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RESEARCH ARTICLE · Angewandte Chemie International Edition · 2017

Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

Fei‐Fei Mao, Chun‐Li Hu, Xiang Xu, Dong Yan, Bing‐Ping Yang, Jiang‐Gao Mao

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Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation EffectOriginalAg 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6Collaborative enhancement from Pb 2+ and F − in Pb 2 (NO 3 ) 2 (H 2 O)F 2 generates the largest second harmonic generation effect among nitrates91Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response121Chemistry-Inspired Adaptable Framework Structures368Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials5ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap36Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties17M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16Hg-Based Infrared Nonlinear Optical Material KHg4Ga5Se12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response101Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge39From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li2Mo3TeO12 to Polyoxometalates12Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response129Double-helix P n Li n chains: novel potential nonlinear optical materials8Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 O43Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy36Synthesis and characterization of a series of transition metal oxychlorides: MBi(SeO 3 ) 2 (H 2 O)Cl (M = Co, Ni, Cu)5A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge27Synthesis, second-harmonic generation (SHG), and photoluminescence (PL) properties of noncentrosymmetric bismuth selenite solid solutions, Bi 2-x Ln x SeO 5 (Ln = La and Eu; x = 0–0.3)2Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System90Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations32A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials71Co‐Crystals of 2‐Amino‐5‐Nitropyridine Barbital with Extreme Birefringence and Large Second Harmonic Generation Effect32Variable Asymmetric Chains in Transition Metal Oxyfluorides: Structure–Second-Harmonic-Generation Property Relationships16Cadmium Iodate Syntheses and Characterization3A noncentrosymmetric coordination polymer based on the benzophenone-3,3′-disulfonyl-4,4′-dicarboxylate ligand exhibiting second-harmonic-generation responses7Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Second-order nonlinear optical crystals with mixed anions250Ultrathin Nanobelts as an Excellent Bifunctional Oxygen Catalyst: Insight into the Subtle Changes in Structure and Synergistic Effects of Bimetallic Metal–Organic Framework82A hydrogen-bonded inorganic-organic network with noncentrosymmetric structure exhibiting second-order nonlinear optical response4Recent advances and future perspectives on infrared nonlinear optical metal halides223Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66Y2(CO3)3·H2O and (NH4)2Ca2Y4(CO3)9·H2O: Partial Aliovalent Cation Substitution Enabling Evolution from Centrosymmetry to Noncentrosymmetry for Nonlinear Optical Response37A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23(H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer19Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size63Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals26Investigation into the optimized growth, anisotropic properties and theoretical calculations of the polar material Cs 2 TeW 3 O 128KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer18M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 ] 2− groups on constructing ordered oxyfluorides14Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold19RbSbSO 4 Cl 2 : an excellent sulfate nonlinear optical material generated due to the synergistic effect of three asymmetric chromophores79Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence34Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 1217Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds16Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges0Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response15A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design114A Niobium Oxyiodate Sulfate with a Strong Second‐Harmonic‐Generation Response Built by Rational Multi‐Component Design25Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties26CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure87CsSbF2SO4: An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO4 (KTP)‐type Structure432New cadmium-selenium-oxyhalides: Noncentrosymmetric Cd5(SeO3)4Cl2(H2O) and centrosymmetric Cd2(SeO3)F2, Cd2(SeO3)(OH)Br17Designing Three Fluorooxoborates with a Wide Transmittance Window by Anionic Group Substitution15HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)28Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140Highly Polarizable Hg2+ Induced a Strong Second Harmonic Generation Signal and Large Birefringence in LiHgPO4265REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Rubidium Cerium (IV) Iodates with High UV‐Light‐Driven Photocatalytic Efficiency2Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6SrI3O9H: A new alkaline earth metal iodate with two different anionic units using mild aqua-solution method8Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra73Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra18Synthesis and Magnetic Properties of the KCu(IO3)3 Compound with [CuO5]∞ Chains7Nontoxic KBBF Family Member Zn2BO3(OH): Balance between Beneficial Layered Structure and Layer Tendency81LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO398LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO337A