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RESEARCH PAPER · Angewandte Chemie · 2018

Rb3VO(O2)2CO3: A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation Response

Guohong Zou, Hongil Jo, Seong‐Ji Lim, Tae‐Soo You, Kang Min Ok

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Rb3VO(O2)2CO3: A Four‐in‐One Carbonatoperoxovanadate Exhibiting an Extremely Strong Second‐Harmonic Generation ResponseOriginalLi2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure87CsSbF2SO4: An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO4 (KTP)‐type Structure432RbB 11 O 16 (OH) 2 : First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System5β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra73Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra18Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin255Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin33Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance172Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance40Emergent Deep‐Ultraviolet Nonlinear Optical Candidates324Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich43Hydroisocyanurates X 2 Y(H 2 C 3 N 3 O 3 ) 4 ·4H 2 O (X = K, Cs; Y = Zn, Cd) with large birefringence stemming from π-conjugated (H 2 C 3 N 3 O 3 ) − anions28Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect42Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization20CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions99An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions15Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials137Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials29K 2 Sb(P 2 O 7 )F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance297K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance38Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method19KSnI 3 ⋅ H 2 O: A New Compound with One‐Dimensional SnI 3 Chains of Pyramidal SnI 5 Polyhedra2An Antimony(III) Fluoride Oxalate with Large Birefringence45Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations71A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations13LiZn(OH)CO3: A Deep‐Ultraviolet Nonlinear Optical Hydroxycarbonate Designed from a Diamond‐like Structure180LiZn(OH)CO3: A Deep‐Ultraviolet Nonlinear Optical Hydroxycarbonate Designed from a Diamond‐like Structure10From Centrosymmetry to Noncentrosymmetry: Tailoring the Structural Arrangements of Carbonates with Strong Nonlinear Optical Response through Partial Anion Substitution33A Lead Mixed Halide with Three Different Coordinated Anions and Strong Second‐Harmonic Generation Response10Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures12A Second‐Order Nonlinear Optical Material Consisting of Two π‐Conjugated Groups10Persistent Second‐Harmonic Generation Enhancement Across an Unprecedented Pressure Range in a Hybrid Antimony Halide0Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal0Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials1

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  1. Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations

    Chemistry - A European Journal · 2018-09-19

    Yanna Chen, Min Zhang, Cong Hu, Hongping Wu, Zhihua Yang, Shilie Pan

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  2. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie International Edition · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  3. A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions

    Angewandte Chemie · 2018-12-27

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Jiang‐He Feng, Jiang‐Gao Mao

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  4. Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites

    Chemistry - A European Journal · 2019-01-13

    Ya-Ping Gong, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  5. CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure

    Angewandte Chemie · 2019-02-26

    Xuehua Dong, Ling Huang, Cuifang Hu, Hongmei Zeng, Zhien Lin, Xin Wang, Kang Min Ok, Guohong Zou

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  6. CsSbF2SO4: An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO4 (KTP)‐type Structure

    Angewandte Chemie International Edition · 2019-02-26

    Xuehua Dong, Ling Huang, Cuifang Hu, Hongmei Zeng, Zhien Lin, Xin Wang, Kang Min Ok, Guohong Zou

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  7. RbB 11 O 16 (OH) 2 : First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System

    ChemistrySelect · 2019-03-26

    Shuaishuai Hu, Shuwei Li, Zhi Su

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  8. β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

    Chemistry - A European Journal · 2019-06-18

    Shujuan Han, Chunmei Huang, Abudukadi Tudi, Shuaishuai Hu, Zhihua Yang, Shilie Pan

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  9. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

    Angewandte Chemie International Edition · 2019-08-26

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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  10. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

    Angewandte Chemie · 2019-08-29

    Ru‐Ling Tang, Chun‐Li Hu, Baolin Wu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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  11. Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin

