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RESEARCH PAPER · Inorganic Chemistry · 2013

Dividing the Spoils: Role of Pyrazine Ligands and Perchlorate Counterions in the Magnetic Properties of Bis(pyrazine)diperchloratecopper(II), [Cu(pz)2](ClO4)2

Sergi Vela, Joaquim Jornet-Somoza, Mark M. Turnbull, R. Feyerherm, Juan J. Novoa, Mercè Deumal

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Dividing the Spoils: Role of Pyrazine Ligands and Perchlorate Counterions in the Magnetic Properties of Bis(pyrazine)diperchloratecopper(II), [Cu(pz)2](ClO4)2OriginalElucidating the 2D Magnetic Topology of the ‘Metal–Radical’ TTTA⋅Cu(hfac)2 System16The origin of the antiferromagnetic behaviour of the charge-transfer compound (HMTTF)[Ni(mnt) 2 ]5Quasi-two-dimensional S=12 magnetism of Cu[C6H2(COO)4][C2H5NH3]230Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 − x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system6The quest for rationalizing the magnetism in purely organic semiquinone-bridged bisdithiazolyl molecular magnets10Pressure and magnetic field effects on a quasi-two-dimensional spin- 12 Heisenberg antiferromagnet6Control of the third dimension in copper-based square-lattice antiferromagnets20Spin Frustration in an Organic Radical Ion Salt Based on a Kagome-Coupled Chain Structure26A Definition of the Magnetic Transition Temperature Using Valence Bond Theory5Room-temperature structural phase transition in the quasi-2D spin- 12 Heisenberg antiferromagnet Cu(pz)2(ClO4)21Halide-bridged Cu(pyrazine)2 perchlorate layers: Structure and magnetism3A high selective fluorescent sensor for Cu2+ in solution and test paper strips78Revisiting the Role of Hydrogen Bonding in the Strong Dimer Superexchange of a 2D Copper(II) Halide Honeycomb-Like Lattice: Structural and Magnetic Study8Extremely well isolated two-dimensional spin- 12 antiferromagnetic Heisenberg layers with a small exchange coupling in the molecular-based magnet CuPOF9Disentangling the magnetic dimensionality of an alleged magnetically isolated cuprate spin-ladder CuHpCl system: a long-lasting issue8Insights into the magnetism and phase transitions of organic radical-based materials56Pitfalls on evaluating pair exchange interactions for modelling molecule-based magnetism9Tight-Binding Approach to Pyrazine-Mediated Superexchange in Copper–Pyrazine Antiferromagnets7Synthesis and Investigation of Magnetic Properties of Rod Shaped Micron Sized Ni4 and Co2Ni2 Cluster based MOFs1Berezinskii—Kosterlitz—Thouless correlations in copper-based quasi-2D spin systems (Review Article)0Asymmetric phase diagram and dimensional crossover in a system of spin- 12 dimers under applied hydrostatic pressure5Enhancing Intramolecular Ferromagnetic Coupling in Tetrathiafulvalene–Nitronyl Nitroxide‐Based Compounds through Spin Polarization Mechanism2A dynamic Jahn-Teller effect and destructive phase transition of [hexakis(3-bromo-2-pyridone)copper(II)] perchlorate polymorphs2Cu(II) coordination complexes of n-chloro-2-pyridones1

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  1. Elucidating the 2D Magnetic Topology of the ‘Metal–Radical’ TTTA⋅Cu(hfac)2 System

    Chemistry - A European Journal · 2014-05-13

    Sergi Vela, Arturo Sopena, Jordi Ribas‐Ariño, Juan J. Novoa, Mercè Deumal

    Read original paper ↗ ·

  2. The origin of the antiferromagnetic behaviour of the charge-transfer compound (HMTTF)[Ni(mnt) 2 ]

    Dalton Transactions · 2014-10-24

    Sergi Vela, Maria Fumanal, Mercè Deumal

    Read original paper ↗ ·

  3. Quasi-two-dimensional S=12 magnetism of Cu[C6H2(COO)4][C2H5NH3]2

    Physical Review B · 2015-02-17

    R. Nath, M. Padmanabhan, Sujesh Baby, A. Thirumurugan, D. Ehlers, M. Hemmida, H.‐A. Krug von Nidda, Alexander A. Tsirlin

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  4. Bimetallic MOFs (H 3 O) x [Cu(MF 6 )(pyrazine) 2 ]·(4 − x)H 2 O (M = V 4+ , x = 0; M = Ga 3+ , x = 1): co-existence of ordered and disordered quantum spins in the V 4+ system

