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RESEARCH PAPER · Crystal Growth & Design · 2017

Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

Fei Liang, Lei Kang, Zheshuai Lin, Yicheng Wu

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Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property RelationshipOriginalBaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations54Langasite Family Midinfrared Nonlinear Optical Oxide Materials: Structure, Property, and Applications28Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters8Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds8Ba 6 Zn 7 Ga 2 S 16 : A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties111Coexistence of Strong Second Harmonic Generation Response and Wide Band Gap in AZn4Ga5S12 (A=K, Rb, Cs) with 3D Diamond‐like Frameworks65AgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response78Noncentrosymmetric quaternary selenide Ba23Ga8Sb2Se38: Synthesis, structure, and optical properties15New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials245Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge2Se4(μ-Se2)]4– Functional Motif in Polar Polyselenides A4Ge4Se12 (A = Rb, Cs)49Effect of Li and NH4 doping on the crystal perfection, second harmonic generation efficiency and laser damage threshold of potassium pentaborate crystals11Thallium indium germanium sulphide (TlInGe2S6) as efficient material for nonlinear optical application20A facile synthesis of two new IR optical perovskites based on 1,4-diazabicyclo[2,2,2]octane with a high laser damage threshold7First principle study of nonlinear optical crystals15Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance30New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold142Optimized oriented seed growth and optical properties of high-quality LiInSe 2 crystals13Research progress of mid-and far-infrared nonlinear optical crystals10Sr 5 ZnGa 6 S 15 : a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance60The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies29PbGa2GeS6 crystal as a novel nonlinear optical material: Band structure aspects36Excitonic spectra in HgGa 2 Se 4 crystals3From AgGaS2 to Li2ZnSiS4: Realizing Impressive High Laser Damage Threshold Together with Large Second-Harmonic Generation Response134High-pressure-assisted synthesis of high-volume ZnGeP2 polycrystalline9Li7Cd4.5Ge4Se16 and Li6.4Cd4.8Sn4Se16: Strong Nonlinear Optical Response in Quaternary Diamond‐Like Selenide Networks10Pushing Nonlinear Optical Oxides into the Mid-Infrared Spectral Region Beyond 10 μm: Design, Synthesis, and Characterization of La3SnGa5O14145Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63Synthesis, Crystal Structures, Optical Properties and Theoretical Calculations of Two Metal Chalcogenides Ba2AlSbS5 and Ba2GaBiSe59Optical and non-linear optical properties of the solid solutions AgGaGe3(1–x)Si3xSe82The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation14LiGa 2 PS 6 and LiCd 3 PS 6 : Molecular Designs of Two New Mid-Infrared Nonlinear Optical Materials88BaM2As2S6 (M = Cd, Hg): Synthesis, crystal structure, optical and electronic properties16Strong Infrared Nonlinear Optical Efficiency and High Laser Damage Threshold Realized in Quaternary Alkali Metal Sulfides Na2Ga2MS6 (M = Ge, Sn) Containing Mixed Nonlinear Optically Active Motifs48Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations61Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra16Photoconductivity and laser operated piezoelectricity the Ag-Ga-Ge-(S,Se) crystals and solid solutions7Advantageous Units in Antimony Sulfides: Exploration and Design of Infrared Nonlinear Optical Materials95K2ZnGe3S8: A Congruent-Melting Infrared Nonlinear-Optical Material with a Large Band Gap41Ternary Mixed-Metal Cd4GeS6: Remarkable Nonlinear-Optical Properties Based on a Tetrahedral-Stacking Framework41Cation substitution inducing gap changes and covalent interaction flexibility enhancing second harmonic generation responses in d10 metal chalcogenides11Elucidating linear and nonlinear optical properties of defect chalcopyrite compounds ZnX2Te4 (X=Al, Ga, In) from electronic transitions13Second-order nonlinear optical crystals with mixed anions250Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold59Intriguing Structural Transition Inducing Variable Birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)32Predicting diamond-like Co-based chalcogenides as unconventional high temperature superconductors7Rational Design of a LiNbO3-like Nonlinear Optical Crystal, Li2ZrTeO6, with High Laser-Damage Threshold and Wide Mid-IR Transparency Window152A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances253Recent advances and future perspectives on infrared nonlinear optical metal