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RESEARCH PAPER · Progress in Solid State Chemistry · 2007

Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences

Mercouri G. Kanatzidis, Kenneth Reinhard Poeppelmeier, Svilen Bobev, Arnold M. Guloy, Shiou Jyh Hwu, Abdou Lachgar, Susan E. Latturner, Raymond, E. Schaak, Dong-Kyun Seo, Slavi C. Sevov, Andreas Stein, B. Dąbrowski, John E. Greedan, M. Greenblatt, Clare P. Grey, Allan J. Jacobson, Douglas A. Keszler, Jing Li, Mas A. Subramanian, Younan Xia, Tahir Çağın, Ulrich Häußermann, Timothy R. Hughbanks, S. D. Mahanti, Dane D. Morgan, Dong-Kyun Seo, Nicola A. Spaldin, William E. Buhro, Daniel E. Giammar, Jennifer Ann Hollingsworth, David C. Johnson, Arthur J. Nozik, Xiaogang Peng, Robert L. Bedard, Nathaniel E. Brese, Guang Cao, Sandeep S. Dhingra, Cherie R. Kagan, David B. Mitzi, Margret J. Geselbracht, George C. Lisensky, Michael W. Lufaso, Paul A. Maggard, O'Keeffe Michael, Angus Paul Wilkinson, Hans‐Conrad zur Loye, T. Egami, John E. Greedan, Jason P. Hodges, James D. Martin, John B. Parise, Brian H. Toby, Terrell A. Vanderah, Peter Carman Burns, Julia Y. Chan, Anne E. Meyer, Christopher B. Murray, Arthur P. Ramirez, Michael D. Ward, Lian Yu, M.Á. Alario-Franco, Peter D. Battle, Thomas Bein, Christopher L. Cahill, P. Shiv Halasyamani, Antoine Maignan, Ram Seshadri

