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RESEARCH PAPER · Inorganic Chemistry · 2014

ReBe2B5O11 (Re = Y, Gd): Rare-Earth Beryllium Borates as Deep-Ultraviolet Nonlinear-Optical Materials

Xue Sheng Yan, Siyang Luo, Zheshuai Lin, Jiyong Yao, Ran He, Yinchao Yue, Chuangtian Chen

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ReBe2B5O11 (Re = Y, Gd): Rare-Earth Beryllium Borates as Deep-Ultraviolet Nonlinear-Optical MaterialsOriginalGrowth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency100K 3 MoPO 7 : the first molybdenum phosphate with edge-sharing MoO 6 octahedra and PO 4 tetrahedra10ChemInform Abstract: REBe2B5O11 (RE: Y, Gd): Rare‐Earth Beryllium Borates as Deep‐Ultraviolet Nonlinear‐Optical Materials.0First-principles materials applications and design of nonlinear optical crystals259PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates43Na4La2(CO3)5 and CsNa5Ca5(CO3)8: Two New Carbonates as UV Nonlinear Optical Materials65Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate ∞2[Be8B16O40F2] Layer Intrabridged by [B12O24] Groups20An non-centrosymmetric mononuclear Zr complex exhibiting UV second-harmonic-generation0Tunable Nonlinear Optical Property and Photocatalytic Activity on Luminescent Chiral Lanthanide Chains5Linear optical and thermo-physical properties of polar K3B6O10Cl crystal21RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material341Growth and Nonlinear Optical Properties of GdAl3(BO3)4 in a Flux without Molybdate21Syntheses and crystal structures of two new sodium borates [Na2(H2O)3][B5O8(OH)2] and Na[enH2][B7O10(OH)4]2A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F)3 Groups49Be2BO3F: A Phase of Beryllium Fluoride Borate Derived from KBe2BO3F2 with Short UV Absorption Edge46Deep Ultraviolet Nonlinear Optical Materials644Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials259ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges17Syntheses, crystal structures and characterization of three alkaline metal borates7Structural Modulation of Nitrate Group with Cations to Affect SHG Responses in RE(OH)2NO3 (RE = La, Y, and Gd): New Polar Materials with Large NLO Effect after Adjusting pH Values of Reaction Systems151Facile Syntheses of Ba2[B4O7(OH)2] and Na[B5O7(OH)2](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet50Beryllium‐Free β‐Rb2Al2B2O7 as a Possible Deep‐Ultraviolet Nonlinear Optical Material Replacement for KBe2BO3F2184Beryllium‐Free β‐Rb2Al2B2O7 as a Possible Deep‐Ultraviolet Nonlinear Optical Material Replacement for KBe2BO3F278Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals58Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257Flux growth and optical properties of K7CaY2(B5O10)3 nonlinear crystal28Removal of A-Site Alkali and Alkaline Earth Metal Cations in KBe2BO3F2-Type Layered Structures To Enhance the Deep-Ultraviolet Nonlinear Optical Capability46Synthesis, characterization and rare earth elements adsorption properties of phosphonate metal organic frameworks29Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials37High magneto-optical performance of GdFeO3 thin film with high orientation and heavy Ce3+ doping18Synthesis, structure, and third-harmonic generation measurements of a mixed alkali metal iodate, KLi2(IO3)323A new non-centrosymmetric Gd-based borate crystal Rb 7 SrGd 2 (B 5 O 10 ) 3 : growth, structure, and nonlinear optical and magnetic properties24Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles146Deep-ultraviolet nonlinear optical crystals by design: A computer-aided modeling blueprint from first principles45Borates: A Rich Source for Optical Materials1089Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials41Facile synthesis of a sandwiched Ti3C2Tx MXene/nZVI/fungal hypha nanofiber hybrid membrane for enhanced removal of Be(II) from Be(NH) complexing solutions97Recent advances in nonlinear optical rare earth structures63A Review on Optical Applications, Prospects, and Challenges of Rare-Earth Oxides216An Overview on Recent Trends in Deep‐Ultraviolet (DUV) and Ultraviolet (UV) Nonlinear Optical Crystals25Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window62Phonon structure engineering for intrinsically spectrally selective emitters by anion groups0Data Mining and Graph Network Deep Learning for Band Gap Prediction in Crystalline Borate Materials18The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates8Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Magnesiothermic reduction of beryllium fluoride: Reaction mechanism and kinetic study13Phonon Structure Engineering for Intrinsically Spectrally Selective Emitters by Anion Groups0Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation1

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  1. Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency

    CrystEngComm · 2014-01-01

    Tongqing Sun, Pai Shan, Hong Chen, Xuanwen Liu, Hongde Liu, Shaolin Chen, Yaan Cao, Yongfa Kong, Jingjun Xu

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  2. K 3 MoPO 7 : the first molybdenum phosphate with edge-sharing MoO 6 octahedra and PO 4 tetrahedra

    RSC Advances · 2014-01-01

    Siyang Luo, Lei Kang, Zheshuai Lin, Chuangtian Chen

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  3. ChemInform Abstract: REBe2B5O11 (RE: Y, Gd): Rare‐Earth Beryllium Borates as Deep‐Ultraviolet Nonlinear‐Optical Materials.

