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RESEARCH PAPER · Trends in Chemistry · 2020

Crystal Engineering of Hybrid Coordination Networks: From Form to Function

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Crystal Engineering of Hybrid Coordination Networks: From Form to FunctionOriginalCrystal engineering of porous coordination networks to enable separation of C2 hydrocarbons184Metal–organic frameworks for C 2 H 2 /CO 2 separation86Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of Methane42Ultramicropore Engineering by Dehydration to Enable Molecular Sieving of H2 by Calcium Trimesate45Ultramicropore Engineering by Dehydration to Enable Molecular Sieving of H2 by Calcium Trimesate10A square lattice topology coordination network that exhibits highly selective C2H2/CO2 separation performance12Post-synthetically modified metal–organic frameworks for sensing and capture of water pollutants43Spiers Memorial Lecture: Coordination networks that switch between nonporous and porous structures: an emerging class of soft porous crystals63Amino‐Functionalised Hybrid Ultramicroporous Materials that Enable Single‐Step Ethylene Purification from a Ternary Mixture132Amino‐Functionalised Hybrid Ultramicroporous Materials that Enable Single‐Step Ethylene Purification from a Ternary Mixture13High Purity/Recovery Separation of Propylene from Propyne Using Anion Pillared Metal-Organic Framework: Application of Vacuum Swing Adsorption (VSA)8Advances in adsorptive separation of benzene and cyclohexane by metal-organic framework adsorbents158The “Chemistree” of Porous Coordination Networks: Taxonomic Classification of Porous Solids to Guide Crystal Engineering Studies52Open Framework Material Based Thin Films: Electrochemical Catalysis and State‐of‐the‐art Technologies40Metal-organic frameworks for C6–C8 hydrocarbon separations140Copper(II) 2,2-Bis(Hydroxymethyl)Propionate Coordination Compounds with Hexamethylenetetramine: From Mononuclear Complex to One-Dimensional Coordination Polymer2Efficient Capture of Trace Acetylene by an Ultramicroporous Metal–Organic Framework with Purine Binding Sites38Neutral Nitrogen Donor Ligand‐based MOFs for Sensing Applications28Breaking the trade-off between selectivity and adsorption capacity for gas separation151Harnessing Shape Complementarity for Upgraded Cyclohexane Purification through Adaptive Bottlenecked Pores in an Imidazole‐Containing MOF40Harnessing Shape Complementarity for Upgraded Cyclohexane Purification through Adaptive Bottlenecked Pores in an Imidazole‐Containing MOF1Supramolecular Properties Directed by Weak Interactions in a Copper (II) Complex Based on 8-Hydroxy Quinoline-Pyridine Binary Ligand Systems: Crystal Structure and Hirshfeld Surface Analyses16One-step ethylene production from a four-component gas mixture by a single physisorbent140Highly selective gas separation by two isostructural boron cluster pillared MOFs55Tuning the switching pressure in square lattice coordination networks by metal cation substitution20Avoiding Pyrolysis and Calcination: Advances in the Benign Routes Leading to MOF‐Derived Electrocatalysts28The First Sulfate‐Pillared Hybrid Ultramicroporous Material, SOFOUR‐1‐Zn, and Its Acetylene Capture Properties7The First Sulfate‐Pillared Hybrid Ultramicroporous Material, SOFOUR‐1‐Zn, and Its Acetylene Capture Properties66Low-dimensional compounds containing bioactive ligands. Part XVII: Synthesis, structural, spectral and biological properties of hybrid organic-inorganic complexes based on [PdCl4]2− with derivatives of 8-hydroxyquinolinium9A Review on Anion-Pillared Metal Organic Framework (Apmof) and its Composites with the Balance of Adsorption Capacity and Separation Selectivity for Efficient Gas Separation1Solvatochromism and the effect of solvent on properties in a two-dimensional coordination polymer of cobalt-trimesate15Unblocking a rigid purine MOF for kinetic separation of xylenes17Innovative Separations Research and Development Needs for Advanced Fuel Cycles9A New Cu(II) Metal Complex Template with 4–tert–Butyl-Pyridinium Organic Cation: Synthesis, Structure, Hirshfeld Surface, Characterizations and Antibacterial Activity12Low-dimensional compounds containing bioactive ligands. Part XVIII: Design, synthesis and crystal structural investigations of ionic heteroleptic Pd(II) complexes based on halo and nitro 8-hydroxyquinoline derivatives0Heterojunction between bimetallic metal-organic framework and TiO2: Band-structure engineering for effective photoelectrochemical water splitting29CO2 Capture by Hybrid Ultramicroporous TIFSIX‐3‐Ni under Humid Conditions Using Non‐Equilibrium Cycling15CO2 Capture by Hybrid Ultramicroporous