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RESEARCH PAPER · Inorganic Chemistry · 2008

Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds

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Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly CompoundsOriginalUranyl Ion Complexes with Cucurbit[n]urils (n = 6, 7, and 8): A New Family of Uranyl-Organic Frameworks127Uranyl Ion Complexes with Cucurbit[5]uril: from Molecular Capsules to Uranyl-Organic Frameworks103Structures, photoluminescence and photocatalytic properties of three new metal–organic frameworks based on non-rigid long bridges69Uranyl–organic bilayer assemblies with flexible aromatic di-, tri- and tetracarboxylic acids55Synthesis and characterizations of a novel dia-type Ag–BPT coordination polymer with tetranuclear motifs as jointing points (BPT = 3,5-bis(3-pyridyl)-1,2,4-triazole)10Structures, Photoluminescence, and Photocatalytic Properties of Six New Metal−Organic Frameworks Based on Aromatic Polycarboxylate Acids and Rigid Imidazole-Based Synthons211Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks79Uranyl–organic assemblies with the macrocyclic ligand 1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetraacetate (TETA)34Hydrothermal Synthesis of Disulfide-Containing Uranyl Compounds: In Situ Ligand Synthesis versus Direct Assembly68Supramolecular chemistry with uranyl tetrahalide ([UO2X4]2−) anions44Syntheses, Structures, and Photoluminescence of Five New Metal−Organic Frameworks Based on Flexible Tetrapyridines and Aromatic Polycarboxylate Acids104A new clover-shaped trinuclear uranium(VI) complex: Synthesis, structure and photoluminescence property26Construction of Three‐Dimensional Uranyl–Organic Frameworks with Benzenetricarboxylate Ligands77A new uranyl(VI) complex of rigid V-shaped carboxylate ligand: Synthesis, structure and properties19Use of Polyazaheterocycles in the Assembly of New Cadmium Sulfate Frameworks: Synthesis, Structure, and Properties38Syntheses, Structures, and Photochemical Properties of Six New Metal−Organic Frameworks Based on Aromatic Dicarboxylate Acids and V-Shaped Imidazole Ligands86Synthesis, structure characterization and photocatalytic properties of two new uranyl naphthalene-dicarboxylate coordination polymer compounds57Syntheses, crystal structures and properties of three novel coordination polymers with tripodal imidazole-containing ligands and benzenetetracarboxylate10Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands45An uranyl citrate coordination polymer with a 3D open-framework involving uranyl cation-cation interactions57One-dimensional uranium–organic coordination polymers: crystal and electronic structures of uranyl-diacetohydroxamate19Six new metal–organic frameworks with multi-carboxylic acids and imidazole-based spacers: syntheses, structures and properties63Temperature-controlled synthesis of two novel coordination polymers modeled by semi-rigid tetrapyridines30Coordination chemistry of pyrazolone based Schiff bases relevant to uranyl sequestering agents: Synthesis, characterization and 3D molecular modeling of some octa-coordinate mono- and binuclear-dioxouranium(VI) complexes12Six New Metal−Organic Frameworks Based on Polycarboxylate Acids and V-shaped Imidazole-Based Synthon: Syntheses, Crystal Structures, and Properties90Revisiting the Uranyl-phthalate System: Isolation and Crystal Structures of Two Types of Uranyl−Organic Frameworks (UOF)78Structures and luminescent properties of new uranyl-based hybrid materials56Uranyl Ion Complexation by Aliphatic Dicarboxylic Acids in the Presence of Cucurbiturils as Additional Ligands or Structure-Directing Agents124Three New Coordination Polymers Based on One Reduced Symmetry Tripodal Linker70Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds412Occurence of an Octanuclear Motif of Uranyl Isophthalate with Cation–Cation Interactions through Edge-Sharing Connection Mode94Structures and photocatalytic activities of metal-organic frameworks derived from rigid aromatic dicarboxylate acids and flexible imidazole-based linkers42Uranyl–Alkali Metal Ion Heterometallic Complexes with Cucurbit[6]uril and a Sulfonated Catechol67A Series of 2D and 3D Metal–Organic Frameworks Based on a Flexible Tetrakis(4-pyridyloxymethylene)methane Ligand and Polycarboxylates: Syntheses, Structures, and Photoluminescent Properties155First Three-Dimensional