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RESEARCH PAPER · Inorganic Chemistry · 2013

Syntheses, Structures, and Nonlinear Optical Properties of Quaternary Chalcogenides: Pb4Ga4GeQ12 (Q = S, Se)

Yu‐Kun Chen, Mei‐Chun Chen, Liujiang Zhou, Ling Chen, Li‐Ming Wu

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Syntheses, Structures, and Nonlinear Optical Properties of Quaternary Chalcogenides: Pb4Ga4GeQ12 (Q = S, Se)OriginalChemInform Abstract: Syntheses, Structures, and Nonlinear Optical Properties of Quaternary Chalcogenides: Pb4Ga4GeQ12 (Q: S, Se).0Ba8Sn4S15: A Strong Second Harmonic Generation Sulfide with Zero-Dimensional Crystal Structure106Manifestation of intrinsic defects in the band structures of quaternary chalcogenide Ag 2 In 2 SiSe 6 and Ag 2 In 2 GeSe 6 crystals14Space formations and nonlinear properties of noncentrosymmetric germanates9Ba3GeS5 and Ba3InS4Cl: Interesting size effects originated from the tetrahedral anions26Surfactant-Thermal Syntheses, Structures, and Magnetic Properties of Mn–Ge–Sulfides/Selenides45Syntheses, Structures, and Nonlinear-Optical Properties of Metal Sulfides Ba2Ga8MS16 (M = Si, Ge)94Designing the syntheses and photophysical simulations of noncentrosymmetric compounds17Syntheses, structures, and optical properties of Ba 4 Ga 4 SnSe 12 and Ba 6 Ga 2 SnSe 1119Ba 2 GeS 4 and Mg 2 SnS 4 : synthesis, structures, optical properties and electronic structures41PbGa 4 S 7 : a wide-gap nonlinear optical material91Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation86Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)24Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441K 2 Sn 2 ZnSe 6 , Na 2 Ge 2 ZnSe 6 , and Na 2 In 2 GeSe 6 : a new series of quaternary selenides with intriguing structural diversity and nonlinear optical properties32Pb 5 Ga 6 ZnS 15 : a noncentrosymmetric framework with chains of T2-supertetrahedra41Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds186Noncentrosymmetric selenide Ba4Ga4GeSe12: Synthesis, structure, and optical properties9A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS725Recent achievements on middle and far-infrared second-order nonlinear optical materials433Syntheses and characterization of three new sulfides with large band gaps: acentric Ba 4 Ga 4 SnS 12 , centric Ba 12 Sn 4 S 23 and Ba 7 Sn 3 S 1327Solvothermal syntheses, crystal structures, optical and thermal properties of new selenidogermanate and polyselenidogermanate6Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method42Sr 5 ZnGa 6 S 15 : a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance60Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63The effect of composition on photoconductivity and nonlinear optical properties in the acentric Ag2In2AB6 (A = Si, Ge, B = S, Se) crystals4Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 41Effect of S and Se replacement on electronic and thermoelectric features of BaCu2GeQ4 (Q = S, Se) chalcogenide crystals27Sn2Ga2S5: A Type of IR Nonlinear-Optical Material22Vibration uncoupling of germanium with different valence states lowers thermal conductivity of Cs2Ge3Ga6Se1410ФАЗОВІ РІВНОВАГИ В СИСТЕМАХ PbGa2Х4–SiХ2 (Х – S, Sе)0Rational design of infrared nonlinear optical chalcogenides by chemical substitution287Sr 4 Pb 1.5 Sb 5 O 5 Se 8 : a new mid-infrared nonlinear optical material with a moderate SHG response22Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations9Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Photoconductivity of the Single Crystals Pb4Ga4GeS12 and Pb4Ga4GeSe120M 2 As 2 Q 5 (M = Ba, Pb; Q = S, Se): a source of infrared nonlinear optical materials with excellent overall performance activated by multiple discrete arsenate anions70Ionothermal Synthesis of Two New Thioantimonates with Transition Metal Regulation4Infrared nonlinear optical sulfide CsCd 4 In 5 S 12 exhibiting large second harmonic generation response16Impact of structure complexity on optoelectronic and non-linear optical properties in quaternary Ag(Pb)–Ga(In)–Si(Ge)–S(Se) systems13A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications115Novel structural transformation in K3ReP2S8 thiophosphates originating from the rare-earth (Re) cation sizes induced local coordination asymmetry25Component Interaction in the Quasi-Ternary System PbSe–Ga2Se3–GeSe21Remarkable phase-matchable second-harmonic generation realized by strong polarities of [PbSe3] and [GaSe4] functional motifs in PbGa4Se718Synthesis, Structure, and optical properties of Y3GaGe0.5S7: A new member in the polar R3MTQ7 family4Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Pb 3.5 GeS 4 Br 3 : the first phase-matching thiogermanate halide infrared nonlinear optical material12RbPbPS 4 : a promising IR nonlinear optical material achieved by lone-pair-cation-substitution-induced structure transformation23Insights into the optoelectronic, thermodynamic, and thermoelectric properties of novel BaYCuX3 (X = Se, Te) semiconductors from first-principles investigation3The electronic structure, optical, and transport properties of novel SrScCu3M4 (M = Se, Te) semiconductors4Impact of structural defects on the electronic and optical properties of Pb4Ga4Ge(S, Se)12 crystals2Cationic substitution engineering induces a new quaternary chalcogenide in the A–M IIIA –M IVA –Q system for optical crystal applications1[K2PbI][Ga7Se12]: A New Lead-Containing Nonlinear Optical Material with Moderate Second-Harmonic Generation Response and Large Birefringence5Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29First-principles study of electronic structure, optical response, and thermal properties of MgCu3MSe4 (M = al, Ga, Sc, Y)0Mixed chalcogenidogermanates: solvothermal synthesis of tetranuclear oxotellurogermanate clusters and photocatalytic performance0

