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RESEARCH PAPER · Inorganic Chemistry · 2012

Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers

Ionut Mihalcea, Christophe Volkringer, Natacha Henry, Thierry Loiseau

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Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates LinkersOriginalSulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid‐State Topotactic Transformation upon Dehydration63An exploration of homo- and heterometallic UO 2 2+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies32Effect of lanthanide contraction on crystal structures of Ln(iii) coordination polymers with dinuclear SBUs based on 3-(4-hydroxypyridinium-1-yl) phthalic acid and oxalic acid27New Ce(iii) sulfate–tartrate-based MOFs: an insight into the controllable self-assembly of acentric metal–organic complexes10One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids29Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors37Synthesis, Structure and Photoluminescence of Lanthanide Metal‐Organic Frameworks, Ln4(TDC)6(DMF)4(H2O)2, where TDC2− = thiophene‐2,5‐dicarboxylate, DMF = N,N‐dimethylformamide4Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O31Construction of Ag(I)–Ln(III) Heterometallic Coordination Polymers Based on Binuclear Ag2(DSPT)2 (H2DSPT = 4′-(2,4-Disulfophenyl)-2,2′:6′2″-terpyridine) Rings and Ln(III) Dimeric Molecular Building Blocks45The crystal chemistry of uranium carboxylates394Synthesis and structural characterization of metal–organic frameworks with the mellitate linker M2(OH)2[C12O12H2]·2H2O (M = Al, Ga, In) MIL-11643Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties29A family of 3D lanthanide–organic frameworks constructed from parallelogram secondary building units: synthesis, structures and properties14Syntheses, structural characterizations and ferroelectric properties of new Ce(III) coordination polymers via isomeric tartaric acid ligands12Chiral one- to three-dimensional uranyl–organic assemblies from (1R,3S)-(+)-camphoric acid47Five Cd( ii ) coordination polymers based on 2,3′,5,5′-biphenyltetracarboxylic acid and N-donor coligands: syntheses, structures and fluorescent properties66Isolation of a series of uranium organophosphinates11MOFs of Uranium and the Actinides95Syntheses, structures and magnetic properties of copper(II) coordination polymers based on 5-tert-butyl isophthalate and two N-donor ligands15Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent77Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands40Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence70Poly[diammonium [diaqua(μ7-benzene-1,2,3,4,5,6-hexacarboxylato)tetraoxidodiuranium(VI)]]8Increasing Complexity in the Uranyl Ion–Kemp’s Triacid System: From One- and Two-Dimensional Polymers to Uranyl–Copper(II) Dodeca- and Hexadecanuclear Species47A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species20Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence37Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55Uranyl Ion Complexes with trans‐3‐(3‐Pyridyl)acrylic Acid Including a Uranyl–Copper(II) Heterometallic Framework21The First Family of Actinide Carboxyphosphinates: Two‐ and Three‐Dimensional Uranyl Coordination Polymers27Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers46Metal–organic coordination polymers based on Cs(I), Rb(I) and isoflavone-3′-sulfonate ligands3Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye91A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate33Uranium(VI) coordination polymers with pyromellitate ligand: Unique 1D channel structures and diverse fluorescence32Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Thorium(IV) organic frameworks with aromatic polycarboxylate ligands11Two-dimensional assemblies in f-element ion (UO22+, Yb3+) complexes with two cyclohexyl-based polycarboxylates21Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies36Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction7A Novel One‐Dimensional Copper Mellitate Complex Featured by {Cu(H 2 O) 2 (urea)[C 6 (COO) 4 (COOH) 2 ]} n 2 n – Polyanions7Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Insertion of Trivalent Lanthanides into Uranyl Vanadate Layers and Frameworks16Three unprecedented high-connected 3D lanthanide–organic frameworks based on benzene-1,2,4,5-tetracarboxylic acid21Four lanthanide–carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: Syntheses, structures, luminescent and magnetic properties15Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates and 3d-Block Metal Counterions34Crystal structures of new uranyl glutarate coordination polymers (NH4)2[(UO2)2(glt)3]·nH2O (n= 3 or 6) and R[UO2(glt)(Hglt)]·H2O (R = Na, K, Rb or Cs)10Two new complexes constructed by semirigid carboxylic acid ligand: Synthesis, crystal structures, absorption