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RESEARCH PAPER · Chemical Reviews · 2014

Crystal Chemistry and Selected Physical Properties of Inorganic Fluorides and Oxide-Fluorides

M. Leblanc, V. Maisonneuve, A. Tressaud

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Crystal Chemistry and Selected Physical Properties of Inorganic Fluorides and Oxide-FluoridesOriginalIonic conductivity of Dion-Jacobson type oxide LiLaTa2O7 and oxynitride LiLaTa2O6.15N0.57 measured by impedance spectroscopy15Influence of Na + ion doping on the phase change and upconversion emissions of the GdF 3 : Yb 3+ , Tm 3+ nanocrystals obtained from the designed molecular precursors28Investigations on the rate performance of LiFePO 4 /CeO 2 composite materials via polyol technique for rechargeable lithium batteries14Li + intercalation in isostructural Li 2 VO 3 and Li 2 VO 2 F with O 2− and mixed O 2− /F − anions84Understanding ferroelectricity in layered perovskites: new ideas and insights from theory and experiments290Synthesis and Application of Nanohybrids Based on Upconverting Nanoparticles and Polymers75Fluoride-coordination chemistry in molecular and low-dimensional magnetism67Large Negative Thermal Expansion and Anomalous Behavior on Compression in Cubic ReO3-Type AIIBIVF6: CaZrF6 and CaHfF6112NaF-KF-AlF3 System: Phase Transition in K2NaAl3F12 Ternary Fluoride22Crystal growth and electronic structure of low-temperature phase SrMgF413Controlled synthesis of NdF3 and NaNdF4 micro- or nanocrystals by one-pot microwave-assisted hydrothermal reaction7Polyfluorides and Neat Fluorine as Host Material in Matrix‐Isolation Experiments26Hydrothermal synthesis and luminescence properties of Eu 2+ -doped BaSiF 6 microrods11Topochemical Oxidation of Perovskite KCoF3 to a K2PtCl6 Structure-Type Oxyfluoride10Towards new materials by hierarchical topotactic syntheses1Crystal chemistry of hydrothermally grown ternary alkali rare earth fluorides12Design of noncentrosymmetric perovskites from centric and acentric basic building units39Elaboration of Nanofluorides and Ceramics for Optical and Laser Applications30Ferroelastic and Ferroelectric Phase Transitions in Fluoro- and Oxyfluorometallates7Group Theoretical Approach on Possible Magnetoelectric Fluorides1Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na 3 NH 4 (TiF 6 )(SO 4 )·H 2 O6Largest perfluorometallate [Ti 10 F 45 ] 5− oligomer and polymeric ([Ti 3 F 13 ] − ) ∞ and ([TiF 5 ] − ) ∞ anions prepared as [XeF 5 ] + salts11Lithiation-driven structural transition of VO 2 F into disordered rock-salt Li x VO 2 F26Magnetic Properties of Transition Metal Fluoride Perovskites8Fluoride ion batteries: Theoretical performance, safety, toxicity, and a combinatorial screening of new electrodes281Thermal properties and phase transition in the fluoride, (NH4)3SnF712On the identification of oxygen and fluorine atoms in disordered inorganic oxyfluoride compounds8Phase transitions in (NH4)2MoO2F4 crystal3Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F19Compositional and Structural Versatility in an Unusual Family of anti-Perovskite Fluorides: [Cu(H2O)4]3[(MF6)(M′F6)]13Anion ordering, magnetic structure and properties of the vacancy ordered perovskite Ba3Fe3O7F16Identify OH groups in TiOF2 and their impact on the lithium intercalation properties24Preparation and temperature-dependent photoluminescence properties of ScF 3 :Eu 3+ submicroparticles18Removal of Fluoride from Semiconductor Wastewater to Synthesize Cryolite0Structural diversities induced by cation sizes in a series of fluorogermanophosphates: A 2 [GeF 2 (HPO 4 ) 2 ] (A = Na, K, Rb, NH 4 , and