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RESEARCH PAPER · Journal of Materials Chemistry C · 2018

K 2 MnGe 3 S 8 : a new multifunctional semiconductor featuring [MnGe 3 S 8 ] 2− layers and demonstrating interesting nonlinear optical response and antiferromagnetic properties

Zhuang Li, Xingxing Jiang, Changjiang Yi, Molin Zhou, Yangwu Guo, Xiaoyu Luo, Zheshuai Lin, Yicheng Wu, Youguo Shi, Jiyong Yao

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K 2 MnGe 3 S 8 : a new multifunctional semiconductor featuring [MnGe 3 S 8 ] 2− layers and demonstrating interesting nonlinear optical response and antiferromagnetic propertiesOriginalSolid-State Preparation, Structural Characterization, Physical Properties, and Theoretical Studies of a Series of Novel Rare-Earth Metal Chalcogenides with Unprecedented Closed-Cavities15Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response13Quaternary semiconductor Ba 8 Zn 4 Ga 2 S 15 featuring unique one-dimensional chains and exhibiting desirable yellow emission24Rational design of infrared nonlinear optical chalcogenides by chemical substitution287Non-centrosymmetric sulfides A 2 Ba 6 MnSn 4 S 16 (A = Li, Ag): syntheses, structures and properties21Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability16Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75A 3 Mn 2 Sb 3 S 8 (A = K and Rb): a new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks53Centrosymmetric or Noncentrosymmetric? Transition Metals Talking in K 2 TGe 3 S 8 (T = Co, Fe)25Triclinic Layered A2ZnSi3S8 (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A2MIIBMIV3Q8 Family11A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation22A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation64Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184Antiferromagnetic quaternary chalco-halide Ba 3 (FeS 4 )I with long Fe⋯Fe distances3Infrared nonlinear optical sulfide CsCd 4 In 5 S 12 exhibiting large second harmonic generation response16Chalcogen dependent metal vacancies and disorder in Ba2Ln1−Mn2−S5 and Ba2−Ln1−Mn2−Se5 (Ln = Pr, Nd, and Gd) structures5Rb2FeGe3S8 and Cs2FeGe3S8: New layered chalcogenides in A2MIIMIV3Q8 family with antiferromagnetic property6d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)18Breaking the bottleneck of simultaneously wide band gap and large nonlinear optical coefficient by a “pore reconstruction” strategy in a salt-inclusion chalcogenide26K2CdGe3S8: A New Infrared Nonlinear Optical Sulfide6NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances13Alkali halide flux synthesis, crystal structure, and photoelectric response of quaternary thiosilicates K 3 Ga 3 Si 7 S 20 and K 2 ZnSi 3 S 81Effectively designing infrared nonlinear optical materials with magnetism, MMn 6 Ga 6 S 16 (M = Ca, Sr, Ba, and Pb), aided by stable open frameworks13Salt-inclusion chalcogenides with d-orbital components: unveiling remarkable nonlinear optical properties and dual-band photoluminescence10K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds5AI2Mg3Ga12S22 (AI = K, Rb): T2-type supertetrahedra coupled with [MgS6] octahedra for designing wide-band gap infrared nonlinear optical materials with well-balanced properties16A new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence property5Contemporary Chalcogenide Materials Chemistry1SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0LiMn(IO 3 ) 3 : A Noncentrosymmetric Iodate Synthesized by Polyhedral Volume Ratio Modulation0Laporte Selection Rule Induced the Suppression of d ‐ d Transitions and Vacancies Enhanced the Second Harmonic Generation in I 4¯‐MnGa 2 S 40

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  1. Solid-State Preparation, Structural Characterization, Physical Properties, and Theoretical Studies of a Series of Novel Rare-Earth Metal Chalcogenides with Unprecedented Closed-Cavities

    Crystal Growth & Design · 2018-11-14

    Hong Chen, Pengfei Liu, Hua Lin, Li‐Ming Wu, Xin‐Tao Wu

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  2. Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response

