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RESEARCH PAPER · Coordination Chemistry Reviews · 2015

Recent advances on second-order NLO materials based on metal iodates

Chun‐Li Hu, Jiang‐Gao Mao

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Recent advances on second-order NLO materials based on metal iodatesOriginalStructures, Thermal Behaviors, and Luminescent Properties of Anhydrous Lanthanum Iodate Polymorphs26Preparation, nonlinear optical properties, and theoretical analysis of the non-centrosymmetric bismuth oxyfluoride, Bi 7 F 11 O 525Oxychalcogenide BaGeOSe2: Highly Distorted Mixed-Anion Building Units Leading to a Large Second-Harmonic Generation Response96Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340Na 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands12Role of the metal cation types around VO 4 groups on the nonlinear optical behavior of materials: experimental and theoretical analysis19Synthesis, crystal structure and second-order nonlinear optical property of a novel pentanary selenide (K 3 I)[InB 12 (InSe 4 ) 3 ]48K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units18KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate7RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold124New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies25Two new hetero-dinuclear nickel(II)/zinc(II) complexes with compartmental Schiff bases: Synthesis, characterization and self assembly55Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels109BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution207Emerging Multifunctional Metal–Organic Framework Materials1587A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS725Differences and Similarities between Lanthanum and Rare-Earth Iodate Anhydrous Polymorphs: Structures, Thermal Behaviors, and Luminescent Properties12A two-dimensional metal-organic framework composed of paddle-wheel cobalt clusters with permanent porosity11Recent achievements on middle and far-infrared second-order nonlinear optical materials433A second-order nonlinear optical material with a 5-fold interpenetrating diamondoid framework based on two achiral precursors: spontaneous resolution to absolute chiral induction29Estimation of conventional C–H⋯π (arene), unconventional C–H⋯π (chelate) and C–H⋯π (thiocyanate) interactions in hetero-nuclear nickel( ii )–cadmium( ii ) complexes with a compartmental Schiff base72M 3 V 2 B 10 O 23 (M = Ca, Sr): two new vanadoborates with [V 2 B 10 O 23 ] ∞ double layers11Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds8Role of spin–orbit interaction on the nonlinear optical response of CsPbCO 3 F using DFT35The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances104Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 639Iodide-Iodates M3[IO3]12·Ag4I, M = Bi, Tb, with a Framework Structure and High Second-Harmonic Generation Optical Response19Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response121Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba 4 B 11 O 20 F42New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )12Controlled release of drug molecules in metal–organic framework material HKUST-183Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)32Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials5Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties17Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se137Hg-Based Infrared Nonlinear Optical Material KHg4Ga5Se12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response101A series of porous metal–organic frameworks with hendecahedron cage: Structural variation and drug slow release properties13Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations12Crystal Structure of Electroceramics0Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg 2 GeS 4 and BaAg 2 SnS 468Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation26Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance30NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers8Oxyhalides: prospecting ore for optical functional materials with large laser damage thresholds76Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures25Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13Synthesis, Crystal Structure, and Topology–Symmetry Analysis of a New Modification of NaIn[IO3]44The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies29Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System90Bi 2 (IO 3 )(IO 6 ): First combination of [IO 3 ] − and [IO 6 ] 5− anions in three-dimensional framework9Li7Cd4.5Ge4Se16 and Li6.4Cd4.8Sn4Se16: Strong Nonlinear Optical Response in Quaternary Diamond‐Like Selenide Networks10Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials237Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials24A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials71Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257Synergetic Influence of Alkali-Metal and Lone-Pair Cations on Frameworks of Tellurites15Synthesis and characterization of three hetero-dinuclear complexes with CuO 2 M cores (M = Na, Hg): Exploration of their phenoxazinone synthase mimicking activity24Strong SHG Response via High Orientation of Tetrahedral Functional Motifs in Polyselenide A2Ge4Se10 (A = Rb, Cs)31Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates BiMTeO6 (M = Al, Ga)21Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Second-order nonlinear optical crystals with mixed anions250Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold59PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units52Synthesis and Crystal Structure of New Indium Iodate (K0.6Na0.4Ba)In[IO3]64A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances252Excellent Infrared Nonlinear Optical Crystals BaMO(IO3)5 (M = V, Ta) Predicted by First Principle Calculations9Recent advances and future perspectives on infrared nonlinear optical metal