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RESEARCH PAPER · Zeitschrift für anorganische und allgemeine Chemie · 1996

Syntheses and Structures of Two New Cu/Nb/pyrazine Complexes: Three dimensional CuNb(pyz)2OF5 · (pyz)(H2O) and two dimensional [Cu(pyz)2.5]+ [NbF6]− · (pyz)

P. Shiv Halasyamani, Kevin R. Heier, Michael J. Willis, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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Syntheses and Structures of Two New Cu/Nb/pyrazine Complexes: Three dimensional CuNb(pyz)2OF5 · (pyz)(H2O) and two dimensional [Cu(pyz)2.5]+ [NbF6]− · (pyz)OriginalHydro(solvo)thermal synthesis and structure of a three-dimensional zinc fluorophosphate: Zn2(4,4′-bipy)(PO3F)252Coordination Polymers of Co(NCS)2 with Pyrazine and 4,4‘-Bipyridine: Syntheses and Structures410[pyH]2[Cu(py)4(MX6)2] (MX6 = ZrF62-, NbOF52-, MoO2F42-; py = Pyridine): Rarely Observed Ordering of Metal Oxide Fluoride Anions81The Polar [WO2F4]2- Anion in the Solid State65A density functional study of nuclear magnetic resonance spin–spin coupling constants in transition-metal systems50Cu(C10H9N3)2MOF5·2H2O (M = Nb, Ta): Aligned [MOF5]2- Oxide Fluoride Anions35The Structure-Directing Properties of [VOF5]2-66Polar Compounds Constructed with the [Cr2O7]2- Anion32Structural Relationships, Interconversion, and Optical Properties of the Uranyl Iodates, UO2(IO3)2and UO2(IO3)2(H2O): A Comparison of Reactions under Mild and Supercritical Conditions115Synthesis, structure and magnetic properties of 3D interpenetrating nets of M(pyrazine)[Au(CN)2]2 (M=Cu, Ni, Co) supported by aurophilic interactions85Synthesis and characterisation of 4,4′-bipyridine bridged supramolecules derived from [(N–N)Cu(H2O)4]X2, [(N–N)=diamine] and linear 4,4′-bipyridine. X-ray crystal structures of [(2,2′-bpy)Cu(4,4′-bpy)(OClO3)2]n and [(1,10-phen)Cu[(4,4′-bpy)(OClO3)]n(ClO4)n·nH2O15Cation Effects on the Formation of the One-Dimensional Uranyl Iodates A2[(UO2)3(IO3)4O2] (A=K, Rb, Tl) and AE[(UO2)2(IO3)2O2] (H2O) (AE=Sr, Ba, Pb)53From Linear Inorganic Chains to Helices: Chirality in the M(pyz)(H2O)2MoO2F4 (M = Zn, Cd) Compounds62Out-of-Center Distortions in d0 Transition Metal Oxide Fluoride Anions124AgI, CdII, and HgII complexes with 2,5-bis(pyridyl)pyrazine ligands: syntheses, spectral analyses, single crystal, and powder X-ray analyses12One-dimensional coordination polymer [Co(H2O)4(pyz)](NO3)2·2H2O (pyz=pyrazine) with intra- and inter-chain H-bonds: structure, electronic spectral studies and magnetic properties38Structure of Dibenzocrown Ethers and Their H-bonded Adducts. 3. Isolation of Oxonium Ions by Biphenyl-20-crown-6 and (1.5)Dibenzo-18-Crown-6 In0Structure of Dibenzocrown Ethers and their H-bonded Adducts. 3. Isolation of Oxonium Ions by Biphenyl-20-crown-6 and [1.5]Dibenzo-18-Crown-6 in Complexes with [NbF6]− and [TaF6]−10Two-Dimensional Heisenberg Antiferromagnets: Syntheses, X-ray Structures, and Magnetic Behavior of [Cu(pz)2](ClO4)2, [Cu(pz)2](BF4)2, and [Cu(pz)2(NO3)](PF6)81Structure of oxonium hexafluoroniobate and hexafluorotantalate complexes with crown ethers of different dimensionality18Density-functional computation of 99Tc NMR chemical shifts34Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride Anions46Copper(II) complexes of 3-amino-1,2,4-triazine and 2-aminopyrazine: Strategies for designing crystalline materials using coordination polymers13Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8Density-functional computation of 93Nb NMR chemical shifts18Synthesis, crystal and electronic structure, and theoretical investigations of charge-transfer, optical, and bonding properties of a [VF6]3− anion compound2Orientational order of [VOF5]2− and [NbOF5]2− polar units in chains40Chemistry of Polar Transition-Metal Oxides1Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model16Dividing the Spoils: Role of Pyrazine Ligands and Perchlorate Counterions in the Magnetic Properties of Bis(pyrazine)diperchloratecopper(II), [Cu(pz)2](ClO4)224From Solution to the Solid State: Control of Niobium Oxide–Fluoride [NbO x F y ] n − Species26Design and construction of copper(I) complexes based on flexi-dentate cyclic N2-donor Schiff bases via in situ reduction of copper(II) precursors22Robust Packing Patterns and Luminescence Quenching in Mononuclear [Cu(II)( phen )2] Sulfates34Magnetic properties of three dimensional bimetallic, copper(II)-niobium(V) pyrazine complex0Highly Selective Separation of C2H2 from CO2 by a New Dichromate-Based Hybrid Ultramicroporous Material142Enhanced Stability toward Humidity in a Family of Hybrid Ultramicroporous Materials Incorporating Cr2O72– Pillars16Making an order: the concerted alignment of [MOF5]2− (M = Nb and Ta) dipolar anions in one-dimensional coordination chains sustained by tris(3,4,5-trimethyl-1H-pyrazole)copper(II)2A series of oxyfluoride chains containing asymmetric basic building units of both early- and late-transition metal cations5Metal-organic framework based carbon capture and purification technologies for clean environment44Effect of Deuteration on Phase Transitions in Vanadium Dioxotetrafluoride2Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving138Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving59Crystal Engineering of Hybrid Coordination Networks: From Form to Function78CoMOF5(pyrazine)(H2O)2 (M = Nb, Ta): Two-Layered Cobalt Oxyfluoride Antiferromagnets with Spin Flop Transitions21Early-Stage Formation of the SIFSIX-3-Zn Metal–Organic Framework: An Automated Computational Study5Crystal Engineering of Reticular Materials for Gas‐ and Liquid‐Phase Hydrocarbon Separation3

