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RESEARCH PAPER · Chemistry of Materials · 2011

Tl2Hg3Q4 (Q = S, Se, and Te): High-Density, Wide-Band-Gap Semiconductors

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Tl2Hg3Q4 (Q = S, Se, and Te): High-Density, Wide-Band-Gap SemiconductorsOriginalChemInform Abstract: Tl2Hg3Q4 (Q: S, Se, and Te): High‐Density, Wide‐Band‐Gap Semiconductors.0Cationic quaternary chalcohalide nanobelts: Hg4In2Q3Cl8 (Q = S, Se, Te)12Oxygen, sulfur, selenium, tellurium and polonium0Structures and properties of the ternary thallium chalcogenides Tl2MQ3 (M = Zr, Hf; Q = S, Se)8Physico-chemical interaction in the Tl2Se–HgSe–DIVSe2 systems (DIV – Si, Sn)18Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg–In–S–Cl Chalcohalide: Hg7InS6Cl539Crystal Growth and Characterization of the X-ray and γ-ray Detector Material Cs2Hg6S746Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides57CsHgInS3: a New Quaternary Semiconductor for γ-ray Detection60Oxygen, sulfur, selenium, tellurium and polonium3New Quaternary Chalcogenides, Tl18Pb2M7Q25 (M = Ti, Zr, and Hf; Q = S and Se): Crystal Structure, Electronic Structure, and Electrical Transport Properties9CsCdInQ3 (Q = Se, Te): New Photoconductive Compounds As Potential Materials for Hard Radiation Detection55New Metal Chalcogenides Ba4CuGa5Q12 (Q = S, Se) Displaying Strong Infrared Nonlinear Optical Response118Photoconductivity in Tl6SI4: A Novel Semiconductor for Hard Radiation Detection46Cs2MIIMIV3Q8 (Q = S, Se, Te): An Extensive Family of Layered Semiconductors with Diverse Band Gaps96Five New Chalcohalides, Ba3GaS4X (X = Cl, Br), Ba3MSe4Cl (M = Ga, In), and Ba7In2Se6F8: Syntheses, Crystal Structures, and Optical Properties50Crystalline and Glassy Phases in the Cs/Bi/As/S System8A first-principles study on the structural, elastic, electronic, and optical properties of CdRh2O422Manifestation of intrinsic defects in the band structures of quaternary chalcogenide Ag 2 In 2 SiSe 6 and Ag 2 In 2 GeSe 6 crystals14Noncentrosymmetric chalcohalide NaBa 4 Ge 3 S 10 Cl with large band gap and IR NLO response104LiPbSb3S6: A Semiconducting Sulfosalt with Very Low Thermal Conductivity24Crystal Growth of Tl 4 CdI 6 : A Wide Band Gap Semiconductor for Hard Radiation Detection39Syntheses, Structures, and Physical Properties of CsRE2Ag3Te5(RE = Pr, Nd, Sm, Gd–Er) and RbRE2Ag3Te5(RE = Sm, Gd–Dy)18Surfactant-Thermal Syntheses, Structures, and Magnetic Properties of Mn–Ge–Sulfides/Selenides45Investigation of Semi-Insulating Cs2Hg6S7 and Cs2Hg6-xCdxS7 Alloy for Hard Radiation Detection12Synthesis, structures, optical properties and electronic structures of PbGa2Q4 (Q=S, Se) crystals13Second Harmonic Generation Response Optimized at Various Optical Wavelength Ranges through a Series of Cubic Chalcogenides Ba6Ag2.67+4δSn4.33−δS16–xSex41K2Hg2Se3: Large-Scale Synthesis of a Photoconductor Material Prototype with a Columnar Polyanionic Substructure17TlHgInS3: An Indirect-Band-Gap Semiconductor with X-ray Photoconductivity Response21Synthese kristalliner Chalkogenide in ionischen Flüssigkeiten43Synthesis of Crystalline Chalcogenides in Ionic Liquids150Synthesis, crystal and electronic structure, and optical properties of two new chalcogenide-iodides: Ba 3 Q 4 I 2 (Q = S, Se)5Crystal structure of dirubidium trimercury(II) tetraselenide, Rb2Hg3Se40Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds186Electronic structure of layered quaternary chalcogenide materials for band-gap engineering: The example of Cs2MIIM3IVQ814The role of the alkali and chalcogen atoms on the stability of the layered chalcogenide A 2 M I I M 3 I V Q 8 (A = alkali-metal; M = metal-cations; Q = chalcogen) compounds: a density functional theory investigation within van der Waals corrections8Superlight and Superflexible Three‐Dimensional Semiconductor Frameworks A(X≡Y)4 (A=Si, Ge; X/Y=C, B, N) with Tunable Optoelectronic and Mechanical Properties from First‐Principles3Defect Antiperovskite Compounds Hg 3 Q 2 I 2 (Q = S, Se, and Te) for Room-Temperature Hard Radiation Detection72Role of Stoichiometry in the Growth of Large Pb2P2Se6 Crystals for Nuclear Radiation Detection19(C4C1Im)6[Hg7Se10]: The Salt of a Molecular Selenido Mercurate Anion Obtained from Ionic Liquids3Modular Crystal Chemistry of Thallium Sulfosalts24Ultra-low thermal conductivity in Na/Sb chalcobismuthates: synthesis, crystal structures, optical properties and 23 Na NMR spectroscopy2Anti-corrosive surface effect of ascorbic acid caused on the ZnO nanoparticles — Experimental and theoretical investigations6Heterometallic Pb–Ag Iodides from 1‐D Chains to 2‐D Layers Induced by Transition Metal Complex Cations: Syntheses, Crystal Structures, and Photocatalytic Properties14Wide Band Gap Chalcogenide Semiconductors513Wide Band Gap Chalcogenide Semiconductors.420Impact of dyes isomerization effect on the charge transfer phenomenon occurring on the dye/nanosemiconductor interface9The effect of potassium insertion on optoelectronic properties of cadmium chalcogenides16First-principles investigations of metal chalcogenides Tl2Hg3X4(X=S,Se,Te) for advanced optoelectronic and thermoelectric applications20Cubic Stuffed-Diamond Semiconductors LiCu 3 TiQ 4 (Q = S, Se, and Te)17Ba 3 HgGa 2 S 7 : A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg 2 Ga 4 S 14 ] 12– String and Exhibiting a High Photocurrent Response27Layered Zn-based semiconductors K2Zn3S4 and Rb2Zn3Se4: Crystal growth, structure and potential p-type transparent conductivity2Three new low-dimensional organic inorganic hybrid metal halides: Syntheses, structures and properties7Formation of Tellurido Mercurates with Tunable Optical Band Gaps in Ionic Liquids at Room Temperature0

