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RESEARCH PAPER · Inorganic Chemistry · 2007

(6,3)-Honeycomb Structures of Uranium(VI) Benzenedicarboxylate Derivatives: The Use of Noncovalent Interactions to Prevent Interpenetration

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(6,3)-Honeycomb Structures of Uranium(VI) Benzenedicarboxylate Derivatives: The Use of Noncovalent Interactions to Prevent InterpenetrationOriginalHydrothermal chemistry of Th(IV) with aromatic dicarboxylates: New framework compounds and in situ ligand syntheses78Unprecedented 3D polycatenation based on ribbons of rings found in two metallosupramolecular polymers whose open frameworks show reversible collapse upon de- and rehydration31Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds218Uranyl−Organic Frameworks with 1,2,3,4-Butanetetracarboxylate and 1,2,3,4-Cyclobutanetetracarboxylate Ligands70Coordination polymer based on Cu(ii), Co(ii) and 4,4′-bipyridine-2,6,2′,6′-tetracarboxylate: synthesis, structure and adsorption properties26Uranyl–organic bilayer assemblies with flexible aromatic di-, tri- and tetracarboxylic acids55Hydrothermal Synthesis, Structures, and Luminescent Properties of Seven d10 Metal−Organic Frameworks Based on 9,9-Dipropylfluorene-2,7-Dicarboxylic Acid (H2DFDA)102Construction of one-, two- and three-dimensional Cu(I) polymeric architectures containing bis(diphenylphosphino)acetylene and 4,4′-bipyridine linking ligands10Poly[bis(dimethylammonium) [bis(dimethylamine-κN)tris(μ2-terephthalato-κ2O1:O4)dizinc(II)]N,N-dimethylformamide disolvate hexahydrate]5Amino Acid Based MOFs: Synthesis, Structure, Single Crystal to Single Crystal Transformation, Magnetic and Related Studies in a Family of Cobalt and Nickel Aminoisophthales119Hierarchical self-assembly of heteronuclear co-ordination networks52Lead(ii) complexes of bis- and tris-bidentate compartmental ligands based on pyridyl-pyrazole and pyridyl-triazole fragments: coordination networks and a discrete dimeric box33Lotus-Root-like One-Dimensional Polymetallocages with Drastic Void Adaptability Constructed from 4,4′-Bis(1,2,4-triazol-1-ylmethyl)biphenyl and Zn(II) or Co(II) and Their Fluorescein Encapsulation Properties35Adjusting the Porosity and Interpenetration of Cadmium(II) Coordination Polymers by Ligand Modification: Syntheses, Structures, and Adsorption Properties96Construction of Three‐Dimensional Uranyl–Organic Frameworks with Benzenetricarboxylate Ligands77Supramolecular Isomerism in Honeycomb Metal−Organic Frameworks Driven by CH···π Interactions: Homochiral Crystallization from an Achiral Ligand through Chiral Inducement88Synthesis, structure characterization and photocatalytic properties of two new uranyl naphthalene-dicarboxylate coordination polymer compounds57Coordination polymers of flexible tetracarboxylic acids with metal ions. II. Supramolecular assemblies of 5,5′-methylene- and 5,5′-(ethane-1,2-diyl)-bis(oxy)diisophthalic acidligands with d-transition metals54Luminescent silver(i) coordination networks based on bis-(3,5-dimethylpyrazolyl)naphthalene ligands12Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands45An uranyl citrate coordination polymer with a 3D open-framework involving uranyl cation-cation interactions57Construction of Coordination Polymers with a Bifurcating Ligand: Synthesis, Structure, Photoluminescence, and Magnetic Studies58Revisiting the Uranyl-phthalate System: Isolation and Crystal Structures of Two Types of Uranyl−Organic Frameworks (UOF)78Coordination Polymers of 5-(2-Amino/Acetamido-4-carboxyphenoxy)-benzene-1,3-dioic Acids with Transition Metal Ions: Synthesis, Structure, and Catalytic Activity54Occurence of an Octanuclear Motif of Uranyl Isophthalate with Cation–Cation Interactions through Edge-Sharing Connection Mode94Three-Dimensional Hybrid Framework Containing U2O13 Dimers Connected via Cation–Cation Interactions48Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids50Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems83Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with UVI═O–LnIII Bonding (Ln = Ce, Nd)117Coordination chemistry of the nitro-terephthalate molecule, highlighting two new main group complexes3Uranyl Hybrid Material Derived from In Situ Ligand Synthesis: Formation, Structure, and an Unusual Phase Transformation36Uranyl Hybrid Material Derived from In Situ Ligand Synthesis: Formation, Structure, and an Unusual Phase Transformation7Nanomaterials and nanotechnologies in nuclear energy chemistry46Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers82Syntheses, structures, and fluorescent properties of two uranium coordination polymers with carboxylic