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RESEARCH PAPER · Inorganic Chemistry · 2017

Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge

Jiang-He Feng, Chun‐Li Hu, Houping Xia, Fang Kong, Jiang‐Gao Mao

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Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff EdgeOriginalEffect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses103Three new d10 transition metal selenites containing PO4 tetrahedron: Cd7(HPO4)2(PO4)2(SeO3)2, Cd6(PO4)1.34(SeO3)4.66 and Zn3(HPO4)(SeO3)2(H2O)16Variable Asymmetric Chains in Transition Metal Oxyfluorides: Structure–Second-Harmonic-Generation Property Relationships16PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units52NaCa4V5O17 with isolated V2O7 dimer and V3O10 trimer exhibiting a large birefringence18Rational Design of a LiNbO3-like Nonlinear Optical Crystal, Li2ZrTeO6, with High Laser-Damage Threshold and Wide Mid-IR Transparency Window152Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold19Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges0Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties26Designing Three Fluorooxoborates with a Wide Transmittance Window by Anionic Group Substitution15Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)28Shedding Light on the Intrinsic Characteristics of 3D Distorted Fluorite-Type Zirconium Tellurite Single Crystals12NaYTe2O7: A new compound with mixed valence of tellurium and large birefringence6X-ray derived experimental charge density distribution in two isostructural oxyfluorotellurates, FeTeO3F and GaTeO3F3BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains11Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge28Recent progress in selenite and tellurite based SHG materials32Noncentrosymmetric Fluorooxoborates A10B13O15F19 (A = K and Rb) with Unexpected [B10O12F13]7– Units and Deep-Ultraviolet Cutoff Edges26BaF 2 TeF 2 (OH) 2 : A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering157Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites23Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O5Cation Substitution of Hexagonal Triple Perovskites: A Case in Trimetallic Tellurates A2A′BTe2O910Structure-performance relationship in tri-coordinated nonlinear optical materials toward optimal second harmonic generation and phase matching31Two Tellurium(IV)-Based Sulfates Exhibiting Strong Second Harmonic Generation and Moderate Birefringence as Promising Ultraviolet Nonlinear Optical Materials28Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo 2 O 8 F150La 3 Ga 3 Ge 2 S 3 O 10 : An Ultraviolet Nonlinear Optical Oxysulfide Designed by Anion‐Directed Band Gap Engineering63La3Ga3Ge2S3O10: An Ultraviolet Nonlinear Optical Oxysulfide Designed by Anion‐Directed Band Gap Engineering18Two new tellurite halides with cationic layers: syntheses, structures, and characterizations of CdPb 2 Te 3 O 8 Cl 2 and Cd 13 Pb 8 Te 14 O 42 Cl 1418K3ZrF4(SbF4)(SbF5) and K8(ZrF6)(Sb2Zr2F20): Two Zirconium Fluoroantimonites with Low Dimensional Structures and Wide Transparency Range12Growth and Characterization of a Nonlinear Optical Crystal Cd3Te2WO10 Decorated by WO4 Tetrahedra Showing a Large Band Gap9From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties27Shedding light on intrinsic characteristics and optical properties of novel selenite and tellurite crystals ZrSe 2 O 6 , HfSe 2 O 6 and HfTe 3 O 87AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap21A survey of stereoactive oxysalts for linear and nonlinear optical applications40Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability4Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties4LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10

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  1. Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)

    Inorganic Chemistry · 2018-03-06

    Leyan Nian, Kui Wu, Guijie He, Zhihua Yang, Shilie Pan

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  2. A Series of Rare-Earth Borates K 7 MRE 2 B 15 O 30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with Large Second Harmonic Generation Responses

    Chemistry of Materials · 2018-03-08

    Zhiqing Xie, Miriding Mutailipu, Guijie He, Guopeng Han, Ying Wang, Zhihua Yang, Min Zhang, Shilie Pan