    Angewandte Chemie International Edition · 2019-09-17

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  12. Sn2B5O9Cl: A Material with Large Birefringence Enhancement Activated Prepared via Alkaline‐Earth‐Metal Substitution by Tin

    Angewandte Chemie · 2019-09-17

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  13. Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance

    Angewandte Chemie International Edition · 2019-10-26

    Bin‐Wen Liu, Xiao‐Ming Jiang, Bingxuan Li, Hui‐Yi Zeng, Guo‐Cong Guo

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  14. Li[LiCs2Cl][Ga3S6]: A Nanoporous Framework of GaS4 Tetrahedra with Excellent Nonlinear Optical Performance

    Angewandte Chemie · 2019-10-26

    Bin‐Wen Liu, Xiao‐Ming Jiang, Bingxuan Li, Hui‐Yi Zeng, Guo‐Cong Guo

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  15. Emergent Deep‐Ultraviolet Nonlinear Optical Candidates

    Angewandte Chemie International Edition · 2019-12-10

    Miriding Mutailipu, Shilie Pan

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  16. Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich

    Angewandte Chemie · 2019-12-10

    Miriding Mutailipu, Shilie Pan

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  17. Hydroisocyanurates X 2 Y(H 2 C 3 N 3 O 3 ) 4 ·4H 2 O (X = K, Cs; Y = Zn, Cd) with large birefringence stemming from π-conjugated (H 2 C 3 N 3 O 3 ) − anions

    CrystEngComm · 2020-01-01

    Kaijin Kang, Xianghe Meng, Fei Liang, Jian Tang, Tixian Zeng, Wenlong Yin, Zheshuai Lin, Mingjun Xia

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  18. Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect

    Inorganic Chemistry Frontiers · 2020-01-01

    Xianghe Meng, Kaijin Kang, Fei Liang, Jian Tang, Wenlong Yin, Zheshuai Lin, Mingjun Xia

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  19. Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization

    Dalton Transactions · 2020-01-01

    Huanke Zhao, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  20. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie International Edition · 2020-02-06

    Jin Chen, Chun‐Li Hu, Xiaohan Zhang, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  21. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

    Angewandte Chemie · 2020-02-06

    Jin Chen, Chun‐Li Hu, Xiaohan Zhang, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  22. An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions

    Angewandte Chemie International Edition · 2020-03-18

    Shuai Liu, Xiaomeng Liu, Sangen Zhao, Youchao Liu, Lina Li, Qingran Ding, Yanqiang Li, Zheshuai Lin, Junhua Luo, Maochun Hong

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  23. An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions

    Angewandte Chemie · 2020-03-18

    Shuai Liu, Xiaomeng Liu, Sangen Zhao, Youchao Liu, Lina Li, Qingran Ding, Yanqiang Li, Zheshuai Lin, Junhua Luo, Maochun Hong

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  24. Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2020-06-19

    Xuefang Lu, Zhaohui Chen, Xuerui Shi, Qun Jing, Ming‐Hsien Lee

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  25. Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials

    Angewandte Chemie · 2020-06-19

    Xuefang Lu, Zhaohui Chen, Xuerui Shi, Qun Jing, Ming‐Hsien Lee

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  26. K 2 Sb(P 2 O 7 )F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance

    Angewandte Chemie International Edition · 2020-08-03

    Yalan Deng, Ling Huang, Xuehua Dong, Lei Wang, Kang Min Ok, Hongmei Zeng, Zhien Lin, Guohong Zou

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  27. K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance

    Angewandte Chemie · 2020-08-03

    Yalan Deng, Ling Huang, Xuehua Dong, Lei Wang, Kang Min Ok, Hongmei Zeng, Zhien Lin, Guohong Zou

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  28. Ba3(BO3)(CO3)F: The First Borate Carbonate Fluoride Synthesized by the High‐Temperature Solution Method