    ChemInform · 2014-04-03

    Xue Sheng Yan, Siyang Luo, Zheshuai Lin, Jiyong Yao, Ran He, Yinchao Yue, Chuangtian Chen

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  4. First-principles materials applications and design of nonlinear optical crystals

    Journal of Physics D Applied Physics · 2014-05-23

    Zheshuai Lin, Xingxing Jiang, Lei Kang, Pifu Gong, Siyang Luo, Ming‐Hsien Lee

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  5. PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates

    CrystEngComm · 2014-06-12

    Yucheng Hao, Xiang Xu, Fang Kong, Jun‐Ling Song, Jiang‐Gao Mao

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  6. Na4La2(CO3)5 and CsNa5Ca5(CO3)8: Two New Carbonates as UV Nonlinear Optical Materials

    Inorganic Chemistry · 2014-07-16

    Min Luo, Genxiang Wang, Chensheng Lin, Ning Ye, Yuqiao Zhou, Wendan Cheng

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  7. Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate ∞2[Be8B16O40F2] Layer Intrabridged by [B12O24] Groups

    Inorganic Chemistry · 2014-08-01

    Siyang Luo, Wenjiao Yao, Pifu Gong, Jiyong Yao, Zheshuai Lin, Chuangtian Chen

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  8. An non-centrosymmetric mononuclear Zr complex exhibiting UV second-harmonic-generation

    Functional Materials Letters · 2014-12-01

    Cai-Yun Han, Mei Qu, Qin-Qin Dang, Xian‐Ming Zhang

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  9. Tunable Nonlinear Optical Property and Photocatalytic Activity on Luminescent Chiral Lanthanide Chains

    Chinese Journal of Chemistry · 2014-12-01

    Mei Qu, Minmin Liu, Jiang Liu, Xian‐Ming Zhang

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  10. Linear optical and thermo-physical properties of polar K3B6O10Cl crystal

    Journal of Materiomics · 2015-07-14

    Hongping Wu, Hongwei Yu, Zhihua Yang, Jian Wei Han, Kui Wu, Shilie Pan

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  11. RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material

    Journal of the American Chemical Society · 2015-08-10

    T. Thao Tran, Jiangang He, James M. Rondinelli, P. Shiv Halasyamani

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  12. Growth and Nonlinear Optical Properties of GdAl3(BO3)4 in a Flux without Molybdate

    Crystal Growth & Design · 2015-12-09

    Yinchao Yue, Yangyang Zhu, Ying Zhao, Heng Tu, Zhanggui Hu

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  13. Syntheses and crystal structures of two new sodium borates [Na2(H2O)3][B5O8(OH)2] and Na[enH2][B7O10(OH)4]

    Zeitschrift für Naturforschung B · 2015-12-11

    Yanjing Wang, Ai‐Quan Jia, Xing‐Shun Chen, Hua‐Tian Shi, Qian‐Feng Zhang

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  14. A Deep-Ultraviolet Nonlinear Optical Crystal: Strontium Beryllium Borate Fluoride with Planar Be(O/F)3 Groups

    Chemistry of Materials · 2016-06-02

    Na Yu, Shichao Wang, Ning Ye, Fei Liang, Zheshuai Lin, Min Luo, Kenneth Reinhard Poeppelmeier

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  15. Be2BO3F: A Phase of Beryllium Fluoride Borate Derived from KBe2BO3F2 with Short UV Absorption Edge

    Inorganic Chemistry · 2016-06-22

    Shu Hai Guo, Lijuan Liu, Mingjun Xia, Lei Kang, Qian Huang, Chao Li, Xiaoyang Wang, Zheshuai Lin, Chuangtian Chen

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  16. Deep Ultraviolet Nonlinear Optical Materials

    Chemistry of Materials · 2016-07-12

    T. Thao Tran, Hongwei Yu, James M. Rondinelli, Kenneth Reinhard Poeppelmeier, P. Shiv Halasyamani

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  17. Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials

    Journal of the American Chemical Society · 2016-12-24

    T. Thao Tran, Joshua Young, James M. Rondinelli, P. Shiv Halasyamani

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  18. ScMO(BO 3 ) (M = Ca and Cd): new Sc-based oxyborates featuring interesting edge-sharing sandwich-like chains and UV cut-off edges

    Dalton Transactions · 2017-01-01

    Ruru Ma, Dongdong Xu, Yun Mo Yang, Xin Su, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  19. Syntheses, crystal structures and characterization of three alkaline metal borates

    CrystEngComm · 2017-01-01

    Sambasivam Sangaraju, Lili Liu, Yun Mo Yang, Guopeng Han, Beenish Bashir, Zhihua Yang, Shilie Pan

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  20. Structural Modulation of Nitrate Group with Cations to Affect SHG Responses in RE(OH)2NO3 (RE = La, Y, and Gd): New Polar Materials with Large NLO Effect after Adjusting pH Values of Reaction Systems