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  3. Three new d10 transition metal selenites containing PO4 tetrahedron: Cd7(HPO4)2(PO4)2(SeO3)2, Cd6(PO4)1.34(SeO3)4.66 and Zn3(HPO4)(SeO3)2(H2O)

    Journal of Solid State Chemistry · 2018-03-28

    Yun‐Xiang Ma, Ya-Ping Gong, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  4. Variable Asymmetric Chains in Transition Metal Oxyfluorides: Structure–Second-Harmonic-Generation Property Relationships

    Inorganic Chemistry · 2018-05-15

    Belal Ahmed, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  5. PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units

    Inorganic Chemistry · 2018-08-30

    Yun‐Xiang Ma, Chun‐Li Hu, Bingxuan Li, Fang Kong, Jiang‐Gao Mao

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  6. NaCa4V5O17 with isolated V2O7 dimer and V3O10 trimer exhibiting a large birefringence

    Journal of Solid State Chemistry · 2018-09-12

    Zhiqing Xie, Shichao Cheng, Shuwei Li, Hanqin Ding

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  7. Rational Design of a LiNbO3-like Nonlinear Optical Crystal, Li2ZrTeO6, with High Laser-Damage Threshold and Wide Mid-IR Transparency Window

    Journal of the American Chemical Society · 2018-09-13

    Weiqun Lu, Zeliang Gao, Xitao Liu, Xiangxin Tian, Qian Wu, Conggang Li, Youxuan Sun, Yang Liu, Xutang Tao

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  8. Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold

    Dalton Transactions · 2019-01-01

    Qi Wu, Xian Liu, Fei Liang, Siran Xu, Hongbing Pi, Xue Han, Yang Liu, Zheshuai Lin, Yanjun Li

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  9. Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges

    New Journal of Chemistry · 2019-01-01

    Shuaishuai Hu, Zhi Su

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  10. Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties

    Crystal Growth & Design · 2019-01-24

    Conggang Li, Zeliang Gao, Peng Zhao, Xiangxin Tian, Haoyuan Wang, Qian Wu, Weiqun Lu, Youxuan Sun, Deliang Cui, Xutang Tao

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  11. Designing Three Fluorooxoborates with a Wide Transmittance Window by Anionic Group Substitution

    Inorganic Chemistry · 2019-03-04

    Dequan Jiang, Guopeng Han, Ying Wang, Hao Li, Zhihua Yang, Shilie Pan

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  12. Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)

    Science China Materials · 2019-03-22

    Zhiqing Xie, Ying Wang, Shichao Cheng, Guopeng Han, Zhihua Yang, Shilie Pan

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  13. Shedding Light on the Intrinsic Characteristics of 3D Distorted Fluorite-Type Zirconium Tellurite Single Crystals

    Inorganic Chemistry · 2019-04-19

    Weiqun Lu, Zeliang Gao, Xiaoli Du, Xiangxin Tian, Qian Wu, Conggang Li, Youxuan Sun, Yang Liu, Xutang Tao

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  14. NaYTe2O7: A new compound with mixed valence of tellurium and large birefringence

    Journal of Alloys and Compounds · 2019-10-02

    Houping Xia, Jinni Shen, Zhi-An Zhu, Yang‐Yang Lv, Qian Ma, Haiqing Wang

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  15. X-ray derived experimental charge density distribution in two isostructural oxyfluorotellurates, FeTeO3F and GaTeO3F

    Physica B Condensed Matter · 2019-11-19

    K. Sujatha, S. Israel, Chellam Anzline

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  16. BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains

    Dalton Transactions · 2020-01-01

    Ting Wang, Yi-Gang Chen, Yao Guo, Fang Wang, Qi Song, Ying‐Jie Jia, Xian‐Ming Zhang

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  17. Gd(NO 3 )(Se 2 O 5 )·3H 2 O: a nitrate–selenite nonlinear optical material with a short ultraviolet cutoff edge