acids15Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers92Synthesis and Characterization of Four Novel Divalent Transition Metal-Dicarboxylate Coordination Polymers With Chelating Aromatic Amine Ligands (Metal = Mn2+, Co2+, Cu2+, Zn2+)0Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers85Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O31Interpenetration control in metal–organic frameworks for functional applications563A two-dimensional metal organic network with 1,3,5-benzenetricarboxylate and cobalt (II) ions: synthesis, structure and topology8The crystal chemistry of uranium carboxylates394Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties29Synthesis, crystal structure, photoluminescence property and photoelectronic behavior of two uranyl-organic frameworks constructed from 1, 2, 4, 5-benzenetetracarboxylic acid as ligand34MOFs of Uranium and the Actinides95Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent77Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules60Synthesis, crystal structure, and characterization of two three-fold interpenetrating Co(II) coordination polymers based on 1,4-benzenedicarboxylic acid and length modulated bisimidazole ligands16Three different pillared assemblies with abundant topological architectures based on 4-sulfobenzoic ligand6Poly[diammonium [diaqua(μ7-benzene-1,2,3,4,5,6-hexacarboxylato)tetraoxidodiuranium(VI)]]8Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55Two new two-dimensional layered uranyl-bearing polycarboxylates from semi-rigid tetracarboxylic acids15Design, Synthesis, and Photoluminescence Properties of One-, Two-, and Three-Dimensional Coordination Polymers: Anion-Assisted Argentophillic Interactions as Building Blocks27Structures and electronic properties of metal organic frameworks: DFT and ab initio FMO calculations for model systems7Lone pair–π interaction-induced generation of non-interpenetrated and photochromic cuboid 3-D naphthalene diimide coordination networks60Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye91A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31Design and synthesis of a chiral uranium-based microporous metal organic framework with high SHG efficiency and sequestration potential for low-valent actinides58Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Control of Interpenetration in Two-Dimensional Metal–Organic Frameworks by Modification of Hydrogen Bonding Capability of the Organic Bridging Subunits33Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Synthesis, crystal structure, and spectra of the Np(V) terephthalate [C(NH2)3]3[NpO2(C6H4(COO)2)2]·5H2O and An(VI) terephthalates [AnO2(C6H4(COO)2)] (An = U, Np, Pu)6Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions449Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers53Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Synthesis and structure of dimeric complexes of U(VI) and Np(VI) with isophthalic acid anions, {AnO2[C6H4(COO)(COOH)]2(H2O)}25Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework52A Family of Uranyl Coordination Polymers Containing O-Donor Dicarboxylates and Trispyridyltriazine Guests36The templated synthesis of a unique type of tetra-nuclear uranyl-mediated two-fold interpenetrating uranyl–organic framework36Solvothermal synthesis of uranium(VI) phases with aromatic carboxylate ligands: A dinuclear complex with 4-hydroxybenzoic acid and a 3D framework with terephthalic acid28Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology34Counter-ion control of structure in uranyl ion complexes with 2,5-thiophenedicarboxylate39Uranium(VI) hybrid materials with [(UO 2 ) 3 (µ 3 ‐O)(µ 2 ‐OH) 3 ] + as the sub–building unit via uranyl–cation interactions21From Helicates to Borromean Links: Chain Length Effect in Uranyl Ion Complexes of Aliphatic α,ω-Dicarboxylates21Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes41Entangled Uranyl Organic Frameworks with (10,3)-b Topology and Polythreading Network: Structure, Luminescence, and Computational Investigation43Exploring Crystal Engineering for Porous Uranyl–Organic Frameworks: Insight into Hydrolysis and In Situ Reaction, Structural Variation‐Dependent Physical Properties6Solvent‐Dependent Synthesis of Porous Anionic Uranyl–Organic Frameworks Featuring a Highly Symmetrical (3,4)‐Connected ctn or bor Topology for Selective Dye Adsorption64Exploring New Assembly Modes of Uranyl Terephthalate: Templated Syntheses and Structural Regulation of a Series of Rare 2D → 3D Polycatenated Frameworks39Influence of Pyrazine/Piperazine Based Guest Molecules in the Crystal Structures of Uranyl Thiophene Dicarboxylate Coordination