halides223Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23(H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer19A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials78A pair of homochiral trinuclear Zn( ii ) clusters exhibiting unusual ferroelectric behaviour at high temperature7ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences50Adjustable optical nonlinearity in d 10 cations containing chalcogenides via dp hybridization interaction13Formation of a tetranuclear supramolecule via non-covalent Pb⋯Cl tetrel bonding interaction in a hemidirected lead( ii ) complex with a nickel( ii ) containing metaloligand38Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 41KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer18Li 2 ZnGeS 4 : a promising diamond-like infrared nonlinear optical material with high laser damage threshold and outstanding second-harmonic generation response43LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution68Lone pair effects on ternary infrared nonlinear optical materials19Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence34Synthesis and nonlinear optical properties of new gallium thiophosphate Rb 2 Ga 2 P 2 S 913Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 1217Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds16BaV2O6·H2O: A nonlinear optical crystal with a large bandgap7Broadening Frontiers of Infrared Nonlinear Optical Materials with π-Conjugated Trigonal-Planar Groups67A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design114A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design25TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)9Bioactive Hetero Bimetallic Ni(II)/Zn(II) Complexes with Compartmental Schiff Bases and Triphenylphosphine as Co-Ligand: Synthesis, Characterization and Thermal Decomposition1HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49Structure–Property Correlation Studies of Potassium 4,4′-Bis(dinitromethyl)-3,3′-azofurazanate: A Noncentrosymmetric Primary Explosive14Shedding Light on the Intrinsic Characteristics of 3D Distorted Fluorite-Type Zirconium Tellurite Single Crystals12Density Functional Theory Investigations of the Optoelectronic Properties of Li2MnGeS4 and Li2CoSnS41KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active44Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Synthesis and Crystal Structure of a New Iodate (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 Analogous to Sr[IO3]22Two Indium Sulfate Tellurites: Centrosymmetric In 2 (SO 4 )(TeO 3 )(OH) 2 (H 2 O) and Non-centrosymmetric In 3 (SO 4 )(TeO 3 ) 2 F 3 (H 2 O)33Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6SrI3O9H: A new alkaline earth metal iodate with two different anionic units using mild aqua-solution method8Synthesis, Characterization, and Crystal Structure Determination of a New Lithium Zinc Iodate Polymorph LiZn(IO3)320Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides63Nonlinear Optical Crystals for Second Harmonic Generation19A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups53K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold114(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior92(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior11A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals48Rational design of infrared nonlinear optical chalcogenides by chemical substitution287A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates7Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material20Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr 6 A 4 M 4 S 16 (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials28Evidence of reaction intermediates in microwave-assisted synthesis of SHG active α-La(IO 3 ) 3 nanocrystals4Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance17Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture33KNiB4O6F3: A Layered Fluorooxoborate with Charge‐Oriented Ordering18Drug delivery by micro and meso metal-organic frameworks33Key Factors Controlling the Large Second Harmonic Generation in Nonlinear Optical Materials37CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)218Quaternary rare-earth sulfide LaSnGa3S7: Synthesis, structure, thermal and optical properties5(Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template38Synthesis, Crystal Structure, and Optical Properties of the First Alkali Metal Rare-Earth Iodate Fluoride: Li2Ce(IO3)4F222ZnIO3F: Zinc Iodate Fluoride with Large Birefringence and Wide Band Gap57Hexagonal In2Se3: A Defect Wurtzite-Type Infrared Nonlinear Optical Material with Moderate Birefringence Contributed by Unique InSe5 Unit75K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46Aliovalent-substituted synthesis for a non-centrosymmetric phosphate with enhanced nonlinear-optical response5KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19Synthesis and Crystal Structure of New Iodate Na3Fe[IO3]6 of the A3M[IO3]6 Structural Family (A = Na, K, Rb, Cs, Tl; M = Ti, Fe, Ge, In, Pt)5BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution19Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence24A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107New Alkaline-Earth Metal Fluoroiodates Exhibiting Large Birefringence and Short Ultraviolet Cutoff Edge with Highly Polarizable (IO 3 F) 2– Units63Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides113Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50High-Pressure Raman Study of Fe(IO3)3: Soft-Mode Behavior Driven by Coordination Changes of Iodine Atoms34Hierarchical Contribution of Anions to Second Harmonic Generation in A2HgI4 (A = Na, Ag, Cu) Regulated Dramatically by Metal Cations4Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm38From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution11AMnAs3S6 (A = Cs, Rb): Phase-Matchable Infrared Nonlinear Optical Functional Motif [As3S6]3– Obtained via Surfactant–Thermal Method32