Inorganic–Organic Hybrid Material Constructed From an “Inverted Keggin” Polyoxometalate and a Copper(I)-Organic Complex160Crystal Engineering with the Uranyl Cation III. Mixed Aliphatic Dicarboxylate/Aromatic Dipyridyl Coordination Polymers: Synthesis, Structures, and Speciation74Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids50Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril32Nucleobase assemblies supported by uranyl cation coordination and other non-covalent interactions3Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems83Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with UVI═O–LnIII Bonding (Ln = Ce, Nd)117Four 3D metal–organic frameworks derived from barium(ii) and isoflavonesulfonate ligands14Metal–organic frameworks based on naphthalene-1,5-diyldioxy-di-acetate: structures, topologies, photoluminescence and photocatalytic properties94Syntheses, structures and fluorescence of two coordination complexes of Zn(ii) and 1,3-bis(2-methylimidazolyl)propane: solvent effect47Two novel 3D metal–organic frameworks based on two tetrahedral ligands: syntheses, structures, photoluminescence and photocatalytic properties107Two novel high-dimensional iron(ii) coordination polymers modeled by semi-rigid tetrapyridines10Variable architectures of Zinc coordination polymers modeled by tetra-pyridine ligands with different anions123-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials76Single-site photocatalysts with a porous structure20Syntheses, Structures, and Characteristics of Four New Metal–Organic Frameworks Based on Flexible Tetrapyridines and Aromatic Polycarboxylate Acids76Syntheses, structures and luminescent properties of two one-dimensional uranium oxyfluorides12Diverse Structures of Metal–Organic Frameworks Based on a New Star-Like Tri(4-pyridylphenyl)amine Ligand59Nanomaterials and nanotechnologies in nuclear energy chemistry46Synthesis, Crystal Structure and Luminescence Properties of a New Cd(II) Complex Based on 5-Methylisophthalic Acid and 1,3-Bis(1,2,4-triazole)propane4Syntheses, structures, and fluorescent properties of two uranium coordination polymers with carboxylic acids15Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers92From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange82Alkyl substituents introduced into novel d 10 -metalimidazole-4,5-dicarboxylate frameworks: synthesis, structure diversities and photoluminescence properties23Bisactinyl halogenated complexes: relativistic density functional theory calculation and experimental synthesis9Synthesis and Characterization of Four Novel Divalent Transition Metal-Dicarboxylate Coordination Polymers With Chelating Aromatic Amine Ligands (Metal = Mn2+, Co2+, Cu2+, Zn2+)0Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71Four New Three-Dimensional Polyoxometalate-Based Metal–Organic Frameworks Constructed From [Mo6O18(O3AsPh)2]4– Polyoxoanions and Copper(I)-Organic Fragments: Syntheses, Structures, Electrochemistry, and Photocatalysis Properties128Cage clusters built from uranyl ions bridged through peroxo and 1-hydroxyethane-1,1-diphosphonic acid ligands26Chiral uranyl-organic compounds assembled with achiral furandicarboxylic acid by spontaneous resolution45Lanthanide coordination polymers with hexa-carboxylate ligands derived from cyclotriphosphazene as bridging linkers: synthesis, thermal and luminescent properties33Metal–organic frameworks based on 1,3,5-triazine-2,4,6-triyltrithio-triacetate: structures, topologies, photoluminescence and photocatalytic properties35Metal(ii) complexes based on 1,4-bis(3-pyridylaminomethyl)benzene: structures, photoluminescence and photocatalytic properties38New metal–organic frameworks based on 2,5-thiophenedicarboxylate and pyridine- or imidazole-based spacers: syntheses, topological structures, and properties62Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors37Uranyl–copper(ii) heterometallic oxalate complexes: coordination polymers and frameworks47Various crystal structures based on 4,4′-(diethynylanthracene-9,10-diyl) dibenzoic acid: from 0D dimer to 3D net framework17Metal(II) Complexes Based on Benzene-1,2,3-triyldioxy-triacetate: Structures and Photoluminescence Properties26Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers85Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O31Two new polyoxometalate-templated supramolecular compounds constructed by a new