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Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciencesOriginalYb3CoSn6 and Yb4Mn2Sn5: New polar intermetallics with 3D open-framework structures23Artificial Neural Network Method to Construct Potential Energy Surfaces for Transition Metal Nanoparticles: Pt, Au, and Ag3Use of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn 2 SnS 4 (N 2 H 4 ) 2 ]52KMBP2O8 (M = Sr, Ba): A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework99Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33− Unit46Building Units and Intergrowths: Toward the Design of an Extended Family of Acentric Bi-Based Materials with Second Harmonic Generacy19Chalcogens and Metal Chalcogenides19Hybrid materials through linkage of chalcogenide tetrahedral clusters68Syntheses and characterization of some solid-state actinide (Th, U, Np) compounds79Arrays of Chiral Nanotubes and a Layered Coordination Polymer Containing Gallium–Sulfide Supertetrahedral Clusters51TEM and ED confirmation of conversion of 3D and 2D perovskite-type into fluorite-type structure3Hydrazine-hydrothermal method to synthesize three-dimensional chalcogenide framework for photocatalytic hydrogen generation132CsAlZr2(PO4)4: an anhydrous aluminium zirconium phosphate with a novel three-dimensional framework2New quenched-in fluorite-type materials in the Bi2O3–La2O3–PbO system: Synthesis and complex phase behaviour up to 750°C2Magnetoelectricity21Syntheses and Structures of Sc2Nb4–xSn5, YNb6Sn6, and ErNb6Sn5: Exploratory Studies in Ternary Rare-Earth Niobium Stannides6Syntheses and Characterization of Nine Quaternary Uranium Chalcogenides Among the Compounds A2M3UQ6 (A = K, Rb, Cs; M = Pd, Pt; Q = S, Se)23Synthesis, structure and characterization of two new copper(І)-thioarsenates (ІІІ) constructed by the [AsS3]3− and CuS units25A 3-D chiral organic–inorganic hybrid zinc vanadate assembled from helical units20Self-cleaning antimicrobial surfaces by bio-enabled growth of SnO2 coatings on glass29K 13 CoSn 17– x ( x = 0.1): A New Ternary Phase Containing Cobalt Centered [Sn 9 ] Cluster Synthesized via High‐Temperature Reaction8New strategies to prepare crystalline chalcogenides166Solid-state actinide acid phosphites from phosphorous acid melts3Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability46Surfactant-thermal method to prepare two novel two-dimensional Mn–Sb–S compounds for photocatalytic applications32Surfactant-Thermal Syntheses, Structures, and Magnetic Properties of Mn–Ge–Sulfides/Selenides45[Mn(dien) 2 ]MnSnS 4 , [Mn(1,2-dap)] 2 Sn 2 S 6 and [Mn(en) 2 ]MnGeS 4 : from 1D anionic and neutral chains to 3D neutral frameworks33Structure–property relationships in fluorite-type Bi 2 O 3 –Yb 2 O 3 –PbO solid-electrolyte materials1From Solid‐State Chemistry to Soft Chemistry Routes4Lewis Base Mediated Polymorph Selectivity of Pyrite CuSe2 through Atom Transfer in Solid-State Metathesis15Circumventing Diffusion in Kinetically Controlled Solid-State Metathesis Reactions54Crystal structure and luminescence properties of self-activated phosphor CsDyP 2 O 714Toward Reaction-by-Design: Achieving Kinetic Control of Solid State Chemistry with Metathesis111Nanoparticles Restrictions in Environmental Cleanup5Recent progress in crystalline metal chalcogenides as efficient photocatalysts for organic pollutant degradation179Layered Two-Phase Magnetoelectric Materials0Layered Two-Phase Magnetoelectric Materials0Synthesis, Structures, and Luminescent Properties of Sodium Rare‐Earth Metal(III) Chloride Oxotellurates(IV), Na2Ln3Cl3[TeO3]4 (Ln = Sm, Eu, Gd, Tb, Dy, and Ho)10Unexpected Competition between Antiferromagnetic and Ferromagnetic States in Hf 2 MnRu 5 B 2 : Predicted and Realized16Environmental Nanotechnology: Applications of Nanoparticles for Bioremediation26Exploring the Surfactant–Thermal Synthesis of Crystalline Functional Thioarsenates48Designing and Teaching a Course about Characterization Techniques for Solid State Materials in an Undergraduate Institution15Characterization and Ecotoxicological Evaluation of Nanostructured Chitosan Particles2Selective metathesis synthesis of MgCr 2 S 4 by control of thermodynamic driving forces43Microbes: A Potential Tool for Bioremediation22Toxicity/risk assessment of nanomaterials when used in soil treatment2Rational Solid-State Synthesis Routes for Inorganic Materials1Recent advances in nonmetallic atom-doped metal nanocrystals: Synthesis and catalytic applications21Observing and Modeling the Sequential Pairwise Reactions that Drive Solid‐State Ceramic Synthesis88Rational Solid-State Synthesis Routes for Inorganic Materials114One Pot Three Component Synthesis of Substituted 3,4,6,7-Tetrahydro-3,3,6,6-Tetramethyl-9,10-Diphenylacridine-1,8(2H,5H,9H,10H)-Diones Catalyzed by Mesostrucrted In 2 O 3 -SiO 24In-situ, Ex-situ, and nano-remediation strategies to treat polluted soil, water, and air – A review262Advances and Applications of Bioremediation: Network of Omics, System Biology, Gene Editing and Nanotechnology14Investigation of Metastable Low Dimensional Halometallates5Formation of the Metastable Iron (III) Germanate Fe2GeO5 through Kinetic Control of the Oxidative Reaction0Structural evolution of transition metal orthoborates (Zn3B2O6−Co3B2O6) with the Kotoite mineral structure: Synthesis, structure and properties13Nanomaterials for Fabrication of Thermomechanical Robust Composite1Green formulation of palladium nanoparticles on photocatalytic behavior of fabric dyes removal and its antibacterial assay24Transformation of K2Sb8Q13 and KSb5Q8 Bulk Crystals to Sb2Q3 (Q = S, Se) Nanofibers by Acid–Base Solution Chemistry7Synthesis and properties of semiconductor bismuth sulfide iodide for photoelectrochemical applications5Mesoporous Materials for Metal-Laden Wastewater Treatment22Methods for the synthesis of barium titanate as a component of functional dielectric ceramics3Mn-Doped Ca14Mg4Ga12O36 with the Tululite Mineral Structure for Color-Tunable Emission14Functionalized Nanostructured Materials for Supercapacitor Applications1Concentration-Dependent Layer-Stacking and the Influence on Phase-Conversion in Colloidally Synthesized WSe2 Nanocrystals2Rational Pathways to Ordered Multianion Chalcogenides Using Retrosynthetic Crystal Chemistry16Soil pollution: an agricultural and environmental problem with nanotechnological remediation opportunities and challenges34Antiperovskite materials: advances in synthesis, unique properties, and emerging applications in energy and electronics5The Dugganite Structure as a Host for New Colored Compounds and for Oxygen Evolution Studies1Kinetic effects of ball-milling precursors on the synthesis pathway of KSbF40Interface chemistry in solid-state batteries: Advances, challenges, and future prospects12Direct Joule-Heated Non-Equilibrium Synthesis Enables High Performing Thermoelectrics1Dual‐Functional Phosphors Based on Ba 2 Zn 2 TeP 2 O 11 : White‐Light Emission and Luminescence Quenching Sensors0Some Personal Reflections on NASSCC and the Growth of Solid State Chemistry at Iowa State University0Bioactive Glasses for Bone Regeneration2Phase-Pure Synthesis and Thermal Transport Properties of Metallic Telluride Cu5Ge2Te71Some personal reflections on NASSCC and the growth of solid state chemistry at Iowa State University0