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  1. Structures, Thermal Behaviors, and Luminescent Properties of Anhydrous Lanthanum Iodate Polymorphs

    Inorganic Chemistry · 2015-03-19

    Mohamed B. Taouti, Yan Suffren, Olivier Leynaud, Djamal Benbertal, A. Brenier, Isabelle Gautier‐Luneau

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  2. Preparation, nonlinear optical properties, and theoretical analysis of the non-centrosymmetric bismuth oxyfluoride, Bi 7 F 11 O 5

    Journal of Alloys and Compounds · 2015-11-06

    Wei Hu, Pai Shan, Tongqing Sun, Hongde Liu, Jianming Zhang, Xuanwen Liu, Yongfa Kong, Jingjun Xu

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  3. Oxychalcogenide BaGeOSe2: Highly Distorted Mixed-Anion Building Units Leading to a Large Second-Harmonic Generation Response

    Chemistry of Materials · 2015-11-25

    Bin‐Wen Liu, Xiao‐Ming Jiang, Guan‐E Wang, Hui‐Yi Zeng, Mingjian Zhang, Shu‐Fang Li, Wei‐Huan Guo, Guo‐Cong Guo

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  4. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

    Ying Wang, Shilie Pan

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  5. Na 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands

    RSC Advances · 2016-01-01

    Xiaowen Wu, Yi Hu, Hui Pan, Zhi Su

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  6. Role of the metal cation types around VO 4 groups on the nonlinear optical behavior of materials: experimental and theoretical analysis

    Dalton Transactions · 2016-01-01

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  7. Synthesis, crystal structure and second-order nonlinear optical property of a novel pentanary selenide (K 3 I)[InB 12 (InSe 4 ) 3 ]

    Dalton Transactions · 2016-01-01

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  8. K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units

    Chemistry - A European Journal · 2016-01-07

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  9. KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate

    Inorganic Chemistry Communications · 2016-01-11

    Guo-Xiang He, Yi-gang Chen, Nan Qing Yang, Meiling Xing, Xian‐Ming Zhang

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  10. RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold

    Chemistry of Materials · 2016-02-02

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  11. New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)

    Inorganic Chemistry · 2016-02-05

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  12. NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies

    The Journal of Physical Chemistry C · 2016-02-16

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  13. Two new hetero-dinuclear nickel(II)/zinc(II) complexes with compartmental Schiff bases: Synthesis, characterization and self assembly

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  14. Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels

    Chemistry - A European Journal · 2016-06-01

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  15. BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution

    Journal of the American Chemical Society · 2016-07-18

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  16. Emerging Multifunctional Metal–Organic Framework Materials

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    Bin Li, Hui‐Min Wen, Yuanjing Cui, Wei Zhou, Guodong Qian, Banglin Chen

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  17. A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS7

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  18. Differences and Similarities between Lanthanum and Rare-Earth Iodate Anhydrous Polymorphs: Structures, Thermal Behaviors, and Luminescent Properties

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  19. A two-dimensional metal-organic framework composed of paddle-wheel cobalt clusters with permanent porosity

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  20. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

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  21. A second-order nonlinear optical material with a 5-fold interpenetrating diamondoid framework based on two achiral precursors: spontaneous resolution to absolute chiral induction

    Dalton Transactions · 2017-01-01

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  22. Estimation of conventional C–H⋯π (arene), unconventional C–H⋯π (chelate) and C–H⋯π (thiocyanate) interactions in hetero-nuclear nickel( ii )–cadmium( ii ) complexes with a compartmental Schiff base

    Dalton Transactions · 2017-01-01

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  23. M 3 V 2 B 10 O 23 (M = Ca, Sr): two new vanadoborates with [V 2 B 10 O 23 ] ∞ double layers

    New Journal of Chemistry · 2017-01-01

    Zhaohui Chen, Yaqin Liu, Yunjing Shi, Wenyao Zhang, Qun Jing, Yuan Fang, Xiaoyu Dong

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  24. Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds

    Dalton Transactions · 2017-01-01

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  25. Role of spin–orbit interaction on the nonlinear optical response of CsPbCO 3 F using DFT

