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RESEARCH PAPER · Angewandte Chemie · 2015

A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular Units

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A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular UnitsOriginalCrystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE 3 S 3 BO 3 (RE = Sm, Gd)18Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na 3 NH 4 (TiF 6 )(SO 4 )·H 2 O6Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels109Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation381Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2113Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)220Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth892Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth99Na2(H2en)[B5O8(OH)]2[B3O4(OH)]2 and Na3(HCOO)[B5O8(OH)]: Two Borates Co‐Templated by Inorganic Cations and Organic Compounds20Rb 3 VO(O 2 ) 2 CO 3 : A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response207Rb3VO(O2)2CO3: A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response42Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23Prediction of Fluorooxoborates with Colossal Second Harmonic Generation (SHG) Coefficients and Extremely Wide Band Gaps: Towards Modulating Properties by Tuning the BO 3 /BO 3 F Ratio in Layers99Prediction of Fluorooxoborates with Colossal Second Harmonic Generation (SHG) Coefficients and Extremely Wide Band Gaps: Towards Modulating Properties by Tuning the BO3/BO3F Ratio in Layers24Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn5(BO3)3OH3Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra73Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra18CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22Two Covalent Ultraviolet Nonlinear Optical Crystals3Synthesis, Crystal Structure, and Characterization of a Noncentrosymmetric Sulfate Cs2Ca2(SO4)320Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm38Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )212Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )57New Polymorphism for Ba3Zn2(BO3)3F with Two Polymorphs Exhibiting Anomalous Phase Transition2M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures20Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response130Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response8Das erste Hochdruck‐Chromoxonitridoborat CrB4O6N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate0The First High‐Pressure Chromium Oxonitridoborate CrB 4 O 6 N—an Unexpected Link to Nitridosilicate Chemistry13Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units102Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units9High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence21High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence199Explorations of New SHG Materials in Mercury Iodate Sulfate System**9Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups78Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups7Enhanced Interlayer Interaction and Second-Harmonic-Generation Response in a KBe 2 BO 3 F 2 -Type Inorganic–Organic Hybrid Zinc Borate33Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal19An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles32Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence10The Birefringence Modulation in Short‐Wave Ultraviolet Sulfates with Functional π‐Conjugated Cations and Polymerized Heteroleptic Tetrahedral Anions18[C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence13A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9M 3 MoO 4 (HCO 3 ) (M = Rb and Cs): cation-tuned synthesis of two noncentrosymmetric molybdate-carbonates with isolated [MoO 4 ] and [HCO 3 ] groups0Lithium Borate-Squarate: An Organic–Inorganic Groups-Mixed Nonlinear Optical Crystal with Large Birefringence4Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br10Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units0LiHgTeO 3 : a Hg( i )-containing tellurite crystal with typical Hg–Hg bonds0Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties1Reverse Weak Polarity‐Induced Ordered Layer Control for Enhanced Second‐Harmonic Generation in Ultraviolet Nonlinear Optical Crystals2Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal0

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  1. Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE 3 S 3 BO 3 (RE = Sm, Gd)

    New Journal of Chemistry · 2016-01-01

    Yang Chi, Sheng‐Ping Guo, Hong-Jian Kong, Huaiguo Xue

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  2. Hydrogen bond-assisted crystallization: structure, growth and characterization of a new mixed-anion transition metal fluoride Na 3 NH 4 (TiF 6 )(SO 4 )·H 2 O

    New Journal of Chemistry · 2016-01-01

    Dongdong Xu, Fangfang Zhang, Yanzhou Sun, Zhihua Yang, Xiaoyu Dong, Shilie Pan

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  3. Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels

    Chemistry - A European Journal · 2016-06-01

    Qi Wei, Jiajia Wang, Chao He, Jian‐Wen Cheng, Guo‐Yu Yang

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  4. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

    Angewandte Chemie International Edition · 2016-08-24

    Guohong Zou, Chensheng Lin, Hongil Jo, Gnu Nam, Tae‐Soo You, Kang Min Ok

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  5. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

    Angewandte Chemie · 2016-08-24

    Guohong Zou, Chensheng Lin, Hongil Jo, Gnu Nam, Tae‐Soo You, Kang Min Ok

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  6. Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2

    Angewandte Chemie International Edition · 2016-11-30

    Sangen Zhao, Yi Jin Yang, Yaoguo Shen, Bingqing Zhao, Lina Li, Chengmin Ji, Zhenyue Wu, Daqiang Yuan, Zheshuai Lin, Maochun Hong, Junhua Luo

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  7. Cooperation of Three Chromophores Generates the Water‐Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2

    Angewandte Chemie · 2016-11-30

    Sangen Zhao, Yi Jin Yang, Yaoguo Shen, Bingqing Zhao, Lina Li, Chengmin Ji, Zhenyue Wu, Daqiang Yuan, Zheshuai Lin, Maochun Hong, Junhua Luo

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  8. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie International Edition · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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  9. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

    Angewandte Chemie · 2017-01-16

    Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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  10. Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth

    Angewandte Chemie International Edition · 2017-03-02

    Bingbing Zhang, Guoqiang Q. Shi, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  11. Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth

    Angewandte Chemie · 2017-03-02

    Bingbing Zhang, Guoqiang Q. Shi, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  12. Na2(H2en)[B5O8(OH)]2[B3O4(OH)]2 and Na3(HCOO)[B5O8(OH)]: Two Borates Co‐Templated by Inorganic Cations and Organic Compounds

    European Journal of Inorganic Chemistry · 2017-07-20

    Qi Wei, Chao He, Li Quan Sun, Xing‐Tao An, Jie Zhang, Guo‐Yu Yang

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  13. Rb 3 VO(O 2 ) 2 CO 3 : A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response

