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RESEARCH PAPER · Crystal Growth & Design · 2012

Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers

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Six-Fold Coordinated Uranyl Cations in Extended Coordination PolymersOriginalAssembly of Zn/Cd coordination polymers containing helixes or polycatenane structures tuned by the tri-pyridyl–bis-amide ligands with different spacer: syntheses, structures, photoluminescent and photocatalytic properties63One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids29Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors37Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers85Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O31A Uranyl Hybrid Compound Designed from Urea‐Bearing Dipropionic Acid16Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U4O4} and Hexanuclear {U6O4(OH)4} Motifs66Series of Uranyl-4,4′-biphenyldicarboxylates and an Occurrence of a Cation–Cation Interaction: Hydrothermal Synthesis and in Situ Raman Studies36Synthesis, Structure and Properties of a Novel Metal-Organic Coordination Polymer, [Zn (NH3)2(BDC)]n1The crystal chemistry of uranium carboxylates394Isolation of the Large {Actinide}38 Poly-oxo Cluster with Uranium94Synthesis, crystal structure, photoluminescence property and photoelectronic behavior of two uranyl-organic frameworks constructed from 1, 2, 4, 5-benzenetetracarboxylic acid as ligand34Isolation of a series of uranium organophosphinates11Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent77Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules60Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands40Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55Four new dinuclear uranyl complexes based on p- and m-toluic acid: Syntheses, structures, luminescent and photocatalytic properties21Lanthanide Coordination Polymers with “fsy-type” Topology Based on 4,4′-Azobenzoic Acid: Syntheses, Crystal Structures, and Magnetic Properties110UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties29Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye91A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework24Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate33Syntheses, structures, magnetic and luminescence properties of a series of coordination polymers constructed from 1,4-naphthalenedicarboxylate and N-donor ligands14Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands34Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration16Syntheses, crystal structures and properties of four novel coordination polymers assembled from versatile 1,2,3,5-benzenetetracarboxylic acid17A New 3D Pb(II) Inorganic–Organic Hybrid Framework Based on Terephthalate Acid with the Inorganic Pb–O–Pb Connectivity1Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Thorium(IV) organic frameworks with aromatic polycarboxylate ligands11Synthesis, crystal structure, and spectra of the Np(V) terephthalate [C(NH2)3]3[NpO2(C6H4(COO)2)2]·5H2O and An(VI) terephthalates [AnO2(C6H4(COO)2)] (An = U, Np, Pu)6Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies36Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Synthesis and structure of dimeric complexes of U(VI) and Np(VI) with isophthalic acid anions, {AnO2[C6H4(COO)(COOH)]2(H2O)}25Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56A Family of Uranyl Coordination Polymers Containing O-Donor Dicarboxylates and Trispyridyltriazine Guests36Solvothermal synthesis of uranium(VI) phases with aromatic carboxylate ligands: A dinuclear complex with 4-hydroxybenzoic acid and a 3D framework with terephthalic acid28Uranium(VI) hybrid materials with [(UO 2 ) 3 (µ 3 ‐O)(µ 2 ‐OH) 3 ] + as the sub–building unit via uranyl–cation interactions21Cobalt(II) complexes with bis(N-imidazolyl/benzimidazolyl) pyridazine: Structures, photoluminescent and photocatalytic properties23Synthesis and structural features of Np(VI) and Pu(VI) isophthalates2Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31Copper/Zinc-Directed Heterometallic Uranyl-Organic Polycatenating Frameworks: Synthesis, Characterization, and Anion-Dependent Structural Regulation32Solvent‐Dependent Synthesis of Porous