TIFSIX‐3‐Ni under Humid Conditions Using Non‐Equilibrium Cycling60A review on anion-pillared metal–organic frameworks (APMOFs) and their composites with the balance of adsorption capacity and separation selectivity for efficient gas separation102Pillar Modularity in fsc Topology Hybrid Ultramicroporous Materials Based upon Tetra(4-pyridyl)benzene8Crystal Engineering and Photomagnetic Studies of CN-Bridged Coordination Polymers Based on Octacyanidometallates(IV) and [Ni(cyclam)]2+6Negative electrostatic potentials in a Hofmann-type metal-organic framework for efficient acetylene separation113Dense packing of xenon in an ultra-microporous metal–organic framework for benchmark xenon capture and separation33Crystal Engineering of Ionic Cocrystals Sustained by Azolium···Azole Heterosynthons9A Robust Molecular Porous Material for C2H2/CO2 Separation13A novel strategy of post defect modification (PDM) for synthesizing hydrophobic FA-UiO-66-CF3 with enhanced n-hexane vapor adsorption capacity under humidity16Control over Phase Transformations in a Family of Flexible Double Diamondoid Coordination Networks through Linker Ligand Substitution15Optimizing Sieving Effect for CO 2 Capture from Humid Air Using an Adaptive Ultramicroporous Framework26The crystallinity and processability trade-off1Immobilization of purified enzyme EreB in metalorganic framework (MOF) mesopores for erythromycin degradation20Shape‐Memory Effect Enabled by Ligand Substitution and CO2 Affinity in a Flexible SIFSIX Coordination Network27Shape‐Memory Effect Enabled by Ligand Substitution and CO2 Affinity in a Flexible SIFSIX Coordination Network4Preparation of Cu‐BTC@Fe 3 O 4 Composites for the Thermodynamics and Kinetics Performance on Xylene Isomers Adsorption2Efficient C2H2/CO2 and C2H2/C2H4 separations in a novel fluorinated metal–organic framework56Ultramicroporous Lonsdaleite Topology MOF with High Propane Uptake and Propane/Methane Selectivity for Propane Capture from Simulated Natural Gas25Bridging linker installation strategy in the engineering of copper( ii ) complexes: activation of nitriles, efficient catalysts for the cyanosilylation of aldehydes2Crystal engineering of a new platform of hybrid ultramicroporous materials and their C 2 H 2 /CO 2 separation properties16Selective sorting of hexane isomers by anion-functionalized metal-organic frameworks with optimal energy regulation36Cross‐Linking CdSO4‐Type Nets with Hexafluorosilicate Anions to Form an Ultramicroporous Material for Efficient C2H2/CO2 and C2H2/C2H4 Separation7Effect of spacer functional group on the coordination geometry and molecular conformation4Heteroligand Zr-MOFs Explored by Xenon: Active Site Recognition by Synchrotron PXRD, Hyperpolarization NMR, and GCMC Simulations3A new type of C 2 H 2 binding site in a cis -bridging hexafluorosilicate ultramicroporous material that offers trace C 2 H 2 capture4A pcu topology metal–organic framework, Ni(1,4-bib)(inca) 2 , that exhibits high CO 2 /N 2 selectivity and low water vapour affinity2Chemical consolidants for cultural heritage preservation: does crystal engineering have a role to play?3Fine-tuning of gas uptake and selectivity in a hexafluorozirconate pillared coordination network that features two porous phases0Functional flexible adsorbents and their potential utility25Ultramicroporous Al( iii ) MOFs with selective CO 2 adsorption, acid resistance, and efficient Cr( vi ) sorption properties5Water vapour sorption properties of a family of square lattice topology porous coordination networks2An Ultramicroporous Physisorbent Sustained by a Trifecta of Directional Supramolecular Interactions16A Needle in a Haystack: Transient Porosity in a Closed Pore Square Lattice Coordination Network1A Needle in a Haystack: Transient Porosity in a Closed Pore Square Lattice Coordination Network5Synthesis, structural characterization, and computational studies of a novel bis(1-(2-pyrimidyl)piperazinium tetrachlorozincate(II) complex: Insights into electronic properties, molecular docking, and drug-likeness1The Prototypal Diamondoid Topology Hybrid Ultramicroporous Materials and Their Water Vapor Sorption Properties3Crystallographic visualization of C3-hydrocarbon-induced structural transformation and guest encapsulation within a flexible coordination network0Crystal Engineering of Reticular Materials for Gas‐ and Liquid‐Phase Hydrocarbon Separation4Water-Induced Dynamic Structural Adaptivity of Zr-MOF for Holistic Metrics Optimization in Atmospheric Water Harvesting4Crystal Engineering of Chelating Hybrid Ultramicroporous Materials via Pillar Modulation for Energy‐Efficient Acetylene Separation0

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