of organic dye and photoluminescence properties21Series of Hydrated Heterometallic Uranyl-Cobalt(II) Coordination Polymers with Aromatic Polycarboxylate Ligands: Formation of U═O—Co Bonding upon Dehydration Process29Tetrahydrofurantetracarboxylic Acid: An Isomerizable Framework-Forming Ligand in Homo- and Heterometallic Complexes with UO22+, Ag+, and Pb2+23Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species93Two uranyl heterocyclic carboxyl compounds with fluorescent properties as high sensitivity and selectivity optical detectors for nitroaromatics13Coordination Polymers and Cage-Containing Frameworks in Uranyl Ion Complexes with rac- and (1R,2R)-trans-1,2-Cyclohexanedicarboxylates: Consequences of Chirality38Syntheses and Structures of Four Pairs of Coordination Polymers Based on 2,2′-((5-(Methoxycarbonyl)-1,3-phenylene)bis(oxy))dipropanoic Acid31Experimental and Theoretical Approaches to Three Uranyl Coordination Polymers Constructed by Phthalic Acid and N,N′-Donor Bridging Ligands: Crystal Structures, Luminescence, and Photocatalytic Degradation of Tetracycline Hydrochloride56Mixed-Ligand Uranyl Polyrotaxanes Incorporating a Sulfate/Oxalate Coligand: Achieving Structural Diversity via pH-Dependent Competitive Effect29Uranyl Complexes as Scaffolding or Spacers for Cucurbit[6]uril Molecules in Homo‐ and Heterometallic Species, Including a Uranyl–Lanthanide Complex13Synthesis and characterization of heterometallic uranyl pyridinedicarboxylate compounds19Copper and manganese complexes based on 1,4-naphthalene dicarboxylic acid ligand and its derivative: Syntheses, crystal structures, and magnetic properties4Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité0Nine isomorphous lanthanide–uranyl f–f bimetallic materials with 2-thiophenecarboxylic acid and terpyridine: structure and concomitant luminescent properties19Preparation and Structure Analysis of Three New Copper Complexes of Mellitic Acid With 4,4′‐Bipyridine and 1,3‐ bis (4‐pyridyl)Propane3Hydrothermal synthesis, crystal structure and properties of a two-dimensional uranyl coordination polymer based on a flexible zwitterionic ligand2Molecular Assemblies of a Series of Mixed Tetravalent Uranium and Trivalent Lanthanide Complexes Associated with the Dipicolinate Ligand, in Aqueous Medium10A novel luminescence method for the estimation of uranyl ions using trimesic acid‑cadmium complex9Novel Heterometallic Uranyl-Transition Metal Materials: Structure, Topology, and Solid State Photoluminescence Properties45Two uranyl-copper(II) bimetallic coordination polymers containing trans-3,3(pyridyl)acrylic acid: Structural variance through synthetic subtleties9Formation of uranyl phthalate coordination polymers with unusual 2D net topologies in the presence of organic cations16Full-Range Ratiometric Detection of D2O in H2O by a Heterobimetallic Uranyl/Lanthanide Framework with 4f/5f Bimodal Emission41Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions4Structural diversity and applications of Ce(III)-based coordination polymers38Contrasting Structure-Directing Effects in the Uranyl–Phthalate/Isophthalate Isomer Systems19Hydrothermal Syntheses of Uranium Oxide Hydrate Materials with Sm(III) Ions: pH-Driven Diversities in Structures and Morphologies and Sm-Doped Porous Uranium Oxides Derived from Their Thermal Decompositions20Varied role of organic carboxylate dizwitterions and anionic donors in mixed-ligand uranyl ion coordination polymers14Multitopic metal–organic carboxylates available as supramolecular building units36Two Neptunium(III) Mellitate Coordination Polymers: Completing the Series Np–Cf of Trans-Uranic An(III) Mellitates13Ligand competition on uranyl ion: further examples of zwitterionic vs. anionic carboxylate coordination9Metal–Organic Frameworks for Luminescence Thermometry44-(Ammoniomethyl)benzoate, a protic zwitterionic bifunctional linker in uranyl ion carboxylate complexes5Uranyl ion coordination polymers with the dibenzobarrelene-based rac - and ( R , R )- trans -9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylate ligands41,1ʹ-Dimethyl-4,4ʹ-bipyridinium as a multivalent structure-directing counterion to anionic uranyl ion polycarboxylate complexes9Enhanced water stability and catalytic activity of Fe-based metal–organic frameworks with co-ligands for 2,4-dichlorophenol degradation5(Benzene-1,2,4,5-tetrayl)tetrakis(3-(1-carboxylatomethylpyridinium)), a novel uranyl-complexing tetrazwitterion3Single‐cell nanoencapsulation of Saccharomyces cerevisiae with metal–organic complex nanoshells of Fe 3+ and benzenehexacarboxylic acid3Self-Assembly of Luminescent Lanthanide Benzenetetracarboxylates: Role of pH in Directing Structure0Uranyl-organic framework: From structure design to cutting-edge applications1Mechanisms and construction of lanthanide-based rare-earth luminescence sensors0