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  1. ChemInform Abstract: Syntheses, Structures, and Nonlinear Optical Properties of Quaternary Chalcogenides: Pb4Ga4GeQ12 (Q: S, Se).

    ChemInform · 2013-09-12

    Yu‐Kun Chen, Mei‐Chun Chen, Liujiang Zhou, Ling Chen, Li‐Ming Wu

    Read original paper ↗ ·

  2. Ba8Sn4S15: A Strong Second Harmonic Generation Sulfide with Zero-Dimensional Crystal Structure

    Chemistry of Materials · 2013-12-17

    Zhong‐Zhen Luo, Chensheng Lin, Weilong Zhang, Hao Zhang, Zhangzhen He, Wen‐Dan Cheng

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  3. Manifestation of intrinsic defects in the band structures of quaternary chalcogenide Ag 2 In 2 SiSe 6 and Ag 2 In 2 GeSe 6 crystals

    CrystEngComm · 2014-01-01

    M. Makowska-Janusik, Ivan V. Kityk, G.L. Myronchuk, O. Zamuraeva, O.V. Parasyuk

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  4. Space formations and nonlinear properties of noncentrosymmetric germanates

    Journal of Solid State Chemistry · 2014-06-23

    Anton Sergeevich Korotkov

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  5. Ba3GeS5 and Ba3InS4Cl: Interesting size effects originated from the tetrahedral anions

    Journal of Solid State Chemistry · 2014-07-14

    Mingyan Pan, Sheng‐Qing Xia, Xiao‐Cun Liu, Xu-Tang Tao

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  6. Surfactant-Thermal Syntheses, Structures, and Magnetic Properties of Mn–Ge–Sulfides/Selenides

    Inorganic Chemistry · 2014-09-10

    Guodong Zhang, Pei‐Zhou Li, Junfeng Ding, Yi Liu, Wei‐Wei Xiong, Lina Nie, Tom Wu, Yanli Zhao, Alfred Iing Yoong Tok, Qichun Zhang

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  7. Syntheses, Structures, and Nonlinear-Optical Properties of Metal Sulfides Ba2Ga8MS16 (M = Si, Ge)

    Inorganic Chemistry · 2014-11-20

    Bin‐Wen Liu, Hui‐Yi Zeng, Ming‐Jian Zhang, Yuhang Fan, Guo‐Cong Guo, Jin‐Shun Huang, Zhen‐Chao Dong

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  8. Designing the syntheses and photophysical simulations of noncentrosymmetric compounds

    Inorganic Chemistry Frontiers · 2014-12-01

    Wen‐Dan Cheng, Chensheng Lin, Zhong‐Zhen Luo, Hao Zhang

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  9. Syntheses, structures, and optical properties of Ba 4 Ga 4 SnSe 12 and Ba 6 Ga 2 SnSe 11

    Dalton Transactions · 2014-12-05

    Wenlong Yin, Zuohong Lin, Lei Kang, Bin Kang, Jianguo Deng, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  10. Ba 2 GeS 4 and Mg 2 SnS 4 : synthesis, structures, optical properties and electronic structures

    RSC Advances · 2015-01-01

    Kui Wu, Shilie Pan, Zhihua Yang

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  11. PbGa 4 S 7 : a wide-gap nonlinear optical material

    Journal of Materials Chemistry C · 2015-01-01

    Xiaoshuang Li, Lei Kang, Chao Li, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  12. Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation

    Chemistry of Materials · 2015-02-16

    Yong‐Fang Shi, Yukun Chen, Mei‐Chun Chen, Li‐Ming Wu, Hua Lin, Liujiang Zhou, Ling Chen

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  13. Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7

    Inorganic Chemistry · 2015-03-05

    Kui Wu, Xin Su, Shilie Pan, Zhihua Yang

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  14. Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)

    Journal of Solid State Chemistry · 2015-04-02

    Hua‐Jun Zhao

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  15. Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis

    Journal of the American Chemical Society · 2015-09-23

    Lei Kang, Molin Zhou, Jiyong Yao, Zheshuai Lin, Yicheng Wu, Chuangtian Chen

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  16. K 2 Sn 2 ZnSe 6 , Na 2 Ge 2 ZnSe 6 , and Na 2 In 2 GeSe 6 : a new series of quaternary selenides with intriguing structural diversity and nonlinear optical properties

    Dalton Transactions · 2016-01-01

    Molin Zhou, Chao Li, Xiaoshuang Li, Jiyong Yao, Yicheng Wu

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  17. Pb 5 Ga 6 ZnS 15 : a noncentrosymmetric framework with chains of T2-supertetrahedra

    Dalton Transactions · 2016-01-01

    Ruihuan Duan, Ju‐Song Yu, Hua Lin, Yujun Zheng, Hua‐Jun Zhao, Shangxiong Huangfu, Muhammad Ali Khan, Ling Chen, Li‐Ming Wu

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  18. Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds

    Chemistry of Materials · 2016-04-05

    Kui Wu, Zhihua Yang, Shilie Pan

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  19. Noncentrosymmetric selenide Ba4Ga4GeSe12: Synthesis, structure, and optical properties

    Journal of Solid State Chemistry · 2016-06-06

    Wenlong Yin, Abishek K. Iyer, Chao Li, Xinsong Lin, Jiyong Yao, Arthur Mar

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  20. A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS7

    Crystals · 2016-09-23

    Ni Zhen, Leyan Nian, Guangmao Li, Kui Wu, Shilie Pan

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  21. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

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  22. Syntheses and characterization of three new sulfides with large band gaps: acentric Ba 4 Ga 4 SnS 12 , centric Ba 12 Sn 4 S 23 and Ba 7 Sn 3 S 13

    Dalton Transactions · 2017-01-01

    Ruihuan Duan, Pengfei Liu, Hua Lin, Shangxiong Huangfu, Li‐Ming Wu

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  23. Solvothermal syntheses, crystal structures, optical and thermal properties of new selenidogermanate and polyselenidogermanate

    Journal of Chemical Sciences · 2017-01-21

    Shuzhen Liu, Peipei Sun, Jingyu Han, Yun Liu, Yali Shen, Chunying Tang, HUI SUN, Dingxian Jia

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  24. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

    Crystal Growth & Design · 2017-03-15

    Fei Liang, Lei Kang, Zheshuai Lin, Yicheng Wu

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  25. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion

    Crystals · 2017-04-12

    Kui Wu, Shilie Pan

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  26. PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method

    Crystal Growth & Design · 2017-12-28

    Yi‐Zhi Huang, Hao Zhang, Chensheng Lin, Wen‐Dan Cheng, Zhengxiao Guo, Guoliang Chai

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  27. Sr 5 ZnGa 6 S 15 : a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance

    Inorganic Chemistry Frontiers · 2018-01-01

    Hua Lin, Bingxuan Li, Hong Chen, Pengfei Liu, Li‐Ming Wu, Xin‐Tao Wu, Qi‐Long Zhu

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  28. Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)

    Dalton Transactions · 2018-01-01

    Ruijiao Chen, Xiaowen Wu, Zhi Su

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  29. Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)

    Inorganic Chemistry · 2018-03-06

    Leyan Nian, Kui Wu, Guijie He, Zhihua Yang, Shilie Pan

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  30. The effect of composition on photoconductivity and nonlinear optical properties in the acentric Ag2In2AB6 (A = Si, Ge, B = S, Se) crystals

    Optik · 2018-11-13

    G.L. Myronchuk, Oksana Zamurueva, O.V. Parasyuk, Ivan V. Kityk, Paweł Czaja, Michał Piasecki

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  31. Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 4

    New Journal of Chemistry · 2019-01-01

    Yi Huang, Xiaowen Wu, Sadeh Beysen

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  32. Effect of S and Se replacement on electronic and thermoelectric features of BaCu2GeQ4 (Q = S, Se) chalcogenide crystals

