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RESEARCH PAPER · Crystal Growth & Design · 2011

Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems

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Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel SystemsOriginalSyntheses, structures and luminescent properties of two one-dimensional uranium oxyfluorides12Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures46Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers82Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers92From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange82An exploration of homo- and heterometallic UO 2 2+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies32One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids29Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors37Three‐Dimensional MOF‐Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8)127Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O31A Uranyl Hybrid Compound Designed from Urea‐Bearing Dipropionic Acid162,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids56Series of Uranyl-4,4′-biphenyldicarboxylates and an Occurrence of a Cation–Cation Interaction: Hydrothermal Synthesis and in Situ Raman Studies36The crystal chemistry of uranium carboxylates394Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids70MOFs of Uranium and the Actinides95Synthesis and Crystal Structure of Two Cu(II)-Benzene-1,2,4,5- Tetracarboxylates With Three-Dimensional Open Frameworks0Synthesis and Crystal Structure of Two Cu II ‐benzene‐1,2,4,5‐tetracarboxylates with Three‐Dimensional Open Frameworks8Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent77Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules60A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species20Two-Dimensional Coordination Polymers Comprising Mixed Tripodal Ligands for Selective Colorimetric Detection of Water and Iodine Capture56Synthesis, Crystal Structure, Hydrogen Bonding, and Thermal Behavior of a Three‐Dimensional Cu II ‐benzene‐1,2,4,5‐tetracarboxylate Templated by 1,9‐Diaminononane1Topological Diversity of Supramolecular Networks Constructed from Copper(II) Aminoalcohol Blocks and 2,6-Naphthalenedicarboxylate Linkers: Self-Assembly Synthesis, Structural Features, and Magnetic Properties44Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55Copper(I) and Copper(II) Uranyl Heterometallic Hybrid Materials49Four new dinuclear uranyl complexes based on p- and m-toluic acid: Syntheses, structures, luminescent and photocatalytic properties21Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye91A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate33Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands34Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration16Uranium( vi ) complexes with isonicotinic acid: from monomer to 2D polymer with unique U–N bonding43Uranium(VI) coordination polymers with pyromellitate ligand: Unique 1D channel structures and diverse fluorescence32Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Thorium(IV) organic frameworks with aromatic polycarboxylate ligands11Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies36Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction7Solvothermal synthesis of uranium(VI) phases with aromatic carboxylate ligands: A dinuclear complex with 4-hydroxybenzoic acid and a 3D framework with terephthalic acid28A family of uranium–carboxylic acid hybrid materials: synthesis, structure and mixed-dye selective adsorption17Dioxo-vanadium( v ), oxo-rhenium( v ) and dioxo-uranium( vi ) complexes with a tridentate Schiff base ligand21Hydrothermal synthesis, structures and properties of two uranyl oxide hydroxyl hydrate phases with Co( ii ) or Ni( ii ) ions31Uranium(VI) hybrid materials with [(UO 2 ) 3 (µ 3 ‐O)(µ 2 ‐OH) 3 ] + as the sub–building unit via uranyl–cation interactions21One-dimensional uranium(VI) coordination polymers with pyridinecarboxylate ligands14Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs14Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits38Structures of Metal–Organic Frameworks with Rod Secondary Building Units909Conversion of supramolecular organic framework to uranyl-organic coordination complex: a new “matrix-free” strategy for highly efficient capture of uranium18Dicyanoaurate-based heterobimetallic uranyl coordination polymers26Two Three‐Dimensional Actinide–Silver Heterometallic Coordination Polymers Based on 2,2′‐Bipyridine‐3,3′‐dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs21Experimental and Theoretical Approaches to Three Uranyl Coordination Polymers Constructed by Phthalic Acid and N,N′-Donor Bridging Ligands: Crystal Structures, Luminescence, and Photocatalytic Degradation of Tetracycline Hydrochloride56Utilizing bifurcated halogen-bonding interactions with the uranyl oxo group in the assembly of a UO2–3-bromo-5-iodobenzoic acid coordination polymer17Syntheses and characterization of two new compounds based on versatile 1,2,3,5-benzenetetracarboxylic acid and 2,2′-bibenzimidazole3Isolating Equatorial and Oxo Based Influences on Uranyl Vibrational Spectroscopy in a Family of Hybrid Materials Featuring Halogen Bonding Interactions with Uranyl Oxo Atoms20Structural studies of a series of uranyl alkylacetamides and piracetam complexes obtained in nitric acid aqueous solution9Hydrothermal Synthesis, Crystal Structure, and Photoluminescent Properties of Li[UO2(CH3COO)3]3[Co(H2O)6]1Synthesis, Crystal Structure, Hydrogen Bonding and Thermal Behaviour of a Three-Dimensional Cu(II)-Benzene-1,2,4,5-Tetracarboxylate Templated by 1,9-Diaminononane0Uranyl oxide hydrate phases with heavy lanthanide ions: [Ln(UO 2 ) 2 O 3 (OH)]·0.5H 2 O (Ln = Tb, Dy, Ho and Yb)30An Anionic Uranium-Based Metal–Organic Framework with Ultralarge Nanocages for Selective Dye Adsorption67Speciation of Actinide Complexes, Clusters, and Nanostructures in Solution2Bimetallic Uranyl Organic Frameworks Supported by Transition-Metal-Ion-Based Metalloligand Motifs: Synthesis, Structure Diversity, and Luminescence Properties48Uranyl-Organic Coordination Compounds Incorporating Photoactive Vinylpyridine Moieties: Synthesis, Structural Characterization, and Light-Induced Fluorescence Attenuation26Etude de la précipitation quantitative de l’uranium(VI) et du plutonium(IV) en milieu acide nitrique par de nouveaux ligands organiques0Effect of solution acidity on the structure of amino acid-bearing uranyl compounds7Irradiation and isolation of fission products from uranium metal–organic frameworks13Syntheses, Crystal Structures, and Spectroscopic Studies of Uranyl Oxide Hydrate Phases with La(III)/Nd(III) Ions32A unique uranyl framework containing uranyl pentamers as secondary building units: synthesis, structure, and spectroscopic properties25Layer-structured uranyl-oxide hydroxy-hydrates with Pr( iii ) and Tb( iii ) ions: hydroxyl to oxo transition driven by interlayer cations19Uranyl oxide hydrate frameworks with lanthanide ions25Quantitative Precipitation of Uranyl or Plutonyl Nitrate with N-(1-Adamantyl)acetamide in Nitric Acid Aqueous Solution9[U(H2O)2]{[(UO2)10O10(OH)2][(UO4)(H2O)2]}: A Mixed-Valence Uranium Oxide Hydrate Framework20State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization20Synthetic uranium oxide hydrate materials: Current advances and future perspectives30Enhancing photosensitivity via the assembly of a uranyl coordination polymer8The confinement effect of layered double hydroxides on intercalated pyromellitic acidic anions and highly selective uranium extraction from simulated seawater25Varied role of organic carboxylate dizwitterions and anionic donors in mixed-ligand uranyl ion coordination polymers14Zwitterionic and Anionic Polycarboxylates as Coligands in Uranyl Ion Complexes, and Their Influence on Periodicity and Topology19Intercalation of salicylaldoxime into layered double hydroxide: Ultrafast and highly selective uptake of uranium from different water systems via versatile binding modes33Pertechnetate/Perrhenate-Linked Frameworks of UIV, UIV6-Hexamer and Uranyl (VI) Building Units3