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  1. ChemInform Abstract: Tl2Hg3Q4 (Q: S, Se, and Te): High‐Density, Wide‐Band‐Gap Semiconductors.

    ChemInform · 2011-11-17

    Simon Johnsen, Sebastian Chirambatte Peter, Sandy L. Nguyen, Jung‐Hwan Song, Hosub Jin, Arthur J Freeman, Mercouri G. Kanatzidis

    Read original paper ↗ ·
  2. Cationic quaternary chalcohalide nanobelts: Hg4In2Q3Cl8 (Q = S, Se, Te)

    RSC Advances · 2012-01-01

    Yi Liu, Pushkar D. Kanhere, Yuan Shyuan Hoo, Kaiqi Ye, Qingyu Yan, Rajdeep Singh Rawat, Zhong Chen, Jan Ma, Qichun Zhang

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  3. Oxygen, sulfur, selenium, tellurium and polonium

    Annual Reports Section A (Inorganic Chemistry) · 2012-01-01

    Lucia Myongwon Lee, Ignacio Vargas‐Baca

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  4. Structures and properties of the ternary thallium chalcogenides Tl2MQ3 (M = Zr, Hf; Q = S, Se)

    Dalton Transactions · 2012-01-01

    Cheriyedath Raj Sankar, Bryan A. Kuropatwa, Abdeljalil Assoud, Holger Kleinke

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  5. Physico-chemical interaction in the Tl2Se–HgSe–DIVSe2 systems (DIV – Si, Sn)

    Materials Research Bulletin · 2012-03-29

    M. Yu. Mozolyuk, Л.В. Піскач, A.O. Fedorchuk, Ivan D. Olekseyuk, O.V. Parasyuk

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  6. Synthesis, Crystal Structure, and Optical Properties of a Three-Dimensional Quaternary Hg–In–S–Cl Chalcohalide: Hg7InS6Cl5

    Inorganic Chemistry · 2012-03-29

    Yi Liu, Fengxia Wei, Sing Ning Yeo, Fu Min Lee, Christian Kloc, Qingyu Yan, Huey Hoon Hng, Jan Ma, Qichun Zhang

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  7. Crystal Growth and Characterization of the X-ray and γ-ray Detector Material Cs2Hg6S7

