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RESEARCH PAPER · Journal of the American Chemical Society · 2013

Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12

Hua Lin, Ling Chen, Liujiang Zhou, Li‐Ming Wu

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Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12OriginalChemInform Abstract: Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12.0Ba8Sn4S15: A Strong Second Harmonic Generation Sulfide with Zero-Dimensional Crystal Structure106Deep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)459Crystal structure and magnetic and photocatalytic properties of a new ternary rare-earth mixed chalcogenide, Dy 4 S 4 Te 347Li2CdGeS4, A Diamond-Like Semiconductor with Strong Second-Order Optical Nonlinearity in the Infrared and Exceptional Laser Damage Threshold193Ag 3 Ga 3 SiSe 8 : a new infrared nonlinear optical material with a chalcopyrite structure34Optical Nonlinearity in Cu2CdSnS4 and α/β-Cu2ZnSiS4: Diamond-like Semiconductors with High Laser-Damage Thresholds87An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property94Designing the syntheses and photophysical simulations of noncentrosymmetric compounds17Quaternary rare-earth selenides with closed cavities: Cs[RE 9 Mn 4 Se 18 ] (RE = Ho–Lu)28Recent advances on second-order NLO materials based on metal iodates328Second Harmonic Generation Response Optimized at Various Optical Wavelength Ranges through a Series of Cubic Chalcogenides Ba6Ag2.67+4δSn4.33−δS16–xSex41Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation86Strong IR NLO Material Ba4MGa4Se10Cl2: Highly Improved Laser Damage Threshold via Dual Ion Substitution Synergy97Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)24Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups279Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 2018All-metal electride molecules CuAg@Ca 7 M (M = Be, Mg, and Ca) with multi-excess electrons and all-metal polyanions: molecular structures and bonding modes as well as large infrared nonlinear optical responses27AXII4XIII5Te 12 (A = Rb, Cs; X II = Mn, Zn, Cd; X III = Ga, In): quaternary semiconducting tellurides with very low thermal conductivities25Syntheses, structures, physical and electronic properties of quaternary semiconductors: Cs[RE 9 Cd 4 Se 18 ] (RE = Tb–Tm)14Synthesis, crystal structure and second-order nonlinear optical property of a novel pentanary selenide (K 3 I)[InB 12 (InSe 4 ) 3 ]48The effect of indium substitution on the structure and NLO properties of Ba 6 Cs 2 Ga 10 Se 20 Cl 446(Cs6Cl)6Cs3[Ga53Se96]: A Unique Long Period-Stacking Structure of Layers Made from Ga2Se6 Dimers via Cis or Trans Intralayer Linking12The structure and band gap design of high Si doping level Ag1−xGa1−xSixSe2 (x=1/2)15Strong Infrared NLO Tellurides with Multifunction: CsXII4In5Te12 (XII = Mn, Zn, Cd)58Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302Syntheses, crystal and electronic structure of a series of quaternary rare-earth sulfides MgRE6Si2S14 (RE = Y, Ce, Pr, Nd and Sm)7Predicting Global Minimum in Complex Beryllium Borate System for Deep-ultraviolet Functional Optical Applications29Quaternary non-centrosymmetric sulfide Y 4 GaSbS 9 : Syntheses, structures, optical properties and theoretical studies16Non‐centrosymmetric Selenides AZn4In5Se12 (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties47Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit102Recent achievements on middle and far-infrared second-order nonlinear optical materials433A novel 2-D Mn selenidostannate( iv ) incorporating high-nuclear Mn clusters with spin canting behavior8Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity44Centrosymmetric to noncentrosymmetric structural transformation of new quaternary selenides induced by isolated dimeric [Sn 2 Se 4 ] units: from Ba 8 Ga 2 Sn 7 Se 18 to Ba 10 Ga 2 Sn 9 Se 2210Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence54Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters8Syntheses and characterization of three new sulfides with large band gaps: acentric Ba 4 Ga 4 SnS 12 , centric Ba 12 Sn 4 S 23 and Ba 7 Sn 3 S 1327Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 252Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 639Wide band gap design of new chalcogenide compounds: KSrPS 4 and CsBaAsS 422Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds101Second harmonic generation response of the cubic chalcogenides Ba(6−x)Srx[Ag(4−y)Sn(y/4)](SnS4)49Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases208Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51Coexistence of Strong Second Harmonic Generation Response and Wide Band Gap in AZn4Ga5S12 (A=K, Rb, Cs) with 3D Diamond‐like Frameworks65ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap36Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se137Hg-Based Infrared Nonlinear Optical Material