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RESEARCH PAPER · Inorganic Chemistry · 2011

LiGaGe2Se6: A New IR Nonlinear Optical Material with Low Melting Point

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LiGaGe2Se6: A New IR Nonlinear Optical Material with Low Melting PointOriginalChemInform Abstract: LiGaGe2Se6: A New IR Nonlinear Optical Material with Low Melting Point.0Synthesis, Structure, and Properties of Li2In2MQ6 (M = Si, Ge; Q = S, Se): A New Series of IR Nonlinear Optical Materials125Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides57Syntheses, Structures, Optical and Magnetic Properties of Ba2MLnSe5(M = Ga, In;Ln= Y, Nd, Sm, Gd, Dy, Er)54A New Mixed Halide, Cs2HgI2Cl2: Molecular Engineering for a New Nonlinear Optical Material in the Infrared Region145Synthesis, structural characterization and optical properties of new compounds: Centrosymmetric Ba2GaMQ5 (M=Sb,Bi; Q=Se,Te), Ba2InSbTe5 and noncentrosymmetric Ba2InSbSe533Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation85Hg2Br3I: a new mixed halide nonlinear optical material in the infrared region28Syntheses, Structures, and Nonlinear Optical Properties of Quaternary Chalcogenides: Pb4Ga4GeQ12 (Q = S, Se)60Nonlinear Active Materials: An Illustration of Controllable Phase Matchability113Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12219Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680Ba8Sn4S15: A Strong Second Harmonic Generation Sulfide with Zero-Dimensional Crystal Structure106Noncentrosymmetric chalcohalide NaBa 4 Ge 3 S 10 Cl with large band gap and IR NLO response104Synthesis, Structure and Bonding, Optical Properties of Ba4MTrQ6 (M=Cu, Ag; Tr=Ga, In; Q=S, Se)18Ag 3 Ga 3 SiSe 8 : a new infrared nonlinear optical material with a chalcopyrite structure34Recherche et élaboration de nouveaux matériaux pour les applications laser non-linéaires du moyen infrarouge0Syntheses, Structures, and Nonlinear-Optical Properties of Metal Sulfides Ba2Ga8MS16 (M = Si, Ge)94Designing the syntheses and photophysical simulations of noncentrosymmetric compounds17An investigation of new infrared nonlinear optical material: BaCdSnSe 4 , and three new related centrosymmetric compounds: Ba 2 SnSe 4 , Mg 2 GeSe 4 , and Ba 2 Ge 2 S 696Ba 2 GeS 4 and Mg 2 SnS 4 : synthesis, structures, optical properties and electronic structures41Phase-Change Behavior and Nonlinear Optical Second and Third Harmonic Generation of the One-Dimensional K(1–x)CsxPSe6 and Metastable β-CsPSe662Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Sn2SiS4, synthesis, structure, optical and electronic properties18Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 2018BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties97The structure and band gap design of high Si doping level Ag1−xGa1−xSixSe2 (x=1/2)15Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302Crystal Growth, Structure, and Optical Properties of LiGaGe2Se636Electronic structure and optical properties of noncentrosymmetric LiGaGe 2 Se 6 , a promising nonlinear optical material27Recent studies of nonlinear chalcogenide crystals for the mid-IR148Recent achievements on middle and far-infrared second-order nonlinear optical materials433Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity44Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters8Wide band gap design of new chalcogenide compounds: KSrPS 4 and CsBaAsS 422Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds101Electronic structure and optical properties of noncentrosymmetric LiGaSe 2 : Experimental measurements and DFT band structure calculations36Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases208Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties17AgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response78New quaternary thallium indium germanium selenide TlInGe 2 Se 6 : Crystal and electronic structure20Li2MnSnSe4: A New Quaternary Diamond‐Like Semiconductor with Nonlinear Optical Response and Antiferromagnetic Property16LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point56Electronic structure and laser induced piezoelectricity of a new quaternary compound TlInGe3S815Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge39Thallium indium germanium sulphide (TlInGe2S6) as efficient material for nonlinear optical application20K 2 MnGe 3 S 8 : a new multifunctional semiconductor featuring [MnGe 3 S 8 ] 2− layers and demonstrating interesting nonlinear optical response and antiferromagnetic properties33New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold142From AgGaS2 to Li2ZnSiS4: Realizing Impressive High Laser Damage Threshold Together with Large Second-Harmonic Generation Response134Li7Cd4.5Ge4Se16 and Li6.4Cd4.8Sn4Se16: Strong Nonlinear Optical Response in Quaternary Diamond‐Like Selenide Networks10Four two-dimensional ternary selenides based on group 13 and 14 metals: Syntheses, crystal structures, and electrochemical properties6Electronic structure and optical properties of LiGa0.5In0.5Se2 single crystal, a nonlinear optical mid-IR material12Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations61Prediction and Characterization of NaGaS2, A High Thermal Conductivity Mid-Infrared Nonlinear Optical Material for High-Power Laser Frequency Conversion38TlInGe2S6, A Prospective Nonlinear Optical Material: First-Principles DFT Calculations of the Electronic Structure and Optical Properties14Structure and Optical Properties of the Li2In2GeSe6 Crystal13Synthesis and Characterization