halides223The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation26Pressure-Assisted Method for the Preparations of High-Quality AaGaS2 and AgGaGeS4 Crystals for Mid-Infrared Laser Applications11Cyano-Based Materials with Giant Optical Anisotropy and Second Harmonic-Generation Effect24A review on the development of infrared nonlinear optical materials with triangular anionic groups38Ba10Zn7M6Q26: Two New Mid-infrared Nonlinear Optical Crystals with T2 Supertetrahedron 3D Framework11Recent progress on new infrared nonlinear optical materials with application prospect133A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials78Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response13Metal-cation substitutions induced the enhancement of second harmonic generation in A 8 BS 6 (A = Cu, and Ag; B = Si, Ge, and Sn)14Mn-Based tin sulfide Sr 3 MnSn 2 S 8 with a wide band gap and strong nonlinear optical response30SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance20SrCdSnQ 4 (Q = S and Se): infrared nonlinear optical chalcogenides with mixed NLO-active and synergetic distorted motifs69Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis7SrCdGeS4 and SrCdGeSe4: Promising Infrared Nonlinear Optical Materials with Congruent-Melting Behavior74Broadening Frontiers of Infrared Nonlinear Optical Materials with π-Conjugated Trigonal-Planar Groups67Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties26Theoretical Design of Layered AlGaS3 as a New Nonlinear Optical Material with a Strong Second Harmonic Generation Response5Synthesis and structural characterization of microcrystalline Ga2S3 layers on a GaP semiconductor substrate21Hierarchy in nonlinear optical responses induced by metal cation tailoring effect in the In-containing chalcogenide compounds4[Ge2S5(S2)]4−, A NLO‐Active Unit Leading to an Asymmetric Structure Discovered in Li2Cs4Ge2S5(S2)Cl2: An Experimental and Theoretical study18BaHgGeSe 4 and SrHgGeSe 4 : Two New Hg-Based Infrared Nonlinear Optical Materials142Growth and physicochemical investigations on wide bandgap 2D polymeric amino acetic acid sulfato dilithium metal–organic framework1Sr 6 Cd 2 Sb 6 O 7 S 10 : Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups124Sr6Cd2Sb6O7S10: Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups22Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide188Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide48Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140Sn 2 Ga 2 S 5 : A Polar Semiconductor with Exceptional Infrared Nonlinear Optical Properties Originating from the Combined Effect of Mixed Asymmetric Building Motifs81Ba 8 SrPb 24 O 24 Cl 18 : the first alkali-earth metal lead( ii ) oxyhalide with an intriguing multimember-ring layer9Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like Family32Nitrate nonlinear optical crystals: A survey on structure-performance relationships146LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition12Computational and experimental assessment on the nonlinear optical properties of platinum(II) arylacetylides with donor-acceptor structures3Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides64Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance172Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance40First-Principles Design and Simulations Promote the Development of Nonlinear Optical Crystals299Influence of component and structure on laser induced voltage in sandstone6Broadband CrOCl Saturable Absorber with a Spectral Region Extension to 10.6 µm33Atom-Resolved Analysis of Birefringence of Nonlinear Optical Crystals by Bader Charge Integration57An unprecedented planar π-conjugated [B 2 P 5 ] 5− group with ultra-large birefringence and nonlinearity: an ab initio study17ВПЛИВ РОЗМІРІВ ЗЕРЕН КРИСТАЛІЧНОГО ПОРОШКУ НА ІНТЕНСИВНІСТЬ ГЕНЕРАЦІЇ ДРУГОЇ ГАРМОНІКИ0A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals48Rational design of infrared nonlinear optical chalcogenides by chemical substitution287Alkali-earth metal lead( ii ) oxyhalide Ba 27 Pb 8 O 8 Cl 54 exhibiting interesting [Pb 4 Ba 4 O 4 ] 8+ species8Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr 6 A 4 M 4 S 16 (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials28Evidence of reaction intermediates in microwave-assisted synthesis of SHG active α-La(IO 3 ) 3 nanocrystals4Inorganic planar π-conjugated groups in nonlinear optical crystals: review and outlook145Langasite Family Nonlinear Optical Crystals9Large optical polarizability causing positive effects on the birefringence of planar-triangular BO 3 groups in ternary borates18Li 2 CdSiS 4 , a promising IR NLO material with a balanced E g and SHG response originating from the effect of Cd with d 10 configuration36Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture33Nonlinear