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  1. Hydro(solvo)thermal synthesis and structure of a three-dimensional zinc fluorophosphate: Zn2(4,4′-bipy)(PO3F)2

    Chemical Communications · 1997-01-01

    P. Shiv Halasyamani, Mark J. Drewitt, Dermot O’Hare

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  2. Coordination Polymers of Co(NCS)2 with Pyrazine and 4,4‘-Bipyridine: Syntheses and Structures

    Inorganic Chemistry · 1997-02-01

    Jian Lü, Tasneem Paliwala, Shiao C. Lim, Carolyn Yu, Tianyan Niu, Allan J. Jacobson

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  3. [pyH]2[Cu(py)4(MX6)2] (MX6 = ZrF62-, NbOF52-, MoO2F42-; py = Pyridine): Rarely Observed Ordering of Metal Oxide Fluoride Anions

    Inorganic Chemistry · 1998-01-01

    Kevin R. Heier, Alexander J. Norquist, Christopher G. Wilson, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  4. The Polar [WO2F4]2- Anion in the Solid State

    Inorganic Chemistry · 1999-02-02

    Kevin R. Heier, Alexander J. Norquist, P. Shiv Halasyamani, A. Duarte, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  5. A density functional study of nuclear magnetic resonance spin–spin coupling constants in transition-metal systems

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 1999-03-01

    Jana Khandogin, Tom Ziegler

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  6. Cu(C10H9N3)2MOF5·2H2O (M = Nb, Ta): Aligned [MOF5]2- Oxide Fluoride Anions

    Inorganic Chemistry · 1999-07-01

    Alexander J. Norquist, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  7. The Structure-Directing Properties of [VOF5]2-

    Inorganic Chemistry · 2000-08-16

    Margaret E. Welk, Alexander J. Norquist, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  8. Polar Compounds Constructed with the [Cr2O7]2- Anion

    Inorganic Chemistry · 2001-03-16

    Alexander J. Norquist, Kevin R. Heier, P. Shiv Halasyamani, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  9. Structural Relationships, Interconversion, and Optical Properties of the Uranyl Iodates, UO2(IO3)2and UO2(IO3)2(H2O): A Comparison of Reactions under Mild and Supercritical Conditions