of Ag2MnSnS4, a New Diamond‐like Semiconductor14First-principles DFT calculations of the electronic structure and optical properties of TlInGe2Se6, a prospective NLO material24Zn 3 P 2 S 8 : A Promising Infrared Nonlinear-Optical Material with Excellent Overall Properties70Recent advances and future perspectives on infrared nonlinear optical metal halides223Electronic, bonding and optical properties of the LiGaGe2X6 (X = S, Se, and Te) compounds: An ab initio study2Recherche et élaboration de nouveaux matériaux pour les applications laser non-linéaires du moyen infrarouge0Recent progress on new infrared nonlinear optical materials with application prospect133Electronic band structure and basic optical constants of TlGaSn2Se6, a promising NLO semiconductor: First-principles calculations under DFT framework12SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance20Broadening Frontiers of Infrared Nonlinear Optical Materials with π-Conjugated Trigonal-Planar Groups67MnSiP2: A New Mid-IR Ternary Phosphide with Strong SHG Effect and Ultrabroad Transparency Range66Effect of S and Se replacement on electronic and thermoelectric features of BaCu2GeQ4 (Q = S, Se) chalcogenide crystals27Growth and physicochemical investigations on wide bandgap 2D polymeric amino acetic acid sulfato dilithium metal–organic framework1Synthesis, Structure, and Characterization of Two Mixed-Cation Quaternary Chalcogenides K2BaSnQ4 (Q = S, Se)19LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition12Vibration uncoupling of germanium with different valence states lowers thermal conductivity of Cs2Ge3Ga6Se1410Investigation of structural, mechanical, dynamic, electronic and optical properties of seleno-germanates A 2 GeSe 4 (A = Mg, Ca and γ -Sr) from first principles7Rational design of infrared nonlinear optical chalcogenides by chemical substitution287A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties59Non-centrosymmetric sulfides A 2 Ba 6 MnSn 4 S 16 (A = Li, Ag): syntheses, structures and properties21Optical and electronic properties of lithium thiogallate (LiGaS 2 ): experiment and theory25PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material120KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19Synthesis of WSe2 Nanorods by Selenium Powder Precursor for Photocatalytic Application and Fuel Additive20Layered and Cubic Semiconductors AGaM′Q4 (A+ = K+, Rb+, Cs+, Tl+; M′4+ = Ge4+, Sn4+; Q2– = S2–, Se2–) and High Third-Harmonic Generation29Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75Bi 32 Cd 3 P 10 O 76 : a new congruently melting nonlinear optical crystal with a large SHG response and a wide transparent region24Crystal growth and thermal annealing of AgGaGe5Se12 crystal10Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system3Preparation of 0–2 dimensional organic-decorated quaternary TM-Cd-Sb-Se (TM = Zn, Mn, Fe) compounds by solvothermal method: Syntheses, crystal structures and properties9Two ternary antimony-chalcogenides of Cs4Sb4S8 and Cs3Sb5Se913Vast Structural and Polymorphic Varieties of Semiconductors AMM′Q4 (A = K, Rb, Cs, Tl; M = Ga, In; M′ = Ge, Sn; Q = S, Se)10β-BaGa 4 Se 7 : a promising IR nonlinear optical crystal designed by predictable structural rearrangement46Impact of structure complexity on optoelectronic and non-linear optical properties in quaternary Ag(Pb)–Ga(In)–Si(Ge)–S(Se) systems13Cs2Bi2OSi2O7: A Promising Bismuth Silicate Nonlinear Optical Crystal with Face-Sharing BiO5 Polyhedra Exhibiting Strengthened Second Harmonic Generation Response and Birefringence43Crystal Growth, Characterization, and Thermal Annealing of Nonlinear Optical Crystals AgGaGenSe2(n+1) (n = 1.5, 1.75, 2, 3, 4, 5, and 9) for Mid-infrared Applications12AgGaGeSe4: An Infrared Nonlinear Quaternary Selenide with Good Performance6Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal19AInSn2S6 (A = K, Rb, Cs)─Layered Semiconductors Based on the SnS2 Structure6Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Electronic band structure and optical properties of Li2In2GeSe6 crystal6Efficient Synthesis, Spectroscopic Characterization, and Nonlinear Optical Properties of Novel Salicylaldehyde-Based Thiosemicarbazones: Experimental and Theoretical Studies37Crystal Growth, Thermal Treatment, and Characterization of Nonlinear Optical Crystal LiGa0.5In0.5Se2 for Mid-infrared Applications8Syntheses, crystal structure and properties of two chalcogenidoantimonates Mn(en)3Sb2S4 and Co(en)3Sb2Se48The compatibly large nonlinear optical effect and high laser-induced damage threshold in a thiophosphate CsInP2S7 constructed with [P2S7]4- and [InS6]9-15Insights into the optoelectronic, thermodynamic, and thermoelectric properties of novel BaYCuX3 (X = Se, Te) semiconductors from first-principles investigation3First-Principles Study of the Mechanical, Electronic, and Optical Properties of Ternary Chalcogenide Compounds5The electronic structure, optical, and transport properties of novel SrScCu3M4 (M = Se, Te) semiconductors4Five Transition Metal-Mixed Germanium Chalcogenide Materials: Solvothermal Syntheses, Crystal Structures, Photoelectric Response Properties, and Ion-Exchange Properties3Li-based ternary semiconductors: Probing electronic, mechanical, optical, and transport nature from first principles study7SrZnGeSe4: An Infrared Nonlinear Optical Crystal Material with Wide Transmission Range and Large SHG Response7CsGaGe₃Se₈: Enhanced optical anisotropy and bandgap via cation-substitution-driven dimensionality reduction0