tridentate ligand 2,4,6-tris[1-(4-oxidroxypyridinium)-ylmethyl]-mesitylene23Two new coordination polymers constructed by naphthalene-1,4-dicarboxylic acid and 2,4-diamino-6-methyl-triazine15Six New 2D or 3D Metal–Organic Frameworks Based on Bithiophene-Containing Ligand and Dicarboxylates: Syntheses, Structures, and Properties53New photocatalyst for the degradation of organic dyes based on [Co2(1,4-BDC)(NCP)2]n·4nH2O54Structural Diversities and Fluorescent and Photocatalytic Properties of a Series of CuII Coordination Polymers Constructed from Flexible Bis-pyridyl-bis-amide Ligands with Different Spacer Lengths and Different Aromatic Carboxylates1402,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids56Two new Cu(II) complexes constructed by mixed-organic tectonics: Structures, magnetic properties and photocatalytic degradation of organic dyes29The crystal chemistry of uranium carboxylates394Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties29Structural and functional studies on ternary coordination polymers from 5-bromoisophthalate and imidazole based flexible linker23Synthesis, crystal structure, photoluminescence property and photoelectronic behavior of two uranyl-organic frameworks constructed from 1, 2, 4, 5-benzenetetracarboxylic acid as ligand34A polyoxometalate-based complex with visible-light photochromism as the electrocatalyst for generating hydrogen from water10Construction of a series of coordination polymers based on 1,4-naphthalenedicarboxylic and flexible dipyridyl ligands38MOFs of Uranium and the Actinides95Novel coordination polymers of Zn( ii ) and Cd( ii ) tuned by different aromatic polycarboxylates: synthesis, structures and photocatalytic properties76Photocatalytic organic pollutants degradation in metal–organic frameworks1671Structural variability, topological analysis and photocatalytic properties of neoteric Cd( ii ) coordination polymers based on semirigid bis(thiazolylbenzimidazole) and different types of carboxylic acid linkers82Structures, photoluminescence and photocatalytic properties of two novel metal–organic frameworks based on tetrazole derivatives35A Systematic Research on the Synthesis, Structures, and Application in Photocatalysis of Cluster-Based Coordination Complexes91Transition-metal ion modified monolacunary tungstates: Synthesis, structural characterization and property7Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules60Syntheses, characterizations, thermal stability and photoluminescence of four silver coordination polymers with mixed ligands17Ligand configuration introduced into a 3D self-interpenetrated coordination polymer as visible-light-driven photocatalyst11A novel 3D heterometallic coordination complex with (3,4,5)-connected net topology: Synthesis, structure and luminescent property15A trilaminar cobalt coordination network with trinuclear and uninuclear building units13Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55Four new dinuclear uranyl complexes based on p- and m-toluic acid: Syntheses, structures, luminescent and photocatalytic properties21Microwave and Conventional Hydro(solvo)thermal Syntheses of Three Co(II) Coordination Polymers: Supramolecular Isomerism and Structural Transformations Accompanied by Tunable Magnetic Properties26Two new two-dimensional layered uranyl-bearing polycarboxylates from semi-rigid tetracarboxylic acids15Anion Recognition by Uranyl–Salophen Derivatives as Probed by Infrared Multiple Photon Dissociation Spectroscopy and Ab Initio Modeling15Synthesis, Crystal Structures and Properties of Two Transition Metal Complexes Based on 4, 4'-{[2, 2'-(ethane-1, 2-bicarboxymethyl)] amino-bis(acetyl)} Dibenzoic Acid0The First Family of Actinide Carboxyphosphinates: Two‐ and Three‐Dimensional Uranyl Coordination Polymers27Novel uranyl( vi ) complexes incorporating propylene-bridged salen-type N 2 O 2 -ligands: a structural and computational approach50Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers46UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties29Series metal–organic frameworks constructed from 1,10-phenanthroline and 3,3′,4,4′-biphenyltetracarboxylic acid: Hydrothermal synthesis, luminescence and photocatalytic properties50Synthesis and crystal structure of nickel coordination polymer with 2,8-di(pyridine-4-yl)dibenzothiophene3Design, synthesis and structure of uranyl coordination polymers from 2-D