    Chemistry of Materials · 2001-03-20

    Amanda C. Bean, Shane M. Peper, Thomas E. Albrecht‐Schmitt

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  10. Synthesis, structure and magnetic properties of 3D interpenetrating nets of M(pyrazine)[Au(CN)2]2 (M=Cu, Ni, Co) supported by aurophilic interactions

    Polyhedron · 2001-05-01

    Daniel B. Leznoff, Bao-Yu Xue, Cecilia L. Stevens, Alan Storr, Robert C. Thompson, Brian O. Patrick

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  11. Synthesis and characterisation of 4,4′-bipyridine bridged supramolecules derived from [(N–N)Cu(H2O)4]X2, [(N–N)=diamine] and linear 4,4′-bipyridine. X-ray crystal structures of [(2,2′-bpy)Cu(4,4′-bpy)(OClO3)2]n and [(1,10-phen)Cu[(4,4′-bpy)(OClO3)]n(ClO4)n·nH2O

    Polyhedron · 2001-07-01

    S.K. Chawla, M.S. Hundal, Jaspreet Kaur, Sangeeta Obrai

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  12. Cation Effects on the Formation of the One-Dimensional Uranyl Iodates A2[(UO2)3(IO3)4O2] (A=K, Rb, Tl) and AE[(UO2)2(IO3)2O2] (H2O) (AE=Sr, Ba, Pb)

    Journal of Solid State Chemistry · 2001-11-01

    Amanda C. Bean, Thomas E. Albrecht‐Schmitt

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  13. From Linear Inorganic Chains to Helices: Chirality in the M(pyz)(H2O)2MoO2F4 (M = Zn, Cd) Compounds

    Inorganic Chemistry · 2002-07-24

    Paul A. Maggard, Amy L. Kopf, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier, Kang Min Ok, P. Shiv Halasyamani

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  14. Out-of-Center Distortions in d0 Transition Metal Oxide Fluoride Anions

    Inorganic Chemistry · 2002-09-07

    Margaret E. Welk, Alexander J. Norquist, Frederick P. Arnold, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

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  15. AgI, CdII, and HgII complexes with 2,5-bis(pyridyl)pyrazine ligands: syntheses, spectral analyses, single crystal, and powder X-ray analyses

    Journal of Chemical Crystallography · 2003-01-01

    Olivier Vallat, Antonia Neels, Helen Stoeckli-Evans

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  16. One-dimensional coordination polymer [Co(H2O)4(pyz)](NO3)2·2H2O (pyz=pyrazine) with intra- and inter-chain H-bonds: structure, electronic spectral studies and magnetic properties

    Polyhedron · 2004-12-30

    K.T. Holman, Hassan Hasan Hammud, S. Isber, M. Tabbal

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  17. Structure of Dibenzocrown Ethers and Their H-bonded Adducts. 3. Isolation of Oxonium Ions by Biphenyl-20-crown-6 and (1.5)Dibenzo-18-Crown-6 In

    Unknown journal · 2006-01-01

    Eduard V. Ganin, V.O. Gelmboldt, Larisa V. Koroeva, Marina S. Fonarı, Yurii A. Simonov, Janusz S. Lipkowski, Gerbert L. Kamalov

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  18. Structure of Dibenzocrown Ethers and their H-bonded Adducts. 3. Isolation of Oxonium Ions by Biphenyl-20-crown-6 and [1.5]Dibenzo-18-Crown-6 in Complexes with [NbF6]− and [TaF6]−

    Journal of Inclusion Phenomena and Macrocyclic Chemistry · 2006-05-30

    Eduard V. Ganin, V.O. Gelmboldt, Larisa V. Koroeva, Marina S. Fonarı, Yurii A. Simonov, Janusz S. Lipkowski, Sergei A. Kotlyar, Gerbert L. Kamalov

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  19. Two-Dimensional Heisenberg Antiferromagnets: Syntheses, X-ray Structures, and Magnetic Behavior of [Cu(pz)2](ClO4)2, [Cu(pz)2](BF4)2, and [Cu(pz)2(NO3)](PF6)

