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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2020

Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides

Junben Huang, Jianian Cheng, Bing‐Hua Lei, Zhonglei Wei, Shilie Pan, Zhihua Yang

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Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalidesOriginalDistinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)2( R )- and ( S )-[C 8 H 10 NO 3 ] 2 [NbOF 5 ]: noncentrosymmetric niobium oxyfluorides with large optical anisotropy3Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal17Review of Heteroleptic Tetrahedra as Birefringent or Nonlinear Optical Motifs17Screening Nitrides with High Debye Temperatures as Nonlinear Optical Materials19Predicting Diamond-like Nitrides as Infrared Nonlinear Optical Materials with High Thermal Conductivity20Honeycomb layered topology construction for exceptional long-wave infrared nonlinear optical crystals29LaAeAl 3 S 7 (Ae = Ca, Sr): Cairo pentagonal layered thioaluminates achieving a good balance between a strong second harmonic generation response and a wide bandgap23Shooting mid-infrared nonlinear optical materials with targeted balance performances in ternary d0-transition metal oxides through first-principles13Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups7Hg 3 AsS 4 X (X = Cl and Br): two Hg-based chalcogenides as long-wave infrared nonlinear optical crystals with superior comprehensive performances33Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships13Recent progress in structural design strategies of high-birefringence optical crystals54Research progress and future prospect of chalcogenides with large optical anisotropy46A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations1Giant Birefringence and Ultrahigh Thermal Conductivity in Layered MgMoN 20

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  1. Distinctive modulation of optical anisotropy by halogens in α/β-Cd–P–X (X = Cl, Br, and I)

    Dalton Transactions · 2021-01-01

    Kewang Zhang, Junben Huang, Zhikang Chen, Bei Zhang, Ming‐Hsien Lee, Jun Zhang

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  2. ( R )- and ( S )-[C 8 H 10 NO 3 ] 2 [NbOF 5 ]: noncentrosymmetric niobium oxyfluorides with large optical anisotropy

    Inorganic Chemistry Frontiers · 2022-01-01

    Jihyeon Moon, Kang Min Ok

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  3. Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal

    Inorganic Chemistry Frontiers · 2022-01-01

    Yuanyu Yang, Yao Guo, Yi-Gang Chen, Xiwei Hu, Xia Zhang, Xian‐Ming Zhang, Xian-Ming Zhang, Xian-Ming Zhang

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  4. Review of Heteroleptic Tetrahedra as Birefringent or Nonlinear Optical Motifs

    Crystal Growth & Design · 2022-01-18

    Junben Huang, Shan Shu, Gemei Cai

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  5. Screening Nitrides with High Debye Temperatures as Nonlinear Optical Materials

    The Journal of Physical Chemistry C · 2022-04-13

    Junben Huang, Shan Shu, Gemei Cai

    Read original paper ↗ ·

  6. Predicting Diamond-like Nitrides as Infrared Nonlinear Optical Materials with High Thermal Conductivity

    Chemistry of Materials · 2022-11-02

    Junben Huang, Congwei Xie, Lei Wei, Qiang Bian, Zhihua Yang, Shilie Pan

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  7. Honeycomb layered topology construction for exceptional long-wave infrared nonlinear optical crystals

    Materials Horizons · 2023-01-01

    Jindong Chen, Chensheng Lin, Xiaotian Jiang, Guangsai Yang, Min Luo, Xin Zhao, Bingxuan Li, Guang Peng, Ning Ye, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  8. LaAeAl 3 S 7 (Ae = Ca, Sr): Cairo pentagonal layered thioaluminates achieving a good balance between a strong second harmonic generation response and a wide bandgap

    Inorganic Chemistry Frontiers · 2023-01-01

    Jingjing Xu, Kui Wu, Bingbing Zhang, Haohai Yu, Huaijin Zhang

    Read original paper ↗ ·

  9. Shooting mid-infrared nonlinear optical materials with targeted balance performances in ternary d0-transition metal oxides through first-principles

    Materials Today Physics · 2023-03-02

    Junben Huang, Gemei Cai

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  10. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

    Angewandte Chemie International Edition · 2023-06-29

    Wenlong Xie, Fuming Li, Jianbang Chen, Zhihuang Yang, Guangmao Li, Shilie Pan

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  11. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

    Angewandte Chemie · 2023-06-29

    Wenlong Xie, Fuming Li, Jianbang Chen, Zhihuang Yang, Guangmao Li, Shilie Pan

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  12. Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Ning Zhao, Dazhi Lu, Jingjing Xu, Kui Wu, Haohai Yu, Huaijin Zhang

    Read original paper ↗ ·

  13. Hg 3 AsS 4 X (X = Cl and Br): two Hg-based chalcogenides as long-wave infrared nonlinear optical crystals with superior comprehensive performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Feng Xu, Xiang Xu, Bingxuan Li, Ge Zhang, Chan Zheng, Jindong Chen, Ning Ye

    Read original paper ↗ ·

  14. Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides

    The Journal of Physical Chemistry C · 2024-01-14

    Xueting Pan, Junben Huang, Yineng Huang

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  15. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  16. Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships

    Coordination Chemistry Reviews · 2025-04-06

    Junben Huang, Chenglong Zhang, Siying Chen, Ailijiang Abudurusuli

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  17. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  18. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

    Zhen-Cheng Wu, Sheng‐Ping Guo

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  19. A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations

    Materials Chemistry Frontiers · 2026-01-01

    Zhi Fang, G Xu, Wenhu Wang, Huanhuan Wang, Jian Wei Han

    Read original paper ↗ ·

  20. Giant Birefringence and Ultrahigh Thermal Conductivity in Layered MgMoN 2

    Crystal Growth & Design · 2026-06-22

    Xu Liu, Ailijiang Abudurusuli, Zhaofeng Wu, Junben Huang

    Read original paper ↗ ·
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