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  1. ChemInform Abstract: LiGaGe2Se6: A New IR Nonlinear Optical Material with Low Melting Point.

    ChemInform · 2012-02-23

    Dajiang Mei, Wenlong Yin, Kai Feng, Zheshuai Lin, Lei Bai, Jiyong Yao, Yicheng Wu

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  2. Synthesis, Structure, and Properties of Li2In2MQ6 (M = Si, Ge; Q = S, Se): A New Series of IR Nonlinear Optical Materials

    Inorganic Chemistry · 2012-05-04

    Wenlong Yin, Kai Feng, Wenyu Hao, Jiyong Yao, Yicheng Wu

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  3. Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides

    Journal of the American Chemical Society · 2012-05-14

    Daniel P. Shoemaker, Duck Young Chung, John F. Mitchell, Travis H. Bray, L. Soderholm, Peter J. Chupas, Mercouri G. Kanatzidis

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  4. Syntheses, Structures, Optical and Magnetic Properties of Ba2MLnSe5(M = Ga, In;Ln= Y, Nd, Sm, Gd, Dy, Er)

    Inorganic Chemistry · 2012-06-06

    Wenlong Yin, Kai Feng, Wendong Wang, Youguo Shi, Wenyu Hao, Jiyong Yao, Yicheng Wu

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  5. A New Mixed Halide, Cs2HgI2Cl2: Molecular Engineering for a New Nonlinear Optical Material in the Infrared Region

    Journal of the American Chemical Society · 2012-08-15

    Gang Zhang, Yanjun Li, Kui Jiang, Hui‐Yi Zeng, Tao Liu, Xingguo Chen, Jingui Qin, Zheshuai Lin, Peizhen Fu, Yicheng Wu, Chuangtian Chen

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  6. Synthesis, structural characterization and optical properties of new compounds: Centrosymmetric Ba2GaMQ5 (M=Sb,Bi; Q=Se,Te), Ba2InSbTe5 and noncentrosymmetric Ba2InSbSe5

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    Wenyu Hao, Dajiang Mei, Wenlong Yin, Kai Feng, Jiyong Yao, Yicheng Wu

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  7. Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation

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    Collin D. Morris, In Jae Chung, Sungoh Park, Connor M. Harrison, Daniel J. Clark, Joon Ik Jang, Mercouri G. Kanatzidis

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  8. Hg2Br3I: a new mixed halide nonlinear optical material in the infrared region

    CrystEngComm · 2013-01-01

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  9. Syntheses, Structures, and Nonlinear Optical Properties of Quaternary Chalcogenides: Pb4Ga4GeQ12 (Q = S, Se)

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  10. Nonlinear Active Materials: An Illustration of Controllable Phase Matchability

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  11. Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12

    Journal of the American Chemical Society · 2013-07-31

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  12. Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials

