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RESEARCH PAPER · Dalton Transactions · 2020

Two new ammonium/alkali-rare earth metal difluorophosphates ALa(PO 2 F 2 ) 4 (A = NH 4 and K) with moderate birefringence and short cutoff edges

Wenyao Zhang, Zhonglei Wei, Zhihua Yang, Shilie Pan

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Two new ammonium/alkali-rare earth metal difluorophosphates ALa(PO 2 F 2 ) 4 (A = NH 4 and K) with moderate birefringence and short cutoff edgesOriginalK 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups14From BaCl 2 to Ba(NO 3 )Cl: significantly enhanced birefringence derived from π-conjugated [NO 3 ]14From centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH 4 ) n−2 AE(PO 2 F 2 ) n (AE = Mg, Sr and Ba; n = 2, 3 and 4)9RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers9Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate212Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate22BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response32SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence32KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge6From Monofluorophosphates A2PO3F to Difluorophosphates APO2F2 (A = alkali metal): Design of a Potential Deep-Ultraviolet Nonlinear Optical Materials System with a Shortened Phase-Matching Wavelength41Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence6Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence10Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7K 2 MgMoP 2 O 10 and K 3 Mg 2 MoP 3 O 14 : two new molybdophosphates exhibiting different optical anisotropies induced by variable dimensionality of the anion framework4Novel antimony phosphates with enlarged birefringence induced by lone pair cations4Syntheses, structures and characterization of noncentrosymmetric MZnPO 4 (M = K, NH 4 )4Synthesis and magnetic properties of two fluorophosphates K 2 Mn(PO 3 F)F 3 and Na 2 Mn(HPO 4 )F 3 with a S = 2 uniform spin chain structure5The Birefringence Modulation in Short‐Wave Ultraviolet Sulfates with Functional π‐Conjugated Cations and Polymerized Heteroleptic Tetrahedral Anions18Structure and optical properties of alkali rare-earth double phosphates of M3RE(PO4)2 (M = K, Rb; RE = Y, La, and Lu)4MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction1Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27A tri-alkali/alkaline-earth metal fluorophosphate deep-ultraviolet birefringent crystal with coexisting PO 3 F and PO 2 F 24Tailoring UV waveplate materials via rational assembly of functional motifs in scandium fluoride phosphate2Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal1Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions1Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence1

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  1. K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups

    Dalton Transactions · 2020-01-01

    Wenyao Zhang, Wenqi Jin, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  2. From BaCl 2 to Ba(NO 3 )Cl: significantly enhanced birefringence derived from π-conjugated [NO 3 ]

    New Journal of Chemistry · 2021-01-01

    Zhen Chen, Hao Zeng, Shujuan Han, Zhihua Yang, Shilie Pan

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  3. From centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH 4 ) n−2 AE(PO 2 F 2 ) n (AE = Mg, Sr and Ba; n = 2, 3 and 4)

    Dalton Transactions · 2021-01-01

    Wenyao Zhang, Wenqi Jin, Meng Cheng, Ruonan Zhang, Zhihua Yang, Shilie Pan

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  4. RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers

    Dalton Transactions · 2021-01-01

    Rui Zhang, Xin Su, Jie Zhang, Mingyao Xiong, Yineng Huang

    Read original paper ↗ ·

  5. Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate

    Angewandte Chemie International Edition · 2021-09-15

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  6. Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate

    Angewandte Chemie · 2021-09-15

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  7. BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response

    Materials Today Physics · 2022-10-05

    Y. Long, X. Dong, Lilian Huang, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Guangtian Zou

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  8. SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence

    Inorganic Chemistry · 2022-10-20

    Ying Long, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  9. KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge

    Dalton Transactions · 2023-01-01

    Zhiyuan Zhang, Die Xu, Zhencheng Wu, Mei Hu, Xin Su, Yineng Huang

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  10. From Monofluorophosphates A2PO3F to Difluorophosphates APO2F2 (A = alkali metal): Design of a Potential Deep-Ultraviolet Nonlinear Optical Materials System with a Shortened Phase-Matching Wavelength

    Chemistry of Materials · 2023-07-06

    Wenqi Jin, Congwei Xie, Xueling Hou, Meng Cheng, Evgenii Tikhonov, Mengfan Wu, Shilie Pan, Zhihua Yang

