and Their Derivatives: From Structural Engineering to Multifunctional Applications in Energy, Catalysis, and Biomedicine1Photoinduced Electronic Modulation in a Thorium Cluster: Enabling Dual Radiation Sensing and Photothermal Conversion0Adsorption Electro-Neutralization of Ionic Liquids in Thorium-MOFs for Enhanced Photocatalytic CO2 Reduction0Uranyl-organic framework: From structure design to cutting-edge applications1

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