Polymers: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye47Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters16Structural Consequences of 1,4-Cyclohexanedicarboxylate Cis/Trans Isomerism in Uranyl Ion Complexes: From Molecular Species to 2D and 3D Entangled Nets67Complexes of Uranyl Ions with Aromatic Di‐ and Tetracarboxylates Involving [Ni(bipy)n]2+ (n = 2, 3) Counterions12Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation40A hydrolytically stable uranyl organic framework for highly sensitive and selective detection of Fe 3+ in aqueous media70Six uranyl-organic frameworks with naphthalene-dicarboxylic acid and bipyridyl-based spacers: syntheses, structures, and properties27Ordered Entanglement in Actinide-Organic Coordination Polymers40Semirigid Tripodal Ligand Based Uranyl Coordination Polymer Isomers Featuring 2D Honeycomb Nets33Synthesis and crystal structures of two new uranyl coordination compounds obtained in aqueous solutions of 1-butyl-2,3-dimethylimidazolium chloride4Organic Compounds of Actinyls: Systematic Computational Assessment of Structural and Topological Properties in [AnO2(C2O4)n](2n−2)–(An = U, Np, Pu, Am;n= 1–3) Complexes16Crystal Structure of An(VI) Complexes with Succinate Anions, [PuO2(C4H4O4)(H2O)] and Cs2[(AnO2)2(C4H4O4)3]·H2O (An = U, Np, Pu)4An Unprecedented Interpenetrating Structure Built from Two Differently Bonded Frameworks: Synthesis, Characteristics, and Efficient Removal of Anionic Dyes from Aqueous Solutions12Tubelike Uranyl–Phenylenediacetate Assemblies from Screening of Ligand Isomers and Structure-Directing Counterions28Metal‐Carboxyl Helical Chain Secondary Units Supported Ion‐Exchangeable Anionic Uranyl–Organic Framework15Noncomplexed Cucurbituril-Mediated Structural Evolution of Layered Uranyl Terephthalate Compounds13A thio-functionalized zinc phosphite with a large-channel framework and enhanced removal ability of mercury ion from aqueous solutions5Secondary building units of MOFs20Why Design Matters: From Decorated Metal Oxide Clusters to Functional Metal–Organic Frameworks23Variability of Uranyl Carboxylates from Rigid Terophenyldicarboxylic Acid Ligands17Construction of Hybrid Bimetallic Uranyl Compounds Based on a Preassembled Terpyridine Metalloligand22Controlling the secondary assembly of porous anionic uranyl–organic polyhedra through organic cationic templates5Uranyl ion complexes with 2,2′:6′,2′′-terpyridine-4′-carboxylate. Interpenetration of networks involving “expanded ligands”10Facile carboxylation of natural eggshell membrane for highly selective uranium (VI) adsorption from radioactive wastewater26Contrasting Structure-Directing Effects in the Uranyl–Phthalate/Isophthalate Isomer Systems19UoC-3: A Metal–Organic Framework with an Anionic Framework Based on Uranyl UO22+ Nodes and Partly Fluorinated Benzene-1,3,5-Tribenzoate Linkers22Luminescent uranium–thiophene dicarboxylate frameworks supported by transition-metal–organic cations: dimensionality and luminescence control in uranyl speciation10Synthesis and Biomedical Applications of Highly Porous Metal–Organic Frameworks23Guest molecular guided syntheses of 2-dimensional uranyl complexes with rigid benzenedicarboxylate ligands2Axial coordination-assisted interwoven isomerism in 3D hydrogen-bonded organic frameworks for efficient natural gas purification7Synthesis of MOFs0Uranyl-organic framework: From structure design to cutting-edge applications1

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  1. Hydrothermal chemistry of Th(IV) with aromatic dicarboxylates: New framework compounds and in situ ligand syntheses

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  10. Amino Acid Based MOFs: Synthesis, Structure, Single Crystal to Single Crystal Transformation, Magnetic and Related Studies in a Family of Cobalt and Nickel Aminoisophthales

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  16. Supramolecular Isomerism in Honeycomb Metal−Organic Frameworks Driven by CH···π Interactions: Homochiral Crystallization from an Achiral Ligand through Chiral Inducement

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  35. Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers

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  36. Syntheses, structures, and fluorescent properties of two uranium coordination polymers with carboxylic acids

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  43. The crystal chemistry of uranium carboxylates

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  45. Synthesis, crystal structure, photoluminescence property and photoelectronic behavior of two uranyl-organic frameworks constructed from 1, 2, 4, 5-benzenetetracarboxylic acid as ligand

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