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  2. Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid‐State Topotactic Transformation upon Dehydration

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  4. Effect of lanthanide contraction on crystal structures of Ln(iii) coordination polymers with dinuclear SBUs based on 3-(4-hydroxypyridinium-1-yl) phthalic acid and oxalic acid

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  5. New Ce(iii) sulfate–tartrate-based MOFs: an insight into the controllable self-assembly of acentric metal–organic complexes

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  6. One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids

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  7. Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors

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  8. Synthesis, Structure and Photoluminescence of Lanthanide Metal‐Organic Frameworks, Ln4(TDC)6(DMF)4(H2O)2, where TDC2− = thiophene‐2,5‐dicarboxylate, DMF = N,N‐dimethylformamide

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  9. Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O

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  10. Construction of Ag(I)–Ln(III) Heterometallic Coordination Polymers Based on Binuclear Ag2(DSPT)2 (H2DSPT = 4′-(2,4-Disulfophenyl)-2,2′:6′2″-terpyridine) Rings and Ln(III) Dimeric Molecular Building Blocks

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  11. The crystal chemistry of uranium carboxylates

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  12. Synthesis and structural characterization of metal–organic frameworks with the mellitate linker M2(OH)2[C12O12H2]·2H2O (M = Al, Ga, In) MIL-116

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  13. Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties

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  14. A family of 3D lanthanide–organic frameworks constructed from parallelogram secondary building units: synthesis, structures and properties

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  15. Syntheses, structural characterizations and ferroelectric properties of new Ce(III) coordination polymers via isomeric tartaric acid ligands

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  16. Chiral one- to three-dimensional uranyl–organic assemblies from (1R,3S)-(+)-camphoric acid

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  17. Five Cd( ii ) coordination polymers based on 2,3′,5,5′-biphenyltetracarboxylic acid and N-donor coligands: syntheses, structures and fluorescent properties

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  18. Isolation of a series of uranium organophosphinates

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  19. MOFs of Uranium and the Actinides

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  20. Syntheses, structures and magnetic properties of copper(II) coordination polymers based on 5-tert-butyl isophthalate and two N-donor ligands

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  21. Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent

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  22. Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands

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  23. Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence

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  24. Poly[diammonium [diaqua(μ7-benzene-1,2,3,4,5,6-hexacarboxylato)tetraoxidodiuranium(VI)]]

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  25. Increasing Complexity in the Uranyl Ion–Kemp’s Triacid System: From One- and Two-Dimensional Polymers to Uranyl–Copper(II) Dodeca- and Hexadecanuclear Species

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  26. A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species

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  27. Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes

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  28. CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence

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  29. Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies

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  30. Uranyl Ion Complexes with trans‐3‐(3‐Pyridyl)acrylic Acid Including a Uranyl–Copper(II) Heterometallic Framework

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  31. The First Family of Actinide Carboxyphosphinates: Two‐ and Three‐Dimensional Uranyl Coordination Polymers

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  32. Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers

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  33. Metal–organic coordination polymers based on Cs(I), Rb(I) and isoflavone-3′-sulfonate ligands

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  34. Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye

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  35. A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties

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  36. Hybrid Materials of the f-Elements Part I

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  37. Hybrid Materials of the f-Elements Part II

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  38. Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate

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  39. Uranium(VI) coordination polymers with pyromellitate ligand: Unique 1D channel structures and diverse fluorescence

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  40. Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties

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  41. Thorium(IV) organic frameworks with aromatic polycarboxylate ligands

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  42. Two-dimensional assemblies in f-element ion (UO22+, Yb3+) complexes with two cyclohexyl-based polycarboxylates

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  43. Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies

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  44. Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction

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  45. A Novel One‐Dimensional Copper Mellitate Complex Featured by {Cu(H 2 O) 2 (urea)[C 6 (COO) 4 (COOH) 2 ]} n 2 n – Polyanions

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  46. Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks

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  47. Insertion of Trivalent Lanthanides into Uranyl Vanadate Layers and Frameworks

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  48. Three unprecedented high-connected 3D lanthanide–organic frameworks based on benzene-1,2,4,5-tetracarboxylic acid

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  49. Four lanthanide–carboxylate coordination polymers with mixed 2,3-naphthalenedicarboxylate and phen ligands: Syntheses, structures, luminescent and magnetic properties

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  50. Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors

    Inorganic Chemistry · 2015-09-02

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