Cs)4The design and preparation of the thermally stable, Mn 4+ ion activated, narrow band, red emitting fluoride Na 3 GaF 6 :Mn 4+ for warm WLED applications161Designing new ferroelectrics with a general strategy112Thermal, optical, and dielectric properties of fluoride Rb2TaF76Structural aspects of the formation of solid solutions in the NaF-KF-AlF3 system12Prediction of Extremely Strong Antiferromagnetic Superexchange in Silver(II) Fluorides: Challenging the Oxocuprates(II)21Prediction of Extremely Strong Antiferromagnetic Superexchange in Silver(II) Fluorides: Challenging the Oxocuprates(II)9[OsF6]x−: Molecular Models for Spin‐Orbit Entangled Phenomena25Anomalous behaviour of thermodynamic properties at successive phase transitions in (NH 4 ) 3 GeF 75(Oxo)(Fluoro)–Aluminates in KF–Al2O3 System: Thermal Stability and Structural Correlation16Structural chemistry of fluoride and mixed-ligand fluoride complexes of gallium(III)12Controlled hydroxy-fluorination reaction of anatase to promote Mg 2+ mobility in rechargeable magnesium batteries17Group 3 metal trihalide complexes with neutral N-donor ligands – exploring their affinity towards fluoride24Surfactant-free aqueous synthesis of novel Ba 3 Gd 2 F 12 :Ln 3+ nanocrystals with luminescence properties5Na3GaF6– A crystal chemical and solid state NMR spectroscopic study2An Organogold(III) Difluoride with a trans Arrangement23An Organogold(III) Difluoride with a trans Arrangement11Synthesis and Physical Properties of the Oxofluoride Cu2(SeO3)F213Perovskite (ACuF3) to double perovskite (A3CuF6) (A = K, Rb) transformation by a simple shaking procedure with hydrogen peroxide6Novel sol–gel fabrication of Yb3+/Tm3+ co-doped β-NaYF4 thin films and investigation of their upconversion properties18Energy Transfer and Multicolor Tunable Luminescence Properties of NaGd0.5Tb0.5−xEux(MoO4)2 Phosphors for UV-LED30Ferromagnetic Rb2CoF6 obtained from a single source precursor3Double Perovskite K3InF6 as an Upconversion Phosphor and Its Structural Transformation Through Rubidium Substitution12Descent in Symmetry during Solid State Transitions and Other Anomalies in Mixed Valence Compounds AxMxⅡM1-xⅢF3 (A = K, Rb, Cs; M = V, Cr; x = 0.0 - 1.0)0Exploring transition metal fluoride chelates – synthesis, properties and prospects towards potential PET probes35Investigation of mixed-metal (oxy)fluorides as a new class of water oxidation electrocatalysts81Designing Three Fluorooxoborates with a Wide Transmittance Window by Anionic Group Substitution15Heteroanionic Materials by Design: Progress Toward Targeted Properties236High-temperature Raman study of K2ZrF6 phase transitions5Understanding the Structure and Ground State of the Prototype CuF2 Compound Not Due to the Jahn–Teller Effect13Heat capacity, thermal expansion and sensitivity to hydrostatic pressure of (NH4)3SiF7 at successive structural phase transitions3Coordination chemistry and applications of medium/high oxidation state metal and non-metal fluoride and oxide-fluoride complexes with neutral donor ligands46Terminal and bridging fluorine ligands in TiF4 as studied by 19F NMR in solids12Spectral kinetic study of four-component BaF2–ZnF2–CdF2-YbF3 fluoride ceramics by selective laser excitation3Strong magnetic exchange and frustrated ferrimagnetic order in a weberite-type inorganic–organic hybrid fluoride7Structural, thermal and optical properties of elpasolite-like (NH4)2KZrF75Low-temperature formation of Pb2OF2 with O/F anion ordering by solid state reaction9Infrared Spectroscopic and Theoretical Studies of the 3d Transition Metal Oxyfluoride Molecules9High-pressure high-temperature preparation and