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  11. Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence

    Inorganic Chemistry · 2023-10-17

    Yuhang Wang, Fu-Ying Li, Dong‐Xue Jiao, Qi Wei, Li Wei, Guo‐Yu Yang

    Read original paper ↗ ·

  12. Sr(NH2SO3)(NO3)·H2O: An Ultraviolet Nonlinear Optical Material Exhibiting Strong Second-Harmonic Generation Response and Sufficient Birefringence

    Inorganic Chemistry · 2023-10-20

    Xia Hao, Chensheng Lin, Min Luo, Ning Ye

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  13. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

    Materials Chemistry Frontiers · 2024-01-01

    Karishma Prasad, Vivian Nguyen, Bingheng Ji, Jasmine Quah, Danielle Goodwin, Jian Wang

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  14. K 2 MgMoP 2 O 10 and K 3 Mg 2 MoP 3 O 14 : two new molybdophosphates exhibiting different optical anisotropies induced by variable dimensionality of the anion framework

    Dalton Transactions · 2024-01-01

    Zhixia Gao, Qiuyuan Feng, Juanjuan Lu, Hong Lei Du

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  15. Novel antimony phosphates with enlarged birefringence induced by lone pair cations

    Dalton Transactions · 2024-01-01

    Mei Hu, Jialong Wang, Nuerbiye Tuerhong, Zhiyuan Zhang, Qun Jing, Zhaohui Chen, Yonglei Yang, Ming‐Hsien Lee

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  16. Syntheses, structures and characterization of noncentrosymmetric MZnPO 4 (M = K, NH 4 )

    Dalton Transactions · 2024-01-01

    Jiawei Zhao, Wei Wei, Meihui Chen, Yanna Chen, Donghai An

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  17. Synthesis and magnetic properties of two fluorophosphates K 2 Mn(PO 3 F)F 3 and Na 2 Mn(HPO 4 )F 3 with a S = 2 uniform spin chain structure

    CrystEngComm · 2024-01-01

    Qi Luo, Ningxia Li, Zhiying Zhao, Meiyan Cui, Zhangzhen He

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  18. The Birefringence Modulation in Short‐Wave Ultraviolet Sulfates with Functional π‐Conjugated Cations and Polymerized Heteroleptic Tetrahedral Anions

    Advanced Optical Materials · 2024-02-07

    Yanran Shang, Hongyuan Sha, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  19. Structure and optical properties of alkali rare-earth double phosphates of M3RE(PO4)2 (M = K, Rb; RE = Y, La, and Lu)

    Optical Materials · 2024-10-13

    Qun Jing, Mei Hu, Menglin Zhu, Jialong Wang, Haiming Duan, Zhaohui Chen

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  20. MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction

    The Journal of Physical Chemistry C · 2024-11-26

    Xue Bai, Xin Su, Wenqi Jin

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  21. Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

    Coordination Chemistry Reviews · 2024-11-27

    Fan Liu, Pifu Gong, Zheshuai Lin, Lei Kang

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  22. A tri-alkali/alkaline-earth metal fluorophosphate deep-ultraviolet birefringent crystal with coexisting PO 3 F and PO 2 F 2

    Inorganic Chemistry Frontiers · 2025-01-01

    Tao Ouyang, Ji Qi, Yanqiang Li, Shanshan Chen, Weiqi Huang, Zhiyong Bai, Sangen Zhao, Junhua Luo

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  23. Tailoring UV waveplate materials via rational assembly of functional motifs in scandium fluoride phosphate

    Chemical Communications · 2025-01-01

    Huijian Zhao, Conggang Li, Ning Ye, Zhanggui Hu

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  24. Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal

    Crystal Growth & Design · 2025-11-26

    Feng Xu, Mengya Qin, Bin Su, Chao He, Shaohua Yu, Yu Li, Rong Guo, Chan Zheng

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  25. Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions

    Journal of Solid State Chemistry · 2025-12-24

    Shuaikun Li, Yanhong Wang, Haibo Li, Hang Liu, Yun Lv, Hongcheng Lu

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  26. Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence

    Crystal Growth & Design · 2026-06-29

    Ying Long, Xuehua Dong, Lin Qi, Lindong Luan, Zichen Ren, Zhien Lin, Guohong Zou

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