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RESEARCH PAPER · Inorganic Chemistry · 2014

Syntheses, Structures, and Nonlinear-Optical Properties of Metal Sulfides Ba2Ga8MS16 (M = Si, Ge)

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Syntheses, Structures, and Nonlinear-Optical Properties of Metal Sulfides Ba2Ga8MS16 (M = Si, Ge)OriginalChemInform Abstract: Syntheses, Structures, and Nonlinear‐Optical Properties of Metal Sulfides Ba2Ga8MS16 (M: Si, Ge).0Na4MgM2Se6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M2Se6]6– Units Exhibiting Large Laser-Damage Thresholds56[A 3 X][Ga 3 PS 8 ] (A = K, Rb; X = Cl, Br): promising IR non-linear optical materials exhibiting concurrently strong second-harmonic generation and high laser induced damage thresholds189BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties97Crystal and electronic structures, and photoluminescence and photocatalytic properties of α-EuZrS 326Syntheses, Structures, and Nonlinear Optical Properties of Two Sulfides Na2In2MS6 (M = Si, Ge)53Ba4Ga2Se8: A ternary selenide containing chains and discrete Se22− units14Syntheses and structural characterization of non-centrosymmetric Na2M2M'S6 (M, M′=Ga, In, Si, Ge, Sn, Zn, Cd) sulfides36Midinfrared Nonlinear Optical Thiophosphates from LiZnPS4 to AgZnPS4: A Combined Experimental and Theoretical Study100Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds186Noncentrosymmetric selenide Ba4Ga4GeSe12: Synthesis, structure, and optical properties9A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS725Analysis and prediction of mid-IR nonlinear optical metal sulfides with diamond-like structures336Phase Transition and Second Harmonic Generation in Thiophosphates Ag2Cd(P2S6) and AgCd3(PS4)S2 Containing Two Second-Order Jahn–Teller Distorted Cations47Recent achievements on middle and far-infrared second-order nonlinear optical materials433Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity44Centrosymmetric to noncentrosymmetric structural transformation of new quaternary selenides induced by isolated dimeric [Sn 2 Se 4 ] units: from Ba 8 Ga 2 Sn 7 Se 18 to Ba 10 Ga 2 Sn 9 Se 2210Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence54Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 252The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances104Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds101Noncentrosymmetric chalcogenides BaZnSiSe4 and BaZnGeSe4 featuring one-dimensional structures56Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Ba 6 Zn 7 Ga 2 S 16 : A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties111AgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response78Hg-Based Infrared Nonlinear Optical Material KHg4Ga5Se12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response101Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge2Se4(μ-Se2)]4– Functional Motif in Polar Polyselenides A4Ge4Se12 (A = Rb, Cs)49Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge39PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method42NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers8New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold142Novel Eu 2+ -activated thiogallate phosphors for white LED applications: structural and spectroscopic analysis2A Series of Lanthanide Selenidogermanates: The First Coexistence of Three Types of Selenidogermanate Units in the Same Architecture10A new 3-D cuprous thiogermanate with rare 3-D [Cu-S-Cu]n network7Strong SHG Response via High Orientation of Tetrahedral Functional Motifs in Polyselenide A2Ge4Se10 (A = Rb, Cs)31Strong Infrared Nonlinear Optical Efficiency and High Laser Damage Threshold Realized in Quaternary Alkali Metal Sulfides Na2Ga2MS6 (M = Ge, Sn) Containing Mixed Nonlinear Optically Active Motifs48A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances253A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials78BaMnSnS 4 and BaCdGeS 4 : infrared nonlinear optical sulfides containing highly distorted motifs with centers of moderate electronegativity48Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 41Synthesis and nonlinear optical properties of new gallium thiophosphate Rb 2 Ga 2 P 2 S 913Syntheses, structures, optical properties, and electronic structures of Ba6Cu2GSn4S16 (G = Fe, Ni) and Sr6D2FeSn4S16 (D = Cu, Ag)9Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition12A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties59Li 2 CdSiS 4 , a promising IR NLO material with a balanced E g and SHG response originating from the effect of Cd with d 10 configuration36Quaternary