luminescent properties of EuF3/C composites4Magnetic and magnetoelectric properties of AFeF5 (A = Ca, Sr) spin-chain compounds1Heat capacity, thermal expansion and barocaloric effect in fluoride $\hbox {K}_{2}\hbox {TaF}_{7}$9Synthesis of inorganic fluorides in molten salt fluxes and ionic liquid mediums48Compression Behavior of Copper Hydroxyfluoride CuOHF as a Case Study of the High-Pressure Responses of the Hydrogen-Bonded Two-Dimensional Layered Materials12Synthesis and characterization of K5Sn2OF112Synthesis of the perovskite-type oxyfluoride AgTiO 2 F: an approach adopting the HSAB principle12Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196The structure of the metastable K 18 Ta 5 Zr 5 F 63 phase4The magnetic properties of multiferroic Sr3Fe2F126Assembly of the Thiolated [Au1Ag22(S‐Adm)12]3+ Superatom Complex into a Framework Material through Direct Linkage by SbF6− Anions118Assembly of the Thiolated [Au1Ag22(S‐Adm)12]3+ Superatom Complex into a Framework Material through Direct Linkage by SbF6− Anions15Significantly Improved Cyclability of Conversion‐Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction41Serendipitous formation of K15NaSn5F361Preparation and Optical Properties of ALF3: Cr3+ Phosphor2Periodic Tendril Perversion and Helices in the AMoO2F3 (A = K, Rb, NH4, Tl) Family44Calorimetric, dilatometric and DTA under pressure studies of the phase transitions in elpasolite (NH4)2KZrF73Temperature and time-dependent luminescence of single crystals of KTb3F1010K2SnOF4 and K2WO3F2 – different but similar2Investigation of thermal properties and structure of complex fluoride K3ZrF76Canted antiferromagnetism in high-purity NaFeF3 prepared by a novel wet-chemical synthesis method10Growth Peculiarities and Properties of KR3F10 (R = Y, Tb) Single Crystals28Ablation properties of C/C-UHTCs and their preparation by reactive infiltration of K2MeF6 (Me = Zr, Ti) molten salt26S = 1/2 Chain in BiVO3F: Spin Dimers versus Photoanodic Properties19Quasi-nodal lines in rhombohedral magnetic materials3A Geometrically Frustrated Family of MIIMIIIF5(H2O)2 Mixed–Metal Fluorides with Complex Magnetic Interactions14Thermochemistry of sodium rare earth ternary fluorides, NaREF418The nature of the interaction of RE(NO3)3 (yttrium subgroup) with HF or NH4F3MgF2-Based Organized Porous Inorganic Nanofluorides as Heterogeneous Catalysts for Fluorination of 2-Chloropyridine5Nitrogen-Doped Lithium Lanthanum Titanate Nanofiber-Polymer Composite Electrolytes for All-Solid-State Lithium Batteries30Properties of cerium (III) fluoride nanopowder obtained by pulsed electron beam evaporation7Exploratory Synthesis for Complex Metal Fluorides Using Solid-State Fluorine Sources6Designing new polar materials1Cu(II)-Catalyzed Unsymmetrical Dioxidation of gem -Difluoroalkenes to Generate α,α-Difluorinated-α-phenoxyketones14Versatile Superatom Complex Nanocluster for the Construction of Framework Materials11Fluorinated Materials as Positive Electrodes for Li- and Na-Ion Batteries96Efficient luminescence of doped bismuth oxychloride nanophosphors and its surfaces prompted applications5Interactions of yttrium and lanthanum fluorides with other fluorides6Na2FeF4 as a stable cathode material for Na-ion batteries9Layered Hybrid iron Fluorides2Solvothermal and hydrothermal methods for preparative solid-state chemistry5Contribution of Mössbauer spectrometry to structural characterizations of iron-based fluorinated materials: Application to pyrochlore (NH4)CuFeF6 and a new derived hydrate1The quaternary fluoride LiNaCa2Al2F12 in aluminum electrolytes: synthesis, structure, thermal stability6A new high-pressure