    Journal of Materials Chemistry C · 2019-01-01

    Zhuang Li, Shengzi Zhang, Wenlong Yin, Kaijin Kang, Yangwu Guo, Wenhao Xing, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  3. Quaternary semiconductor Ba 8 Zn 4 Ga 2 S 15 featuring unique one-dimensional chains and exhibiting desirable yellow emission

    Chemical Communications · 2019-01-01

    Yanyan Li, Pengfei Liu, Hua Lin, Li‐Ming Wu, Xin‐Tao Wu, Qi‐Long Zhu

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  4. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

    Hua Lin, Wenbo Wei, Hong Chen, Xintao Wu, Qi‐Long Zhu

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  5. Non-centrosymmetric sulfides A 2 Ba 6 MnSn 4 S 16 (A = Li, Ag): syntheses, structures and properties

    Dalton Transactions · 2020-01-01

    Ruihuan Duan, Hua Lin, Yue Wang, Yuqiao Zhou, Li‐Ming Wu

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  6. Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability

    Inorganic Chemistry · 2020-05-15

    Zhuang Li, Youquan Liu, Shengzi Zhang, Wenhao Xing, Wenlong Yin, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  7. Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2020-10-23

    Zhuang Li, Jiyong Yao, Yicheng Wu

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  8. A 3 Mn 2 Sb 3 S 8 (A = K and Rb): a new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks

    Inorganic Chemistry Frontiers · 2021-01-01

    Yu Xiao, Man-Man Chen, Yaying Shen, Pengfei Liu, Hua Lin, Yi Liu

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  9. Centrosymmetric or Noncentrosymmetric? Transition Metals Talking in K 2 TGe 3 S 8 (T = Co, Fe)

    Inorganic Chemistry · 2021-06-29

    Bingheng Ji, Krishna Pandey, Colin P. Harmer, Fei Wang, Kui Wu, Jin Hu, Jian Wang

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  10. Triclinic Layered A2ZnSi3S8 (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A2MIIBMIV3Q8 Family

    Inorganic Chemistry · 2021-07-28

    Lihua Gao, Ya Feng Yang, Bingbing Zhang, Xiaowen Wu, Kui Wu

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  11. A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation

    Angewandte Chemie · 2021-08-04

    Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  12. A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2021-08-04

    Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  13. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

    Hong Chen, Wenbo Wei, Hua Lin, Xintao Wu

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  14. Antiferromagnetic quaternary chalco-halide Ba 3 (FeS 4 )I with long Fe⋯Fe distances

    Journal of Materials Chemistry C · 2022-01-01

    Yi Xiao, Xian Zhang, Ruiqi Wang, Simin An, Fuqiang Huang

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  15. Infrared nonlinear optical sulfide CsCd 4 In 5 S 12 exhibiting large second harmonic generation response

    Journal of Materials Chemistry C · 2022-01-01

    Yang Wang, Ruiqi Wang, Xiangli Che, Fei Liang, Min Luo, Yufeng Tang, Yunzhen Cao, Fuqiang Huang

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  16. Chalcogen dependent metal vacancies and disorder in Ba2Ln1−Mn2−S5 and Ba2−Ln1−Mn2−Se5 (Ln = Pr, Nd, and Gd) structures

    Journal of Alloys and Compounds · 2022-01-05

    Gopabandhu Panigrahi, Subhendu Jana, Mohd Ishtiyak, Bikash Tripathy, Sairam K. Malladi, Manish K. Niranjan, Jai Prakash

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  17. Rb2FeGe3S8 and Cs2FeGe3S8: New layered chalcogenides in A2MIIMIV3Q8 family with antiferromagnetic property

    Journal of Solid State Chemistry · 2022-06-02

    Weikang Wang, Wangzhu Cao, Ling‐Yun Zhang, Guobao Li, Yuandong Wu, Shaoguo Wen, Dajiang Mei

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  18. d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)

