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RESEARCH PAPER · Inorganic Chemistry · 2010

Novel Noncentrosymmetric Zinc Coordination Polymer Containing an Unusual Zinc Carboxylate−Sulfonate Substructure with a (10,3)-d Topology and Its Second-Harmonic-Generation Properties

Qing‐Yan Liu, Yu‐Ling Wang, Zeng-Mei Shan, Rong Cao, Yun-Liang Jiang, Zujian Wang, Er-Lei Yang

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Novel Noncentrosymmetric Zinc Coordination Polymer Containing an Unusual Zinc Carboxylate−Sulfonate Substructure with a (10,3)-d Topology and Its Second-Harmonic-Generation PropertiesOriginalA disulfide ligand with axial chirality generated in situ for the construction of an unusual hxg topological coordination polymer17From ladder, net to framework: Coordination polymers based on Zn(ii)/Cd(ii) ions and mixed bicarboxyl- and bipyridine-containing linear ligands29New heterometallic frameworks with flexible sulfonate-carboxylate ligand: syntheses, structures, and properties13Topological diversity in zinc coordination polymers with 5-substituted isophthalate and bis(4-pyridylmethyl)piperazine ligands47Two Porous Zinc Coordination Polymers with (10,3) Topological Features Based on a N-Centered Tripodal Ligand and the Conversion of a (10,3)-d Subnet to a (10,3)-a Subnet62Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics1005Metal-organic frameworks with N-(4-pyridylmethyl)iminodiacetate ligand: Synthesis, structure and sorption properties36Nickel coordination polymers with {48.62} and bnn topologies constructed from common square-pyramidal 5-connected nodes19Diversity of Lanthanide(III)–Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties107A 3D Polar Nanotubular Coordination Polymer with Dynamic Structural Transformation and Ferroelectric and Nonlinear-Optical Properties59Zinc(ΙΙ) complexes with 5,6-dihydro-1,4-dithiin-2,3-dicarboxylic anhydrate and differentN-donors: syntheses, crystal structures, and emission properties10Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties31A one-dimensional heterometallic coordination polymer with a three-dimensional supramolecular framework: poly[μ2-aqua-diaqua(2,2′-bipyridyl)(μ5-2-sulfonatobutanedioato)copper(II)sodium(I)]2Noncentrosymmetric Organic Solid and Its Zinc Coordination Polymer with Diamonded Network Prepared from an Ionothermal Reaction: Syntheses, Crystal Structures, and Second-Order Nonlinear Optics Properties58Syntheses, structures, and properties of CdIIand CoIIcomplexes with 5-(pyridin-4-yl)isophthalate11A Non-Centrosymmetric Dual-Emissive Metal–Organic Framework with Distinct Nonlinear Optical and Tunable Photoluminescence Properties78Eight Zn(ii) coordination networks based on flexible 1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates: crystal structures, water clusters, and topologies81Metal–organic framework with two different types of rigid triscarboxylates: net topology and gas sorption behaviour12Towards polynuclear metal complexes with enhanced bioactivities: Synthesis, crystal structures and DNA cleaving activities of CuII, NiII, ZnII, CoII and MnII complexes derived from 4-carboxy-1-(4-carboxybenzyl) pyridinium bromide26First Three-Dimensional Self-Penetrating Coordination Polymer Containing Rare (10,3)-d Subnets: Synthesis, Structure, and Properties30A three-dimensional polymeric potassium complex of 5-sulfonobenzene-1,2,4-tricarboxylic acid: poly[μ-aqua-aqua-μ9-(2,4-dicarboxy-5-sulfonatobenzoato)-dipotassium(I)]2Structures and properties of four coordination polymers constructed from 1,3-bis-(4-pyridyl)-propane and aromatic dicarboxylic acids11Two Cadmium Coordination Compounds with 5‐Sulfonyl‐1,2,4‐benzenetricarboxylate Ligand: Syntheses, Structures, and Photoluminescence8A homochiral Cu(II) coordination polymer built from helical motif based on two V-shaped ligands9Luminescent zinc aliphatic dicarboxylate coordination polymers with bis(4-pyridylmethyl)piperazine: Effect of chain length and steric bulk on topology and water molecule aggregation16Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures30Self-triggered conformations of disulfide ensembles in coordination polymers with multiple metal clusters16Chain, ladder and self-penetrated cobalt and nickel coordination polymers containing sterically bulky isophthalate and long-spanning dipyridylamide ligands9A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO4-type network constructed by carboxylate–sulfonate ligands and strontium ions11Two second-order non-linear optical coordination polymers with noninterpenetrating honeycomb-like 2-D (6,3)-type networks6Utilization of mixed ligands to construct diverse Ni(II)-coordination polymers based on terphenyl-2,2′,4,4′-tetracarboxylic acid and varied N-donor co-ligands7Hydrothermal synthesis, crystal structure, and properties of a novel tetranuclear calcium complex constructed with aromatic sulfonate-carboxylate ligand1Synthesis, structure and properties of a 3D acentric coordination polymer with noninterpenetrated (10,3)-d topology3Terbium-biphenyl-3,3′-disulfonyl-4,4′-dicarboxylate framework with sulfonate sites for luminescent sensing of Cr3+ ion35A luminescent two-fold interpenetrated pillared-layer metal-organic framework for highly selective and sensitive sensing of Fe3+12Evans–Showell-type polyoxometalate constructing novel 3D inorganic architectures with alkaline earth metal linkers: syntheses, structures and catalytic properties17Synthesis and Structural Studies of Three‐Dimensional Supramolecular Motifs Derived from Neutral and Cationic Zinc Alkanesulfonates14A new zinc coordination polymer in (10, 3)-d framework with unusual redox property5A noncentrosymmetric coordination polymer based on the benzophenone-3,3′-disulfonyl-4,4′-dicarboxylate ligand exhibiting second-harmonic-generation responses7A hydrogen-bonded inorganic-organic network with noncentrosymmetric structure exhibiting second-order nonlinear optical response4The effect of coordination habits of metal ions on fabricating metal-organic frameworks with thiophenedicarboxylate9The effect of N-methyl pyrrolidone to modulate the topological structures of metal-organic frameworks1A two-fold interpenetrating metal-organic framework based on [Co4O(COO)6] cluster: Synthesis, crystal structure and catalytic properties7Crystal structure and Hirshfeld surface analysis of diethyl 5-(2-cyanophenoxy)isophthalate3A Zinc(II) Coordination Polymer Based on a Chain of {Zn 2 O 7 } Bitetrahedra Bridged by 3‐Methoxybenzoates2A 3D supramolecular framework assembled via π⋅⋅⋅π interactions and CH⋅⋅⋅Cl hydrogen-bonds with second-harmonic generation response2Synthesis, Crystal Structures, and Properties of Two Compounds Based on Carboxylate-Sulfonate Ligand1Distinct nonlinear optical responses in three pairs of 2D homochiral Ag( i ) enantiomers modulated by dicarboxylic acid ligands25Syntheses, Crystal Structures, and Properties of Four Coordination Compounds with Sulfonate-Naphthol Ligand0From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials9From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials50

