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RESEARCH PAPER · Chem Catalysis · 2023

Identifying selective catalysts in polypropylene hydrogenolysis by decoupling scission pathways

Shibashish D. Jaydev, Marc‐Eduard Usteri, Antonio José Martín, Javier Pérez‐Ramírez

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Identifying selective catalysts in polypropylene hydrogenolysis by decoupling scission pathwaysOriginalToward a unified metric of catalyst comparison in polymer hydrogenolysis3Investigation into the Reaction Pathways and Catalyst Deactivation for Polyethylene Hydrogenolysis over Silica-Supported Cobalt Catalysts58Effect of Hydrogen Spillover on the Ru/TiO2-Catalyzed Guaiacol Hydrodeoxygenation: Rutile vs Anatase TiO2100Boosting the catalytic performance of metal–zeolite catalysts in the hydrocracking of polyolefin wastes by optimizing the nanoscale proximity56Consumer Grade Polyethylene Recycling via Hydrogenolysis on Ultrafine Supported Ruthenium Nanoparticles2Consumer Grade Polyethylene Recycling via Hydrogenolysis on Ultrafine Supported Ruthenium Nanoparticles38Review on Catalytic Depolymerization of Polyolefin Waste by Hydrogenolysis: State-of-the-Art and Outlook57Catalytic Upcycling of Polyolefins316Assessment of transport phenomena in catalyst effectiveness for chemical polyolefin recycling45Hydrogenolysis of Polyethylene by Metal–Organic Framework Confined Single-Site Ruthenium Catalysts16Challenges and opportunities in catalytic hydrogenolysis of oxygenated plastics waste: polyesters, polycarbonates, and epoxy resins44Elucidating the effect of nanocube support morphology on the hydrogenolysis of polypropylene over Ni/CeO 2 catalysts7Heterogeneous catalysis strategies for polyolefin plastic upcycling: co-reactant-assisted and direct transformation under mild conditions15Mechanistic Insights into Polypropylene Hydrogenolysis Using Ni/Al2O3 Catalysts17Boosting the Application of Spent Catalysts in Waste Plastic Catalytic Pyrolysis: Maximizing Gasoline Product Selectivity and Quality4Reductive Upcycling of Polyolefins, Polyesters and Mixed Plastic Wastes to Valuable Chemicals: Bridging Chemical Catalysis With Plastic Waste Management35Ru-Catalyzed Polyethylene Hydrogenolysis under Quasi-Supercritical Conditions25Predicting a generalized mechanism of branched alkane hydrogenolysis on Ru, Ir, and Pt surfaces relevant to polymer upcycling applications3Methods for Carbon Mass Closure in Polyolefin Hydrocracking6Plastic waste recycling: an overview of the mechanical, chemical, and thermal technologies18Surface and Interface Properties of Metal Species for Waste Plastic Hydroconversion6Enhancing selectivity and yield in polyethylene hydrogenolysis using goal-aware Bayesian algorithm execution0Selective Conversion of Polyolefin Waste to Branched Alkanes via Methane‐Free Tandem Hydrocracking–Isomerization2Hydrocracking Polyolefins to Jet Fuel over a NiW/WO x Catalyst2Structure–performance relationships in heterogeneous catalysts for polyolefin plastic hydroconversion1Ceria‐Based Catalysts for Sustainable Processing of Plastic Waste0Advances in Catalytic Hydrogenolysis of Waste Plastics to Value-Added Products0Co 1 /Ru Single‐Atom Alloy Catalyst for Sustainable Polypropylene Hydrogenolysis to Long‐Chain Liquid Products1A Mesopore-Confined and Graphene Oxide-Localized Ruthenium Catalyst Increases Rates of Mid-Chain Polyolefin Hydrogenolysis0Breaking the Yield‐Selectivity Trade‐Off in Polypropylene Upcycling via Ternary‐Active ZnAlO Nanocomposites0Efficient and Selective Low-Temperature Polypropylene Hydrogenolysis Using Zr-Doped Mixed Metal Oxides Catalysts0

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31 direct citing papers saved.

  1. Toward a unified metric of catalyst comparison in polymer hydrogenolysis

    Chem Catalysis · 2023-05-01

    Ryan Helmer, Manish Shetty

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  2. Investigation into the Reaction Pathways and Catalyst Deactivation for Polyethylene Hydrogenolysis over Silica-Supported Cobalt Catalysts

    ACS Sustainable Chemistry & Engineering · 2023-06-27

    Siddhesh S. Borkar, Ryan Helmer, Suraj Panicker, Manish Shetty

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  3. Effect of Hydrogen Spillover on the Ru/TiO2-Catalyzed Guaiacol Hydrodeoxygenation: Rutile vs Anatase TiO2

    ACS Catalysis · 2023-08-24

    Hyungjoo Kim, Hyungjoo Kim, Jae Hyun Park, Jeong‐Myeong Ha, Do Heui Kim, Do Heui Kim