organic–inorganic halide hybrids containing unprecedented linear [MIX 2 ] − coordination units and quasi-two-dimensional lone pairs20Salt-inclusion chalcogenides: an emerging class of IR nonlinear optical materials54Syntheses, structures, and photocatalytic properties of open-framework Ag–Sn–S compounds26The functionality of tetrahedral units in fluoroxoiodates: fluorine-modulating effects in iodates with lone pair electrons3Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior44One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy17Data-driven prediction of diamond-like infrared nonlinear optical crystals with targeting performances28Molecular Construction from AgGaS 2 to CuZnPS 4 : Defect-Induced Second Harmonic Generation Enhancement and Cosubstitution-Driven Band Gap Enlargement97Noncentrosymmetric Orthophosphate YM3(PO4)3 (M = Sr, Ba) Crystals: Single Crystal Growth, Structure, and Properties34Cd4SiQ6 (Q = S, Se): Ternary Infrared Nonlinear Optical Materials with Mixed Functional Building Motifs21Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials164Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials55Rb21.89W32.66O108: An Excellent Mid- and Far-IR Nonlinear-Optical Material with a Wide Band Gap4Investigation of the Thermal Properties and Crystal Growth of the Nonlinear Optical Crystals AgGaS 2 and AgGaGeS 434Volume Modulation of Nonlinear Optical Properties by Cation Substitution8A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)30A2SnS5: A Structural Incommensurate Modulation Exhibiting Strong Second‐Harmonic Generation and a High Laser‐Induced Damage Threshold (A=Ba, Sr)86HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure146Ab Initio High-Pressure Study of Semiconductor-Metal Phase Transition of the Chalcogenide Compound KPSe62Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability16A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials131Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides114Evaluation of nonlinear optical properties of quaternary chalcogenide halides Ba4Si3Se9Br2 and Ba4Ge3Se9Br222Optoelectronic and non-linear optical properties of Lu-doped AgGaGe3Se8 crystallites3α‑Li2ZnGeS4: A Wide-Bandgap Diamond-like Semiconductor with Excellent Balance between Laser-Induced Damage Threshold and Second Harmonic Generation Response158Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm38Effect of Pb Substitution in Sr2-xPbxGeSe4 on Crystal Structures and Nonlinear Optical Properties Predicted by DFT Calculations17Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75Solvothermal syntheses, crystal structures, and photoelectric response properties of two quaternary mercury-thioarsenates(III)8Na4CdGe2S7: A Sodium-Rich Quaternary Wide-Band-Gap Chalcogenide with Two-Dimensional [Ge2CdS7]∞ Layers6AMnAs3S6 (A = Cs, Rb): Phase-Matchable Infrared Nonlinear Optical Functional Motif [As3S6]3– Obtained via Surfactant–Thermal Method32Origin of ultra-wide IR transmission and ultra-large birefringence of mercurous halide series with one dimensional chain-like structure: An ab initio study15Phase Matching, Strong Frequency Doubling, and Outstanding Laser-Induced Damage Threshold in the Biaxial, Quaternary Diamond-like Semiconductor Li 4 CdSn 2 S 779Simple New Method for the Preparation of La(IO3)3 Nanoparticles6Synthesis, crystal structure, and electronic structure of Li2PbSiS4: a quaternary thiosilicate with a compressed chalcopyrite-like structure4A New Nonlinear Optical Selenide Crystal AgLiGa 2 Se 4 with Good Comprehensive Performance in Mid‐Infrared Region44Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides20A 3 Mn 2 Sb 3 S 8 (A = K and Rb): a new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks53A review on the recently developed promising infrared nonlinear optical materials103Cu 4 MnGe 2 S 7 and Cu 2 MnGeS 4 : two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond22Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system3Growth of a large-aperture mid-infrared nonlinear optical La 3 Nb 0.5 Ga 5.5 O 14 crystal for optical parametric chirped-pulse amplification13M 2 As 2 Q 5 (M = Ba, Pb; Q = S, Se): a source of infrared nonlinear optical materials with excellent overall performance activated by multiple discrete arsenate anions70Recent progress in oxychalcogenides as IR nonlinear optical materials79Role of lone-pair electrons in determining the thermal transport behavior of LiAsS 2 : first-principles investigation5Solvothermal Syntheses, Structures, and Characterizations of Four Thioarsenates A 7Cu 4As 3S 13 (A = Rb, Cs), Rb 2Cu 5As 3S 8, and CsCu 2AsS 30Synthesis, characterization and theoretical investigation of a new chalcohalide, Ba 4 GaS 4 F 311Identification of Potential Optoelectronic Applications for Metal Thiophosphates19

