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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2020

Synthesis, Crystal Structure, and Characterization of a Noncentrosymmetric Sulfate Cs2Ca2(SO4)3

Yaoguo Shen, Xiaoling Xue, Wenyuan Tu, Zhiqun Liu, Renwen Yan, Hong Zhang, Junrong Jia

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Synthesis, Crystal Structure, and Characterization of a Noncentrosymmetric Sulfate Cs2Ca2(SO4)3OriginalCompeting hydrogen-bonding interactions in a high- T c organic molecular-ionic crystal with evident nonlinear optical response2Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterization28Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge20Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence53A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency15A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency96HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response19Crystal Structure and Theoretical Analysis of Cs2Ca3(SO4)47Advances in second-order nonlinear optical sulfates38LiRE(SO 4 ) 2 (RE = Y, Gd, Eu): noncentrosymmetric chiral rare-earth sulfates with very large band gaps21A lithium–scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency7Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials47Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge53Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal16Na 10 Zn(NO 3 ) 4 (SO 3 S) 4 : a nonlinear optical crystal combining inorganic π-conjugated and non-π-conjugated heteroanion groups8A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction6Promising Functional Structural Building Unit Trisulfimide (SO2N)33– and Its Contributions to Second Harmonic Generation and Birefringence1Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs8Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures0

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  1. Competing hydrogen-bonding interactions in a high- T c organic molecular-ionic crystal with evident nonlinear optical response

    CrystEngComm · 2021-01-01

    Wentao Xu, Jun‐Chao Liu, Yu‐Ling Zeng, Hua Zhang, Zhong‐Xia Wang

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  2. Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterization

    CrystEngComm · 2021-01-01

    Chao Wu, Lin Lin, Tianhui Wu, Zhipeng Huang, Chi Zhang

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  3. Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge

    New Journal of Chemistry · 2021-01-01

    Yuchen Yan, Yanna Chen, Bao Jiang, Qun Jing, Jun Zhang

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  4. Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap

    Journal of Materials Chemistry C · 2021-01-01

    Qinke Xu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  5. From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence

    Chemistry of Materials · 2021-11-22

    Tianhui Wu, Xingxing Jiang, Yiran Zhang, Zujian Wang, Hongyuan Sha, Chao Wu, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  6. A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency

    Angewandte Chemie · 2021-12-11

    Chao Wu, Xingxing Jiang, Yilei Hu, Chunbo Jiang, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  7. A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency

    Angewandte Chemie International Edition · 2021-12-11

    Chao Wu, Xingxing Jiang, Yilei Hu, Chunbo Jiang, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  8. HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response

    Journal of Alloys and Compounds · 2022-01-11

    Yinglei Han, Xin Lei Zhao, Feng Xu, Bingxuan Li, Ning Ye, Min Luo

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  9. Crystal Structure and Theoretical Analysis of Cs2Ca3(SO4)4

    Crystals · 2022-01-18

    P. Fang, Wenyue Tang, Yaoguo Shen, Jinquan Hong, Yongming Li, Junrong Jia

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  10. Advances in second-order nonlinear optical sulfates

    Coordination Chemistry Reviews · 2022-02-17

    Yaoguo Shen, Wenyue Tang, Xiaoxin Lin

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  11. LiRE(SO 4 ) 2 (RE = Y, Gd, Eu): noncentrosymmetric chiral rare-earth sulfates with very large band gaps

    Materials Chemistry Frontiers · 2022-11-30

    Sunghwan Cho, Kang Min Ok

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  12. A lithium–scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency

    Dalton Transactions · 2023-01-01

    Zilong Geng, Hong‐Xin Tang, Ruibiao Fu, Zuju Ma, Xin‐Tao Wu

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  13. Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Gangji Yi, Guohong Zou

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  14. Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge

    Chinese Journal of Structural Chemistry · 2023-02-24

    Chen Xu, Yanqiang Li, Junhua Luo, Sangen Zhao

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  15. Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal

    Crystal Growth & Design · 2023-06-27

    Wen Zhi Yang, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin

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  16. Na 10 Zn(NO 3 ) 4 (SO 3 S) 4 : a nonlinear optical crystal combining inorganic π-conjugated and non-π-conjugated heteroanion groups

    Inorganic Chemistry Frontiers · 2023-11-07

    Zihao Yu, Qingran Ding, Yuhang Jiang, Weiqi Huang, Changsheng Yang, Sangen Zhao, Junhua Luo

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  17. A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction

    Inorganic Chemistry Frontiers · 2024-01-01

    Hao Fu, Xiaohui Zhang, Peiyu Liu, Bo Li, Baolin Wu, Ye Tao, Qianshuang Lu, Yingjie Li, Jiaxi Huang, Fangfang Zhang, Tingchao He, Zhi Chen, Heng Wang, Chenliang Su, Hong‐Ying Zang, Xiujun Yu, Xiaopeng Li

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  18. Promising Functional Structural Building Unit Trisulfimide (SO2N)33– and Its Contributions to Second Harmonic Generation and Birefringence

    Crystal Growth & Design · 2024-08-14

    Chu‐Feng Zhu, Xin Liu, Rui‐Xi Wang, Li‐Ming Wu, Ling Chen

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  19. Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs

    European Journal of Inorganic Chemistry · 2025-08-26

    Xuehua Dong, Ling Huang, Guohong Zou

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  20. Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures

    Laser & Photonics Review · 2026-08-15

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xin-Tao Wu

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