    Inorganic Chemistry · 2022-12-27

    Bingheng Ji, Fei Wang, Kui Wu, Bingbing Zhang, Jian Wang

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  19. Breaking the bottleneck of simultaneously wide band gap and large nonlinear optical coefficient by a “pore reconstruction” strategy in a salt-inclusion chalcogenide

    Materials Horizons · 2023-01-01

    Shao‐Min Pei, Bin‐Wen Liu, Wen‐Fa Chen, Xiao‐Ming Jiang, Guo‐Cong Guo

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  20. K2CdGe3S8: A New Infrared Nonlinear Optical Sulfide

    Symmetry · 2023-01-15

    Zixuan Wu, Wen‐Fa Chen, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  21. NaMn3Ga3S8: Noncentrosymmetric inorganic metal chalcogenide with nonlinear optical response, antiferromagnetic, and photoluminescence performances

    Materials Today Chemistry · 2023-09-20

    Pengcheng Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  22. Alkali halide flux synthesis, crystal structure, and photoelectric response of quaternary thiosilicates K 3 Ga 3 Si 7 S 20 and K 2 ZnSi 3 S 8

    CrystEngComm · 2024-01-01

    Jia-Ting Liu, Abdusalam Ablez, Qianqian Hu, Jun-Hao Tang, Chuan Lv, Lu Yang, Mei‐Ling Feng, Xiao‐Ying Huang

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  23. Effectively designing infrared nonlinear optical materials with magnetism, MMn 6 Ga 6 S 16 (M = Ca, Sr, Ba, and Pb), aided by stable open frameworks

    Inorganic Chemistry Frontiers · 2024-01-01

    Kaixuan Li, Yujie Zhang, Xianchao Zhu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  24. Salt-inclusion chalcogenides with d-orbital components: unveiling remarkable nonlinear optical properties and dual-band photoluminescence

    Chemical Science · 2024-01-01

    Shao‐Min Pei, Ming‐Shu Zhang, Fan Wu, Yan Guo, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  25. K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties

    Inorganic Chemistry · 2024-08-26

    Guili Wang, Pifu Gong, Jiyong Yao

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  26. Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds

    Dalton Transactions · 2025-01-01

    Guili Wang, Bohui Xu, Chunxiao Li, Pifu Gong, Zheshuai Lin, Jiyong Yao

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  27. AI2Mg3Ga12S22 (AI = K, Rb): T2-type supertetrahedra coupled with [MgS6] octahedra for designing wide-band gap infrared nonlinear optical materials with well-balanced properties

    Science China Materials · 2025-01-22

    Mengmeng Chen, Xu Liu, Abudukadi Tudi, Cui Chen, Qixian Ren, Zhihua Yang, Yabo Wu, Shilie Pan

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  28. A new selenide semiconductor NaMn3Ga3Se8 with strong second-harmonic generation and significant luminescence property

    Chinese Journal of Structural Chemistry · 2025-03-24

    Qi Sun, Hongshan Wang, Linlin Liu, Zuxin Chen, Junjie Li, Shilie Pan

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  29. Contemporary Chalcogenide Materials Chemistry

    Royal Society of Chemistry eBooks · 2025-07-04

    Guang Han, Yao Chen, Xiaoyuan Zhou, Duncan H. Gregory

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  30. SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice

    Inorganic Chemistry · 2026-01-21

    Chenyao Zhao, Yanhong Wang, Yun Lv, SeungGyum Jung, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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  31. LiMn(IO 3 ) 3 : A Noncentrosymmetric Iodate Synthesized by Polyhedral Volume Ratio Modulation

    Inorganic Chemistry · 2026-05-26

    Ruilan Kong, Weitong Wang, Shuoxing Yang, S W, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yizhi Wu, HS Wu

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  32. Laporte Selection Rule Induced the Suppression of d ‐ d Transitions and Vacancies Enhanced the Second Harmonic Generation in I 4¯‐MnGa 2 S 4

    Small · 2026-08-23

    Weiping Guo, Ya Yang, Yi Fang, Hong‐Hua Cui, Lingyun Li, Yan Yu, Zhong‐Zhen Luo, Zhigang Zou

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