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RESEARCH PAPER · Journal of the American Chemical Society · 2019

Highly Polarizable Hg2+ Induced a Strong Second Harmonic Generation Signal and Large Birefringence in LiHgPO4

Baolin Wu, Chun‐Li Hu, Fei‐Fei Mao, Ru‐Ling Tang, Jiang‐Gao Mao

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Highly Polarizable Hg2+ Induced a Strong Second Harmonic Generation Signal and Large Birefringence in LiHgPO4OriginalLiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution68Structural insights into three phosphates with distinct polyanionic configurations20Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 611Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges0Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra73Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra18Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)17Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis36Emergent Deep‐Ultraviolet Nonlinear Optical Candidates324Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich43Li2K4TiOGe4O12: A Stable Mid-Infrared Nonlinear Optical Material69Design, synthesis, crystal structure and luminescent properties introduced by Eu 3+ of a new type of rare-earth borophosphate CsNa 2 REE 2 (BO 3 )(PO 4 ) 2 (REE = Y, Gd)23Large nonlinear optical effect in tungsten bronze structures via Li/Na cross-substitutions4M 4 LiBe 4 P 7 O 24 and M 4 Li(Li 3 P)P 7 O 24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework9Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence49Polar polymorphism: α- and β-KCsWP 2 O 9 nonlinear optical materials with a strong second harmonic generation response25Second harmonic generation responses of KH 2 PO 4 : importance of K and breaking down of Kleinman symmetry49Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization20Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer33Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response23Two new ammonium/alkali-rare earth metal difluorophosphates ALa(PO 2 F 2 ) 4 (A = NH 4 and K) with moderate birefringence and short cutoff edges26Ultraviolet nonlinear optical crystal: (NH4)ZnPO47Key Factors Controlling the Large Second Harmonic Generation in Nonlinear Optical Materials37MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings23Molecular Construction from AgGaS 2 to CuZnPS 4 : Defect-Induced Second Harmonic Generation Enhancement and Cosubstitution-Driven Band Gap Enlargement96Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O951An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions99An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions15Strong Second Harmonic Generation in a Tungsten Bronze Oxide by Enhancing Local Structural Distortion48Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates37A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids128Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials130High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence10Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9K 2 Sb(P 2 O 7 )F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance297K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance38CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered Structure49Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research19Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research140Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36Bi 32 Cd 3 P 10 O 76 : a new congruently melting nonlinear optical crystal with a large SHG response and a wide transparent region24A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)319Cs 2 AlB 5 O 10 : a short-wavelength nonlinear optical crystal with moderate second harmonic generation response12Sn2B5O9Br as an Outstanding Bifunctional Material with Strong Second‐Harmonic Generation Effect and Large Birefringence84Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides20Ba 3 [Al(PO 4 ) 3 ]: rational design of a promising deep-UV transparent SHG crystal with balanced overall performance originating from the condensation of quartz-type [Al(PO 4 ) 4 ] 9− units16K 3 B 4 PO 10 and K 2 MB 4 PO 10 (M = Rb/Cs): rare mixed-coordinated borophosphates with large birefringence33BaTi(BO 3 ) 2 : an excellent birefringent material with highly coplanar isolated [BO 3 ] groups16Breaking through the “3.0 eV wall” of energy band gap in mid-infrared nonlinear optical rare earth chalcogenides by charge-transfer engineering144Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials41Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)2From centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH 4 ) n−2 AE(PO 2 F 2 ) n (AE = Mg, Sr and Ba; n = 2, 3 and 4)9Hg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds39In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219K 2 ZnMoP 2 O 10 : a novel nonlinear optical molybdophosphate with a strong second harmonic generation response and moderate birefringence24On the crystal chemistry of inorganic nitrides: crystal-chemical parameters, bonding behavior, and opportunities in the exploration of their compositional space17Potassium L-ascorbate monohydrate: a new metal–organic nonlinear optical crystal6Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26Sn 14 O 11 Br 6 : a promising birefringent material with a [Sn 14 O 11 Br 6 ] layer26Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence37A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups106A2(TeO)P2O7 (A = K, Rb, Cs): Three new tellurite-pyrophosphates with large birefringence17Large Second-Harmonic Response and Giant Birefringence of CeF 2 (SO 4 ) Induced by Highly Polarizable Polyhedra248Second-order nonlinear optical property of the ultraviolet transparent alkali metal-rare earth metal carbonate Na3Y(CO3)3.3H2O5Introduction of Li into Ag-Based Noncentrosymmetric Sulfides for High-Performance Infrared Nonlinear Optical Materials40UV Solar‐Blind‐Region Phase‐Matchable Optical Nonlinearity and Anisotropy in a π‐Conjugated Cation‐Containing Phosphate196UV Solar‐Blind‐Region Phase‐Matchable Optical Nonlinearity and Anisotropy in a π‐Conjugated Cation‐Containing Phosphate28Te(CS(NH2)2)4SO4·2H2O: A Three-in-One Semiorganic Nonlinear Optical Crystal with an Unusual Quadrilateral (TeS4)6– Chromophore14α-Ca2CdP2 and β-Ca2CdP2: Two Polymorphic Phosphide-Based Infrared Nonlinear Crystals with Distorted NLO-Active Tetrahedral Motifs Realizing Large Second Harmonic Generation Effects and Suitable Band Gaps30AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−58High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies323Fluorine‐Driven Enhancement of Birefringence in the Fluorooxosulfate: A Deep Evaluation from a Joint Experimental and Computational Study139LiB2O3F: A Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Designed Based on a Boron-Rich Strategy61Cs2ZnSn3S8: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure24Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals146Hydroxyfluorooxoborate Na[B3O3F2(OH)2]⋅[B(OH)3]: Optimizing the Optical Anisotropy with Heteroanionic Units for Deep Ultraviolet Birefringent Crystals16[Ag(NH 3 ) 2 ] 2 SO 4 : A Strategy for the Coordination of Cationic Moieties to Design Nonlinear Optical Materials**6[Ag(NH3)2]2SO4: A Strategy for the Coordination of Cationic Moieties to Design Nonlinear Optical Materials**85Solvothermal Syntheses of Three-Dimensional Open-Framework Thioantimonates Displaying Nonlinear Optical Responses5Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides28Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate212Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate22Synthesis, Crystal Structure, and Nonlinear Optical Property of an Anhydrous Sulfate KTb(SO4)216Tin(II)-Induced Large Birefringence Enhancement in Metal Phosphates22Strong SHG Responses in a Beryllium‐Free Deep‐UV‐Transparent Hydroxyborate via Covalent Bond Modification89Strong SHG Responses in a Beryllium‐Free Deep‐UV‐Transparent Hydroxyborate via Covalent Bond Modification9Cd3(PO4)(TePO6): A Novel Cadmium Tellurite‐Phosphate featuring a {[TePO6]3−}∞ Chain15Helical {[HgS]} n Chain-Induced Balanced Nonlinear-Optical Performance for Trigonal Mercury Sulfide29Enhancement of band gap and birefringence induced via π -conjugated chromophore with “tail effect”28Ca-cluster-constructed deep-ultraviolet nonlinear-optical crystal Na2Ca17Al2(PO4)14 with strong NLO response11K6Bi13(PO4)15, K5Bi(P2O7)2, A5Bi5(PO4)4(P2O7)2 (A=K, Rb): New bismuth phosphates with different condensed phosphate groups8Complex coordinated functional groups: A great genes for nonlinear optical materials64Anion-Tuned Synthesis of Ag Coordination Compounds: Approaches for Optimizing Second-Harmonic-Generation (SHG) Response5Hierarchical Modulation of Optical Anisotropy Driven by Metal Cation Polyhedra in Fluorooxoborates MIIB4O6F2 (MII=Be, Mg, Pb, Zn, Cd)6[C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy40A novel 2-(aminomethyl)pyridineH 2 PO 4 crystal with second-order nonlinear optical performance8BaSc 2 (HPO 3 ) 4 (H 2 O) 2 : a new nonlinear optical phosphite exhibiting a 3D {[Sc 2 (HPO 3 ) 4 ] 2− } ∞ anionic framework and phase-matchable SHG effect32Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps28Cd 4 