polymorph of K 2 MoO 2 F 40Facile Preparation of 3d Interconnected Macroporous Cef34Crystal Growth and Crystal Structures of Gold(V) Compounds: Cu(AuF6)2, Ag(AuF6)2, and O2(CuF)3(AuF6)4 ⋅ HF357Fe Mössbauer Spectrometry to explore natural and artificial nanostructures3First-principles calculations to investigate Structural, Electronic, optical and mechanical properties of Cu-based fluoroperovskite XCuF3 (X = K, Ru)29Growth and characterization of the KDy3F10 and Na0.38Dy0.62F2.24 fluoride crystals for the Faraday devices4One-dimensional LaF3:RE3+ (RE=Eu, Nd) nanostructured phosphors: Controllable synthesis and luminescence properties18Comparative Study on Crystal Structures and Synthetic Techniques of Ternary Hafnium/Zirconium Fluorides7An overview of metal hydroxyfluoride–A novel semiconductor material5InF3(H2O)2 : An indium fluoride dihydrate phase with direct O-H...F hydrogen bonding between isolated columns of InF4(OH2)2 corner-sharing octahedra0Rare-Earth Ion-Activated Nanostructured Fluorescent Marker for Easy Naked Eye Detection and Swift Imaging of Latent Fingerprints24Enhancing the electrochemical properties of Na2Mn2P3O9N by partial substitution at Mn site: A first-principles study1Phase Diagram of the MgF2–SrF2 System and Interactions of Magnesium and Strontium Fluorides with Other Fluorides2Phase Diagram of the MgF2–SrF2 System and Interactions of Magnesium and Strontium Fluorides with Other Fluorides0Insertion of fluorine into a LiFePO 4 electrode material by gas–solid fluorination2K 3 Mo 2 O 5.6 F 3.4 and K 3 V 2 O 3.3 F 5.7 – exploring transition metal cation valence and anion distribution in oxyfluorides0Exploring the Potential of Lithium Metal Oxyfluoride, LiMOF, Compounds (M = Mn, Fe, Co, and Ni) for Advanced Li-Ion Battery Applications: A Comprehensive Ab Initio Investigation24Chemical pressure as an effective tool for tuning the structural disordering and barocaloric efficiency of complex fluorides (NH4)3MF7 (M: Sn, Ti, Ge, Si)3Where do the Fluorine Atoms Go in Inorganic‐Oxide Fluorinations? A Fluorooxoborate Illustration under Terahertz Light1Where do the Fluorine Atoms Go in Inorganic‐Oxide Fluorinations? A Fluorooxoborate Illustration under Terahertz Light33Polymorphisms in M2+AlF5(H2O)7 (M2+ = Fe2+, Co2+, or Ni2+): Syntheses, Crystal Structures, and Characterization of New Mixed Metal Fluoride Hydrates0Pinalites: Optical Properties and Quantum Magnetism of Heteroanionic A3MO5X2 Compounds6Polyanion Condensation in Inorganic and Hybrid Fluoridometallates (IV) of Octahedrally Coordinated Ti, Zr, Hf, V, Cr, W, Mn, Ge, Sn, and Pb3Crystal structure of Ba6Cd12Mn4SiF480Microwave-assisted solvothermal synthesis of Eu3+-doped CsY2F7 and RbY2F7 phosphorescent nanoparticles5Extending the Family of Hybrid Layered Fluoride Perovskites2Reaction pathways for the formation of complex fluorides revealed by in situ synchrotron X-ray diffraction1Fluorides: Inorganic Solid‐State and Structural Chemistry0Topochemical Synthesis and Formation Mechanism of Garnet Multimetal Fluorides2Synthesis and characterisation of Vanadium(III) fluorides α-BaVF5 and BaV(F,OH)5 with an S = 1 spin chain structure1Crystal structure of new barium manganese fluorides dihydrates, Ba10Mn2F25·2H2O0Structure and Thermal Behavior of Potassium Oxofluorozirconate K2Zr3OF122DFT+U and QTAIM insights into magnetic and optoelectronic properties, and bonding analyses of Europium-Hexafluorozirconate (EuZrF6)3Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates6Ordre/désordre anionique dans les hydroxyfluorures à base de Mg, Ni, Cu & Zn : corrélation composition/structure & propriétés physico-chimiques0