x Ce 9 (IO 3 ) 36 (A = K, La): the effects of a change in the intermediate valence on the second-harmonic generation response7A three-dimensional noncentrosymmetric zinc-4,4′,4′'-nitrilotribenzoate structure exhibiting second-harmonic generation responses5A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups53K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold114(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior92(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior11(NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization31A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates7Ba(B 2 OF 3 (OH) 2 ) 2 with well-ordered OH/F anions and a unique B 2 OF 3 (OH) 2 dimer30Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material20From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation14From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides36Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance17Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design302CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material120Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO3)2F290Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials164Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials55Synthesis, Crystal Structure, and Optical Properties of the First Alkali Metal Rare-Earth Iodate Fluoride: Li2Ce(IO3)4F222Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O951ZnIO3F: Zinc Iodate Fluoride with Large Birefringence and Wide Band Gap57K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates37K4Sb(SO4)3Cl: The first apatite-type sulfate ultraviolet nonlinear optical material with sharply enlarged birefringence61Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence24A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Pyridine-modulated Ni/Co bimetallic metal-organic framework nanoplates for electrocatalytic oxygen evolution84New Alkaline-Earth Metal Fluoroiodates Exhibiting Large Birefringence and Short Ultraviolet Cutoff Edge with Highly Polarizable (IO 3 F) 2– Units63High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence10LiGaF2(IO3)2: A mixed-metal gallium iodate-fluoride with large birefringence and wide band gap39Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50K 2 Sb(P 2 O 7 )F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance297K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance38Exploration of the Structural and Vibrational Properties of the Ternary Molybdate Tl5BiHf(MoO4)6 with Isolated MoO4 Units and Tl+ Conductivity14A 2 Bi 2 (SeO 3 ) 3 F 2 (A = K and Rb): Excellent Mid-Infrared Nonlinear Optical Materials with Both Strong SHG Responses and Large Band Gaps64Pb 18 O 8 Cl 15 I 5 : A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties165Pb18O8Cl15I5: A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties29Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm38From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution11Intense d ‑ p Hybridization Induced a Vast SHG Response Disparity between Tetrahedral Vanadates and Arsenates13Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )212Giant Optical Anisotropy in the UV‐Transparent 2D Nonlinear Optical Material Sc(IO 3 ) 2 (NO 3 )57Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement37Barium fluoroiodate crystals with a large band gap and birefringence22From Ce(IO 3 ) 4 to CeF 2 (IO 3 ) 2 : fluorinated homovalent substitution simultaneously enhances SHG response and bandgap for mid-infrared nonlinear optics26Pb 2 TiFO(SeO 3 ) 2 Br: a new polar compound with the strongest second harmonic generation in the selenite bromide family29Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites23SrTi(IO 3 ) 6 ·2H 2 O and SrSn(IO 3 ) 6 : distinct arrangements of lone pair electrons leading to large birefringences11Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.518Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11A Polar Material with Facility of Crystal Growth and a Large Second-Harmonic Generation Response3Large Second-Harmonic Response and Giant Birefringence of CeF 2 (SO 4 ) Induced by Highly Polarizable Polyhedra248Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O5Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups18A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance35CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation47Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response130Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response8High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies323[ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain86[o‐C5H4NHOH]2[I7O18(OH)]⋅3 H2O: An Organic–Inorganic Hybrid SHG Material Featuring an [I7O18(OH)] Branched Polyiodate Chain21Ultrathin One-Dimensional Ni-MIL-77 Nanobelts for High-Performance Electrocatalytic Urea Evolution15A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation50Linear and Nonlinear Optical Properties of Centrosymmetric Sb 4 O 5 SO 4 and Noncentrosymmetric Sb 4 O 4 (SO 4 )(OH) 2 Induced by Lone Pair Stereoactivity55A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation22A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation63Controllable Syntheses, Crystal Structure Evolution, and Photoluminescence of Polymorphic Zirconium Oxyfluorides6Chemical substitution – oriented design of a new polar PbFIO3 achieving a balance between large second-harmonic generation response and wide band gap16AMoO3(IO3) (A = Na and K): Two promising optical materials via properly assembling the Λ-shaped basic building units19M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion12