    Inorganic Chemistry · 2007-04-14

    F. Matthew Woodward, P. J. Gibson, Geoffrey B. Jameson, Christopher P. Landee, Mark M. Turnbull, Roger DuWayne Willett

    Read original paper ↗ ·

  20. Structure of oxonium hexafluoroniobate and hexafluorotantalate complexes with crown ethers of different dimensionality

    Polyhedron · 2007-09-05

    Marina S. Fonarı, Yurii A. Simonov, Wen‐Jwu Wang, Shang‐Wei Tang, Eduard V. Ganin, V.O. Gelmboldt, T. S. Chernaya, Olga A. Alekseeva, Nina G. Furmanova

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  21. Density-functional computation of 99Tc NMR chemical shifts

    Magnetic Resonance in Chemistry · 2008-10-14

    Michæl Bühl, Volodymyr Golubnychiy

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  22. Chemical Hardness and the Adaptive Coordination Behavior of the d0 Transition Metal Oxide Fluoride Anions

    Zeitschrift für anorganische und allgemeine Chemie · 2009-04-08

    Michael R. Marvel, Rachelle Ann F. Pinlac, Julien Lesage, Charlotte L. Stern, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  23. Copper(II) complexes of 3-amino-1,2,4-triazine and 2-aminopyrazine: Strategies for designing crystalline materials using coordination polymers

    Inorganica Chimica Acta · 2009-05-19

    Lixin Li, Mark M. Turnbull, Jared Ackers, Jungpeng Chen, Hongyu Lin, Baofei Pan, Hui Wang, Bruce M. Foxman

    Read original paper ↗ ·

  24. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

    Unknown journal · 2010-06-11

    P. Shiv Halasyamani

    Read original paper ↗ ·

  25. Density-functional computation of 93Nb NMR chemical shifts

    Magnetic Resonance in Chemistry · 2010-06-15

    Michæl Bühl, Bernd Wrackmeyer

    Read original paper ↗ ·

  26. Synthesis, crystal and electronic structure, and theoretical investigations of charge-transfer, optical, and bonding properties of a [VF6]3− anion compound

    Monatshefte für Chemie - Chemical Monthly · 2011-12-22

    Yi-Ping Tong, Hong Shu Liu, Zhen Jin, Yan‐Wen Lin

    Read original paper ↗ ·

  27. Orientational order of [VOF5]2− and [NbOF5]2− polar units in chains

    Journal of Solid State Chemistry · 2012-01-24

    Romain Gautier, Martin D. Donakowski, Kenneth Reinhard Poeppelmeier

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  28. Chemistry of Polar Transition-Metal Oxides

    Elsevier eBooks · 2013-01-01

    P. Shiv Halasyamani

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  29. Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model

    Crystal Growth & Design · 2013-07-31

    Romain Gautier, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  30. Dividing the Spoils: Role of Pyrazine Ligands and Perchlorate Counterions in the Magnetic Properties of Bis(pyrazine)diperchloratecopper(II), [Cu(pz)2](ClO4)2

    Inorganic Chemistry · 2013-10-30

    Sergi Vela, Joaquim Jornet-Somoza, Mark M. Turnbull, R. Feyerherm, Juan J. Novoa, Mercè Deumal

    Read original paper ↗ ·

  31. From Solution to the Solid State: Control of Niobium Oxide–Fluoride [NbO x F y ] n − Species

    Inorganic Chemistry · 2013-12-12

    Hongcheng Lu, Romain Gautier, Martin D. Donakowski, Zheng‐Tang Liu, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·

  32. Design and construction of copper(I) complexes based on flexi-dentate cyclic N2-donor Schiff bases via in situ reduction of copper(II) precursors

    Polyhedron · 2014-06-12

    Subrata Jana, Shouvik Chattopadhyay

    Read original paper ↗ ·

  33. Robust Packing Patterns and Luminescence Quenching in Mononuclear [Cu(II)( phen )2] Sulfates

    The Journal of Physical Chemistry C · 2014-12-11

    Elena Melnic, Eduard B. Coropceanu, Olga V. Kulikova, Anatolii V. Siminel, Dane Anderson, Héctor J. Rivera-Jacquez, Artëm E. Masunov, Marina S. Fonarı, Victor Kravtsov