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  1. A disulfide ligand with axial chirality generated in situ for the construction of an unusual hxg topological coordination polymer

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  2. From ladder, net to framework: Coordination polymers based on Zn(ii)/Cd(ii) ions and mixed bicarboxyl- and bipyridine-containing linear ligands

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  3. New heterometallic frameworks with flexible sulfonate-carboxylate ligand: syntheses, structures, and properties

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  4. Topological diversity in zinc coordination polymers with 5-substituted isophthalate and bis(4-pyridylmethyl)piperazine ligands

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  5. Two Porous Zinc Coordination Polymers with (10,3) Topological Features Based on a N-Centered Tripodal Ligand and the Conversion of a (10,3)-d Subnet to a (10,3)-a Subnet

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  6. Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics

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  7. Metal-organic frameworks with N-(4-pyridylmethyl)iminodiacetate ligand: Synthesis, structure and sorption properties

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  8. Nickel coordination polymers with {48.62} and bnn topologies constructed from common square-pyramidal 5-connected nodes

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  9. Diversity of Lanthanide(III)–Organic Extended Frameworks with a 4,8-Disulfonyl-2,6-naphthalenedicarboxylic Acid Ligand: Syntheses, Structures, and Magnetic and Luminescent Properties

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  10. A 3D Polar Nanotubular Coordination Polymer with Dynamic Structural Transformation and Ferroelectric and Nonlinear-Optical Properties

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  11. Zinc(ΙΙ) complexes with 5,6-dihydro-1,4-dithiin-2,3-dicarboxylic anhydrate and differentN-donors: syntheses, crystal structures, and emission properties

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  12. Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties

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  13. A one-dimensional heterometallic coordination polymer with a three-dimensional supramolecular framework: poly[μ2-aqua-diaqua(2,2′-bipyridyl)(μ5-2-sulfonatobutanedioato)copper(II)sodium(I)]

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  14. Noncentrosymmetric Organic Solid and Its Zinc Coordination Polymer with Diamonded Network Prepared from an Ionothermal Reaction: Syntheses, Crystal Structures, and Second-Order Nonlinear Optics Properties

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  15. Syntheses, structures, and properties of CdIIand CoIIcomplexes with 5-(pyridin-4-yl)isophthalate

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  16. A Non-Centrosymmetric Dual-Emissive Metal–Organic Framework with Distinct Nonlinear Optical and Tunable Photoluminescence Properties

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  17. Eight Zn(ii) coordination networks based on flexible 1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates: crystal structures, water clusters, and topologies

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  18. Metal–organic framework with two different types of rigid triscarboxylates: net topology and gas sorption behaviour

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  19. Towards polynuclear metal complexes with enhanced bioactivities: Synthesis, crystal structures and DNA cleaving activities of CuII, NiII, ZnII, CoII and MnII complexes derived from 4-carboxy-1-(4-carboxybenzyl) pyridinium bromide

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  20. First Three-Dimensional Self-Penetrating Coordination Polymer Containing Rare (10,3)-d Subnets: Synthesis, Structure, and Properties

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  21. A three-dimensional polymeric potassium complex of 5-sulfonobenzene-1,2,4-tricarboxylic acid: poly[μ-aqua-aqua-μ9-(2,4-dicarboxy-5-sulfonatobenzoato)-dipotassium(I)]

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  22. Structures and properties of four coordination polymers constructed from 1,3-bis-(4-pyridyl)-propane and aromatic dicarboxylic acids

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  23. Two Cadmium Coordination Compounds with 5‐Sulfonyl‐1,2,4‐benzenetricarboxylate Ligand: Syntheses, Structures, and Photoluminescence

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  24. A homochiral Cu(II) coordination polymer built from helical motif based on two V-shaped ligands

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  25. Luminescent zinc aliphatic dicarboxylate coordination polymers with bis(4-pyridylmethyl)piperazine: Effect of chain length and steric bulk on topology and water molecule aggregation

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  26. Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures

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  27. Self-triggered conformations of disulfide ensembles in coordination polymers with multiple metal clusters

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  28. Chain, ladder and self-penetrated cobalt and nickel coordination polymers containing sterically bulky isophthalate and long-spanning dipyridylamide ligands

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  29. A novel second-order non-linear optical coordination polymer with three-fold interpenetrated CdSO4-type network constructed by carboxylate–sulfonate ligands and strontium ions

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  30. Two second-order non-linear optical coordination polymers with noninterpenetrating honeycomb-like 2-D (6,3)-type networks

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  31. Utilization of mixed ligands to construct diverse Ni(II)-coordination polymers based on terphenyl-2,2′,4,4′-tetracarboxylic acid and varied N-donor co-ligands

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  32. Hydrothermal synthesis, crystal structure, and properties of a novel tetranuclear calcium complex constructed with aromatic sulfonate-carboxylate ligand

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  33. Synthesis, structure and properties of a 3D acentric coordination polymer with noninterpenetrated (10,3)-d topology

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  34. Terbium-biphenyl-3,3′-disulfonyl-4,4′-dicarboxylate framework with sulfonate sites for luminescent sensing of Cr3+ ion

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  35. A luminescent two-fold interpenetrated pillared-layer metal-organic framework for highly selective and sensitive sensing of Fe3+

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  36. Evans–Showell-type polyoxometalate constructing novel 3D inorganic architectures with alkaline earth metal linkers: syntheses, structures and catalytic properties

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  37. Synthesis and Structural Studies of Three‐Dimensional Supramolecular Motifs Derived from Neutral and Cationic Zinc Alkanesulfonates

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  38. A new zinc coordination polymer in (10, 3)-d framework with unusual redox property

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  39. A noncentrosymmetric coordination polymer based on the benzophenone-3,3′-disulfonyl-4,4′-dicarboxylate ligand exhibiting second-harmonic-generation responses

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  41. The effect of coordination habits of metal ions on fabricating metal-organic frameworks with thiophenedicarboxylate

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  42. The effect of N-methyl pyrrolidone to modulate the topological structures of metal-organic frameworks

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  49. Syntheses, Crystal Structures, and Properties of Four Coordination Compounds with Sulfonate-Naphthol Ligand

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  50. From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials

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