KHg4Ga5Se12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response101LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point56Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge39Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg 2 GeS 4 and BaAg 2 SnS 468PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method42Design and synthesis of a nonlinear optical material BaAl 4 S 7 with a wide band gap inspired from SrB 4 O 764New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold142Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures25Sr 5 ZnGa 6 S 15 : a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance60Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13Copper-Phenylacetylide Nanobelt/Single-Walled Carbon Nanotube Composites: Mechanochromic Luminescence Phenomenon and Thermoelectric Performance45Pushing Nonlinear Optical Oxides into the Mid-Infrared Spectral Region Beyond 10 μm: Design, Synthesis, and Characterization of La3SnGa5O14145Cs2Ge3In6Se14: A Structure Transformation Driven by the Size Preference and Its Properties8Six New Members of the A2MIIMIV3Q8 Family and Their Structural Relationship26The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation14Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations61Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra16Ternary Mixed-Metal Cd4GeS6: Remarkable Nonlinear-Optical Properties Based on a Tetrahedral-Stacking Framework41A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances253Cu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination26Recent advances and future perspectives on infrared nonlinear optical metal halides223Solid-State Preparation, Structural Characterization, Physical Properties, and Theoretical Studies of a Series of Novel Rare-Earth Metal Chalcogenides with Unprecedented Closed-Cavities15Recent progress on new infrared nonlinear optical materials with application prospect133Adjustable optical nonlinearity in d 10 cations containing chalcogenides via dp hybridization interaction13Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response13Centric-to-acentric structure transformation induced by a stereochemically active lone pair: a new insight for design of IR nonlinear optical materials90From CuFeS 2 to Ba 6 Cu 2 FeGe 4 S 16 : rational band gap engineering achieves large second-harmonic-generation together with high laser damage threshold22Impressive second harmonic generation response in a novel phase-matchable NLO-active MOF derived from achiral precursors38Mn-Based tin sulfide Sr 3 MnSn 2 S 8 with a wide band gap and strong nonlinear optical response30Partial substitution induced centrosymmetric to noncentrosymmetric structure transformation and promising second-order nonlinear optical properties of (K 0.38 Ba 0.81 )Ga 2 Se 495SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance20SrCdSnQ 4 (Q = S and Se): infrared nonlinear optical chalcogenides with mixed NLO-active and synergetic distorted motifs69BaV2O6·H2O: A nonlinear optical crystal with a large bandgap7Broadening Frontiers of Infrared Nonlinear Optical Materials with π-Conjugated Trigonal-Planar Groups67Ba10In6Zn7S26-nZnS: An Inorganic Composite System with Interface Phase-Matching Tuned for High-Performance Infrared Nonlinear Optical Materials13[Ge2S5(S2)]4−, A NLO‐Active Unit Leading to an Asymmetric Structure Discovered in Li2Cs4Ge2S5(S2)Cl2: An Experimental and Theoretical study18Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide188Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide48Synthesis, Structure, and Characterization of Two Mixed-Cation Quaternary Chalcogenides K2BaSnQ4 (Q = S, Se)19Ba10In6Zn7S10Se16 and Ba10In6Zn7Se26: Two new infrared nonlinear optical materials with T2 super tetrahedron6Ba2Si3P6: 1D Nonlinear Optical Material with Thermal Barrier Chains99Synthesis, characterization and theoretical calculation of a noncentrosymmetric compound, Cs0.92B0.92Si5.08O122AHgSnQ4 (A = Sr, Ba; Q = S, Se): A Series of Hg-Based Infrared Nonlinear-Optical Materials with Strong Second-Harmonic-Generation Response and Good Phase Matchability76Sn 2 Ga 2 S 5 : A Polar Semiconductor with Exceptional Infrared Nonlinear Optical Properties Originating from the Combined Effect of Mixed Asymmetric Building Motifs81LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition12Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency81Rb10Zn4Sn4S17: A Chalcogenide with Large Laser Damage Threshold Improved from the Mn-Based Analogue28Rational design of infrared nonlinear optical chalcogenides by chemical substitution287A highly distorted HgS 4 tetrahedron-induced moderate second-harmonic generation response of EuHgGeS 462A new type of novel salt-inclusion chalcogenide with ultralow thermal conductivity14Ba 6 In 6 Zn 4 Se 19 : a high performance infrared nonlinear optical crystal with [InSe 3 ] 3− trigonal planar functional motifs22Li 2 CdSiS 4 , a promising IR NLO material with a balanced E g and SHG response originating from the effect of Cd with d 10 configuration36Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture33Molecular Construction from AgGaS 2 to