    Crystal Growth & Design · 2012-05-09

    Hao Li, John A. Peters, Zhifu Liu, Maria Sebastian, Christos D. Malliakas, John Androulakis, Li‐Dong Zhao, In Jae Chung, Sandy L. Nguyen, Simon Johnsen, Bruce W. Wessels, Mercouri G. Kanatzidis

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  8. Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides

    Journal of the American Chemical Society · 2012-05-14

    Daniel P. Shoemaker, Duck Young Chung, John F. Mitchell, Travis H. Bray, L. Soderholm, Peter J. Chupas, Mercouri G. Kanatzidis

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  9. CsHgInS3: a New Quaternary Semiconductor for γ-ray Detection

    Chemistry of Materials · 2012-11-12

    Hao Li, Christos D. Malliakas, Zhifu Liu, John A. Peters, Hosub Jin, Collin D. Morris, Li‐Dong Zhao, Bruce W. Wessels, Arthur J Freeman, Mercouri G. Kanatzidis

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  10. Oxygen, sulfur, selenium, tellurium and polonium

    Annual Reports Section A (Inorganic Chemistry) · 2013-01-01

    Lucia Myongwon Lee, Ignacio Vargas‐Baca

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  11. New Quaternary Chalcogenides, Tl18Pb2M7Q25 (M = Ti, Zr, and Hf; Q = S and Se): Crystal Structure, Electronic Structure, and Electrical Transport Properties

    Inorganic Chemistry · 2013-02-01

    Cheriyedath Raj Sankar, Anna Becker, Abdeljalil Assoud, Holger Kleinke

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  12. CsCdInQ3 (Q = Se, Te): New Photoconductive Compounds As Potential Materials for Hard Radiation Detection

    Chemistry of Materials · 2013-05-15

    Hao Li, Christos D. Malliakas, John A. Peters, Zhifu Liu, Jino Im, Hosub Jin, Collin D. Morris, Li‐Dong Zhao, Bruce W. Wessels, Arthur J Freeman, Mercouri G. Kanatzidis

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  13. New Metal Chalcogenides Ba4CuGa5Q12 (Q = S, Se) Displaying Strong Infrared Nonlinear Optical Response

    Chemistry of Materials · 2013-05-15

    Shu‐Ming Kuo, Yu-Ming Chang, In Jae Chung, Joon‐Ik Jang, Bo-Hsian Her, Siao‐Han Yang, John B. Ketterson, Mercouri G. Kanatzidis, Kuei‐Fang Hsu

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  14. Photoconductivity in Tl6SI4: A Novel Semiconductor for Hard Radiation Detection

    Chemistry of Materials · 2013-07-08

    Sandy L. Nguyen, Christos D. Malliakas, John A. Peters, Zhifu Liu, Jino Im, Li‐Dong Zhao, Maria Sebastian, Hosub Jin, Hao Li, Simon Johnsen, Bruce W. Wessels, Arthur J Freeman, Mercouri G. Kanatzidis

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  15. Cs2MIIMIV3Q8 (Q = S, Se, Te): An Extensive Family of Layered Semiconductors with Diverse Band Gaps

    Chemistry of Materials · 2013-08-13

    Collin D. Morris, Hao Li, Hosub Jin, Christos D. Malliakas, John A. Peters, Pantelis N. Trikalitis, Arthur J Freeman, Bruce W. Wessels, Mercouri G. Kanatzidis

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  16. Five New Chalcohalides, Ba3GaS4X (X = Cl, Br), Ba3MSe4Cl (M = Ga, In), and Ba7In2Se6F8: Syntheses, Crystal Structures, and Optical Properties

    Inorganic Chemistry · 2013-09-11

    Kai Feng, Wenlong Yin, Zuohong Lin, Jiyong Yao, Yicheng Wu

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  17. Crystalline and Glassy Phases in the Cs/Bi/As/S System

    Inorganic Chemistry · 2013-09-24

    Tarun K. Bera, Ratnasabapathy G. Iyer, Christos D. Malliakas, Mercouri G. Kanatzidis

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  18. A first-principles study on the structural, elastic, electronic, and optical properties of CdRh2O4

    Journal of Materials Science · 2013-10-21

    Lei Guo, Shengtao Zhang, Wei Feng, Guozhong Hu

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  19. Manifestation of intrinsic defects in the band structures of quaternary chalcogenide Ag 2 In 2 SiSe 6 and Ag 2 In 2 GeSe 6 crystals

    CrystEngComm · 2014-01-01

    M. Makowska-Janusik, Ivan V. Kityk, G.L. Myronchuk, O. Zamuraeva, O.V. Parasyuk

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  20. Noncentrosymmetric chalcohalide NaBa 4 Ge 3 S 10 Cl with large band gap and IR NLO response

