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RESEARCH PAPER · JACS Au · 2025

Ru-Catalyzed Polyethylene Hydrogenolysis under Quasi-Supercritical Conditions

Sung Min Kim, Boda Yang, Oliver Y. Gutiérrez, Wei Zhang, Carlos Lizandara‐Pueyo, Piyush Ingale, Ivana Jevtovikj, Reni Grauke, János Szanyi, Huamin Wang, Stephan A. Schunk, Johannes A. Lercher

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42 direct citing works

Ru-Catalyzed Polyethylene Hydrogenolysis under Quasi-Supercritical ConditionsOriginalHydrogenolysis of LDPE over Ni-catalyst promoted by n-hexane solvent7Polymer Upcycling by Catalytic Hydrogenolysis: The Role of Polyolefin Short-Chain Branching3On the role of hydrogen-deficient species during alkylamine hydrotreating on platinum catalysts1Advances of rare earth-based catalysts for recycling CO 2 and plastic waste17Intrinsically Bifunctional and Tunable Tungsten Carbide Catalysts Enable Efficient PVC-Compatible Polyolefin Hydrocracking8Catalytic valorization of polyolefins: from catalysts and processes to reactors0Efficient polyolefin upcycling to liquid fuels via Ru–zeolite physical mixtures and pathway control2Tandem hydropyrolysis–hydrogenolysis of polyolefin wastes over morphology‐tuned Co 3 O 4 for jet‐fuel hydrocarbons0Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production3Hydrogenolysis Versus Hydrocracking for Polyolefin Upcycling0One-pot co-upcycling of mixed polyolefin waste6Shape-Selective Conversion of High-Density Polyethylene into Benzene with Zeolite-Encapsulated Subnanometer Pt Catalysts6Techno-economic analysis and life cycle assessment for the catalytic hydrogenolysis and hydrocracking of polyethylene6Compressed CO 2 -Assisted Catalytic Hydrocracking of Polyethylene over Ru-Loaded Zeolites0Impact of Small-Alkane Solvents on Polyolefin Hydrogenolysis over a Ruthenium Catalyst0Hydrotreatment of Nylon 66 and Amide Model Compounds Over Sulfided NiMo Catalysts0Controlling Polyolefin Hydrogenolysis Selectivity by Engineering Single-Site Nickel(II) Hydride Active Catalytic Species0Extreme Nanoconfinement Dramatically Enhances Small Molecule Solubility in Nonpolar Polymers1Catalytic Hydrogenolysis of Polyethylene-Based Plastics into Fuels Using Ruthenium Catalysts Supported on Micro/Mesoporous Carbons0Reductive catalytic upcycling of polyethylene using 2-propanol as transfer hydrogen-donor source1Ambient‐Pressure Polyolefin Upcycling With Earth‐Abundant Catalyst0Ambient‐Pressure Polyolefin Upcycling With Earth‐Abundant Catalyst0Internal transport modulates catalytic hydrogenolysis of polyolefins0Highly active and selective heterogeneous Ru/La2O3-CeO2 catalyst for hydrogenolysis of LDPE to valuable chemicals0Homogeneous Ru/La2O2CO3 Catalyst for Efficient Thermal Cracking of Crosslinked Polyethylene0

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  1. Hydrogenolysis of LDPE over Ni-catalyst promoted by n-hexane solvent

    Journal of the Energy Institute · 2025-06-18

    Haifeng Xu, Cong Dong, Bingyan Sun, Kaige Wang, Bo Wang, Guanqun Luo

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  2. Polymer Upcycling by Catalytic Hydrogenolysis: The Role of Polyolefin Short-Chain Branching

    ACS Catalysis · 2025-09-23

    Zachary M. Gdowski, Rishi Raj, Aditya Bhan, K. Andre Mkhoyan, Mahesh K. Mahanthappa, Frank S. Bates

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  3. On the role of hydrogen-deficient species during alkylamine hydrotreating on platinum catalysts