CuZnPS 4 : Defect-Induced Second Harmonic Generation Enhancement and Cosubstitution-Driven Band Gap Enlargement97KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure146Crystal chemistry, second-order nonlinear optical, and magnetic properties of Eu8Sn4Se2014Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability16A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials131Ultrafast broadband reverse saturation absorption in Al-doped InSe thin films for optical limiting at visible/near-infrared25Salt-Inclusion Chalcogenide [Ba4Cl2][ZnGa4S10]: Rational Design of an IR Nonlinear Optical Material with Superior Comprehensive Performance Derived from AgGaS2134Chalcophosphates: A Treasure House of Infrared Nonlinear Optical Materials75AMnAs3S6 (A = Cs, Rb): Phase-Matchable Infrared Nonlinear Optical Functional Motif [As3S6]3– Obtained via Surfactant–Thermal Method32Ultralow thermal conductivity in the quaternary semiconducting chalcogenide Cs 4 [Ho 26 Cd 7 Se 48 ] with an unprecedented closed cavity architecture7In4Pb5.5Sb5S19: A Stable Quaternary Chalcogenide with Low Thermal Conductivity11Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95A 3 Mn 2 Sb 3 S 8 (A = K and Rb): a new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks53Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47Ba 2 Ge 2 Te 5 : a ternary NLO-active telluride with unusual one-dimensional helical chains and giant second harmonic-generation tensors31From Ce(IO 3 ) 4 to CeF 2 (IO 3 ) 2 : fluorinated homovalent substitution simultaneously enhances SHG response and bandgap for mid-infrared nonlinear optics26New nonlinear optical-active AAgGa 6 S 10 (A = K, Rb, Cs) featuring {[AgGa 6 S 10 ] − } ∞ framework and high laser damage threshold42Structural diversities in centrosymmetric La 8 S 4 Cl 8 La 12 S 8 Cl 4 [SbS 3 ] 8 and non-centrosymmetric Ln 12 S 8 Cl 8 [SbS 3 ] 4 (Ln = La and Ce): syntheses, crystal and electronic structures, and optical properties10A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling Effect25Inorganic Chalcogenides: From Zero‐Dimensional Clusters to Three‐Dimensional Frameworks5Relationship Between Structure and Electroluminescent, Photochromic, or Second‐Order Nonlinear Optical Property1Relationship Between Structure and Electroluminescent, Photochromic, or Second‐Order Nonlinear Optical Property1AZn4Ga5Se12 (A = K, Rb, or Cs): Infrared Nonlinear Optical Materials with Simultaneous Large Second Harmonic Generation Responses and High Laser-Induced Damage Thresholds34BaCdGeSe4: Synthesis, structure and nonlinear optical properties13Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides28Highly Distorted [HgS 4 ] Motif-Driven Structural Symmetry Degradation and Strengthened Second-Harmonic Generation Response in the Defect Diamond-Like Chalcogenide Hg 3 P 2 S 847Triclinic Layered A2ZnSi3S8 (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A2MIIBMIV3Q8 Family11A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation22A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation64Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184Ultrafast Broadband Nonlinear Optical Response in Co-Doped Sb2Se3 Nanofilms at Near-Infrared9Highly polarized [GeOTe 3 ] motif-driven structural order promotion and an enhanced second harmonic generation response in the new nonlinear optical oxytelluride Ba 3 Ge 2 O 4 Te 334First-principles study of opto-electronic and thermoelectric properties of SrCdSnX4 (X=S, Se, Te) alkali metal chalcogenides35Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks63Rational combination of multiple structural groups on regulating nonlinear optical property in hexagonal Ln3MGeS7 polar crystals10AAg 2 PS 4 (A = K, Na/K): the first-type of noncentrosymmetric alkali metal Ag-based thiophosphates exhibiting excellent second-order nonlinear optical performances21Ba 6 In 2 Ge 2 Te 15 : a THz birefringent material with an intriguing quasi-[Te 5 ] 4− chain possessing large optical anisotropy and an ultrawide transmission range7Broad transparency and wide band gap achieved in a magnetic infrared nonlinear optical chalcogenide by suppressing d–d transitions41Infrared nonlinear optical sulfide CsCd 4 In 5 S 12 exhibiting large second harmonic generation response16Phase matching achieved by isomorphous substitution in IR nonlinear optical material Ba 2 SnSSi 2 O 7 with an undiscovered [SnO 4 S] functional motif47Rational design via dual-site aliovalent substitution leads to an outstanding IR nonlinear optical material with well-balanced comprehensive properties69Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation17Optimizing the Nonlinear Optical Performance of an A-N-M-Q (A: Alkali Metal; N: d10 Metal; M: Main Group Metal; Q: Chalcogen) System44From Cc to P 6 3 mc : Structural Variation in La 3 S 2 Cl 2 [SbS 3 ] and La 3 OSCl 2 [SbS 3 ] Induced by the Isovalent Anion Substitution22BaSi7P10 and SrSi7P10: Two Infrared Nonlinear Optical Phosphides with T2 Supertetrahedra Exhibiting Strong Second‐Harmonic Generation Effects22