    Chemical Communications · 2016-01-01

    Jamie L. Manson, John A. Schlueter, Kerry E. Garrett, Paul Goddard, Tom Lancaster, Johannes S. Möller, Stephen J. Blundell, Andrew J. Steele, Isabel Franke, Francis Laurence Pratt, John Singleton, Jesper Bendix, Saul H. Lapidus, M. Uhlarz, Oscar E. Ayala-Valenzuela, R. McDonald, Mary Gurak, C. Baines

    Read original paper ↗ ·

  5. The quest for rationalizing the magnetism in purely organic semiquinone-bridged bisdithiazolyl molecular magnets

    Physical Chemistry Chemical Physics · 2016-01-01

    Maria Fumanal, Mercè Deumal

    Read original paper ↗ ·

  6. Pressure and magnetic field effects on a quasi-two-dimensional spin- 12 Heisenberg antiferromagnet

    Physical review. B./Physical review. B · 2016-02-25

    N. Barbero, T. Shiroka, C.P. Landee, M. Pikulski, H. R. Ott, J. Mesot

    Read original paper ↗ ·

  7. Control of the third dimension in copper-based square-lattice antiferromagnets

    Physical review. B./Physical review. B · 2016-03-25

    Paul Goddard, John Singleton, Isabel Franke, Johannes S. Möller, Tom Lancaster, Andrew J. Steele, Craig V. Topping, Stephen J. Blundell, Francis Laurence Pratt, C. Baines, Jesper Bendix, R. McDonald, Jamie Brambleby, M. R. Lees, Saul H. Lapidus, Peter W. Stephens, Brendan Twamley, Marianne M. Conner, Kylee Funk, Jordan F. Corbey, Hope E. Tran, John A. Schlueter, Jamie L. Manson

    Read original paper ↗ ·

  8. Spin Frustration in an Organic Radical Ion Salt Based on a Kagome-Coupled Chain Structure

    Journal of the American Chemical Society · 2016-08-18

    Lars Postulka, Stephen M. Winter, Adam G. Mihailov, Aaron M. Mailman, Abdeljalil Assoud, Craig M. Robertson, B. Wolf, Michael Lang, Richard T. Oakley

    Read original paper ↗ ·

  9. A Definition of the Magnetic Transition Temperature Using Valence Bond Theory

    The Journal of Physical Chemistry A · 2018-01-29

    Joaquim Jornet-Somoza, Mercè Deumal, J. Borge, Michael A. Robb

    Read original paper ↗ ·

  10. Room-temperature structural phase transition in the quasi-2D spin- 12 Heisenberg antiferromagnet Cu(pz)2(ClO4)2

    Physical Review Materials · 2019-05-07

    N. Barbero, Marisa Medarde, T. Shang, Denis V. Sheptyakov, C.P. Landee, J. Mesot, H. R. Ott, T. Shiroka

    Read original paper ↗ ·

  11. Halide-bridged Cu(pyrazine)2 perchlorate layers: Structure and magnetism

    Polyhedron · 2019-07-30

    Jeffrey C. Monroe, C.P. Landee, Mark M. Turnbull, Matthew I. J. Polson, Jan L. Wikaira

    Read original paper ↗ ·

  12. A high selective fluorescent sensor for Cu2+ in solution and test paper strips

    Dyes and Pigments · 2019-09-21

    Fu Shi, Shiqiang Cui, Hongling Liu, Shouzhi Pu

    Read original paper ↗ ·

  13. Revisiting the Role of Hydrogen Bonding in the Strong Dimer Superexchange of a 2D Copper(II) Halide Honeycomb-Like Lattice: Structural and Magnetic Study

    Inorganic Chemistry · 2020-04-13

    Jeffrey C. Monroe, Maria Àngels Carvajal, Mercè Deumal, C.P. Landee, M. Rademeyer, Mark M. Turnbull