    Chemistry of Materials · 2017-01-04

    Yunxia Song, Min Luo, Chensheng Lin, Ning Ye

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  21. Facile Syntheses of Ba2[B4O7(OH)2] and Na[B5O7(OH)2](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet

    Inorganic Chemistry · 2017-01-11

    Chao Wu, Longhua Li, Jun‐Ling Song, Gang Yang, Mark Graeme Humphrey, Chi Zhang

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  22. Beryllium‐Free β‐Rb2Al2B2O7 as a Possible Deep‐Ultraviolet Nonlinear Optical Material Replacement for KBe2BO3F2

    Angewandte Chemie International Edition · 2017-01-31

    T. Thao Tran, Nathan Z. Koocher, James M. Rondinelli, P. Shiv Halasyamani

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  23. Beryllium‐Free β‐Rb2Al2B2O7 as a Possible Deep‐Ultraviolet Nonlinear Optical Material Replacement for KBe2BO3F2

    Angewandte Chemie · 2017-02-01

    T. Thao Tran, Nathan Z. Koocher, James M. Rondinelli, P. Shiv Halasyamani

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  24. Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals

    Crystals · 2017-03-25

    Yi Jin Yang, Xingxing Jiang, Zheshuai Lin, Yicheng Wu

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  25. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

    Coordination Chemistry Reviews · 2018-03-15

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  26. Flux growth and optical properties of K7CaY2(B5O10)3 nonlinear crystal

    Materials Research Bulletin · 2018-07-30

    Artem B. Kuznetsov, Dmitry M. Ezhov, К. А. Кох, Nadezda G. Kononova, Vyacheslav S. Shevchenko, Sergey V. Rashchenko, Efim V. Pestryakov, В. А. Светличный, Лапин Иван Николаевич, Alexander E. Kokh

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  27. Removal of A-Site Alkali and Alkaline Earth Metal Cations in KBe2BO3F2-Type Layered Structures To Enhance the Deep-Ultraviolet Nonlinear Optical Capability

    Inorganic Chemistry · 2018-08-15

    Lei Kang, Zheshuai Lin, Feng Liu, Bing Qiang Huang

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  28. Synthesis, characterization and rare earth elements adsorption properties of phosphonate metal organic frameworks

    Applied Surface Science · 2019-03-07

    Bianca Maranescu, Lavinia Lupa, Aurelia Visa

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  29. Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials

    Chemistry of Materials · 2019-03-12

    Liling Cao, Yunxia Song, Guang Peng, Min Luo, Yi Jin Yang, Chensheng Lin, Dan Zhao, Feng Xu, Zheshuai Lin, Ning Ye

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  30. High magneto-optical performance of GdFeO3 thin film with high orientation and heavy Ce3+ doping

    Ceramics International · 2019-05-02

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  31. Synthesis, structure, and third-harmonic generation measurements of a mixed alkali metal iodate, KLi2(IO3)3

    Journal of Solid State Chemistry · 2019-12-10

    Hongil Jo, Hyung Gu Kim, Hye Ryung Byun, Joon Ik Jang, Kang Min Ok

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  32. A new non-centrosymmetric Gd-based borate crystal Rb 7 SrGd 2 (B 5 O 10 ) 3 : growth, structure, and nonlinear optical and magnetic properties

    Dalton Transactions · 2020-01-01

    Wang Liu, Xiaomeng Liu, Jun Shen, Yunfei Li, Huimin Song, Jingcheng Feng, Zheshuai Lin, Guochun Zhang

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  33. Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles

    Coordination Chemistry Reviews · 2020-01-10

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  34. Deep-ultraviolet nonlinear optical crystals by design: A computer-aided modeling blueprint from first principles

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  35. Borates: A Rich Source for Optical Materials

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  36. Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials

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  37. Facile synthesis of a sandwiched Ti3C2Tx MXene/nZVI/fungal hypha nanofiber hybrid membrane for enhanced removal of Be(II) from Be(NH) complexing solutions

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  38. Recent advances in nonlinear optical rare earth structures

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  39. A Review on Optical Applications, Prospects, and Challenges of Rare-Earth Oxides

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  40. An Overview on Recent Trends in Deep‐Ultraviolet (DUV) and Ultraviolet (UV) Nonlinear Optical Crystals

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  41. Rb5Ba2(B10O17)2(BO2): The formation of unusual functional [BO2]− in borates with deep-ultraviolet transmission window

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  42. Phonon structure engineering for intrinsically spectrally selective emitters by anion groups

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  43. Data Mining and Graph Network Deep Learning for Band Gap Prediction in Crystalline Borate Materials

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  44. The local state of hydrogen atoms and proton transfer in the crystal structure of natural berborite, Be2(BO3)(OH)‧H2O: Low-temperature single crystal X-ray analysis, IR and 1H NMR spectroscopy, and crystal chemistry and structural complexity of beryllium borates

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  45. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

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  46. Magnesiothermic reduction of beryllium fluoride: Reaction mechanism and kinetic study

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  48. Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates

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  49. Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency

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