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  1. ChemInform Abstract: Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12.

    ChemInform · 2013-12-02

    Hua Lin, Ling Chen, Liujiang Zhou, Li‐Ming Wu

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  2. Ba8Sn4S15: A Strong Second Harmonic Generation Sulfide with Zero-Dimensional Crystal Structure

    Chemistry of Materials · 2013-12-17

    Zhong‐Zhen Luo, Chensheng Lin, Weilong Zhang, Hao Zhang, Zhangzhen He, Wen‐Dan Cheng

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  3. Deep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)

    Journal of the American Chemical Society · 2013-12-19

    Peng Yu, Li‐Ming Wu, Liujiang Zhou, Ling Chen

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  4. Crystal structure and magnetic and photocatalytic properties of a new ternary rare-earth mixed chalcogenide, Dy 4 S 4 Te 3

    Journal of Materials Chemistry A · 2014-01-01

    Sheng‐Ping Guo, Guo‐Cong Guo

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  5. Li2CdGeS4, A Diamond-Like Semiconductor with Strong Second-Order Optical Nonlinearity in the Infrared and Exceptional Laser Damage Threshold

    Chemistry of Materials · 2014-04-29

    Jacilynn A. Brant, Daniel J. Clark, Yong Soo Kim, Joon Ik Jang, Jian‐Han Zhang, Jennifer A. Aitken

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  6. Ag 3 Ga 3 SiSe 8 : a new infrared nonlinear optical material with a chalcopyrite structure

    CrystEngComm · 2014-06-05

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  7. Optical Nonlinearity in Cu2CdSnS4 and α/β-Cu2ZnSiS4: Diamond-like Semiconductors with High Laser-Damage Thresholds

    Inorganic Chemistry · 2014-07-25

    Kimberly A. Rosmus, Jacilynn A. Brant, Stephen D. Wisneski, Daniel J. Clark, Yong Soo Kim, Joon Ik Jang, Carl D. Brunetta, Jian‐Han Zhang, Matthew N. Srnec, Jennifer A. Aitken

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  8. An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property

    Inorganic Chemistry · 2014-10-15

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  9. Designing the syntheses and photophysical simulations of noncentrosymmetric compounds

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  10. Quaternary rare-earth selenides with closed cavities: Cs[RE 9 Mn 4 Se 18 ] (RE = Ho–Lu)

    Inorganic Chemistry Frontiers · 2015-01-01

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  11. Recent advances on second-order NLO materials based on metal iodates

    Coordination Chemistry Reviews · 2015-01-25

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  12. Second Harmonic Generation Response Optimized at Various Optical Wavelength Ranges through a Series of Cubic Chalcogenides Ba6Ag2.67+4δSn4.33−δS16–xSex