REO(BO 3 ) 3 (RE = Sm, Eu, Tb): three new cadmium–rare earth oxyborates with both good NLO and luminescence properties6Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn 2 PO 4 X (X = F, Cl)47Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds36Large optical anisotropy differentiation induced by the anion-directed regulation of structures29Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures8LiSrSbS 3 : parallel configurations of lone pair electrons inducing a large birefringence16Nain(C2o4)(Hpo4)(H2o)5: An Ultraviolet Transparent Nonlinear Optical Oxalate-Phosphate with Large Birefringence0PNO: a promising deep-UV nonlinear optical material with the largest second harmonic generation effect17Synergistic effect of 2 [V 2 P 2 O 14 ] ∞ layers and hydrogen bonds inducing large birefringence in M(VO) 2 (PO 4 ) 2 ·4H 2 O (M = Ca, Sr, Ba) systems4High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence21High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence199Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra20HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response19HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups36Material research from the viewpoint of functional motifs103Explorations of New SHG Materials in Mercury Iodate Sulfate System**9Cd4InO(BO3)3: A New Nonlinear Optical Crystal Exhibiting Strong Second Harmonic Generation Effect and Moderate Birefringence2Anion-Centered Polyhedron Strategy for Strengthening Photon Emission Induced by Electron–Phonon Coupling13Ultrawide Bandgap and Outstanding Second‐Harmonic Generation Response by a Fluorine‐Enrichment Strategy at a Transition‐Metal Oxyfluoride Nonlinear Optical Material51Ultrawide Bandgap and Outstanding Second‐Harmonic Generation Response by a Fluorine‐Enrichment Strategy at a Transition‐Metal Oxyfluoride Nonlinear Optical Material12One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response29Enhanced Second-Harmonic-Generation Efficiency and Birefringence in Melillite Oxychalcogenides Sr2MGe2OS6 (M = Mn, Zn, and Cd)97Lone Pair-Driven Enhancement of Birefringence in Polar Alkali Metal Antimony Phosphates46Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species6Promising Deep‐Ultraviolet Birefringent Materials via Rational Design and Assembly of Planar π‐Conjugated [B(OH)3] and [B3O3(OH)3] Functional Species83RbLiZn5(PO4)4 and BaLiZn3(PO4)3: two new zinc orthophosphates with all tetrahedra-based anion frameworks11Enhancement of Birefringence in Borophosphate Pushing Phase-Matching into the Short-Wavelength Region150Mid-Infrared Nonlinear Optical Halides with Diamond-like Structures: A Theoretical and Experimental Study43Two Metal Phosphate Nonlinear Optical Materials Simultaneously Exhibiting Ultraviolet Transparence and a Large Birefringence50Coordination metal effect on the nonlinear optical properties and biological activity of double selenates8Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal19Hg2P2S6: A layered mercury hexathiodiphosphate (IV) with large birefringence11Vapor-Induced Conversion of a Centrosymmetric Organic–Inorganic Hybrid Crystal into a Proton-Conducting Second-Harmonic-Generation-Active Material8BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response32Enhancements of Second Harmonic Generation and Birefringence in Traditional RbTiOPO4‐Type Crystals by Aliovalent Substitution of Ti Site1Ag[SC(NH2)2]2F: A Laser Damage-Tolerant Infrared Nonlinear Optical Material9Exploring Short-Wavelength Phase-Matching Nonlinear Optical Crystals by Employing KBe2BO3F2 as the Template95Ag-based chalcogenides and derivatives as promising infrared nonlinear optical materials90Rb 3 B 5 O 8 F 2 and K 0.6 Rb 2.4 B 5 O 8 F 2 : two new deep-ultraviolet transparent nonlinear optical fluorooxoborates designed by cation regulation13A Cation-Driven Approach toward Deep-Ultraviolet Nonlinear Optical Materials17A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures13Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge6Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 234Modulating optical performance by phase transition in a nonlinear optical material β-Li 2 RbBi(PO 4 ) 28Polarization-dependent second harmonic generation in peptide crystals: effects of molecular packing5Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence21Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates51Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates7Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence18Toward Large Second-Harmonic Generation and Deep-UV Transparency in Strongly Electropositive Transition Metal Sulfates112

