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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2014

Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules

Ionut Mihalcea, Natacha Henry, Thierry Loiseau

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Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine MoleculesOriginalMOFs of Uranium and the Actinides95A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species20Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55Two new two-dimensional layered uranyl-bearing polycarboxylates from semi-rigid tetracarboxylic acids15Syntheses, Structures, Thermal and Luminescent Properties of Two Interpenetrating Coordination Polymers Constructed by 2,5‐Thiophenedicarboxylate and Different Dipyridyl Ligands2Substituent Effects of Isophthalate Derivatives on the Construction of Zinc(II) Coordination Polymers Incorporating Flexible Bis(imidazolyl) Ligands59Effects of hydroxy substituents on Cu( ii ) coordination polymers based on 5-hydroxyisophthalate derivatives and 1,4-bis(2-methylimidazol-1-yl)benzene15Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate33Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands34Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration16Uranium( vi ) complexes with isonicotinic acid: from monomer to 2D polymer with unique U–N bonding43Uranium(VI) coordination polymers with pyromellitate ligand: Unique 1D channel structures and diverse fluorescence32Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System143Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Académie des Sciences Prizes: T. Loiseau, L. Fensterbank, A. Böckmann, J.‐F. Carpentier / Arthur Birch Lectureship: S. Zard0Preise der Académie des Sciences: T. Loiseau, L. Fensterbank, A. Böckmann, J.‐F. Carpentier / Arthur Birch Lectureship: S. Zard0Mild hydrothermal crystal growth of new uranium(IV) fluorides, Na3.13Mg1.43U6F30 and Na2.50Mn1.75U6F30: Structures, optical and magnetic properties12Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands13Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers53Syntheses, Structures, and Characteristics of Six Coordination Polymers Based on 1,4‐Bis(imidazol‐1‐yl)benzene and Isophthalates Containing Coordination‐Inert Substituents7Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies36Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction7Synthesis, Structure, and Photoluminescence Properties of an Organically‐Templated Uranyl Selenite3Ex‐Situ Kinetic Investigations of the Formation of the Poly‐Oxo Cluster U3827A Family of Uranyl Coordination Polymers Containing O-Donor Dicarboxylates and Trispyridyltriazine Guests36Solvothermal synthesis of uranium(VI) phases with aromatic carboxylate ligands: A dinuclear complex with 4-hydroxybenzoic acid and a 3D framework with terephthalic acid28Synthesis and characterizations of Zn(II) and Co(II) coordination polymers based on 5-acetamidoisophthalate3Dioxo-vanadium( v ), oxo-rhenium( v ) and dioxo-uranium( vi ) complexes with a tridentate Schiff base ligand21Hydrothermal synthesis, structures and properties of two uranyl oxide hydroxyl hydrate phases with Co( ii ) or Ni( ii ) ions31Uranium(VI) hybrid materials with [(UO 2 ) 3 (µ 3 ‐O)(µ 2 ‐OH) 3 ] + as the sub–building unit via uranyl–cation interactions21Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers34One-dimensional uranium(VI) coordination polymers with pyridinecarboxylate ligands14Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits38Dynamics of Humic Acid and Its Interaction with Uranyl in the Presence of Hydrophobic Surface Implicated by Molecular Dynamics Simulations55A series of coordination polymers constructed from R-isophthalic acid (R=–SO 3 H, –NO 2 , and –OH) and N-donor ligands: Syntheses, structures and fluorescence properties20Reversible solvent-induced transformation of a one-dimensional uranyl coordination polymer using 4,4′-oxybis(benzoate)1Influence of Pyrazine/Piperazine Based Guest Molecules in the Crystal Structures of Uranyl Thiophene Dicarboxylate Coordination Polymers: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye47Synthesis, structure and optical properties of two uranyl oxalate complexes templated by protonated amines0Two new uranyl complexes as visible light driven photocatalysts for degradation of tetracycline14Complexes of Uranyl Ions with Aromatic Di‐ and Tetracarboxylates Involving [Ni(bipy)n]2+ (n = 2, 3) Counterions12Hydrothermal Synthesis, Crystal Structure, and Photoluminescent Properties of Li[UO2(CH3COO)3]3[Co(H2O)6]1Uranyl oxide hydrate phases with heavy lanthanide ions: [Ln(UO 2 ) 2 O 3 (OH)]·0.5H 2 O (Ln = Tb, Dy, Ho and Yb)30Large-Pore Layered Networks, Polycatenated Frameworks, and Three-Dimensional Frameworks of Uranyl Tri(biphenyl)amine/Tri(phenyl)amine Tricarboxylate: Solvent-/Ligand-Dependent Dual Regulation23Bipyridine-Directed Syntheses of Uranyl Compounds Containing Semirigid Dicarboxylate Linkers: Diversity and Consistency in Uranyl Speciation28Syntheses, Crystal Structures, and Spectroscopic Studies of Uranyl Oxide Hydrate Phases with La(III)/Nd(III) Ions32Thorium( iv ) and uranium( vi ) compounds of cucurbit[10]uril: from a one-dimensional nanotube to a supramolecular framework9Hydrothermal synthesis of two 2D uranyl coordination polymers: structure, luminescence, and photocatalytic degradation of rhodamine B16Layer-structured uranyl-oxide hydroxy-hydrates with Pr( iii ) and Tb( iii ) ions: hydroxyl to oxo transition driven by interlayer cations19Rare Three-Dimensional Uranyl–Biphenyl-3,3′-disulfonyl-4,4′-dicarboxylate Frameworks: Crystal Structures, Proton Conductivity, and Luminescence28The versatile coordination chemistry of 1,3-benzenedicarboxylate in the last 20 years: An investigation from the coordination modes to spectroscopic insights7Synthesis, Characterization, and Solid-State Structural Chemistry of Uranium(IV) Aliphatic Dicarboxylates7Contrasting Structure-Directing Effects in the Uranyl–Phthalate/Isophthalate Isomer Systems19Varied role of organic carboxylate dizwitterions and anionic donors in mixed-ligand uranyl ion coordination polymers14The crystal structure of poly[(μ 2-2-aminoisophthalato-κ4O,O′:O″:O″′)-(N-methylpyrrolidone κ1O)-dioxido-uranium(VI)], C13H14N2O7U1Alkali Counterion-Dependent Crystallization of Uranium(IV)–Chloro Structural Units6Series of Hydrated Lanthanide (La, Ce, Pr, Dy, Yb) Pyromellitate 3D Coordination Polymer with Tunnels Encapsulating Dimethylammonium Species and Its Crystal-to-Crystal Transformation upon Dehydration1