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  2. Artificial Neural Network Method to Construct Potential Energy Surfaces for Transition Metal Nanoparticles: Pt, Au, and Ag

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  3. Use of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn 2 SnS 4 (N 2 H 4 ) 2 ]

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  4. KMBP2O8 (M = Sr, Ba): A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework

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  5. Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33− Unit

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  6. Building Units and Intergrowths: Toward the Design of an Extended Family of Acentric Bi-Based Materials with Second Harmonic Generacy

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  8. Hybrid materials through linkage of chalcogenide tetrahedral clusters

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  9. Syntheses and characterization of some solid-state actinide (Th, U, Np) compounds

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  10. Arrays of Chiral Nanotubes and a Layered Coordination Polymer Containing Gallium–Sulfide Supertetrahedral Clusters

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  11. TEM and ED confirmation of conversion of 3D and 2D perovskite-type into fluorite-type structure

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  12. Hydrazine-hydrothermal method to synthesize three-dimensional chalcogenide framework for photocatalytic hydrogen generation

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  13. CsAlZr2(PO4)4: an anhydrous aluminium zirconium phosphate with a novel three-dimensional framework

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  17. Syntheses and Characterization of Nine Quaternary Uranium Chalcogenides Among the Compounds A2M3UQ6 (A = K, Rb, Cs; M = Pd, Pt; Q = S, Se)

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  18. Synthesis, structure and characterization of two new copper(І)-thioarsenates (ІІІ) constructed by the [AsS3]3− and CuS units

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  19. A 3-D chiral organic–inorganic hybrid zinc vanadate assembled from helical units

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  20. Self-cleaning antimicrobial surfaces by bio-enabled growth of SnO2 coatings on glass

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  21. K 13 CoSn 17– x ( x = 0.1): A New Ternary Phase Containing Cobalt Centered [Sn 9 ] Cluster Synthesized via High‐Temperature Reaction

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  24. Syntheses of Two Vanadium Oxide–Fluoride Materials That Differ in Phase Matchability

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