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  1. BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations

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  2. Langasite Family Midinfrared Nonlinear Optical Oxide Materials: Structure, Property, and Applications

    International Journal of Optics · 2017-01-01

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  3. Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters

    Dalton Transactions · 2017-01-01

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  4. Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds

    Dalton Transactions · 2017-01-01

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  5. Ba 6 Zn 7 Ga 2 S 16 : A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties

    Chemistry of Materials · 2017-05-31

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  6. Coexistence of Strong Second Harmonic Generation Response and Wide Band Gap in AZn4Ga5S12 (A=K, Rb, Cs) with 3D Diamond‐like Frameworks

    Chemistry - A European Journal · 2017-06-03

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  7. AgGa2PS6: A New Mid‐Infrared Nonlinear Optical Material with a High Laser Damage Threshold and a Large Second Harmonic Generation Response

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  8. Noncentrosymmetric quaternary selenide Ba23Ga8Sb2Se38: Synthesis, structure, and optical properties

    Journal of Alloys and Compounds · 2017-09-14

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  9. New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials

    Journal of the American Chemical Society · 2017-09-25

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  10. Large Second-Harmonic Generation Responses Achieved by the Dimeric [Ge2Se4(μ-Se2)]4– Functional Motif in Polar Polyselenides A4Ge4Se12 (A = Rb, Cs)

    Chemistry of Materials · 2017-10-05

    Bin‐Wen Liu, Minyi Zhang, Xiao‐Ming Jiang, Shu‐Fang Li, Hui‐Yi Zeng, Guoqiang Wang, Yuhang Fan, Yong-Fei Su, Chunsen Li, Guo‐Cong Guo, Jin‐Shun Huang

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  11. Effect of Li and NH4 doping on the crystal perfection, second harmonic generation efficiency and laser damage threshold of potassium pentaborate crystals

    Optics & Laser Technology · 2017-11-07

    A.N. Vigneshwaran, S. Kalainathan, Chidambaram Ramachandra Raja

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  12. Thallium indium germanium sulphide (TlInGe2S6) as efficient material for nonlinear optical application

    Journal of Alloys and Compounds · 2017-11-24

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  13. A facile synthesis of two new IR optical perovskites based on 1,4-diazabicyclo[2,2,2]octane with a high laser damage threshold

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  14. First principle study of nonlinear optical crystals

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  15. Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance

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  16. New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold

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  17. Optimized oriented seed growth and optical properties of high-quality LiInSe 2 crystals

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  18. Research progress of mid-and far-infrared nonlinear optical crystals

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  19. Sr 5 ZnGa 6 S 15 : a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance

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  20. The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies

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  21. PbGa2GeS6 crystal as a novel nonlinear optical material: Band structure aspects

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  22. Excitonic spectra in HgGa 2 Se 4 crystals

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  23. From AgGaS2 to Li2ZnSiS4: Realizing Impressive High Laser Damage Threshold Together with Large Second-Harmonic Generation Response

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  24. High-pressure-assisted synthesis of high-volume ZnGeP2 polycrystalline

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  25. Li7Cd4.5Ge4Se16 and Li6.4Cd4.8Sn4Se16: Strong Nonlinear Optical Response in Quaternary Diamond‐Like Selenide Networks

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  26. Pushing Nonlinear Optical Oxides into the Mid-Infrared Spectral Region Beyond 10 μm: Design, Synthesis, and Characterization of La3SnGa5O14

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  27. Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)

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  28. Synthesis, Crystal Structures, Optical Properties and Theoretical Calculations of Two Metal Chalcogenides Ba2AlSbS5 and Ba2GaBiSe5

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  29. Optical and non-linear optical properties of the solid solutions AgGaGe3(1–x)Si3xSe8

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    Ahmed M. El-Naggar, A.A. Albassam, O.V. Parasyuk, Ivan V. Kityk, G.L. Myronchuk, O.V. Zamuruyeva, Yu. Kot, D. Myronchuk, Renata Wojnarowska‐Nowak, Serhii Prokhorenko, Michał Piasecki

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  30. The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation

    Journal of Solid State Chemistry · 2018-04-26

    Qiaoqiao Zhang, Qun Jing, Haiming Duan, Haibin Cao

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  31. LiGa 2 PS 6 and LiCd 3 PS 6 : Molecular Designs of Two New Mid-Infrared Nonlinear Optical Materials

    Chemistry of Materials · 2018-05-17

    Jianghe Feng, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  32. BaM2As2S6 (M = Cd, Hg): Synthesis, crystal structure, optical and electronic properties

    Journal of Alloys and Compounds · 2018-05-21

    Yangwu Guo, Fei Liang, Molin Zhou, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  33. Strong Infrared Nonlinear Optical Efficiency and High Laser Damage Threshold Realized in Quaternary Alkali Metal Sulfides Na2Ga2MS6 (M = Ge, Sn) Containing Mixed Nonlinear Optically Active Motifs