rare-earth sulfide LaSnGa3S7: Synthesis, structure, thermal and optical properties5Mild solvothermal syntheses and characterizations of two layered sulfides Ba2Cu2Cd2S5 and Ba3Cu4Hg4S915Chalcogenides: Solid‐State Chemistry11LiBa4Ga5Q12 (Q = S, Se): Noncentrosymmetric Metal Chalcogenides with a Cesium Chloride Topological Structure Displaying a Remarkable Laser Damage Threshold32Optimized Metal Chalcogenides for Boosting Water Splitting292Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials131Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system3AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−58BaCdGeSe4: Synthesis, structure and nonlinear optical properties13Highly Distorted [HgS 4 ] Motif-Driven Structural Symmetry Degradation and Strengthened Second-Harmonic Generation Response in the Defect Diamond-Like Chalcogenide Hg 3 P 2 S 847Investigation into Structural Variation from 3D to 1D and Strong Second Harmonic Generation of the AHgPS4 (A+ = Na+, K+, Rb+, Cs+) Family26Designing A New Infrared Nonlinear Optical Material, β‐BaGa 2 Se 4 Inspired by the Phase Transition of the BaB 2 O 4 (BBO) Crystal75Designing A New Infrared Nonlinear Optical Material, β‐BaGa2Se4 Inspired by the Phase Transition of the BaB2O4 (BBO) Crystal13Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks63Achieving a strong second harmonic generation response and a wide band gap in a Hg-based material41Alkali metal partial substitution-induced improved second-harmonic generation and enhanced laser-induced damage threshold for Ag-based sulfides21First polar quaternary sulphide CsLiGa 6 S 10 with mixed ordered alkali cations displaying excellent infrared nonlinear optical properties16Frequency Conversion Characteristics of Hexagonal Ba2Ga8GeS160Li-Free ternary sulphide Cs 5 Ga 9 S 16 with excellent nonlinear optical performance similar to classic LiGaS 213New Quaternary Sulfide LiGaSiS 4: Synthesis, Structure and Optical Properties0Optical and generation characteristics of new nonlinear Ba2Ga8GeS16 and Ba2Ga8(GeSe2)S14 crystals for the mid-IR range10New quaternary sulfide LiGaSiS4: Synthesis, structure and optical properties0Li2Mg2Si2S6 and Li2Mg2Ge2S6: Two nonlinear optical sulfides featuring a unique, polar trigonal structure incorporating ethane‐like anions5A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications115Phase-matching properties of Ba2Ga8GeS1614Metal chalcogenide materials: Synthesis, structure and properties1AeMg6Ga6S16 (Ae = Ca, Sr, Ba): The First Double Alkaline‐Earth Metal Chalcogenides with Excellent Performances29Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction25Na3SiS3F: A Wide Bandgap Fluorothiosilicate with Unique [SiS3F] Unit and High Laser‐Induced Damage Threshold39KHg4Ga3S9: A Hg-Based Sulfide with Nonlinear-Optical Activity in the A–MII–MIII–Q (A = Alkali Metal; MII = d10 Metal; MIII = Ga, In; Q = S, Se) System17Ba2Ga8GeS16: new nonlinear optical crystals with high laser-induced damage threshold for parametric down-conversion in mid-IR11Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Multi-step cation substitution facilitating the exploration of potential infrared nonlinear optical materials6Barium Chalcogenide Crystals: A Review27[Na2PbI][Ga7S12]: Combining Diamond-Like Anionic Framework with Polycationic Chain toward Achieving Remarkable Nonlinear Optical Response21Laser-induced damage threshold of sulfur-containing crystals of barium chalcogenides10CsMgGa 5 S 9 : a diamond-like network made of mixed tetrahedral units for excellent nonlinear optical properties2AgGaS2 and Derivatives: Design, Synthesis, and Optical Properties10Improved performance of SnS/MWCNT heterostructures for photocatalytic, energy generation and supercapacitors applications13Theoretical material properties of the nonlinear optical crystals: disordered barium gallium chalcogenides0Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties6高性能硫属化物红外非线性光学材料构效关系(特邀)0SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0From Polycrystalline Synthesis to Single‐Crystal Growth: Achieving High‐Optical‐Quality BaGa 2 GeSe 6 crystal via a Dual‐Zone Approach1Thermo-mechanical properties of the Ba 2 Ga 8 GeS 16 nonlinear optical crystal0Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0Homologous lattice coupling drives the formation of tetrahedra-ordered phase exhibiting enhanced optical nonlinearity and band gap0

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  1. ChemInform Abstract: Syntheses, Structures, and Nonlinear‐Optical Properties of Metal Sulfides Ba2Ga8MS16 (M: Si, Ge).