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  2. A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species

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  3. Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies

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  4. Two new two-dimensional layered uranyl-bearing polycarboxylates from semi-rigid tetracarboxylic acids

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  5. Syntheses, Structures, Thermal and Luminescent Properties of Two Interpenetrating Coordination Polymers Constructed by 2,5‐Thiophenedicarboxylate and Different Dipyridyl Ligands

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  6. Substituent Effects of Isophthalate Derivatives on the Construction of Zinc(II) Coordination Polymers Incorporating Flexible Bis(imidazolyl) Ligands

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    Xiaoju Li, Xiaoju Li, Zhenjiang Yu, Tena Guan, Xinxiong Li, Xin‐Xiong Li, Guangchao Ma, Xiaofang Guo

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  7. Effects of hydroxy substituents on Cu( ii ) coordination polymers based on 5-hydroxyisophthalate derivatives and 1,4-bis(2-methylimidazol-1-yl)benzene

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  8. Hybrid Materials of the f-Elements Part I

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  9. Hybrid Materials of the f-Elements Part II

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  10. Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate

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  11. Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands

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  12. Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration

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  13. Uranium( vi ) complexes with isonicotinic acid: from monomer to 2D polymer with unique U–N bonding

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  14. Uranium(VI) coordination polymers with pyromellitate ligand: Unique 1D channel structures and diverse fluorescence

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  15. Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System

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  16. Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties

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  17. Académie des Sciences Prizes: T. Loiseau, L. Fensterbank, A. Böckmann, J.‐F. Carpentier / Arthur Birch Lectureship: S. Zard

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  18. Preise der Académie des Sciences: T. Loiseau, L. Fensterbank, A. Böckmann, J.‐F. Carpentier / Arthur Birch Lectureship: S. Zard

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  19. Mild hydrothermal crystal growth of new uranium(IV) fluorides, Na3.13Mg1.43U6F30 and Na2.50Mn1.75U6F30: Structures, optical and magnetic properties

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  20. Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands

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  21. Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers

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  22. Syntheses, Structures, and Characteristics of Six Coordination Polymers Based on 1,4‐Bis(imidazol‐1‐yl)benzene and Isophthalates Containing Coordination‐Inert Substituents

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  23. Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies

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  24. Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction

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  26. Ex‐Situ Kinetic Investigations of the Formation of the Poly‐Oxo Cluster U38

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  32. Uranium(VI) hybrid materials with [(UO 2 ) 3 (µ 3 ‐O)(µ 2 ‐OH) 3 ] + as the sub–building unit via uranyl–cation interactions

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  33. Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers

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  34. One-dimensional uranium(VI) coordination polymers with pyridinecarboxylate ligands

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  35. Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework

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  36. Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits

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  37. Dynamics of Humic Acid and Its Interaction with Uranyl in the Presence of Hydrophobic Surface Implicated by Molecular Dynamics Simulations

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  39. Reversible solvent-induced transformation of a one-dimensional uranyl coordination polymer using 4,4′-oxybis(benzoate)

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  40. Influence of Pyrazine/Piperazine Based Guest Molecules in the Crystal Structures of Uranyl Thiophene Dicarboxylate Coordination Polymers: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye

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  42. Two new uranyl complexes as visible light driven photocatalysts for degradation of tetracycline

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  43. Complexes of Uranyl Ions with Aromatic Di‐ and Tetracarboxylates Involving [Ni(bipy)n]2+ (n = 2, 3) Counterions

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  44. Hydrothermal Synthesis, Crystal Structure, and Photoluminescent Properties of Li[UO2(CH3COO)3]3[Co(H2O)6]

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  45. Uranyl oxide hydrate phases with heavy lanthanide ions: [Ln(UO 2 ) 2 O 3 (OH)]·0.5H 2 O (Ln = Tb, Dy, Ho and Yb)

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  46. Large-Pore Layered Networks, Polycatenated Frameworks, and Three-Dimensional Frameworks of Uranyl Tri(biphenyl)amine/Tri(phenyl)amine Tricarboxylate: Solvent-/Ligand-Dependent Dual Regulation

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  49. Thorium( iv ) and uranium( vi ) compounds of cucurbit[10]uril: from a one-dimensional nanotube to a supramolecular framework

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  50. Hydrothermal synthesis of two 2D uranyl coordination polymers: structure, luminescence, and photocatalytic degradation of rhodamine B

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