    Chemistry of Materials · 2015-01-30

    Wei-Han Lai, Alyssa S. Haynes, Laszlo Frazer, Yu-Ming Chang, Te-Kun Liu, Jyun-Fan Lin, I. C. Liang, Hwo‐Shuenn Sheu, John B. Ketterson, Mercouri G. Kanatzidis, Kuei‐Fang Hsu

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  13. Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation

    Chemistry of Materials · 2015-02-16

    Yong‐Fang Shi, Yukun Chen, Mei‐Chun Chen, Li‐Ming Wu, Hua Lin, Liujiang Zhou, Ling Chen

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  14. Strong IR NLO Material Ba4MGa4Se10Cl2: Highly Improved Laser Damage Threshold via Dual Ion Substitution Synergy

    Advanced Optical Materials · 2015-03-18

    Yan‐Yan Li, Pengfei Liu, Lei Hu, Ling Chen, Hua Lin, Liujiang Zhou, Li‐Ming Wu

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  15. Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)

    Journal of Solid State Chemistry · 2015-04-02

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  16. Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups

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    Xiaoyu Dong, Qun Jing, Yunjing Shi, Zhihua Yang, Shilie Pan, Kenneth Reinhard Poeppelmeier, Joshua Young, James M. Rondinelli

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  17. Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 20

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    Xiaoshuang Li, Chao Li, Pifu Gong, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  18. All-metal electride molecules CuAg@Ca 7 M (M = Be, Mg, and Ca) with multi-excess electrons and all-metal polyanions: molecular structures and bonding modes as well as large infrared nonlinear optical responses

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  19. AXII4XIII5Te 12 (A = Rb, Cs; X II = Mn, Zn, Cd; X III = Ga, In): quaternary semiconducting tellurides with very low thermal conductivities

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  20. Syntheses, structures, physical and electronic properties of quaternary semiconductors: Cs[RE 9 Cd 4 Se 18 ] (RE = Tb–Tm)

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  21. Synthesis, crystal structure and second-order nonlinear optical property of a novel pentanary selenide (K 3 I)[InB 12 (InSe 4 ) 3 ]

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  22. The effect of indium substitution on the structure and NLO properties of Ba 6 Cs 2 Ga 10 Se 20 Cl 4

    Inorganic Chemistry Frontiers · 2016-01-01

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  23. (Cs6Cl)6Cs3[Ga53Se96]: A Unique Long Period-Stacking Structure of Layers Made from Ga2Se6 Dimers via Cis or Trans Intralayer Linking

    Inorganic Chemistry · 2016-01-21

    Hua Lin, Hong Chen, Zixiong Lin, Hua‐Jun Zhao, Pengfei Liu, Ju‐Song Yu, Ling Chen

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  24. The structure and band gap design of high Si doping level Ag1−xGa1−xSixSe2 (x=1/2)

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  25. Strong Infrared NLO Tellurides with Multifunction: CsXII4In5Te12 (XII = Mn, Zn, Cd)

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  26. Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold

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  27. Syntheses, crystal and electronic structure of a series of quaternary rare-earth sulfides MgRE6Si2S14 (RE = Y, Ce, Pr, Nd and Sm)

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  28. Predicting Global Minimum in Complex Beryllium Borate System for Deep-ultraviolet Functional Optical Applications

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  29. Quaternary non-centrosymmetric sulfide Y 4 GaSbS 9 : Syntheses, structures, optical properties and theoretical studies

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  30. Non‐centrosymmetric Selenides AZn4In5Se12 (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties

    Chemistry - An Asian Journal · 2016-12-01

    Hua Lin, Yu‐Jun Zheng, Xiaoning Hu, Hong Chen, Ju‐Song Yu, Li‐Ming Wu

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  31. Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit

    Chemistry of Materials · 2016-12-26

    Hua Lin, Ling Chen, Ju‐Song Yu, Hong Chen, Li‐Ming Wu

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  32. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

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  33. A novel 2-D Mn selenidostannate( iv ) incorporating high-nuclear Mn clusters with spin canting behavior

    Dalton Transactions · 2017-01-01

    Jian Zhou, Hong Ping Xiao, Hua‐Hong Zou, Xing Liu

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  34. Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity

    Journal of Materials Chemistry C · 2017-01-01

    Ruihuan Duan, Pengfei Liu, Hua Lin, Yi‐Wen Zheng, Ju‐Song Yu, Xin‐Tao Wu, Shangxiong Huangfu, Ling Chen

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  35. Centrosymmetric to noncentrosymmetric structural transformation of new quaternary selenides induced by isolated dimeric [Sn 2 Se 4 ] units: from Ba 8 Ga 2 Sn 7 Se 18 to Ba 10 Ga 2 Sn 9 Se 22

    RSC Advances · 2017-01-01

    Yanyan Li, Jinqiu Wang, Pengfei Liu, Hua Lin, Ling Chen, Li‐Ming Wu

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  36. Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence

    Inorganic Chemistry Frontiers · 2017-01-01

    Jian‐Han Zhang, Daniel J. Clark, Ashley Weiland, Stanislav S. Stoyko, Yong Soo Kim, Joon Ik Jang, Jennifer A. Aitken

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  37. Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters

    Dalton Transactions · 2017-01-01

    Guangmao Li, Ni Zhen, Yu Chu, Zhongxiang Zhou

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  38. Syntheses and characterization of three new sulfides with large band gaps: acentric Ba 4 Ga 4 SnS 12 , centric Ba 12 Sn 4 S 23 and Ba 7 Sn 3 S 13

    Dalton Transactions · 2017-01-01

    Ruihuan Duan, Pengfei Liu, Hua Lin, Shangxiong Huangfu, Li‐Ming Wu

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  39. Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2

    Dalton Transactions · 2017-01-01

    Pengfei Liu, Yanyan Li, Yujun Zheng, Ju‐Song Yu, Ruihuan Duan, Hong Chen, Hua Lin, Ling Chen, Li‐Ming Wu

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  40. Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 6

    Dalton Transactions · 2017-01-01

    Hua Lin, Hong Chen, Yujun Zheng, Ju‐Song Yu, Xin‐Tao Wu, Li‐Ming Wu

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  41. Wide band gap design of new chalcogenide compounds: KSrPS 4 and CsBaAsS 4

    RSC Advances · 2017-01-01

    Jian‐Qiao Jiang, Dajiang Mei, Pifu Gong, Zheshuai Lin, Junbo Zhong, Yuandong Wu

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  42. Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds

    Chemistry of Materials · 2017-01-30

    Shu‐Fang Li, Xiao‐Ming Jiang, Bin‐Wen Liu, Dong Yan, Chensheng Lin, Hui‐Yi Zeng, Guo‐Cong Guo

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  43. Second harmonic generation response of the cubic chalcogenides Ba(6−x)Srx[Ag(4−y)Sn(y/4)](SnS4)4

    Journal of Solid State Chemistry · 2017-02-01

    Alyssa S. Haynes, Te-Kun Liu, Laszlo Frazer, Jyun-Fan Lin, Shuo-Yu Wang, John B. Ketterson, Mercouri G. Kanatzidis, Kuei‐Fang Hsu

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  44. Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases

    Inorganic Chemistry · 2017-03-09

    Mercouri G. Kanatzidis

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  45. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

    Crystal Growth & Design · 2017-03-15

    Fei Liang, Lei Kang, Zheshuai Lin, Yicheng Wu

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  46. Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold

    Crystal Growth & Design · 2017-03-30

    Zhaohui Chen, Zhizhong Zhang, Xiaoyu Dong, Yunjing Shi, Yaqin Liu, Qun Jing

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  47. Coexistence of Strong Second Harmonic Generation Response and Wide Band Gap in AZn4Ga5S12 (A=K, Rb, Cs) with 3D Diamond‐like Frameworks

    Chemistry - A European Journal · 2017-06-03

    Hua Lin, Hong Chen, Yu‐Jun Zheng, Ju‐Song Yu, Xin‐Tao Wu, Li‐Ming Wu

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  48. ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap

    Angewandte Chemie International Edition · 2017-06-20

    Hongming Liu, Qi Wu, Xingxing Jiang, Zheshuai Lin, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  49. ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap

    Angewandte Chemie · 2017-06-20

    Hongming Liu, Qi Wu, Xingxing Jiang, Zheshuai Lin, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  50. Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13

    Journal of Solid State Chemistry · 2017-08-16

    Ailijiang Abudurusuli, Hanqin Ding, Kui Wu

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