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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2010

Syntheses and Physicochemical Properties of Low‐Melting Salts Based on VOF4– and MoOF5–, and the Molecular Geometries of the Dimeric (VOF4–)2 and Mo2O4F62– Anions

Takatsugu Kanatani, Kazuhiko Matsumoto, Rika Hagiwara

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Syntheses and Physicochemical Properties of Low‐Melting Salts Based on VOF4– and MoOF5–, and the Molecular Geometries of the Dimeric (VOF4–)2 and Mo2O4F62– AnionsOriginalChemistry of polynuclear transition-metal complexes in ionic liquids66Electrochemical behavior of hexafluoroniobate, heptafluorotungstate, and oxotetrafluorovanadate anions in N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide room temperature ionic liquid4Novel Fluoroanion Salts0“Fluoride molecular scissors”: A rational construction of new Mo(VI) oxofluorido/1,2,4-triazole MOFs16Ionic Liquids: New Perspectives for Inorganic Synthesis?318Ionische Flüssigkeiten – neue Perspektiven für die anorganische Synthesechemie?71[(Ph)3PBr][Br7], [(Bz)(Ph)3P]2[Br8], [(n-Bu)3MeN]2[Br20], [C4MPyr]2[Br20], and [(Ph)3PCl]2[Cl2I14]: Extending the Horizon of Polyhalides via Synthesis in Ionic Liquids73Lead Fluoridooxidovanadates(V), Pb(V 2 O 2 F 8 ), Pb(VOF 5 ), and Mixed Valent Fluoridooxidovanadate(IV, V), Pb 3 F(V 4 O 3 F 18 )4Preparation of Ionic Liquids of Fluorocomplex and Oxofluorocomplex Anions by Fluoroacid–Base Reactions0Synthesis and crystal structures of (pyH)2[Mo2O4F6] and (pipH2)[Mo2O4F6]; vibrational band assignment for [Mo2O4F6]2− anion4Mononuclear anionic AO 2 X 3 compounds with non-VSEPR structure3Fluorohydrogenate Ionic Liquids, Liquid Crystals, and Plastic Crystals4Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 617Hydroxylammonium Tetrafluoridooxidovanadate(V) – (NH3OH)[VOF4]4Crystallography of Ionic Liquids10Ionic conductivities of 1-ethyl-3-methylimidazolium oxopentafluoromolybdate0Ionic Liquid Materials Based on Fluoroanions1Complexes of molybdenum(VI) oxide tetrafluoride and molybdenum(VI) dioxide difluoride with neutral N- and O-donor ligands14Polyoxometalate catalysts for biomass dissolution: understanding and design1Reactivity of VOF3 with N-Heterocyclic Carbene and Imidazolium Fluoride: Analysis of Ligand–VOF3 Bonding with Evidence of a Minute π Back-Donation of Fluoride16Critical Properties of Metal-Containing Ionic Liquids20Chromium Oxide Tetrafluoride and Its Reactions with Xenon Hexafluoride; the [XeF 5 ] + and [Xe 2 F 11 ] + Salts of the [Cr VI OF 5 ] − , [Cr V OF 5 ] 2− , [Cr V 2 O 2 F 8 ] 2− , and [Cr IV F 6 ] 2− Anions12Group 6 Oxyfluoro‐Anion Salts of [XeF5]+ and [Xe2F11]+: Syntheses and Structures of [XeF5][M2O2F9] (M=Mo, W), [Xe2F11][M′OF5] (M′=Cr, Mo, W), [XeF5][HF2]⋅CrOF4, and [XeF5][WOF5]⋅XeOF417Chromium(VI) Oxyfluoride Dianions, [Cr2O4F6]2− and [CrO2F4]2−; Syntheses and Structures of [XeF5]2[Cr2O4F6], [XeF5]2[Cr2O4F6] ⋅ nX (X=HF, n=4; X=XeOF4, n=2), and [XeF5][Xe2F11][CrO2F4]1

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  1. Chemistry of polynuclear transition-metal complexes in ionic liquids

    Dalton Transactions · 2011-01-01

    Ejaz Ahmed, Michael Ruck

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  2. Electrochemical behavior of hexafluoroniobate, heptafluorotungstate, and oxotetrafluorovanadate anions in N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide room temperature ionic liquid

    Journal of Fluorine Chemistry · 2011-02-26

    Takatsugu Kanatani, Kazuhiko Matsumoto, Toshiyuki Nohira, Rika Hagiwara

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  3. Novel Fluoroanion Salts

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    Rika Hagiwara, Kazuhiko Matsumoto

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  4. “Fluoride molecular scissors”: A rational construction of new Mo(VI) oxofluorido/1,2,4-triazole MOFs

    Inorganic Chemistry Communications · 2011-06-03

    Ganna A. Senchyk, A.B. Lysenko, Harald Krautscheid, K.V. Domasevitch

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  5. Ionic Liquids: New Perspectives for Inorganic Synthesis?

    Angewandte Chemie International Edition · 2011-10-11

    Dominic Freudenmann, Silke Wolf, Michael F. Wolff, Claus Feldmann

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  6. Ionische Flüssigkeiten – neue Perspektiven für die anorganische Synthesechemie?