Anionic Uranyl–Organic Frameworks Featuring a Highly Symmetrical (3,4)‐Connected ctn or bor Topology for Selective Dye Adsorption64A stable pillared-layer Cu( ii ) metal–organic framework with magnetic properties for dye adsorption and separation39Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center19Two Three‐Dimensional Actinide–Silver Heterometallic Coordination Polymers Based on 2,2′‐Bipyridine‐3,3′‐dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs21Synthesis, crystal structures, and properties of three coordination polymers of 5-(1H-imidazol-1-yl) isophthalic acid10Synthesis and characterization of a novel dicyanamide-bridged Co(II) 1-D coordination polymer with a N4-donor Schiff base ligand11Exploring New Assembly Modes of Uranyl Terephthalate: Templated Syntheses and Structural Regulation of a Series of Rare 2D → 3D Polycatenated Frameworks39Structural Consequences of 1,4-Cyclohexanedicarboxylate Cis/Trans Isomerism in Uranyl Ion Complexes: From Molecular Species to 2D and 3D Entangled Nets67Complexes of Uranyl Ions with Aromatic Di‐ and Tetracarboxylates Involving [Ni(bipy)n]2+ (n = 2, 3) Counterions12Novel Viologen Derivative Based Uranyl Coordination Polymers Featuring Photochromic Behaviors61Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Syntheses, crystal structures, and properties of two dinuclear iron(III) complexes constructed with 1,2,3,5-benzenetetracarboxylic acid and chelating N-donor auxiliary coligands2Speciation of Actinide Complexes, Clusters, and Nanostructures in Solution2Semirigid Tripodal Ligand Based Uranyl Coordination Polymer Isomers Featuring 2D Honeycomb Nets33Bimetallic Uranyl Organic Frameworks Supported by Transition-Metal-Ion-Based Metalloligand Motifs: Synthesis, Structure Diversity, and Luminescence Properties48Actinide‐Based Porphyrinic MOF as a Dehydrogenation Catalyst48Organic Compounds of Actinyls: Systematic Computational Assessment of Structural and Topological Properties in [AnO2(C2O4)n](2n−2)–(An = U, Np, Pu, Am;n= 1–3) Complexes16Metal–Organic Frameworks in Modern Physics: Highlights and Perspectives104Structural Diversity of Bipyridinium-Based Uranyl Coordination Polymers: Synthesis, Characterization, and Ion-Exchange Application46Noncomplexed Cucurbituril-Mediated Structural Evolution of Layered Uranyl Terephthalate Compounds13Zero-, mono- and diperiodic uranyl ion complexes with the diphenate dianion: influences of transition metal ion coordination and differential U VI chelation11Rare Three-Dimensional Uranyl–Biphenyl-3,3′-disulfonyl-4,4′-dicarboxylate Frameworks: Crystal Structures, Proton Conductivity, and Luminescence28Complexation and enantioselectivity of sulfur/selenium-substituted uranyl-salophens with R/S-chiral lactone for RRS/SSR-3, 5-Dimethyl-2-(3-fluorophenyl)-2-morpholinols8Quantitative Precipitation of Uranyl or Plutonyl Nitrate with N-(1-Adamantyl)acetamide in Nitric Acid Aqueous Solution9Variability of Uranyl Carboxylates from Rigid Terophenyldicarboxylic Acid Ligands17Controlling the secondary assembly of porous anionic uranyl–organic polyhedra through organic cationic templates5The versatile coordination chemistry of 1,3-benzenedicarboxylate in the last 20 years: An investigation from the coordination modes to spectroscopic insights7Filling the equatorial garland of uranyl ion: its content and limitations6Contrasting Structure-Directing Effects in the Uranyl–Phthalate/Isophthalate Isomer Systems19Rare cis‐Dioxido Uranyl Framework Crystalline Complexes: Synthesis, Structure, Characterization and Properties1Chain, Network and Framework Formation in Uranyl Ion Complexes with 1,1′‐Biphenyl‐3,3′,4,4′‐Tetracarboxylate1Secondary Role of Aliphatic and Heterocyclic Amines in the Formation of Low-Temperature Amine-Bearing U, Np, and Pu(VI) Chromates2Spatially confined coordination platform in covalent organic framework for selective uranium adsorption from aqueous solutions27The crystal structure of poly[(μ 2-2-aminoisophthalato-κ4O,O′:O″:O″′)-(N-methylpyrrolidone κ1O)-dioxido-uranium(VI)], C13H14N2O7U1Results of 25-Year Studies of Uranium Compounds at the Department of Crystallography of St. Petersburg State University3

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