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RESEARCH PAPER · Inorganic Chemistry · 2003

The Fascinating Noncentrosymmetric Copper(II) Phosphates Synthesized via CsCl Salt-Inclusion

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The Fascinating Noncentrosymmetric Copper(II) Phosphates Synthesized via CsCl Salt-InclusionOriginalThe Fascinating Noncentrosymmetric Copper(II) Phosphates Synthesized via CsCl Salt‐Inclusion.016 Copper322 New compounds and structures in the solid state220 New compounds and structures in the solid state5From AgCN Chains to a Fivefold Helix and a Fishnet‐Shaped Framework Structure39Von AgCN‐Ketten zur Fünffachhelix und zur fischernetzartigen Gerüststruktur6Copper: Inorganic & Coordination ChemistryBased in part on the article Copper: Inorganic & Coordination Chemistry by Rebecca R. Conry & Kenneth D. Karlin which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .35Copper: Inorganic & Coordination ChemistryBased in part on the article Copper: Inorganic & Coordination Chemistry by Rebecca R. Conry & Kenneth D. Karlin which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .10Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of a Salt-Inclusion Stannosilicate: [Na3F][SnSi3O9]31Destruction of Noncentrosymmetry through Chalcogenide Salt Inclusion24Hydrothermal Synthesis and Crystal Structure of Novel Alkali Trimolybdates7Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences75Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg6Sb4)(CdI6)19A New Series of Chalcohalide Semiconductors with Composite CdBr2/Sb2Se3 Lattices: Synthesis and Characterization of CdSb2Se3Br2 and Indium Derivatives InSb2S4X (X = Cl and Br) and InM2Se4Br (M = Sb and Bi)37The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids52The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids1Flux Synthesis, Crystal Structures, and Luminescence Properties of Salt-Inclusion Lanthanide Silicates: [K9F2][Ln3Si12O32] (Ln = Sm, Eu, Gd)49Synthetic Approaches for Noncentrosymmetric Molybdates59A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134Flux Synthesis of Salt-Inclusion Uranyl Silicates: [K3Cs4F][(UO2)3(Si2O7)2] and [NaRb6F][(UO2)3(Si2O7)2]47Noncentrosymmetry in New Templated Gallium Fluorophosphates34Salt-Templated Mesoporous Solids Comprised of Interlinked Polyoxovanadate Clusters27Molten Salt Synthesis and Structural Characterization of Novel Salt-Inclusion Vanadium Bronze Cs5FeV5O13Cl618Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Extended Utility of Molten-Salt Chemistry: Unprecedented Synthesis of a Water-Soluble Salt-Inclusion Solid Comprised of High-Nuclearity Vanadium Oxide Clusters20Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs + -based half SOD β-cage9New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Salt-flux synthesis of complex oxides: Cs0.33MoO3, CsFe(MoO4)2, and the inverse salt-inclusion phase Cs2Mo0.65O0.21Cl5.449Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity52Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units5Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks26The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds31Chemistry of Polar Transition-Metal Oxides1New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles56High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na9F2][(UVO2)(UVIO2)2(Si2O7)2]32Sr3B6O11F2: a promising polar fluoroborate with short UV absorption edge and moderate second harmonic generation response30Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials58Two New Barium Borate Fluorides ABa12(BO3)7F4 (A = Li and Na)41Rare‐Earth Cadmium Tellurite Chlorides with a Structural Type Exhibiting [Ln12(TeO3)12] Slabs Alternating with CdCl6 Octahedral Layers11A cesium copper vanadyl-diphosphate: Synthesis, crystal structure and physical properties6M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)15Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13PKU-3: An HCl-Inclusive Aluminoborate for Strecker Reaction Solved by Combining RED and PXRD40Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type11Synthesis, crystal structures, magnetic properties, and lattice dynamics of Ba2XCu(OH)[V2O7] with X=Cl, Br8Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products38Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates61The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Synthesis, Structures, and Luminescent Properties of Sodium Rare‐Earth Metal(III) Chloride Oxotellurates(IV), Na2Ln3Cl3[TeO3]4 (Ln = Sm, Eu, Gd, Tb, Dy, and Ho)10Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials267Bond-length distributions for ions bonded to oxygen: results for the non-metals and discussion of lone-pair stereoactivity and the polymerization of PO 447Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Understanding the Stability of Salt-Inclusion Phases for Nuclear Waste-forms through Volume-based Thermodynamics11Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF 4 –GaPO 4 –ACl (A = Cs, Rb) phase space7Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates14New Microporous Copper Diphosphate Chloride in a Series of Homeotypic Compounds: Hydrothermal Synthesis, Crystal Structure, and Crystal Chemistry1Flux Synthesis, UV–vis Absorbance, and Magnetism of Cesium Copper Silicates with an Isolated Super-Super Exchange Spin Dimer in Cs6Cu2Si9O230A new salt-inclusion compound CsCl·(VOSe 2 O 5 ) 4 showing nearly isolated spin-1/2 chain structure with a typical square lattice1

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  1. The Fascinating Noncentrosymmetric Copper(II) Phosphates Synthesized via CsCl Salt‐Inclusion.