    Angewandte Chemie International Edition · 2018-05-15

    Guohong Zou, Hongil Jo, Seong‐Ji Lim, Tae‐Soo You, Kang Min Ok

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  14. Rb3VO(O2)2CO3: A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response

    Angewandte Chemie · 2018-05-15

    Guohong Zou, Hongil Jo, Seong‐Ji Lim, Tae‐Soo You, Kang Min Ok

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  15. Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations

    Chemistry - A European Journal · 2018-09-19

    Yanna Chen, Min Zhang, Cong Hu, Hongping Wu, Zhihua Yang, Shilie Pan

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  16. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie International Edition · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  17. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  18. Prediction of Fluorooxoborates with Colossal Second Harmonic Generation (SHG) Coefficients and Extremely Wide Band Gaps: Towards Modulating Properties by Tuning the BO 3 /BO 3 F Ratio in Layers

    Angewandte Chemie International Edition · 2019-06-30

    Bingbing Zhang, Evgenii Tikhonov, Congwei Xie, Zhihua Yang, Shilie Pan

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  19. Prediction of Fluorooxoborates with Colossal Second Harmonic Generation (SHG) Coefficients and Extremely Wide Band Gaps: Towards Modulating Properties by Tuning the BO3/BO3F Ratio in Layers

    Angewandte Chemie · 2019-07-01

    Bingbing Zhang, Evgenii Tikhonov, Congwei Xie, Zhihua Yang, Shilie Pan

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  20. Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn5(BO3)3OH

    European Journal of Inorganic Chemistry · 2019-08-16

    Viktoria Falkowski, Alexander Zeugner, Lkhamsuren Bayarjargal, Andreas Saxer, Michael Ruck, Hubert Huppertz

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  21. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

    Angewandte Chemie International Edition · 2019-08-26

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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  22. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

    Angewandte Chemie · 2019-08-29

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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  23. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie International Edition · 2020-02-06

    Jin Chen, Chun‐Li Hu, Xiaohan Zhang, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  24. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie · 2020-02-06

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  25. Two Covalent Ultraviolet Nonlinear Optical Crystals

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  26. Synthesis, Crystal Structure, and Characterization of a Noncentrosymmetric Sulfate Cs2Ca2(SO4)3

    European Journal of Inorganic Chemistry · 2020-02-24

    Yaoguo Shen, Xiaoling Xue, Wenyuan Tu, Zhiqun Liu, Renwen Yan, Hong Zhang, Junrong Jia

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  27. Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm

    Chemistry - An Asian Journal · 2020-09-21

    Xinglong Chen, Kang Min Ok

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  28. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie International Edition · 2020-11-04

    Chao Wu, Xingxing Jiang, Zujian Wang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  29. Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )

    Angewandte Chemie · 2020-11-04

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  30. New Polymorphism for Ba3Zn2(BO3)3F with Two Polymorphs Exhibiting Anomalous Phase Transition

    European Journal of Inorganic Chemistry · 2021-01-24

    Yanna Chen, Wenyao Zhang, Donghai An, Maierhaba Abudoureheman, Zhaohui Chen, Hongyu Mi

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  31. M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures

    European Journal of Inorganic Chemistry · 2021-02-13

    Qiqi Zhang, Fangfang Zhang, Fuming Li, Shujuan Han, Zhihua Yang, Shilie Pan

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  32. Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response

    Angewandte Chemie International Edition · 2021-05-26

    Guang Peng, Chensheng Lin, Huixin Fan, Kaichuang Chen, Bingxuan Li, Ge Zhang, Ning Ye

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  33. Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response

    Angewandte Chemie · 2021-05-26

    Guang Peng, Chensheng Lin, Huixin Fan, Kaichuang Chen, Bingxuan Li, Ge Zhang, Ning Ye

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  34. Das erste Hochdruck‐Chromoxonitridoborat CrB4O6N – ein unerwartetes Bindeglied zur Chemie der Nitridosilikate

    Angewandte Chemie · 2021-08-12

    Birgit Fuchs, Dirk Johrendt, Lkhamsuren Bayarjargal, Hubert Huppertz

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  35. The First High‐Pressure Chromium Oxonitridoborate CrB 4 O 6 N—an Unexpected Link to Nitridosilicate Chemistry

    Angewandte Chemie International Edition · 2021-08-12

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  36. Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units

    Angewandte Chemie International Edition · 2021-10-09

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  37. Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units

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  38. High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence

    Angewandte Chemie · 2022-01-04

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  39. High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence

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  40. Explorations of New SHG Materials in Mercury Iodate Sulfate System**

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    Yilin Li, Mengya Ji, Chun‐Li Hu, Jin Chen, Bingxuan Li, Yuan Hua Lin, Jiang‐Gao Mao

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  41. Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups

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    Jiankang Wang, Yansong Cheng, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  42. Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups

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  43. Enhanced Interlayer Interaction and Second-Harmonic-Generation Response in a KBe 2 BO 3 F 2 -Type Inorganic–Organic Hybrid Zinc Borate

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  44. Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal

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  45. An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles

    Journal of Materials Chemistry C · 2023-01-01

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  46. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

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  47. Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

    Coordination Chemistry Reviews · 2023-08-02

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  48. Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence

    Inorganic Chemistry · 2023-10-20

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  49. The Birefringence Modulation in Short‐Wave Ultraviolet Sulfates with Functional π‐Conjugated Cations and Polymerized Heteroleptic Tetrahedral Anions

    Advanced Optical Materials · 2024-02-07

    Yanran Shang, Hongyuan Sha, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  50. [C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence

    Inorganic Chemistry · 2024-11-18

    Ya-Lan Deng, Chun‐Li Hu, Jiang‐Gao Mao

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