    Journal of Catalysis · 2025-11-24

    Joakim Kattelus, Emma Verkama, Jorge A. Velasco, Reetta S. Karinen, Kari E. Laasonen, Riikka L. Puurunen

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  4. Advances of rare earth-based catalysts for recycling CO 2 and plastic waste

    Chemical Society Reviews · 2025-12-03

    Liangliang Zhang, Shuyan Song, Hongjie Zhang, Xiao Wang

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  5. Intrinsically Bifunctional and Tunable Tungsten Carbide Catalysts Enable Efficient PVC-Compatible Polyolefin Hydrocracking

    Journal of the American Chemical Society · 2025-12-17

    Uchenna C. Nwachukwu, Matthew J. Moegling, Sinhara M. H. D. Perera, Arsalaan Nisar Pathan, Jun Chen, Fereshteh Rezvani, Aswathi Rajeevan Vannante Valappil, Cong Zhou, Lamisa Rahman, Jian Liu, Sung Min Kim, James M. Eagan, Siddharth Deshpande, Marc D. Porosoff, Linxiao Chen

    Read original paper ↗ ·

  6. Catalytic valorization of polyolefins: from catalysts and processes to reactors

    Chemical Society Reviews · 2026-01-01

    Cuncun Wu, Chaojie Guo, Xinquan Xu, Kun Liu, Lu Bai, Nan Yang, Donglong Fu, Jinlong Gong

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  7. Efficient polyolefin upcycling to liquid fuels via Ru–zeolite physical mixtures and pathway control

    Chemical Engineering Journal · 2026-01-31

    Hyeongdong Jung, Junho Suh, Yong Hyun Lim, Hyungjoo Kim, Hyungjoo Kim, Inhak Song, Eunwon Lee, Jae‐Soon Choi, Jungup Bang, Do Heui Kim, Do Heui Kim

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  8. Tandem hydropyrolysis–hydrogenolysis of polyolefin wastes over morphology‐tuned Co 3 O 4 for jet‐fuel hydrocarbons

    AIChE Journal · 2026-02-05

    Dongxian Li, Xiaocao Shan, Xianzhi Meng, Jia Wang, Jianchun Jiang, Arthur J. Ragauskas

    Read original paper ↗ ·

  9. Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production

    Fuel · 2026-02-26

    Sudipta Nayak, Rajat Singhal, S. M. A. Hakim Siddiki, Ken Motokura, Navya Subray Bhat, Navneet Kumar Gupta

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  10. Hydrogenolysis Versus Hydrocracking for Polyolefin Upcycling

    Engineering · 2026-03-01

    Ruoxi Zhang, Aaron David Sadow, Wenyu Huang

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  11. One-pot co-upcycling of mixed polyolefin waste

    Nature Communications · 2026-03-02

    Weilin Tu, Mingyu Chu, Tianran Yan, Qingqing Zhang, Xianpeng Wang, Liang Zhang, Muhan Cao, Qiao Zhang, Mingshan Zhu, Minzhi Zhan, Jinxing Chen

    Read original paper ↗ ·

  12. Shape-Selective Conversion of High-Density Polyethylene into Benzene with Zeolite-Encapsulated Subnanometer Pt Catalysts

    Journal of the American Chemical Society · 2026-03-16

    Yunchao Feng, Hongtao Wang, Tianxiang Chen, Minghao Gao, Zhe He, Gaoqian Yuan, Lichen Liu

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  13. Techno-economic analysis and life cycle assessment for the catalytic hydrogenolysis and hydrocracking of polyethylene

    Joule · 2026-03-23

    Geetanjali Yadav, Taylor Uekert, Jason S. DesVeaux, Elisabeth Van Roijen, Julie E. Rorrer, Anna E. Brenner, Griffin Drake, Guido Zichittella, Nick Carlson, Yuriy Román‐Leshkov, Gregg T. Beckham

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  14. Compressed CO 2 -Assisted Catalytic Hydrocracking of Polyethylene over Ru-Loaded Zeolites