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  13. Ba8Sn4S15: A Strong Second Harmonic Generation Sulfide with Zero-Dimensional Crystal Structure

    Chemistry of Materials · 2013-12-17

    Zhong‐Zhen Luo, Chensheng Lin, Weilong Zhang, Hao Zhang, Zhangzhen He, Wen‐Dan Cheng

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  14. Noncentrosymmetric chalcohalide NaBa 4 Ge 3 S 10 Cl with large band gap and IR NLO response

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  15. Synthesis, Structure and Bonding, Optical Properties of Ba4MTrQ6 (M=Cu, Ag; Tr=Ga, In; Q=S, Se)

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    Xiao‐Wu Lei, Min Yang, Sheng‐Qing Xia, Xiao‐Cun Liu, Mingyan Pan, Xin Li, Xu‐Tang Tao

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  16. Ag 3 Ga 3 SiSe 8 : a new infrared nonlinear optical material with a chalcopyrite structure

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  17. Recherche et élaboration de nouveaux matériaux pour les applications laser non-linéaires du moyen infrarouge

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  18. Syntheses, Structures, and Nonlinear-Optical Properties of Metal Sulfides Ba2Ga8MS16 (M = Si, Ge)

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  19. Designing the syntheses and photophysical simulations of noncentrosymmetric compounds

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  20. An investigation of new infrared nonlinear optical material: BaCdSnSe 4 , and three new related centrosymmetric compounds: Ba 2 SnSe 4 , Mg 2 GeSe 4 , and Ba 2 Ge 2 S 6

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  21. Ba 2 GeS 4 and Mg 2 SnS 4 : synthesis, structures, optical properties and electronic structures

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  22. Phase-Change Behavior and Nonlinear Optical Second and Third Harmonic Generation of the One-Dimensional K(1–x)CsxPSe6 and Metastable β-CsPSe6

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  23. Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7

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  24. Sn2SiS4, synthesis, structure, optical and electronic properties

    Optical Materials · 2015-06-15

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  25. Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis

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  26. Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 20

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  27. BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties

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  28. The structure and band gap design of high Si doping level Ag1−xGa1−xSixSe2 (x=1/2)

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  29. Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold

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  30. Crystal Growth, Structure, and Optical Properties of LiGaGe2Se6

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  31. Electronic structure and optical properties of noncentrosymmetric LiGaGe 2 Se 6 , a promising nonlinear optical material

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  32. Recent studies of nonlinear chalcogenide crystals for the mid-IR

    Semiconductor Science and Technology · 2016-10-26

    L. I. Isaenko, Alexander Yèlisseyev

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  33. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

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  34. Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity

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  35. Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters

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  36. Wide band gap design of new chalcogenide compounds: KSrPS 4 and CsBaAsS 4

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  37. Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds

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  38. Electronic structure and optical properties of noncentrosymmetric LiGaSe 2 : Experimental measurements and DFT band structure calculations

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  39. Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases

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  40. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

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  41. Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties

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  42. AgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response

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  43. New quaternary thallium indium germanium selenide TlInGe 2 Se 6 : Crystal and electronic structure

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  44. Li2MnSnSe4: A New Quaternary Diamond‐Like Semiconductor with Nonlinear Optical Response and Antiferromagnetic Property

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  45. LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point

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  46. Electronic structure and laser induced piezoelectricity of a new quaternary compound TlInGe3S8

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  47. Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2017-11-13

    Jiang-He Feng, Chun‐Li Hu, Houping Xia, Fang Kong, Jiang‐Gao Mao

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  48. Thallium indium germanium sulphide (TlInGe2S6) as efficient material for nonlinear optical application

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    Oleg Yu Khyzhun, Volodymyr Babizhetskyy, Ivan V. Kityk, G.L. Myronchuk, Jarosław Jedryka, Gandham Lakshminarayana, Volodymyr Levytskyy, Oksana Tsisar, Л.В. Піскач, O.V. Parasyuk, A.M. El Naggar, A.A. Albassam, Michał Piasecki

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  49. K 2 MnGe 3 S 8 : a new multifunctional semiconductor featuring [MnGe 3 S 8 ] 2− layers and demonstrating interesting nonlinear optical response and antiferromagnetic properties

    Journal of Materials Chemistry C · 2018-01-01

    Zhuang Li, Xingxing Jiang, Changjiang Yi, Molin Zhou, Yangwu Guo, Xiaoyu Luo, Zheshuai Lin, Yicheng Wu, Youguo Shi, Jiyong Yao

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  50. New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold

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