    ChemInform · 2015-04-01

    Bin‐Wen Liu, Hui‐Yi Zeng, Mingjian Zhang, Yuhang Fan, Guo‐Cong Guo, Jin‐Shun Huang, Zhen‐Chao Dong

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  2. Na4MgM2Se6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M2Se6]6– Units Exhibiting Large Laser-Damage Thresholds

    Inorganic Chemistry · 2015-10-20

    Kui Wu, Zhihua Yang, Shilie Pan

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  3. [A 3 X][Ga 3 PS 8 ] (A = K, Rb; X = Cl, Br): promising IR non-linear optical materials exhibiting concurrently strong second-harmonic generation and high laser induced damage thresholds

    Chemical Science · 2016-01-01

    Bin‐Wen Liu, Hui‐Yi Zeng, Xiao‐Ming Jiang, Guan‐E Wang, Shu‐Fang Li, Li Xu, Guo‐Cong Guo

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  4. BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties

    Dalton Transactions · 2016-01-01

    Ni Zhen, Kui Wu, Ying Wang, Qiang Li, Wenhui Gao, Dianwei Hou, Zhihua Yang, Huaidong Jiang, Yongjun Dong, Shilie Pan

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  5. Crystal and electronic structures, and photoluminescence and photocatalytic properties of α-EuZrS 3

    New Journal of Chemistry · 2016-01-01

    Sheng‐Ping Guo, Yang Chi, Jian‐Ping Zou, Huaiguo Xue

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  6. Syntheses, Structures, and Nonlinear Optical Properties of Two Sulfides Na2In2MS6 (M = Si, Ge)

    Inorganic Chemistry · 2016-02-04

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  7. Ba4Ga2Se8: A ternary selenide containing chains and discrete Se22− units

    Journal of Solid State Chemistry · 2016-02-08

    Wenlong Yin, Abishek K. Iyer, Xinsong Lin, Arthur Mar

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  8. Syntheses and structural characterization of non-centrosymmetric Na2M2M'S6 (M, M′=Ga, In, Si, Ge, Sn, Zn, Cd) sulfides

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  9. Midinfrared Nonlinear Optical Thiophosphates from LiZnPS4 to AgZnPS4: A Combined Experimental and Theoretical Study

    Inorganic Chemistry · 2016-03-25

    Molin Zhou, Lei Kang, Jiyong Yao, Zheshuai Lin, Yicheng Wu, Chuangtian Chen

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  10. Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds

    Chemistry of Materials · 2016-04-05

    Kui Wu, Zhihua Yang, Shilie Pan

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  11. Noncentrosymmetric selenide Ba4Ga4GeSe12: Synthesis, structure, and optical properties

    Journal of Solid State Chemistry · 2016-06-06

    Wenlong Yin, Abishek K. Iyer, Chao Li, Xinsong Lin, Jiyong Yao, Arthur Mar

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  12. A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS7

    Crystals · 2016-09-23

    Ni Zhen, Leyan Nian, Guangmao Li, Kui Wu, Shilie Pan

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  13. Analysis and prediction of mid-IR nonlinear optical metal sulfides with diamond-like structures

    Coordination Chemistry Reviews · 2016-11-22

    Fei Liang, Lei Kang, Zheshuai Lin, Yicheng Wu, Chuangtian Chen

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  14. Phase Transition and Second Harmonic Generation in Thiophosphates Ag2Cd(P2S6) and AgCd3(PS4)S2 Containing Two Second-Order Jahn–Teller Distorted Cations

    Inorganic Chemistry · 2016-12-16

    Yuhang Fan, Xiao‐Ming Jiang, Bin‐Wen Liu, Shu‐Fang Li, Wei‐Huan Guo, Hui‐Yi Zeng, Guo‐Cong Guo, Jin‐Shun Huang

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  15. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

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  16. Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity

    Journal of Materials Chemistry C · 2017-01-01

    Ruihuan Duan, Pengfei Liu, Hua Lin, Yi‐Wen Zheng, Ju‐Song Yu, Xin‐Tao Wu, Shangxiong Huangfu, Ling Chen