    Read original paper ↗ ·

  14. Extremely well isolated two-dimensional spin- 12 antiferromagnetic Heisenberg layers with a small exchange coupling in the molecular-based magnet CuPOF

    Physical review. B./Physical review. B · 2020-08-28

    D. Opherden, N. Nizar, K. Richardson, Jeffrey C. Monroe, Mark M. Turnbull, Matthew I. J. Polson, Sergi Vela, William J. A. Blackmore, Paul Goddard, John Singleton, Eun Sang Choi, F. Xiao, Robert C. Williams, Tom Lancaster, Francis Laurence Pratt, Stephen J. Blundell, Y. Skourski, M. Uhlarz, Alexey N. Ponomaryov, Sergei A. Zvyagin, J. Wosnitza, M. Baenitz, Ivo Heinmaa, Raivo Stern, H. Kühne, C.P. Landee

    Read original paper ↗ ·

  15. Disentangling the magnetic dimensionality of an alleged magnetically isolated cuprate spin-ladder CuHpCl system: a long-lasting issue

    Dalton Transactions · 2021-01-01

    Joaquim Jornet-Somoza, F. Cosi, Maria Fumanal, Mercè Deumal

    Read original paper ↗ ·

  16. Insights into the magnetism and phase transitions of organic radical-based materials

    Journal of Materials Chemistry C · 2021-01-01

    Mercè Deumal, Sergi Vela, Maria Fumanal, Jordi Ribas‐Ariño, Juan J. Novoa

    Read original paper ↗ ·

  17. Pitfalls on evaluating pair exchange interactions for modelling molecule-based magnetism

    Journal of Materials Chemistry C · 2021-01-01

    Maria Fumanal, Joaquim Jornet-Somoza, Sergi Vela, Juan J. Novoa, Jordi Ribas‐Ariño, Mercè Deumal

    Read original paper ↗ ·

  18. Tight-Binding Approach to Pyrazine-Mediated Superexchange in Copper–Pyrazine Antiferromagnets

    Inorganic Chemistry · 2021-07-26

    E. P. Kenny, A. C. Jacko, Benjamin James Powell

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  19. Synthesis and Investigation of Magnetic Properties of Rod Shaped Micron Sized Ni4 and Co2Ni2 Cluster based MOFs

    Zeitschrift für anorganische und allgemeine Chemie · 2021-09-02

    Debal Kanti Singha, S. S. Islam, Chhatan Das, Niyaz Ahmed KC, R. Nath, Partha Mahata

    Read original paper ↗ ·

  20. Berezinskii—Kosterlitz—Thouless correlations in copper-based quasi-2D spin systems (Review Article)

    Low Temperature Physics · 2023-07-01

    D. Opherden, Franz Bartl, Maurits S. J. Tepaske, C.P. Landee, J. Wosnitza, H. Kühne

    Read original paper ↗ ·

  21. Asymmetric phase diagram and dimensional crossover in a system of spin- 12 dimers under applied hydrostatic pressure

    Physical review. B./Physical review. B · 2023-12-26

    Matthew J. Coak, S. P. M. Curley, Z. Hawkhead, J.P. Tidey, David E Graf, Stewart J. Clark, Pinaki Sengupta, Zachary E. Manson, Tom Lancaster, Paul Goddard, Jamie L. Manson

    Read original paper ↗ ·

  22. Enhancing Intramolecular Ferromagnetic Coupling in Tetrathiafulvalene–Nitronyl Nitroxide‐Based Compounds through Spin Polarization Mechanism

    Chemistry - A European Journal · 2024-03-26

    Pau Franquesa-Viñas, Jordi Ribas‐Ariño, Raúl Santiago, Mercè Deumal

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  23. A dynamic Jahn-Teller effect and destructive phase transition of [hexakis(3-bromo-2-pyridone)copper(II)] perchlorate polymorphs

    Journal of Coordination Chemistry · 2025-07-16

    Mathew R. Graci, Mae Palus, Diane A. Dickie, Mark M. Turnbull

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  24. Cu(II) coordination complexes of n-chloro-2-pyridones

    Journal of Coordination Chemistry · 2026-03-30

    Cassidy Palus a, Meghan C. Monk a, Veli Selmani, Louise N. Dawe, Diane A. Dickie, Jan L. Wikaira, Mark M. Turnbull

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