layer to 3-D network structure2Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye91Complexation of uranyl ions by N-(sulfoethyl)-iminodiacetic acid: Hydrothermal synthesis, luminescence, and uranyl sequestration1A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31A series of multidimensional MOFs incorporating a new N-heterocyclic building block: 5,5′-di(pyridin-4-yl)-3,3′-bi(1,2,4-triazole)5Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Syntheses, structures, magnetic and luminescence properties of a series of coordination polymers constructed from 1,4-naphthalenedicarboxylate and N-donor ligands14Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands34Syntheses, Characterizations, Luminescent Properties, and Controlling Interpenetration of Five Metal–Organic Frameworks Based on Bis(4-(pyridine-4-yl)phenyl)amine33Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Structural Influencing Factors on Zn II /Cd II Coordination Polymers Based on Tri‐pyridyl‐bis‐amide: Assembly, Structures, Fluorescent Sensing and Selective Photocatalysis18Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation51Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers53Unexpected cis-dioxido uranyl carboxylate compound: Synthesis, characterization and photocatalytic activity of uranyl-succinate complexes17Synthesis, Structure, and Photoluminescence Properties of an Organically‐Templated Uranyl Selenite3A Family of Fe(II)/Cl Supramolecular Coordination Systems Incorporating 5,5′-Di(pyridin-2-yl)-3,3′-bi(1,2,4-triazole)16Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations25Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56Two 1D coordination polymers constructed from 3,3′,4,4′-biphenyltetracarboxylic acid and 4,4′-bipyridine: hydrothermal syntheses and photocatalytic performance15A Family of Uranyl Coordination Polymers Containing O-Donor Dicarboxylates and Trispyridyltriazine Guests36Probing the Influence of N‐Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials45Construction of a New Co(II) Coordination Polymer With Excellent Photocatalytic Property2A series of coordination polymers with tuned terphenyl tetracarboxylates and bis-pyridyl ligands with different flexibilities manifesting fluorescence properties and photocatalytic activities25Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres37Photocatalysis from a series of polyoxoazocobaltate high-nuclearity nanoclusters17The electrochemical properties, nitrogen adsorption, and photocatalytic activities of three 3D metal–organic frameworks bearing the rigid terphenyl tetracarboxylates ligands40Structural Variations of the First Family of Heterometallic Uranyl Carboxyphosphinate Assemblies by Synergy between Carboxyphosphinate and Imidazole Ligands21Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes41Synthesis, structure, luminescence and photocatalytic properties of an uranyl-2,5-pyridinedicarboxylate coordination polymer32Synthesis, structure, and photocatalytic property of a new Co(II) coordination polymer with 4-connected cds topology3Tuning the morphology of ZnO nanoparticles by Zn-clusters and application on the photoreduction of Cr(VI)7Modulation of the Structure and Properties of Uranyl Ion Coordination Polymers Derived from 1,3,5-Benzenetriacetate by Incorporation of Ag(I) or Pb(II)46Determination of trace uranium by resonance fluorescence method coupled with photo-catalytic technology and dual cloud point extraction21Structure and Photocatalytic Property of a Novel Three-Dimensional Supramolecular Cu(ΙΙ) Coordination Polymer with pcu Topology Based on the Rigid Multifunctional Ligand3Exploring Crystal Engineering for Porous Uranyl–Organic Frameworks: Insight into Hydrolysis and In Situ Reaction, Structural Variation‐Dependent Physical Properties6Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31

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  2. Uranyl Ion Complexes with Cucurbit[5]uril: from Molecular Capsules to Uranyl-Organic Frameworks

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  5. Synthesis and characterizations of a novel dia-type Ag–BPT coordination polymer with tetranuclear motifs as jointing points (BPT = 3,5-bis(3-pyridyl)-1,2,4-triazole)

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  48. 3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials

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