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  17. Centrosymmetric to noncentrosymmetric structural transformation of new quaternary selenides induced by isolated dimeric [Sn 2 Se 4 ] units: from Ba 8 Ga 2 Sn 7 Se 18 to Ba 10 Ga 2 Sn 9 Se 22

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  18. Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence

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  19. Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2

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  20. The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances

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  21. Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds

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  22. Noncentrosymmetric chalcogenides BaZnSiSe4 and BaZnGeSe4 featuring one-dimensional structures

    Journal of Alloys and Compounds · 2017-03-05

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  23. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

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  24. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion

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  25. Ba 6 Zn 7 Ga 2 S 16 : A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties

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  26. AgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response

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  27. Hg-Based Infrared Nonlinear Optical Material KHg4Ga5Se12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response

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  28. Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge2Se4(μ-Se2)]4– Functional Motif in Polar Polyselenides A4Ge4Se12 (A = Rb, Cs)

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  29. Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge

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  30. PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method

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  31. NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers

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    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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  32. New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold

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  33. Novel Eu 2+ -activated thiogallate phosphors for white LED applications: structural and spectroscopic analysis

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    Szu-Ping Lee, Ting‐Shan Chan, Somrita Dutta, Teng‐Ming Chen

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  34. A Series of Lanthanide Selenidogermanates: The First Coexistence of Three Types of Selenidogermanate Units in the Same Architecture

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  35. A new 3-D cuprous thiogermanate with rare 3-D [Cu-S-Cu]n network

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  36. Strong SHG Response via High Orientation of Tetrahedral Functional Motifs in Polyselenide A2Ge4Se10 (A = Rb, Cs)

    Advanced Optical Materials · 2018-05-15

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  37. Strong Infrared Nonlinear Optical Efficiency and High Laser Damage Threshold Realized in Quaternary Alkali Metal Sulfides Na2Ga2MS6 (M = Ge, Sn) Containing Mixed Nonlinear Optically Active Motifs

    Inorganic Chemistry · 2018-05-29

    Shu‐Fang Li, Xiao‐Ming Jiang, Bin‐Wen Liu, Dong Yan, Hui‐Yi Zeng, Guo‐Cong Guo

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  38. A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances

    Coordination Chemistry Reviews · 2018-09-20

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  39. A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials

    Chemical Science · 2019-01-01

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  40. BaMnSnS 4 and BaCdGeS 4 : infrared nonlinear optical sulfides containing highly distorted motifs with centers of moderate electronegativity

    Inorganic Chemistry Frontiers · 2019-01-01

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  41. Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 4

    New Journal of Chemistry · 2019-01-01

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  42. Synthesis and nonlinear optical properties of new gallium thiophosphate Rb 2 Ga 2 P 2 S 9

    New Journal of Chemistry · 2019-01-01

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  43. Syntheses, structures, optical properties, and electronic structures of Ba6Cu2GSn4S16 (G = Fe, Ni) and Sr6D2FeSn4S16 (D = Cu, Ag)

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  44. Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey

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  45. LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition

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  46. A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties

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  47. Li 2 CdSiS 4 , a promising IR NLO material with a balanced E g and SHG response originating from the effect of Cd with d 10 configuration

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    Guangmao Li, Yu Chu, Jun Li, Zhongxiang Zhou

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  48. Quaternary rare-earth sulfide LaSnGa3S7: Synthesis, structure, thermal and optical properties

    Journal of Alloys and Compounds · 2020-02-17

    Jian Tang, Wenhao Xing, Kaijin Kang, Tixian Zeng, Wenlong Yin, Bin Kang

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  49. Mild solvothermal syntheses and characterizations of two layered sulfides Ba2Cu2Cd2S5 and Ba3Cu4Hg4S9

    Journal of Alloys and Compounds · 2020-03-02

    Yan Liu, Xuedan Song, Yongkang Guo, Yiping Zhong, Yanhua Li, Yu Feng Sun, Min Ji, Zhong‐Lu You, Yong‐Lin An

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  50. Chalcogenides: Solid‐State Chemistry

    Encyclopedia of Inorganic and Bioinorganic Chemistry · 2020-03-13

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