    Physical Chemistry Chemical Physics · 2017-01-01

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  26. The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances

    Chemical Communications · 2017-01-01

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  27. Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 6

    Dalton Transactions · 2017-01-01

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  28. Iodide-Iodates M3[IO3]12·Ag4I, M = Bi, Tb, with a Framework Structure and High Second-Harmonic Generation Optical Response

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  29. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

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  30. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie · 2017-01-16

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  31. Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response

    Chemistry of Materials · 2017-01-23

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  32. Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba 4 B 11 O 20 F

    Crystal Growth & Design · 2017-01-26

    Hongping Wu, Hongwei Yu, Weiguo Zhang, Jacqueline Cantwell, Kenneth Reinhard Poeppelmeier, Shilie Pan, P. Shiv Halasyamani

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  33. New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )

    Journal of Solid State Chemistry · 2017-02-16

    Mingli Liang, Matthew L. Marsh, Xian-Xing Shang, Jiang‐Gao Mao, Thomas E. Albrecht‐Schmitt, Fang Kong

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  34. Controlled release of drug molecules in metal–organic framework material HKUST-1

    Inorganic Chemistry Communications · 2017-03-27

    Qing Chen, Qiwei Chen, Qiwei Chen, Qiwei Chen, Chong Zhuang, Piaoping Tang, Ning Lin, Lian-Qiang Wei

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  35. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion

    Crystals · 2017-04-12

    Kui Wu, Shilie Pan

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  36. Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)

    Inorganic Chemistry · 2017-06-01

    Seung‐Jin Oh, Hyung-Gu Kim, Hongil Jo, Tae Gil Lim, Jae Soo Yoo, Kang Min Ok

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  37. Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials

    Inorganic Chemistry · 2017-06-02

    Bing‐Ping Yang, Chun‐Li Hu, Fei‐Fei Mao, Xiang Xu, Jiang‐Gao Mao

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  38. Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties

    Inorganic Chemistry · 2017-06-23

    Molin Zhou, Xingxing Jiang, Yangwu Guo, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  39. Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13

    Journal of Solid State Chemistry · 2017-08-16

    Ailijiang Abudurusuli, Hanqin Ding, Kui Wu

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  40. Hg-Based Infrared Nonlinear Optical Material KHg4Ga5Se12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response

    Chemistry of Materials · 2017-08-29

    Molin Zhou, Yi Jin Yang, Yangwu Guo, Zheshuai Lin, Jiyong Yao, Yicheng Wu, Chuangtian Chen

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  41. A series of porous metal–organic frameworks with hendecahedron cage: Structural variation and drug slow release properties

    Journal of Solid State Chemistry · 2017-09-22

    Lian-Qiang Wei, Yue Li, Liyuan Mao, Qing Chen, Ning Lin

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  42. Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion

    Inorganic Chemistry · 2017-11-09

    Fei‐Fei Mao, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  43. Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations

    Chinese Journal of Chemistry · 2017-11-17

    Fang Kong, Yun‐Xiang Ma, Jiang‐Gao Mao

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  44. Crystal Structure of Electroceramics

    MDPI eBooks · 2017-11-20

    Pramana, Stevin

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  45. Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg 2 GeS 4 and BaAg 2 SnS 4

    Dalton Transactions · 2017-11-27

    Hong Chen, Pei-Fei Liu, Bingxuan Li, Hua Lin, Li‐Ming Wu, Xin‐Tao Wu

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  46. Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation

    New Journal of Chemistry · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Shilie Pan

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  47. Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance

    Dalton Transactions · 2018-01-01

    Zhuang Li, Shengzi Zhang, Wenlong Yin, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  48. NaBaM III Q 3 (M III = Al, Ga; Q = S, Se): first quaternary chalcogenides with isolated edge-sharing (MIII2Q 6 ) 6− dimers

    Dalton Transactions · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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  49. Oxyhalides: prospecting ore for optical functional materials with large laser damage thresholds

    Journal of Materials Chemistry C · 2018-01-01

    Zhihua Yang, Cong Hu, Miriding Mutailipu, Yanzhou Sun, Kui Wu, Min Zhang, Shilie Pan

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  50. Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures

    Chemical Communications · 2018-01-01

    Kui Wu, Bingbing Zhang, Zhihua Yang, Shilie Pan

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