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  3. Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 6

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  4. Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges

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  5. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

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  33. Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials

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  34. High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence

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    Ying‐Jie Jia, Yi-Gang Chen, Ting Wang, Yao Guo, Xiao‐Fang Guan, Xian‐Ming Zhang

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  35. Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis

    Journal of Solid State Chemistry · 2020-07-18

    Wenfeng Zhou, Xiaohui Li, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

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  36. K 2 Sb(P 2 O 7 )F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance

    Angewandte Chemie International Edition · 2020-08-03

    Yalan Deng, Ling Huang, Xuehua Dong, Lei Wang, Kang Min Ok, Hongmei Zeng, Zhien Lin, Guohong Zou

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  37. K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance

    Angewandte Chemie · 2020-08-03

    Yalan Deng, Ling Huang, Xuehua Dong, Lei Wang, Kang Min Ok, Hongmei Zeng, Zhien Lin, Guohong Zou

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  38. CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered Structure

    Inorganic Chemistry · 2020-08-26

    Ying Long, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  39. Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research

    Angewandte Chemie · 2020-10-07

    Tinghao Tong, Wenyao Zhang, Zhihua Yang, Shilie Pan

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  40. Series of Crystals with Giant Optical Anisotropy: A Targeted Strategic Research

    Angewandte Chemie International Edition · 2020-10-07

    Tinghao Tong, Wenyao Zhang, Zhihua Yang, Shilie Pan

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  41. Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

    Inorganic Chemistry Frontiers · 2020-10-26

    Pengfei Li, Chun‐Li Hu, Fang Kong, Shao‐Ming Ying, Jiang‐Gao Mao

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  42. Bi 32 Cd 3 P 10 O 76 : a new congruently melting nonlinear optical crystal with a large SHG response and a wide transparent region

    Inorganic Chemistry Frontiers · 2020-10-29

    Jiankang Wang, Binkai Xiong, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  43. A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)3

    Inorganic Chemistry Communications · 2020-12-07

    Youchao Liu, Yanqiang Li, Zhou Yang, Qingran Ding, Yangxin Chen, Sangen Zhao, Junhua Luo

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  44. Cs 2 AlB 5 O 10 : a short-wavelength nonlinear optical crystal with moderate second harmonic generation response

    Dalton Transactions · 2020-12-10

    Tuohetijiang Baiheti, Shujuan Han, Wenqi Jin, Zhihua Yang, Shilie Pan

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  45. Sn2B5O9Br as an Outstanding Bifunctional Material with Strong Second‐Harmonic Generation Effect and Large Birefringence

    Advanced Optical Materials · 2020-12-16

    Jingyu Guo, Shichao Cheng, Shujuan Han, Zhihua Yang, Shilie Pan

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  46. Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides

    Inorganic Chemistry Frontiers · 2020-12-23

    Junben Huang, Jianian Cheng, Bing‐Hua Lei, Zhonglei Wei, Shilie Pan, Zhihua Yang

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  47. Ba 3 [Al(PO 4 ) 3 ]: rational design of a promising deep-UV transparent SHG crystal with balanced overall performance originating from the condensation of quartz-type [Al(PO 4 ) 4 ] 9− units

    Journal of Materials Chemistry C · 2020-12-24

    Zhi Gang Fang, Chun‐Li Hu, Bing‐Ping Yang, Jiang‐Gao Mao

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  48. K 3 B 4 PO 10 and K 2 MB 4 PO 10 (M = Rb/Cs): rare mixed-coordinated borophosphates with large birefringence

    Inorganic Chemistry Frontiers · 2020-12-30

    Ying Hou, Bingbing Zhang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  49. BaTi(BO 3 ) 2 : an excellent birefringent material with highly coplanar isolated [BO 3 ] groups

    New Journal of Chemistry · 2021-01-01

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  50. Breaking through the “3.0 eV wall” of energy band gap in mid-infrared nonlinear optical rare earth chalcogenides by charge-transfer engineering

    Materials Horizons · 2021-01-01

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