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  2. Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures

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  3. Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures

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  4. Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers

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  5. Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers

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  6. From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange

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  7. An exploration of homo- and heterometallic UO 2 2+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies

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  8. One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids

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  9. Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors

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  10. Three‐Dimensional MOF‐Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8)

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  11. Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O

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  12. A Uranyl Hybrid Compound Designed from Urea‐Bearing Dipropionic Acid

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  13. 2,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids

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  14. Series of Uranyl-4,4′-biphenyldicarboxylates and an Occurrence of a Cation–Cation Interaction: Hydrothermal Synthesis and in Situ Raman Studies

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    Paula M. Cantos, Laurent J. Jouffret, Richard E. Wilson, Peter Carman Burns, Christopher L. Cahill

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  15. The crystal chemistry of uranium carboxylates

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  16. Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids

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  17. MOFs of Uranium and the Actinides

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  18. Synthesis and Crystal Structure of Two Cu(II)-Benzene-1,2,4,5- Tetracarboxylates With Three-Dimensional Open Frameworks

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  19. Synthesis and Crystal Structure of Two Cu II ‐benzene‐1,2,4,5‐tetracarboxylates with Three‐Dimensional Open Frameworks

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  20. Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent

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  21. Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules

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  22. A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species

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  23. Two-Dimensional Coordination Polymers Comprising Mixed Tripodal Ligands for Selective Colorimetric Detection of Water and Iodine Capture

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  24. Synthesis, Crystal Structure, Hydrogen Bonding, and Thermal Behavior of a Three‐Dimensional Cu II ‐benzene‐1,2,4,5‐tetracarboxylate Templated by 1,9‐Diaminononane

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  36. Uranium( vi ) complexes with isonicotinic acid: from monomer to 2D polymer with unique U–N bonding

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  37. Uranium(VI) coordination polymers with pyromellitate ligand: Unique 1D channel structures and diverse fluorescence

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  38. Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties

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  39. Thorium(IV) organic frameworks with aromatic polycarboxylate ligands

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  40. Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies

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  41. Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction

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  42. Solvothermal synthesis of uranium(VI) phases with aromatic carboxylate ligands: A dinuclear complex with 4-hydroxybenzoic acid and a 3D framework with terephthalic acid

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  43. A family of uranium–carboxylic acid hybrid materials: synthesis, structure and mixed-dye selective adsorption

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  45. Hydrothermal synthesis, structures and properties of two uranyl oxide hydroxyl hydrate phases with Co( ii ) or Ni( ii ) ions

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  46. Uranium(VI) hybrid materials with [(UO 2 ) 3 (µ 3 ‐O)(µ 2 ‐OH) 3 ] + as the sub–building unit via uranyl–cation interactions

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  48. Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework

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  49. Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs

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  50. Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits

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