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  1. Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )

    Dalton Transactions · 2017

    Chang‐Yu Meng, Pei Zhang, Rongfang Wang, Lei Geng

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  2. Collaborative enhancement from Pb 2+ and F − in Pb 2 (NO 3 ) 2 (H 2 O)F 2 generates the largest second harmonic generation effect among nitrates

    Chemical Communications · 2017

    Guang Peng, Yi Jin Yang, Yu‐Huan Tang, Min Luo, Tao Yan, Yuqiao Zhou, Chensheng Lin, Zheshuai Lin, Ning Ye

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  3. Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response

    Chemistry of Materials · 2017

    Min Zhang, Xin Su, Miriding Mutailipu, Zhihua Yang, Shilie Pan

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  4. Chemistry-Inspired Adaptable Framework Structures

    Accounts of Chemical Research · 2017

    Zhiguo Xia, Kenneth Reinhard Poeppelmeier

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  5. Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials

    Inorganic Chemistry · 2017

    Bing‐Ping Yang, Chun‐Li Hu, Fei‐Fei Mao, Xiang Xu, Jiang‐Gao Mao

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  6. ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap

    Angewandte Chemie International Edition · 2017

    Hongming Liu, Qi Wu, Xingxing Jiang, Zheshuai Lin, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  7. ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap

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    Hongming Liu, Qi Wu, Xingxing Jiang, Zheshuai Lin, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  8. Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties

    Inorganic Chemistry · 2017

    Molin Zhou, Xingxing Jiang, Yangwu Guo, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  9. M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates

    Crystal Growth & Design · 2017

    Tong-Ying Chang, Bing‐Ping Yang, Chun‐Li Hu, Dong Yan, Jiang‐Gao Mao

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  10. Hg-Based Infrared Nonlinear Optical Material KHg4Ga5Se12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response

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    Molin Zhou, Yi Jin Yang, Yangwu Guo, Zheshuai Lin, Jiyong Yao, Yicheng Wu, Chuangtian Chen

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  11. Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion

    Inorganic Chemistry · 2017

    Fei‐Fei Mao, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  12. Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2017

    Jiang-He Feng, Chun‐Li Hu, Houping Xia, Fang Kong, Jiang‐Gao Mao

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  13. From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li2Mo3TeO12 to Polyoxometalates

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    Seung‐Jin Oh, Seong‐Ji Lim, Tae‐Soo You, Kang Min Ok

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  14. Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response

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    Guohong Zou, Zhien Lin, Hongmei Zeng, Hongil Jo, Seong‐Ji Lim, Tae‐Soo You, Kang Min Ok

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  15. Double-helix P n Li n chains: novel potential nonlinear optical materials

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    Yang‐Yang Hu, Xiaodong Xu, Yingjie Jiang, Guiling Zhang, Weiqi Li, Xiudong Sun, Wei Quan Tian, Yunan Feng

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  16. Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 O

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  17. Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy

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    Xiaoxiao Wang, Xingxing Jiang, Hongming Liu, Lei Yang, Zheshuai Lin, Zhanggui Hu, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  18. Synthesis and characterization of a series of transition metal oxychlorides: MBi(SeO 3 ) 2 (H 2 O)Cl (M = Co, Ni, Cu)

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  19. A Member of Fluorooxoborates: Li2Na0.9K0.1B5O8F2 with the Fundamental Building Block B5O10F2 and a Short Cutoff Edge

    Inorganic Chemistry · 2018

    Shujuan Han, Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  20. Synthesis, second-harmonic generation (SHG), and photoluminescence (PL) properties of noncentrosymmetric bismuth selenite solid solutions, Bi 2-x Ln x SeO 5 (Ln = La and Eu; x = 0–0.3)

    Solid State Sciences · 2018

    Hai-Xin Qi, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  21. Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System

    Chemistry of Materials · 2018

    Min Zhang, Cong Hu, Tushagu Abudouwufu, Zhihua Yang, Shilie Pan

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  22. Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations

    Inorganic Chemistry · 2018

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  23. A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials

    Chemistry of Materials · 2018

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Jiang‐Gao Mao

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  24. Co‐Crystals of 2‐Amino‐5‐Nitropyridine Barbital with Extreme Birefringence and Large Second Harmonic Generation Effect

    Chemistry - A European Journal · 2018

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  25. Variable Asymmetric Chains in Transition Metal Oxyfluorides: Structure–Second-Harmonic-Generation Property Relationships

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  26. Cadmium Iodate Syntheses and Characterization

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  27. A noncentrosymmetric coordination polymer based on the benzophenone-3,3′-disulfonyl-4,4′-dicarboxylate ligand exhibiting second-harmonic-generation responses

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  28. Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O

    Inorganic Chemistry · 2018

    Yahui Li, Hongping Wu, Bingbing Zhang, Zhihua Yang, Guopeng Han, Shilie Pan

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  29. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