    Angewandte Chemie · 2011-10-11

    Dominic Freudenmann, Silke Wolf, Michael Wolff, Claus Feldmann

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  7. [(Ph)3PBr][Br7], [(Bz)(Ph)3P]2[Br8], [(n-Bu)3MeN]2[Br20], [C4MPyr]2[Br20], and [(Ph)3PCl]2[Cl2I14]: Extending the Horizon of Polyhalides via Synthesis in Ionic Liquids

    Inorganic Chemistry · 2011-10-25

    Michael F. Wolff, Alexander Okrut, Claus Feldmann

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  8. Lead Fluoridooxidovanadates(V), Pb(V 2 O 2 F 8 ), Pb(VOF 5 ), and Mixed Valent Fluoridooxidovanadate(IV, V), Pb 3 F(V 4 O 3 F 18 )

    Zeitschrift für anorganische und allgemeine Chemie · 2012-06-20

    Matic Lozinšek, Evgeny Goreshnik, Boris Žemva

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  9. Preparation of Ionic Liquids of Fluorocomplex and Oxofluorocomplex Anions by Fluoroacid–Base Reactions

    Unknown journal · 2012-10-14

    Kazuhiko Matsumoto, Rika Hagiwara

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  10. Synthesis and crystal structures of (pyH)2[Mo2O4F6] and (pipH2)[Mo2O4F6]; vibrational band assignment for [Mo2O4F6]2− anion

    Journal of Fluorine Chemistry · 2013-10-26

    Gleb Veryasov, Dmitry I. Morozov, Evgeny Goreshnik, Adolf Jesih

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  11. Mononuclear anionic AO 2 X 3 compounds with non-VSEPR structure

    Dalton Transactions · 2014-01-01

    M.A. Garcia-Monforte, Miguel Baya, M. Pilar Betoré, Antonio Martı́n, Babil Menjón

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  12. Fluorohydrogenate Ionic Liquids, Liquid Crystals, and Plastic Crystals

    Elsevier eBooks · 2015-01-01

    Kazuhiko Matsumoto, Rika Hagiwara

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  13. Synthetic strategies for new vanadium oxyfluorides containing novel building blocks: structures of V( iv ) and V( v ) containing Sr 4 V 3 O 5 F 13 , Pb 7 V 4 O 8 F 18 , Pb 2 VO 2 F 5 , and Pb 2 VOF 6

    CrystEngComm · 2015-01-01

    Jeongho Yeon, Justin B. Felder, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

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  14. Hydroxylammonium Tetrafluoridooxidovanadate(V) – (NH3OH)[VOF4]

    Acta chimica slovenica · 2015-06-15

    Matic Lozinšek

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  15. Crystallography of Ionic Liquids

    Unknown journal · 2015-12-11

    Neil Winterton

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  16. Ionic conductivities of 1-ethyl-3-methylimidazolium oxopentafluoromolybdate

    Springer eBooks · 2016-01-01

    Rudolf Holze

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  17. Ionic Liquid Materials Based on Fluoroanions

    Elsevier eBooks · 2017-01-01

    Kazuhiko Matsumoto, Rika Hagiwara

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  18. Complexes of molybdenum(VI) oxide tetrafluoride and molybdenum(VI) dioxide difluoride with neutral N- and O-donor ligands

    Journal of Fluorine Chemistry · 2017-06-29

    William Levason, Francesco M. Monzittu, Gillian Reid, Wenjian Zhang, Eric G. Hope

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  19. Polyoxometalate catalysts for biomass dissolution: understanding and design

    Physical Sciences Reviews · 2018-05-31

    Steven P. Kelley, Paula Bertón, Andreas Metlen, Robin Don Rogers

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  20. Reactivity of VOF3 with N-Heterocyclic Carbene and Imidazolium Fluoride: Analysis of Ligand–VOF3 Bonding with Evidence of a Minute π Back-Donation of Fluoride

    Inorganic Chemistry · 2018-10-24

    Žiga Zupanek, Melita Tramšek, Anton Kokalj, Gašper Tavčar

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  21. Critical Properties of Metal-Containing Ionic Liquids

    Industrial & Engineering Chemistry Research · 2019-04-02

    José Omar Valderrama, Luis A. Forero, Roberto E. Rojas

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  22. Chromium Oxide Tetrafluoride and Its Reactions with Xenon Hexafluoride; the [XeF 5 ] + and [Xe 2 F 11 ] + Salts of the [Cr VI OF 5 ] − , [Cr V OF 5 ] 2− , [Cr V 2 O 2 F 8 ] 2− , and [Cr IV F 6 ] 2− Anions

    Chemistry - A European Journal · 2019-08-22

    James T. Goettel, Mark R. Bortolus, Daniel Stuart, Hélène P. A. Mercier, Gary J. Schrobilgen

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  23. Group 6 Oxyfluoro‐Anion Salts of [XeF5]+ and [Xe2F11]+: Syntheses and Structures of [XeF5][M2O2F9] (M=Mo, W), [Xe2F11][M′OF5] (M′=Cr, Mo, W), [XeF5][HF2]⋅CrOF4, and [XeF5][WOF5]⋅XeOF4

    Chemistry - A European Journal · 2020-03-30

    Mark R. Bortolus, Hélène P. A. Mercier, Gary J. Schrobilgen

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  24. Chromium(VI) Oxyfluoride Dianions, [Cr2O4F6]2− and [CrO2F4]2−; Syntheses and Structures of [XeF5]2[Cr2O4F6], [XeF5]2[Cr2O4F6] ⋅ nX (X=HF, n=4; X=XeOF4, n=2), and [XeF5][Xe2F11][CrO2F4]

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    Mark R. Bortolus, Hélène P. A. Mercier, Gary J. Schrobilgen

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