    Dalton Transactions · 2020-01-01

    Chao Wu, Longhua Li, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  18. Recent progress in selenite and tellurite based SHG materials

    Dalton Transactions · 2020-01-01

    Fang Kong, Jiang‐Gao Mao

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  19. Noncentrosymmetric Fluorooxoborates A10B13O15F19 (A = K and Rb) with Unexpected [B10O12F13]7– Units and Deep-Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2020-02-10

    Wenyao Zhang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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  20. BaF 2 TeF 2 (OH) 2 : A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering

    Journal of the American Chemical Society · 2020-02-25

    Jinjie Zhou, Hongping Wu, Hongwei Yu, Shutong Jiang, Zhanggui Hu, Jiyang Wang, Yicheng Wu, P. Shiv Halasyamani

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  21. Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

    Chemical Communications · 2021-01-01

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  22. Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O

    Journal of Solid State Chemistry · 2021-02-28

    Chao Wu, Lin Lin, Tianhui Wu, Zhipeng Huang, Chi Zhang

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  23. Cation Substitution of Hexagonal Triple Perovskites: A Case in Trimetallic Tellurates A2A′BTe2O9

    Inorganic Chemistry · 2021-04-06

    Congcong Jin, Miriding Mutailipu, Wenqi Jin, Shujuan Han, Zhihua Yang, Shilie Pan

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  24. Structure-performance relationship in tri-coordinated nonlinear optical materials toward optimal second harmonic generation and phase matching

    Coordination Chemistry Reviews · 2021-06-08

    Fengjuan Hou, Dajiang Mei, Mingjun Xia, Yuandong Wu

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  25. Two Tellurium(IV)-Based Sulfates Exhibiting Strong Second Harmonic Generation and Moderate Birefringence as Promising Ultraviolet Nonlinear Optical Materials

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    Yunxia Song, Xia Hao, Chensheng Lin, Donghong Lin, Min Luo, Ning Ye

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  26. Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo 2 O 8 F

    Journal of the American Chemical Society · 2021-08-09

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  27. La 3 Ga 3 Ge 2 S 3 O 10 : An Ultraviolet Nonlinear Optical Oxysulfide Designed by Anion‐Directed Band Gap Engineering

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  28. La3Ga3Ge2S3O10: An Ultraviolet Nonlinear Optical Oxysulfide Designed by Anion‐Directed Band Gap Engineering

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  29. Two new tellurite halides with cationic layers: syntheses, structures, and characterizations of CdPb 2 Te 3 O 8 Cl 2 and Cd 13 Pb 8 Te 14 O 42 Cl 14

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  30. K3ZrF4(SbF4)(SbF5) and K8(ZrF6)(Sb2Zr2F20): Two Zirconium Fluoroantimonites with Low Dimensional Structures and Wide Transparency Range

    Inorganic Chemistry · 2022-03-14

    Ting-Kun Jiang, Shengnan Yan, Chun‐Li Hu, Yafeng Li, Fang Kong, Jiang‐Gao Mao

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  31. Growth and Characterization of a Nonlinear Optical Crystal Cd3Te2WO10 Decorated by WO4 Tetrahedra Showing a Large Band Gap

    Crystal Growth & Design · 2022-09-27

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  32. From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties

    Inorganic Chemistry Frontiers · 2023-01-01

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  33. Shedding light on intrinsic characteristics and optical properties of novel selenite and tellurite crystals ZrSe 2 O 6 , HfSe 2 O 6 and HfTe 3 O 8

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  34. AAl(Te 4 O 10 ) (A = Na, Ag) and K 2 Ga 2 (HTe 6 O 16 )(HTeO 3 ): Three Aluminum/Gallium Tellurites with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2023-05-24

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  35. A survey of stereoactive oxysalts for linear and nonlinear optical applications

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  36. Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups

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  37. Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability

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  38. Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties

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  39. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

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