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  30. Ultrathin Nanobelts as an Excellent Bifunctional Oxygen Catalyst: Insight into the Subtle Changes in Structure and Synergistic Effects of Bimetallic Metal–Organic Framework

    Small Methods · 2018

    Xiao Xiao, Qing Li, Xinya Yuan, Yuxia Xu, Mingbo Zheng, Huan Pang

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  31. A hydrogen-bonded inorganic-organic network with noncentrosymmetric structure exhibiting second-order nonlinear optical response

    Inorganic Chemistry Communications · 2018

    Zixuan Chen, Yu‐Ling Wang, Qing‐Yan Liu

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  32. Recent advances and future perspectives on infrared nonlinear optical metal halides

    Coordination Chemistry Reviews · 2018

    Pifu Gong, Fei Liang, Lei Kang, Xingguo Chen, Jingui Qin, Yicheng Wu, Zheshuai Lin

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  33. Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response

    Chemistry - A European Journal · 2018

    Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Zhihua Yang, Shilie Pan

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  34. Y2(CO3)3·H2O and (NH4)2Ca2Y4(CO3)9·H2O: Partial Aliovalent Cation Substitution Enabling Evolution from Centrosymmetry to Noncentrosymmetry for Nonlinear Optical Response

    Chemistry of Materials · 2018

    Guang Peng, Chensheng Lin, Yi Jin Yang, Dan Zhao, Zheshuai Lin, Ning Ye, Jin‐Shun Huang

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  35. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie International Edition · 2018

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  36. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie · 2018

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  37. (H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer

    Chemical Communications · 2019

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Ru‐Ling Tang, Bao-Lin Wu, Jiang‐Gao Mao

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  38. Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size

    Inorganic Chemistry Frontiers · 2019

    Qian Wang, Lei Wang, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  39. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  40. From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals

    Inorganic Chemistry Frontiers · 2019

    Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Hualiang Yu, Shilie Pan

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  41. Investigation into the optimized growth, anisotropic properties and theoretical calculations of the polar material Cs 2 TeW 3 O 12

    CrystEngComm · 2019

    Conggang Li, Peng Zhao, Zeliang Gao, Qian Wu, Xiangxin Tian, Dianxing Ju, Weiqun Lu, Youxuan Sun, Deliang Cui, Xutang Tao

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  42. KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer

    Dalton Transactions · 2019

    Ying‐Jie Jia, Yi-Gang Chen, Ting Wang, Yao Guo, Xiao‐Fang Guan, Xian‐Ming Zhang

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  43. M 2 (SeO 3 )F 2 (M = Zn, Cd): understanding the structure directing effect of [SeO 3 ] 2− groups on constructing ordered oxyfluorides

    CrystEngComm · 2019

    Fengguang You, Pifu Gong, Fei Liang, Xingxing Jiang, Heng Tu, Ying Zhao, Zhanggui Hu, Zheshuai Lin

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  44. Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold

    Dalton Transactions · 2019

    Qi Wu, Xian Liu, Fei Liang, Siran Xu, Hongbing Pi, Xue Han, Yang Liu, Zheshuai Lin, Yanjun Li

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  45. RbSbSO 4 Cl 2 : an excellent sulfate nonlinear optical material generated due to the synergistic effect of three asymmetric chromophores

    Journal of Materials Chemistry C · 2019

    Fangfang He, Yalan Deng, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  46. Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence

    Chemical Communications · 2019

    Guang Peng, Chensheng Lin, Dan Zhao, Liling Cao, Huixin Fan, Kaichuang Chen, Ning Ye

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  47. Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 12

    CrystEngComm · 2019

    Lei Xiao, Fengguang You, Pifu Gong, Zhanggui Hu, Zheshuai Lin

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  48. Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds

    Dalton Transactions · 2019

    Yawen An, Yang Zhong, Tongqing Sun, Haijun Wang, Zhenpeng Hu, Hongde Liu, Shiguo Liu, Yongfa Kong, Jingjun Xu

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  49. Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges

    New Journal of Chemistry · 2019

    Shuaishuai Hu, Zhi Su

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  50. Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response

    Inorganic Chemistry · 2019

    Lingyun Dong, Ying Wang, Bingbing Zhang, Zhihua Yang, Xusheng Ge, Kai Liu, Shigang Shen

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