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  1. Ionic conductivity of Dion-Jacobson type oxide LiLaTa2O7 and oxynitride LiLaTa2O6.15N0.57 measured by impedance spectroscopy

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  4. Li + intercalation in isostructural Li 2 VO 3 and Li 2 VO 2 F with O 2− and mixed O 2− /F − anions

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  10. Crystal growth and electronic structure of low-temperature phase SrMgF4

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  11. Controlled synthesis of NdF3 and NaNdF4 micro- or nanocrystals by one-pot microwave-assisted hydrothermal reaction

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  12. Polyfluorides and Neat Fluorine as Host Material in Matrix‐Isolation Experiments

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  14. Topochemical Oxidation of Perovskite KCoF3 to a K2PtCl6 Structure-Type Oxyfluoride

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  15. Towards new materials by hierarchical topotactic syntheses

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  17. Design of noncentrosymmetric perovskites from centric and acentric basic building units

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  21. Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na 3 NH 4 (TiF 6 )(SO 4 )·H 2 O

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  22. Largest perfluorometallate [Ti 10 F 45 ] 5− oligomer and polymeric ([Ti 3 F 13 ] − ) ∞ and ([TiF 5 ] − ) ∞ anions prepared as [XeF 5 ] + salts

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  23. Lithiation-driven structural transition of VO 2 F into disordered rock-salt Li x VO 2 F

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  29. Synthesis and characterization of new fluoride-containing manganese vanadates A2Mn2V2O7F2 (A=Rb, Cs) and Mn2VO4F

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  33. Preparation and temperature-dependent photoluminescence properties of ScF 3 :Eu 3+ submicroparticles

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  34. Removal of Fluoride from Semiconductor Wastewater to Synthesize Cryolite

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  35. Structural diversities induced by cation sizes in a series of fluorogermanophosphates: A 2 [GeF 2 (HPO 4 ) 2 ] (A = Na, K, Rb, NH 4 , and Cs)

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  36. The design and preparation of the thermally stable, Mn 4+ ion activated, narrow band, red emitting fluoride Na 3 GaF 6 :Mn 4+ for warm WLED applications

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  37. Designing new ferroelectrics with a general strategy

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  38. Thermal, optical, and dielectric properties of fluoride Rb2TaF7

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  39. Structural aspects of the formation of solid solutions in the NaF-KF-AlF3 system

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  40. Prediction of Extremely Strong Antiferromagnetic Superexchange in Silver(II) Fluorides: Challenging the Oxocuprates(II)

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  41. Prediction of Extremely Strong Antiferromagnetic Superexchange in Silver(II) Fluorides: Challenging the Oxocuprates(II)

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  42. [OsF6]x−: Molecular Models for Spin‐Orbit Entangled Phenomena

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  43. Anomalous behaviour of thermodynamic properties at successive phase transitions in (NH 4 ) 3 GeF 7

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  44. (Oxo)(Fluoro)–Aluminates in KF–Al2O3 System: Thermal Stability and Structural Correlation

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  45. Structural chemistry of fluoride and mixed-ligand fluoride complexes of gallium(III)

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  46. Controlled hydroxy-fluorination reaction of anatase to promote Mg 2+ mobility in rechargeable magnesium batteries

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  47. Group 3 metal trihalide complexes with neutral N-donor ligands – exploring their affinity towards fluoride

    Dalton Transactions · 2018-01-01

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  48. Surfactant-free aqueous synthesis of novel Ba 3 Gd 2 F 12 :Ln 3+ nanocrystals with luminescence properties

    CrystEngComm · 2018-01-01

    Yang Feng, Baiqi Shao, Shuang Zhao, Hongpeng You

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  49. Na3GaF6– A crystal chemical and solid state NMR spectroscopic study

    Zeitschrift für Kristallographie - Crystalline Materials · 2018-02-19

    David Böhnisch, Stefan Seidel, Christopher Benndorf, Thomas H. Jansen, Lena Marie Funke, Rolf‐Dieter Hoffmann, Lukas Heletta, Juliane Stahl, Dirk Johrendt, Hellmut Eckert, Thomas Jüstel, Rainer Pöttgen

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  50. An Organogold(III) Difluoride with a trans Arrangement

    Angewandte Chemie International Edition · 2018-03-23

    Alberto Pérez‐Bitrián, Miguel Baya, José M. Casas, Antonio Martı́n, Babil Menjón, Jesús Orduna

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