    Inorganic Chemistry · 2018-05-29

    Shu‐Fang Li, Xiao‐Ming Jiang, Bin‐Wen Liu, Dong Yan, Hui‐Yi Zeng, Guo‐Cong Guo

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  34. Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations

    Inorganic Chemistry · 2018-06-06

    Yangwu Guo, Fei Liang, Jiyong Yao, Zheshuai Lin, Wenlong Yin, Yicheng Wu, Chuangtian Chen

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  35. Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra

    Journal of Alloys and Compounds · 2018-06-22

    Mingjing Tang, Abishek K. Iyer, Dong Zhang, Wenlong Yin, Arthur Mar

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  36. Photoconductivity and laser operated piezoelectricity the Ag-Ga-Ge-(S,Se) crystals and solid solutions

    Materials Science in Semiconductor Processing · 2018-07-02

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  37. Advantageous Units in Antimony Sulfides: Exploration and Design of Infrared Nonlinear Optical Materials

    ACS Applied Materials & Interfaces · 2018-07-12

    Cong Hu, Bingbing Zhang, Bing‐Hua Lei, Shilie Pan, Zhihua Yang

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  38. K2ZnGe3S8: A Congruent-Melting Infrared Nonlinear-Optical Material with a Large Band Gap

    Inorganic Chemistry · 2018-07-13

    Xiaoyu Luo, Fei Liang, Molin Zhou, Yangwu Guo, Zhuang Li, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  39. Ternary Mixed-Metal Cd4GeS6: Remarkable Nonlinear-Optical Properties Based on a Tetrahedral-Stacking Framework

    Inorganic Chemistry · 2018-07-13

    Mengyue Li, Bingxuan Li, Hua Lin, Yong‐Fang Shi, Zuju Ma, Li‐Ming Wu, Xintao Wu, Qi‐Long Zhu

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  40. Cation substitution inducing gap changes and covalent interaction flexibility enhancing second harmonic generation responses in d10 metal chalcogenides

    Journal of Alloys and Compounds · 2018-07-30

    Jianian Cheng, Ming‐Hsien Lee, Jun Zhang

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  41. Elucidating linear and nonlinear optical properties of defect chalcopyrite compounds ZnX2Te4 (X=Al, Ga, In) from electronic transitions

    Solid State Sciences · 2018-08-04

    Yakoub Ayeb, Ali Benghia, Mohammed Benali Kanoun, Rabie Arar, Brahim Lagoun, Souraya Goumri‐Said

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  42. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

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  43. Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2018-08-23

    Sheng‐Ping Guo, Zongdong Sun, Yang Chi, Huaiguo Xue

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  44. Intriguing Structural Transition Inducing Variable Birefringences in ABa2MS4Cl (A = Rb, Cs; M = Ge, Sn)

    Inorganic Chemistry · 2018-08-24

    Yu Chu, Kui Wu, Xin Su, Jian Wei Han, Zhihua Yang, Shilie Pan

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  45. Predicting diamond-like Co-based chalcogenides as unconventional high temperature superconductors

    中国科学通报：英文版 · 2018-09-10

    Jiangping Hu, Yuhao Gu, Congcong Le

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  46. Rational Design of a LiNbO3-like Nonlinear Optical Crystal, Li2ZrTeO6, with High Laser-Damage Threshold and Wide Mid-IR Transparency Window

    Journal of the American Chemical Society · 2018-09-13

    Weiqun Lu, Zeliang Gao, Xitao Liu, Xiangxin Tian, Qian Wu, Conggang Li, Youxuan Sun, Yang Liu, Xutang Tao

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  47. A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances

    Coordination Chemistry Reviews · 2018-09-20

    Kui Wu, Shilie Pan

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  48. Recent advances and future perspectives on infrared nonlinear optical metal halides

    Coordination Chemistry Reviews · 2018-10-23

    Pifu Gong, Fei Liang, Lei Kang, Xingguo Chen, Jingui Qin, Yicheng Wu, Zheshuai Lin

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  49. The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation

    Optik · 2018-10-25

    Qiaoqiao Zhang, Hahaer Mushahali, Haiming Duan, Ming‐Hsien Lee, Qun Jing

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  50. Pressure-Assisted Method for the Preparations of High-Quality AaGaS2 and AgGaGeS4 Crystals for Mid-Infrared Laser Applications

    Inorganic Chemistry · 2018-11-09

    Changbao Huang, Mingsheng Mao, Haixin Wu, Jiaren Ma

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