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  4. Boosting the catalytic performance of metal–zeolite catalysts in the hydrocracking of polyolefin wastes by optimizing the nanoscale proximity

    EES Catalysis · 2023-10-09

    Xinlei Han, Xinru Zhou, Tuo Ji, Feng Zeng, Weiping Deng, Zhenchen Tang, Rizhi Chen

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  5. Consumer Grade Polyethylene Recycling via Hydrogenolysis on Ultrafine Supported Ruthenium Nanoparticles

    Angewandte Chemie · 2023-12-17

    Shibashish D. Jaydev, Antonio José Martín, Marc‐Eduard Usteri, Katia Chikri, Henrik Eliasson, Rolf Erni, Javier Pérez‐Ramírez

    Read original paper ↗ ·

  6. Consumer Grade Polyethylene Recycling via Hydrogenolysis on Ultrafine Supported Ruthenium Nanoparticles

    Angewandte Chemie International Edition · 2023-12-18

    Shibashish D. Jaydev, Antonio José Martín, Marc‐Eduard Usteri, Katia Chikri, Henrik Eliasson, Rolf Erni, Javier Pérez‐Ramírez

    Read original paper ↗ ·

  7. Review on Catalytic Depolymerization of Polyolefin Waste by Hydrogenolysis: State-of-the-Art and Outlook

    Energy & Fuels · 2024-01-22

    Abdulrahman Musa, E. A. Jaseer, Samir Barman, Néstor Garcı́a

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  8. Catalytic Upcycling of Polyolefins

    Chemical Reviews · 2024-08-16

    Jia‐Kai Sun, Jinhu Dong, Lijun Gao, Yu‐Quan Zhao, Hyunjin Moon, Susannah L. Scott

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  9. Assessment of transport phenomena in catalyst effectiveness for chemical polyolefin recycling

    Nature Chemical Engineering · 2024-08-28

    Shibashish D. Jaydev, Antonio José Martín, David Garcia, Katia Chikri, Javier Pérez‐Ramírez

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  10. Hydrogenolysis of Polyethylene by Metal–Organic Framework Confined Single-Site Ruthenium Catalysts

    Chemistry of Materials · 2024-10-24

    Manav Chauhan, Chhaya Thadhani, Bharti Rana, Poorvi Gupta, Biplab Ghosh, Kuntal Manna

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  11. Challenges and opportunities in catalytic hydrogenolysis of oxygenated plastics waste: polyesters, polycarbonates, and epoxy resins

    Green Chemistry · 2024-11-25

    Harisekhar Mitta, Lingfeng Li, Mohammadhossein Havaei, Dambarudhar Parida, Elias Féghali, Kathy Elst, Annelore Aerts, Karolien Vanbroekhoven, Kevin M. Van Geem

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  12. Elucidating the effect of nanocube support morphology on the hydrogenolysis of polypropylene over Ni/CeO 2 catalysts

    Journal of Materials Chemistry A · 2024-12-10

    Donald R. Inns, Megan Carr, Mounib Bahri, Ajay Tomer, Troy D. Manning, Nigel D. Browning, Simon A. Kondrat, John B. Claridge, Alexandros P. Katsoulidis, Matthew J. Rosseinsky

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  13. Heterogeneous catalysis strategies for polyolefin plastic upcycling: co-reactant-assisted and direct transformation under mild conditions

    Chemical Communications · 2024-12-18

    Haokun Wang, Sijie Huang, Shik Chi Edman Tsang

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  14. Mechanistic Insights into Polypropylene Hydrogenolysis Using Ni/Al2O3 Catalysts

    Energy & Fuels · 2025-01-10

    Xiyan Huang, Weixin Meng, Diego A. Acevedo–Guzmán, Hongqi Wang, Balaji Sridharan, Petra Rudolf, Hero Jan Heeres, Jingxiu Xie

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  15. Boosting the Application of Spent Catalysts in Waste Plastic Catalytic Pyrolysis: Maximizing Gasoline Product Selectivity and Quality

    ChemistrySelect · 2025-02-01

    Jinqing Zhang, Xiaodong Wang, Kun Sun, Ting Wang, Hui Jing Zhao, Xiaobo Chen, Xingong Zhang, Chaohe Yang

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  16. Reductive Upcycling of Polyolefins, Polyesters and Mixed Plastic Wastes to Valuable Chemicals: Bridging Chemical Catalysis With Plastic Waste Management

    Advanced Sustainable Systems · 2025-03-20

    Sahil Kumar, Devanshu Sajwan, Devendra Sharma, Venkata Krishnan

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  17. Ru-Catalyzed Polyethylene Hydrogenolysis under Quasi-Supercritical Conditions

    JACS Au · 2025-04-16

    Sung Min Kim, Boda Yang, Oliver Y. Gutiérrez, Wei Zhang, Carlos Lizandara‐Pueyo, Piyush Ingale, Ivana Jevtovikj, Reni Grauke, János Szanyi, Huamin Wang, Stephan A. Schunk, Johannes A. Lercher