    Journal of Materials Chemistry C · 2014-01-01

    Kai Feng, Lei Kang, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  21. LiPbSb3S6: A Semiconducting Sulfosalt with Very Low Thermal Conductivity

    Inorganic Chemistry · 2014-01-09

    Eva C. Agha, Christos D. Malliakas, Jino Im, Hosub Jin, Li‐Dong Zhao, Arthur J Freeman, Mercouri G. Kanatzidis

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  22. Crystal Growth of Tl 4 CdI 6 : A Wide Band Gap Semiconductor for Hard Radiation Detection

    Crystal Growth & Design · 2014-03-20

    Shichao Wang, Zhifu Liu, John A. Peters, Maria Sebastian, Sandy L. Nguyen, Christos D. Malliakas, Constantinos C. Stoumpos, Jino Im, Arthur J Freeman, Bruce W. Wessels, Mercouri G. Kanatzidis

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  23. Syntheses, Structures, and Physical Properties of CsRE2Ag3Te5(RE = Pr, Nd, Sm, Gd–Er) and RbRE2Ag3Te5(RE = Sm, Gd–Dy)

    Inorganic Chemistry · 2014-06-20

    Chang‐Yu Meng, Hong Chen, Peng Wang

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  24. Surfactant-Thermal Syntheses, Structures, and Magnetic Properties of Mn–Ge–Sulfides/Selenides

    Inorganic Chemistry · 2014-09-10

    Guodong Zhang, Pei‐Zhou Li, Junfeng Ding, Yi Liu, Wei‐Wei Xiong, Lina Nie, Tom Wu, Yanli Zhao, Alfred Iing Yoong Tok, Qichun Zhang

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  25. Investigation of Semi-Insulating Cs2Hg6S7 and Cs2Hg6-xCdxS7 Alloy for Hard Radiation Detection

    Crystal Growth & Design · 2014-09-23

    Hao Li, Christos D. Malliakas, Zhifu Liu, John A. Peters, Maria Sebastian, Li‐Dong Zhao, Duck Young Chung, Bruce W. Wessels, Mercouri G. Kanatzidis

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  26. Synthesis, structures, optical properties and electronic structures of PbGa2Q4 (Q=S, Se) crystals

    Journal of Molecular Structure · 2014-11-17

    Kui Wu, Shilie Pan, Hongping Wu, Zhihua Yang

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  27. Second Harmonic Generation Response Optimized at Various Optical Wavelength Ranges through a Series of Cubic Chalcogenides Ba6Ag2.67+4δSn4.33−δS16–xSex

    Chemistry of Materials · 2015-01-30

    Wei-Han Lai, Alyssa S. Haynes, Laszlo Frazer, Yu-Ming Chang, Te-Kun Liu, Jyun-Fan Lin, I. C. Liang, Hwo‐Shuenn Sheu, John B. Ketterson, Mercouri G. Kanatzidis, Kuei‐Fang Hsu

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  28. K2Hg2Se3: Large-Scale Synthesis of a Photoconductor Material Prototype with a Columnar Polyanionic Substructure

    Chemistry of Materials · 2015-05-18

    Günther Thiele, Sina Lippert, Felix Fahrnbauer, Philipp Bron, Oliver Oeckler, Arash Rahimi‐Iman, Martín Koch, Bernhard Roling, Stefanie Dehnen

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  29. TlHgInS3: An Indirect-Band-Gap Semiconductor with X-ray Photoconductivity Response

    Chemistry of Materials · 2015-07-14

    Hao Li, Christos D. Malliakas, Fei Han, Duck Young Chung, Mercouri G. Kanatzidis

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  30. Synthese kristalliner Chalkogenide in ionischen Flüssigkeiten

    Angewandte Chemie · 2015-12-11

    Silke Santner, Johanna Heine, Stefanie Dehnen

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  31. Synthesis of Crystalline Chalcogenides in Ionic Liquids

    Angewandte Chemie International Edition · 2015-12-11

    Silke Santner, Johanna Heine, Stefanie Dehnen

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  32. Synthesis, crystal and electronic structure, and optical properties of two new chalcogenide-iodides: Ba 3 Q 4 I 2 (Q = S, Se)

    Inorganic Chemistry Frontiers · 2015-12-11

    Jian Wang, Kathleen Lee, Kirill A. Kovnir

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  33. Crystal structure of dirubidium trimercury(II) tetraselenide, Rb2Hg3Se4

    Zeitschrift für Kristallographie - New Crystal Structures · 2016-02-09

    Kang–Woo Kim

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  34. Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds

    Chemistry of Materials · 2016-04-05

    Kui Wu, Zhihua Yang, Shilie Pan

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  35. Electronic structure of layered quaternary chalcogenide materials for band-gap engineering: The example of Cs2MIIM3IVQ8

    Physical review. B./Physical review. B · 2016-04-22

    Rafael Besse, Fernando P. Sabino, Juarez L. F. Da Silva

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  36. The role of the alkali and chalcogen atoms on the stability of the layered chalcogenide A 2 M I I M 3 I V Q 8 (A = alkali-metal; M = metal-cations; Q = chalcogen) compounds: a density functional theory investigation within van der Waals corrections

    Journal of Physics Condensed Matter · 2016-11-16

    Rafael Besse, Juarez L. F. Da Silva

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  37. Superlight and Superflexible Three‐Dimensional Semiconductor Frameworks A(X≡Y)4 (A=Si, Ge; X/Y=C, B, N) with Tunable Optoelectronic and Mechanical Properties from First‐Principles

    Chemistry - An Asian Journal · 2017-02-17

    Xinrui Cao, Xiaofei Li, Zi‐Zhong Zhu

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  38. Defect Antiperovskite Compounds Hg 3 Q 2 I 2 (Q = S, Se, and Te) for Room-Temperature Hard Radiation Detection

    Journal of the American Chemical Society · 2017-05-15

    Yihui He, Oleg Y. Kontsevoi, Constantinos C. Stoumpos, Giancarlo G. Trimarchi, Saiful M. Islam, Zhifu Liu, Svetlana S. Kostina, Sanjib Das, Joon-Il Kim, Wenwen Lin, Bruce W. Wessels, Mercouri G. Kanatzidis

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  39. Role of Stoichiometry in the Growth of Large Pb2P2Se6 Crystals for Nuclear Radiation Detection

    ACS Photonics · 2017-11-17

    Yadong Xu, Xu Fu, Hongjian Zheng, Yihui He, Wenwen Lin, Kyle M. McCall, Zhifu Liu, Sanjib Das, Bruce W. Wessels, Mercouri G. Kanatzidis

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  40. (C4C1Im)6[Hg7Se10]: The Salt of a Molecular Selenido Mercurate Anion Obtained from Ionic Liquids

    Zeitschrift für anorganische und allgemeine Chemie · 2018-08-02

    Carsten Donsbach, Stefanie Dehnen

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  41. Modular Crystal Chemistry of Thallium Sulfosalts

    Minerals · 2018-10-24

    Emil Makovicky

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  42. Ultra-low thermal conductivity in Na/Sb chalcobismuthates: synthesis, crystal structures, optical properties and 23 Na NMR spectroscopy

    New Journal of Chemistry · 2019-01-01

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  43. Anti-corrosive surface effect of ascorbic acid caused on the ZnO nanoparticles — Experimental and theoretical investigations

    Applied Surface Science · 2019-03-30

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  44. Heterometallic Pb–Ag Iodides from 1‐D Chains to 2‐D Layers Induced by Transition Metal Complex Cations: Syntheses, Crystal Structures, and Photocatalytic Properties

    European Journal of Inorganic Chemistry · 2019-10-30

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  45. Wide Band Gap Chalcogenide Semiconductors

    Chemical Reviews · 2020-04-06

    Rachel Woods-Robinson, Yanbing Han, Hanyu Zhang, Tursun Ablekim, Imran Khan, Kristin Aslaug Persson, Andriy Zakutayev

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  46. Wide Band Gap Chalcogenide Semiconductors.

    eScholarship (California Digital Library) · 2020-05-01

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  47. Impact of dyes isomerization effect on the charge transfer phenomenon occurring on the dye/nanosemiconductor interface

    Solar Energy Materials and Solar Cells · 2020-09-07

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  48. The effect of potassium insertion on optoelectronic properties of cadmium chalcogenides

    Materials Science in Semiconductor Processing · 2020-10-01

    Imad Khan, Akbar Ali, Izaz Ul Haq, Shah Abdul Aziz, Zahid Ali, Iftikhar Ahmad

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  49. First-principles investigations of metal chalcogenides Tl2Hg3X4(X=S,Se,Te) for advanced optoelectronic and thermoelectric applications

    Journal of Solid State Chemistry · 2022-05-14

    Wilayat Khan, Haleem Ud Din, Sikander Azam, Riadh Neffati

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  50. Cubic Stuffed-Diamond Semiconductors LiCu 3 TiQ 4 (Q = S, Se, and Te)

    Journal of the American Chemical Society · 2022-07-07

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