    Read original paper ↗ ·

  34. Magnetic properties of three dimensional bimetallic, copper(II)-niobium(V) pyrazine complex

    Springer eBooks · 2017-01-01

    R. T. Pardasani, Pushpa Pardasani

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  35. Highly Selective Separation of C2H2 from CO2 by a New Dichromate-Based Hybrid Ultramicroporous Material

    ACS Applied Materials & Interfaces · 2017-01-27

    Hayley S. Scott, Mohana Shivanna, Alankriti Bajpai, David Gerard Madden, Kai‐Jie Chen, Tony Pham, Katherine A. Forrest, Adam Hogan, Brian Space, John J. Perry, Michael John Zaworotko

    Read original paper ↗ ·

  36. Enhanced Stability toward Humidity in a Family of Hybrid Ultramicroporous Materials Incorporating Cr2O72– Pillars

    Crystal Growth & Design · 2017-03-14

    Hayley S. Scott, Mohana Shivanna, Alankriti Bajpai, Kai‐Jie Chen, David Gerard Madden, John J. Perry, Michael John Zaworotko

    Read original paper ↗ ·

  37. Making an order: the concerted alignment of [MOF5]2− (M = Nb and Ta) dipolar anions in one-dimensional coordination chains sustained by tris(3,4,5-trimethyl-1H-pyrazole)copper(II)

    Acta Crystallographica Section C Structural Chemistry · 2018-07-18

    Anastasiya V. Sharko, Oliver Erhart, Harald Krautscheid, K.V. Domasevitch

    Read original paper ↗ ·

  38. A series of oxyfluoride chains containing asymmetric basic building units of both early- and late-transition metal cations

    Journal of Solid State Chemistry · 2018-08-20

    Belal Ahmed, Hongil Jo, Sung Won Yoon, Kwang‐Yong Choi, Kang Min Ok

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  39. Metal-organic framework based carbon capture and purification technologies for clean environment

    Elsevier eBooks · 2019-01-01

    Soumya Mukherjee, Amrit Kumar, Michael John Zaworotko

    Read original paper ↗ ·

  40. Effect of Deuteration on Phase Transitions in Vanadium Dioxotetrafluoride

    Physics of the Solid State · 2019-02-01

    Evgeniy V. Bogdanov, Evgeniy I. Pogoreltsev, М. В. Горев, Мaxim S. Моlokeev, Igor N. Flerov

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  41. Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving

    Angewandte Chemie International Edition · 2019-11-20

    Qingju Wang, Tian Ke, Lifeng Yang, Zhaoqiang Zhang, Xili Cui, Zongbi Bao, Qilong Ren, Qiwei Yang, Huabin Xing

    Read original paper ↗ ·

  42. Separation of Xe from Kr with Record Selectivity and Productivity in Anion‐Pillared Ultramicroporous Materials by Inverse Size‐Sieving

    Angewandte Chemie · 2019-11-20

    Qingju Wang, Ke Tian, Lifeng Yang, Zhaoqiang Zhang, Xili Cui, Zongbi Bao, Qilong Ren, Qiwei Yang, Huabin Xing

    Read original paper ↗ ·

  43. Crystal Engineering of Hybrid Coordination Networks: From Form to Function

    Trends in Chemistry · 2020-04-16

    Soumya Mukherjee, Michael John Zaworotko

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  44. CoMOF5(pyrazine)(H2O)2 (M = Nb, Ta): Two-Layered Cobalt Oxyfluoride Antiferromagnets with Spin Flop Transitions

    Inorganic Chemistry · 2021-08-10

    Ya-Dong Zhou, Yanhong Wang, Jiaojiao Cao, Zhuo Zeng, Tai‐Ping Zhou, Rong‐Zhen Liao, Tao Wang, Zhenxing Wang, Zhengcai Xia, Zhongwen Ouyang, Hongcheng Lu

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  45. Early-Stage Formation of the SIFSIX-3-Zn Metal–Organic Framework: An Automated Computational Study

    Inorganic Chemistry · 2023-01-10

    Bastian Bjerkem Skjelstad, Yuh Hijikata, Satoshi Maeda

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  46. Crystal Engineering of Reticular Materials for Gas‐ and Liquid‐Phase Hydrocarbon Separation

    Advanced Materials · 2026-02-11

    Xia Li, Soumya Mukherjee, Michael John Zaworotko

    Read original paper ↗ ·
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