    Chemistry - A European Journal · 2020-09-25

    Chunmei Huang, Fangfang Zhang, Shichao Cheng, Zhihua Yang, Hao Li, Shilie Pan

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  29. KSnI 3 ⋅ H 2 O: A New Compound with One‐Dimensional SnI 3 Chains of Pyramidal SnI 5 Polyhedra

    ChemistrySelect · 2020-11-18

    Kuan Li, Junwei Feng, Zhi Su

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  30. An Antimony(III) Fluoride Oxalate with Large Birefringence

    Chemistry - A European Journal · 2020-12-10

    Yangxin Chen, Zhangxian Chen, Zhou Yang, Yanqiang Li, Youchao Liu, Qingran Ding, Xin Chen, Sangen Zhao, Junhua Luo

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  31. Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity

    Chemistry - A European Journal · 2020-12-23

    Qi Wei, Chao He, Kui Wang, Xiao‐Fang Duan, Xing‐Tao An, Jinhua Li, Guo‐Ming Wang

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  32. A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations

    Angewandte Chemie International Edition · 2021-03-09

    Yanqiang Li, Zhengyang Zhou, Sangen Zhao, Fei Liang, Qingran Ding, Junliang Sun, Zheshuai Lin, Maochun Hong, Junhua Luo

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  33. A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations

    Angewandte Chemie · 2021-03-09

    Yanqiang Li, Zhengyang Zhou, Sangen Zhao, Fei Liang, Qingran Ding, Junliang Sun, Zheshuai Lin, Maochun Hong, Junhua Luo

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  34. LiZn(OH)CO3: A Deep‐Ultraviolet Nonlinear Optical Hydroxycarbonate Designed from a Diamond‐like Structure

    Angewandte Chemie International Edition · 2021-04-06

    Xiaomeng Liu, Lei Kang, Pifu Gong, Zheshuai Lin

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  35. LiZn(OH)CO3: A Deep‐Ultraviolet Nonlinear Optical Hydroxycarbonate Designed from a Diamond‐like Structure

    Angewandte Chemie · 2021-04-06

    Xiaomeng Liu, Lei Kang, Pifu Gong, Zheshuai Lin

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  36. From Centrosymmetry to Noncentrosymmetry: Tailoring the Structural Arrangements of Carbonates with Strong Nonlinear Optical Response through Partial Anion Substitution

    Advanced Optical Materials · 2021-05-22

    Xianghe Meng, Pifu Gong, Chunlan Tang, Wenlong Yin, Zheshuai Lin, Mingjun Xia

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  37. A Lead Mixed Halide with Three Different Coordinated Anions and Strong Second‐Harmonic Generation Response

    Chemistry - A European Journal · 2021-10-15

    Qirui Shui, Ruibiao Fu, Ziqi Zhou, Zuju Ma, Hong‐Xin Tang, Xin‐Tao Wu

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  38. Chiral Ligand‐Driven Systematic Synthesis of Coordination Polymers with Non‐centrosymmetric Structures

    Chemistry - A European Journal · 2022-01-27

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  39. A Second‐Order Nonlinear Optical Material Consisting of Two π‐Conjugated Groups

    ChemPlusChem · 2023-03-01

    Minjuan Li, Ziyi Wang, Belal Ahmed, Yanqiang Li, Han Wang, Yipeng Song, Xianyu Song, Xiaojun Kuang, Junhua Luo, Sangen Zhao

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  40. Persistent Second‐Harmonic Generation Enhancement Across an Unprecedented Pressure Range in a Hybrid Antimony Halide

    Angewandte Chemie · 2026-04-01

    Wenbo Qiu, Weilong He, Xingxing Jiang, Yu Liu, Boyang Fu, Weizhao Cai

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  41. Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

    Angewandte Chemie · 2026-06-22

    Yang Li, Congcong Jin, Kang Min Ok

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  42. Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials

    Materials Today Physics · 2026-07-04

    D K Li, Yujie Zhang, H Liu, Hongping Wu, Zhanggui Hu, Hongwei Yu

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