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  18. Predicting a generalized mechanism of branched alkane hydrogenolysis on Ru, Ir, and Pt surfaces relevant to polymer upcycling applications

    Journal of Catalysis · 2025-05-08

    Andy Simonson, Lydia Thies, David D. Hibbitts

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  19. Methods for Carbon Mass Closure in Polyolefin Hydrocracking

    JACS Au · 2025-07-24

    Anna E. Brenner, Griffin Drake, Gregg T. Beckham, Yuriy Román‐Leshkov

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  20. Plastic waste recycling: an overview of the mechanical, chemical, and thermal technologies

    Journal of Engineering and Applied Science · 2025-12-01

    Ricardo Júnior de Oliveira Silva, Karin Graf, Maria Lúcia Leite Ribeiro Okimoto

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  21. Surface and Interface Properties of Metal Species for Waste Plastic Hydroconversion

    ACS Catalysis · 2025-12-10

    Fan Yuan, Hongshun Ran, Tingxi Chen, Yaxuan Jing

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  22. Enhancing selectivity and yield in polyethylene hydrogenolysis using goal-aware Bayesian algorithm execution

    Digital Discovery · 2026-01-01

    Makenna L. Pennel, Akash Ramdas, Sean Gasiorowski, Sathya R. Chitturi, Willie Neiswanger, Nicholas Broadbent, Mike Dunne, Felipe H. da Jornada, Daniel Ratner, Christopher J. Tassone, Matteo Cargnello

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  23. Selective Conversion of Polyolefin Waste to Branched Alkanes via Methane‐Free Tandem Hydrocracking–Isomerization

    Advanced Science · 2026-02-03

    X. Wu, Sitan Wang, Matilde Onofri, Kande Liu, KY Lin, Roland C. Turnell‐Ritson, Li Shi, Xuan Meng, Paul J. Dyson

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  24. Hydrocracking Polyolefins to Jet Fuel over a NiW/WO x Catalyst

    ACS Catalysis · 2026-02-04

    Xiaoru Wang, Xiaoru Wang, Zhanwu Lei, Jicong Yan, Penglong Wang, Ruifeng Chong, Fuping Tian, Tao Hu, Ruiguo Cao, Xiang Wang, Xiang Wang

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  25. Structure–performance relationships in heterogeneous catalysts for polyolefin plastic hydroconversion

    Applied Catalysis A General · 2026-03-09

    Haokun Wang, Frederick Z.T. Yang, Supatpong Juntarawatt, Yiyang Li, Roland C. Turnell‐Ritson

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  26. Ceria‐Based Catalysts for Sustainable Processing of Plastic Waste

    Advanced Energy and Sustainability Research · 2026-05-29

    Xinbang Wu, Paul J. Dyson

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  27. Advances in Catalytic Hydrogenolysis of Waste Plastics to Value-Added Products

    Industrial & Engineering Chemistry Research · 2026-06-08

    Xiaofan Zhou, Feng Xing Niu, Zeyuan Wu, Siji Wu, Ziqi Dong, Junyan Li, Da Chen

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  28. Co 1 /Ru Single‐Atom Alloy Catalyst for Sustainable Polypropylene Hydrogenolysis to Long‐Chain Liquid Products

    Advanced Materials · 2026-06-10

    Yuzhen Ge, Yimeng Jin, Alexandra Krestnikova, Sibei Zou, Antonio José Martín, Gonzalo Guillén‐Gosálbez, Javier Pérez‐Ramírez

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  29. A Mesopore-Confined and Graphene Oxide-Localized Ruthenium Catalyst Increases Rates of Mid-Chain Polyolefin Hydrogenolysis

    Journal of the American Chemical Society · 2026-06-26

    Kajol Tonk, Simin Sun, Olajide H. Bamidele, Minghui Niu, Xiaobing Zuo, Jessica V. Lamb, Arthur Jeremy Kropf, Massimiliano Delferro, Byeongdu Lee, Andreas Heyden, Wenyu Huang, Aaron David Sadow

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  30. Breaking the Yield‐Selectivity Trade‐Off in Polypropylene Upcycling via Ternary‐Active ZnAlO Nanocomposites

    ChemSusChem · 2026-09-20

    Guanyu Zhang, Liang Wang, Qiuhan Pu, Ru Sun, Qing Cheng, Yuan Jiang, Ge Kong, ZengJian Guo, Xuesong Zhang, Lujia Han

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  31. Efficient and Selective Low-Temperature Polypropylene Hydrogenolysis Using Zr-Doped Mixed Metal Oxides Catalysts

    ACS Catalysis · 2026-09-21

    Frederick Z.T. Yang, Haokun Wang, Roland C. Turnell‐Ritson, Dermot O’Hare

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