    ACS Sustainable Chemistry & Engineering · 2026-03-27

    Nicholas Gorschak, Lakshmiprasad Gurrala, Allison Tran, Samir Fernando Castilla-Acevedo, Diego Trevisan Melfi, Hashim A. Alzahrani, Van Son Nguyen, Aaron M. Scurto, Alan M. Allgeier, Juan J. Bravo-Suárez, Ana Rita C. Morais

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  15. Impact of Small-Alkane Solvents on Polyolefin Hydrogenolysis over a Ruthenium Catalyst

    Industrial & Engineering Chemistry Research · 2026-04-30

    Pavel A. Kots, Zachary R. Hinton, Mehdi Zare, Brandon C. Vance, María Ley-Flores, Juan Pablo, Thomas H. Epps, LaShanda T. J. Korley, Michele Valsecchi, George Jackson, Amparo Galindo, Dionisios G. Vlachos

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  16. Hydrotreatment of Nylon 66 and Amide Model Compounds Over Sulfided NiMo Catalysts

    ChemCatChem · 2026-05-01

    Boda Yang, Cheng Zhu, Oliver Y. Gutiérrez, Sungmin Kim, Huamin Wang

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  17. Controlling Polyolefin Hydrogenolysis Selectivity by Engineering Single-Site Nickel(II) Hydride Active Catalytic Species

    ACS Catalysis · 2026-06-08

    Bharti Rana, Manav Chauhan, Poorvi Gupta, A Rajendra Kumar, Chhaya Thadhani, Rahul Kalita, Kuntal Manna

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  18. Extreme Nanoconfinement Dramatically Enhances Small Molecule Solubility in Nonpolar Polymers

    ACS Nano · 2026-06-18

    Kaiwen Wang, Joseph Tapia, Tian Ren, Raymond J. Gorte, John M. Vohs, Peng Bai, Daeyeon Lee

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  19. Catalytic Hydrogenolysis of Polyethylene-Based Plastics into Fuels Using Ruthenium Catalysts Supported on Micro/Mesoporous Carbons

    Energy & Fuels · 2026-07-07

    Antigoni G. Margellou, Eleftherios Tosounidis, Kyriazis C. Rekos, Konstantinos S. Triantafyllidis

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  20. Reductive catalytic upcycling of polyethylene using 2-propanol as transfer hydrogen-donor source

    iScience · 2026-07-17

    Antonio Cosimo Pio Trimboli, Viviana Bressi, Emilia Paone, Riccardo Pellegrini, Paolo Lazzarini, Elena Groppo, Francesco Mauriello

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  21. Ambient‐Pressure Polyolefin Upcycling With Earth‐Abundant Catalyst

    Angewandte Chemie · 2026-09-07

    Qianyue Feng, Mingyu Chu, Zhongyu Li, Yeping Xie, Qiao Zhang, Jinxing Chen, Ding Ma

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  22. Ambient‐Pressure Polyolefin Upcycling With Earth‐Abundant Catalyst

    Angewandte Chemie International Edition · 2026-09-07

    Qianyue Feng, Mingyu Chu, Zhongyu Li, Yeping Xie, Qiao Zhang, Jinxing Chen, Ding Ma

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  23. Internal transport modulates catalytic hydrogenolysis of polyolefins

    Journal of Catalysis · 2026-09-17

    Preethi Venugopal, J. Will Medlin, Leon Lefferts, Jimmy Faria

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  24. Highly active and selective heterogeneous Ru/La2O3-CeO2 catalyst for hydrogenolysis of LDPE to valuable chemicals

    Chemical Engineering Journal · 2026-09-18

    Zichen Peng, S. M. A. Hakim Siddiki, Yusuke Kita, Pengru Chen, Masazumi Tamura

    Read original paper ↗ ·

  25. Homogeneous Ru/La2O2CO3 Catalyst for Efficient Thermal Cracking of Crosslinked Polyethylene

    Journal of Wuhan University of Technology-Mater Sci Ed · 2026-09-22

    Xiangyang Peng, Jiandong Wu, Zheng Wang, Lin Liu, Xin Yu, Hongfei Pan, Haining Zhang

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