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  2. 16 Copper

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  3. 22 New compounds and structures in the solid state

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  4. 20 New compounds and structures in the solid state

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  5. From AgCN Chains to a Fivefold Helix and a Fishnet‐Shaped Framework Structure

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  6. Von AgCN‐Ketten zur Fünffachhelix und zur fischernetzartigen Gerüststruktur

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  7. Copper: Inorganic & Coordination ChemistryBased in part on the article Copper: Inorganic & Coordination Chemistry by Rebecca R. Conry & Kenneth D. Karlin which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .

    Encyclopedia of Inorganic Chemistry · 2005-09-07

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  8. Copper: Inorganic & Coordination ChemistryBased in part on the article Copper: Inorganic & Coordination Chemistry by Rebecca R. Conry & Kenneth D. Karlin which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .

    Encyclopedia of Inorganic and Bioinorganic Chemistry · 2005-09-07

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  9. Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of a Salt-Inclusion Stannosilicate: [Na3F][SnSi3O9]

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  10. Destruction of Noncentrosymmetry through Chalcogenide Salt Inclusion

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  11. Hydrothermal Synthesis and Crystal Structure of Novel Alkali Trimolybdates

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  12. Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences

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  13. Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg6Sb4)(CdI6)

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  14. A New Series of Chalcohalide Semiconductors with Composite CdBr2/Sb2Se3 Lattices: Synthesis and Characterization of CdSb2Se3Br2 and Indium Derivatives InSb2S4X (X = Cl and Br) and InM2Se4Br (M = Sb and Bi)

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  15. The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids

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  16. The Versatile Chemistry and Noncentrosymmetric Crystal Structures of Salt‐Inclusion Vanadate Hybrids

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  17. Flux Synthesis, Crystal Structures, and Luminescence Properties of Salt-Inclusion Lanthanide Silicates: [K9F2][Ln3Si12O32] (Ln = Sm, Eu, Gd)

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    Ming-Feng Tang, Pei-Yun Chiang, Yu-Han Su, Yu‐Chi Jung, Guang‐Yi Hou, Bor‐Chen Chang, Kwang‐Hwa Lii

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  18. Synthetic Approaches for Noncentrosymmetric Molybdates

    Inorganic Chemistry · 2008-09-29

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  19. A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

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  20. Flux Synthesis of Salt-Inclusion Uranyl Silicates: [K3Cs4F][(UO2)3(Si2O7)2] and [NaRb6F][(UO2)3(Si2O7)2]

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  21. Noncentrosymmetry in New Templated Gallium Fluorophosphates

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  22. Salt-Templated Mesoporous Solids Comprised of Interlinked Polyoxovanadate Clusters

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  23. Molten Salt Synthesis and Structural Characterization of Novel Salt-Inclusion Vanadium Bronze Cs5FeV5O13Cl6

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  24. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

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  25. A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties

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  26. Extended Utility of Molten-Salt Chemistry: Unprecedented Synthesis of a Water-Soluble Salt-Inclusion Solid Comprised of High-Nuclearity Vanadium Oxide Clusters

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  27. Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs + -based half SOD β-cage

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  28. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

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  29. Salt-flux synthesis of complex oxides: Cs0.33MoO3, CsFe(MoO4)2, and the inverse salt-inclusion phase Cs2Mo0.65O0.21Cl5.44

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  30. Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

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  31. Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units

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  32. Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks

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  33. The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds

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  34. Chemistry of Polar Transition-Metal Oxides

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  35. New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles

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  36. High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na9F2][(UVO2)(UVIO2)2(Si2O7)2]

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  37. Sr3B6O11F2: a promising polar fluoroborate with short UV absorption edge and moderate second harmonic generation response

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  38. Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials

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  39. Two New Barium Borate Fluorides ABa12(BO3)7F4 (A = Li and Na)

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  40. Rare‐Earth Cadmium Tellurite Chlorides with a Structural Type Exhibiting [Ln12(TeO3)12] Slabs Alternating with CdCl6 Octahedral Layers

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  41. A cesium copper vanadyl-diphosphate: Synthesis, crystal structure and physical properties

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  42. M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)

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  43. Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra

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  44. PKU-3: An HCl-Inclusive Aluminoborate for Strecker Reaction Solved by Combining RED and PXRD

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  45. Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type

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  46. Synthesis, crystal structures, magnetic properties, and lattice dynamics of Ba2XCu(OH)[V2O7] with X=Cl, Br

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  47. Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products

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    Gregory W. Morrison, Hans‐Conrad zur Loye

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  48. Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates

    Journal of the American Chemical Society · 2016-05-24

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  49. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges

    Dalton Transactions · 2017-01-01

    Miriding Mutailipu, Min Zhang, Yanna Chen, Xiaoquan Lu, Shilie Pan

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  50. Synthesis, Structures, and Luminescent Properties of Sodium Rare‐Earth Metal(III) Chloride Oxotellurates(IV), Na2Ln3Cl3[TeO3]4 (Ln = Sm, Eu, Gd, Tb, Dy, and Ho)

    Zeitschrift für anorganische und allgemeine Chemie · 2017-10-02

    Dmitri O. Charkin, Sabine Zitzer, Stefan Greiner, Sergey Gennadievich Dorofeev, Andrei V. Olenev, Peter S. Berdonosov, Thomas Schleid, В. А. Долгих

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