    Journal of Alloys and Compounds · 2019-03-19

    Sikander Azam, Muhammad Irfan, Zeesham Abbas, Saleem Ayaz Khan, Ivan V. Kityk, Tanzila Kanwal, M. Sohail, Shabbir Muhammad, Abdullah Godran Al-Sehemi

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  33. Sn2Ga2S5: A Type of IR Nonlinear-Optical Material

    Inorganic Chemistry · 2019-08-28

    Zhi‐Hui Shi, Yang Chi, Zongdong Sun, Wenlong Liu, Sheng‐Ping Guo

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  34. Vibration uncoupling of germanium with different valence states lowers thermal conductivity of Cs2Ge3Ga6Se14

    Science China Materials · 2019-10-25

    Ni Ma, Lin Xiong, Ling Chen, Li‐Ming Wu

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  35. ФАЗОВІ РІВНОВАГИ В СИСТЕМАХ PbGa2Х4–SiХ2 (Х – S, Sе)

    Перспективні технології та прилади · 2019-12-07

    Цісар О. В. Піскач Л. В.

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  36. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

    Hua Lin, Wenbo Wei, Hong Chen, Xintao Wu, Qi‐Long Zhu

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  37. Sr 4 Pb 1.5 Sb 5 O 5 Se 8 : a new mid-infrared nonlinear optical material with a moderate SHG response

    CrystEngComm · 2020-01-01

    Yang Wang, Mengjia Luo, Pei Zhao, Xiangli Che, Yunzhen Cao, Fuqiang Huang

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  38. Highly anisotropic layered selenophosphate AgSbP2Se6: The electronic structure and optical properties by experimental measurements and first-principles calculations

    Chemical Physics · 2020-04-20

    Tuan V. Vu, Anatoliy A. Lavrentyev, B.V. Gabrelian, Dat Duy Vo, V.I. Sabov, M. Yu. Sabov, I. E. Barchiy, Michał Piasecki, Oleg Yu Khyzhun

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  39. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

    Crystal Growth & Design · 2020-12-22

    Mei Yan, Huaiguo Xue, Sheng‐Ping Guo

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  40. Photoconductivity of the Single Crystals Pb4Ga4GeS12 and Pb4Ga4GeSe12

    Unknown journal · 2020-12-31

    Hadj K. Bellagra, Oksana Nyhmatullina, Yuri Kogut, Halyna Myronchuk, Л.В. Піскач

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  41. M 2 As 2 Q 5 (M = Ba, Pb; Q = S, Se): a source of infrared nonlinear optical materials with excellent overall performance activated by multiple discrete arsenate anions

    Journal of Materials Chemistry C · 2021-01-01

    Man-Man Chen, Zuju Ma, Bingxuan Li, Wenbo Wei, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  42. Ionothermal Synthesis of Two New Thioantimonates with Transition Metal Regulation

    Journal of Cluster Science · 2021-04-29

    Gang Yang, Chao Wu, Jinfang Zhang, Chi Zhang

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  43. Infrared nonlinear optical sulfide CsCd 4 In 5 S 12 exhibiting large second harmonic generation response

    Journal of Materials Chemistry C · 2022-01-01

    Yang Wang, Ruiqi Wang, Xiangli Che, Fei Liang, Min Luo, Yufeng Tang, Yunzhen Cao, Fuqiang Huang

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  44. Impact of structure complexity on optoelectronic and non-linear optical properties in quaternary Ag(Pb)–Ga(In)–Si(Ge)–S(Se) systems

    Journal of Alloys and Compounds · 2022-03-18

    Michał Piasecki, G.L. Myronchuk, Oleg Yu Khyzhun, A.O. Fedorchuk, B. Andryievsky, I. Barchyi, M.G. Brik

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  45. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  46. Novel structural transformation in K3ReP2S8 thiophosphates originating from the rare-earth (Re) cation sizes induced local coordination asymmetry

    Materials Today Physics · 2022-10-17

    Xiaodong Tian, Yan Xiao, Bohai Zhang, D. Yang, Kui Wu

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  47. Component Interaction in the Quasi-Ternary System PbSe–Ga2Se3–GeSe2

    Journal of Phase Equilibria and Diffusion · 2022-12-06

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  48. Remarkable phase-matchable second-harmonic generation realized by strong polarities of [PbSe3] and [GaSe4] functional motifs in PbGa4Se7

    Science China Materials · 2023-04-13

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  49. Synthesis, Structure, and optical properties of Y3GaGe0.5S7: A new member in the polar R3MTQ7 family

    Inorganic Chemistry Communications · 2023-05-16

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  50. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

    Coordination Chemistry Reviews · 2023-12-21

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