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RESEARCH PAPER · Chemistry of Materials · 2020

Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O9

Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O9OriginalPolar polymorphism: α- and β-KCsWP 2 O 9 nonlinear optical materials with a strong second harmonic generation response25A new langbeinite-type phosphate K2GdHf(PO4)3: synthesis, crystal structure, band structure and luminescence properties9Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship24Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 254K 2 ZnMoP 2 O 10 : a novel nonlinear optical molybdophosphate with a strong second harmonic generation response and moderate birefringence24RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers9AZn(PO3)3 (A = K, Rb): Deep-Ultraviolet Nonlinear Optical Phosphates Derived from Synergy of a Unique [ZnO6] Octahedron and a [PO3]∞ Chain25Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)214A Lead Mixed Halide with Three Different Coordinated Anions and Strong Second‐Harmonic Generation Response10Two molybdenyl carbonates with different dimensional structures exhibiting huge differences in band gaps7A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations5KPb 3 ( o -C 5 H 4 NCOO) 2 Cl 5 : a brand-new stable lead chloride with good comprehensive nonlinear optical performance5Thermal stability and self-reduction of a new red phosphor NaMg(PO 3 ) 3 :Mn 2+17Phosphogermanate Crystal: A New Ultraviolet–Infrared Nonlinear Optical Crystal with Excellent Optical Performances16A deep ultraviolet transparent birefringent monofluorophosphate: Cd2.5(NH4)2(PO3F)3Cl ⋅ 2H2O4Crystallographic Insights into the Crystal Structure and Intrinsic Properties of Ca12Al14O33-Type Rb3LiZn2(MoO4)4Single Crystals1Two Metal Phosphate Nonlinear Optical Materials Simultaneously Exhibiting Ultraviolet Transparence and a Large Birefringence50Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal19Growth, Structure and Optical Characterization of Rb3Ti3P5O20 Single Crystal2Synthesis, characterization and theoretical calculations of four chiral schiff base materials for second harmonic generation applications7Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)24Single crystal growth and phase transition mechanism of KCsMoP 2 O 9 with efficient second harmonic generation via the emerging additional periodic phase technology4A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 331Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7Four New Sb‐based Orthophosphates: Cation Regulation to Investigate Diversified Structural Architecture1Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20BaMo3O10 Polymorphs with Tunable Symmetries and Properties3(NH4)3(H3O)Zn4(PO4)4: A nonlinear optical zinc orthophosphate crystal9Rational Design of a Niobium Tellurite Crystal Nb2Te3O11 Exhibiting Good Overall Infrared NLO Performance by Structural Genetic Engineering17Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18K 2 MgMoP 2 O 10 and K 3 Mg 2 MoP 3 O 14 : two new molybdophosphates exhibiting different optical anisotropies induced by variable dimensionality of the anion framework4Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer16The effect of co-substitution of heterovalent ions Ga 3+ and Sb 5+ on nonlinear optical properties of phosphate crystals0Electro-elastic characteristics of KCsMoP2O9 crystal: Exploiting strong piezoelectricity for guided wave transducer applications3[C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence10Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Design of true zero-order half-wave plates using KCsMoP2O9 crystal: A novel molybdophosphate material with extremely small birefringence3Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27Deep-ultraviolet nonlinear-optical crystals LiBePO 4 and BeP 2 O 6 synthesized by ionic potential modulation towards uniform arrangement of PO 4 groups5Four noncentrosymmetric molybdophosphates discovered by a chemical substitution strategy4Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5Three Deep-UV Phosphate Optical Materials with Interesting Structural Evolution0A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal1Ag(Te 2 O 3 )(PO 4 ): Linear and Nonlinear Optical Properties of a Noncentrosymmetric Phosphotellurite with P–O–Te Connection1K 6 Mo 8 PO 29 OH·H 2 O and K 6 Mo 5 P 2 O 23 ·7H 2 O: strongly distorted [MoO 6 ] octahedral groups effectively enhance birefringence0K 2 ZnMoP 2 O 10 : crystal growth, optical characterization, and structure–property insights into phase matching0K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response1Dimensionality Engineering of Fluorozirconium Phosphates for Deep-UV-Transparent Crystals with Enhanced Second-Harmonic Generation and Birefringence10

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  1. Polar polymorphism: α- and β-KCsWP 2 O 9 nonlinear optical materials with a strong second harmonic generation response

    Journal of Materials Chemistry C · 2020-01-01

    Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  2. A new langbeinite-type phosphate K2GdHf(PO4)3: synthesis, crystal structure, band structure and luminescence properties

    Acta Crystallographica Section C Structural Chemistry · 2020-07-22

    Hua Nan, Li Chen, Rui-Juan Zhang, Dan Zhao

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  3. Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship

    European Journal of Inorganic Chemistry · 2020-12-22

    Hongil Jo, Xinglong Chen, Hee‐Seung Lee, Kang Min Ok

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  4. Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Lei Wang, Hongmei Wang, Die Zhang, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  5. K 2 ZnMoP 2 O 10 : a novel nonlinear optical molybdophosphate with a strong second harmonic generation response and moderate birefringence

    Journal of Materials Chemistry C · 2021-01-01

    Haonan Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  6. RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers

    Dalton Transactions · 2021-01-01

    Rui Zhang, Xin Su, Jie Zhang, Mingyao Xiong, Yineng Huang

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  7. AZn(PO3)3 (A = K, Rb): Deep-Ultraviolet Nonlinear Optical Phosphates Derived from Synergy of a Unique [ZnO6] Octahedron and a [PO3]∞ Chain

    Crystal Growth & Design · 2021-03-04

    Tong Yu, Lin Xiong, Xiaomeng Liu, Yi‐Chang Yang, Zheshuai Lin, Li‐Ming Wu, Ling Chen

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  8. Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]

    Crystal Growth & Design · 2021-06-24

    Xiaoqing Jiang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  9. Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)2

    Crystal Growth & Design · 2021-09-17

    Yunqiao Guo, Die Zhang, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  10. A Lead Mixed Halide with Three Different Coordinated Anions and Strong Second‐Harmonic Generation Response

    Chemistry - A European Journal · 2021-10-15

    Qirui Shui, Ruibiao Fu, Ziqi Zhou, Zuju Ma, Hong‐Xin Tang, Xin‐Tao Wu

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  11. Two molybdenyl carbonates with different dimensional structures exhibiting huge differences in band gaps

    Inorganic Chemistry Frontiers · 2021-11-26

    Yunqiao Guo, Yalan Deng, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  12. A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations

    Dalton Transactions · 2021-12-13

    Maierhaba Abudoureheman, Juanjuan Zheng, Peng Wang, Bo Wei, Zhiyong Guo, Zhaohui Chen, Yanna Chen

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  13. KPb 3 ( o -C 5 H 4 NCOO) 2 Cl 5 : a brand-new stable lead chloride with good comprehensive nonlinear optical performance

    Inorganic Chemistry Frontiers · 2022-01-01

    Wen-Xiu Bao, Ziqi Zhou, Hong‐Xin Tang, Ruibiao Fu, Zuju Ma, Xin‐Tao Wu

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  14. Thermal stability and self-reduction of a new red phosphor NaMg(PO 3 ) 3 :Mn 2+

    CrystEngComm · 2022-01-01

    Shuang-Yin Zhu, Dan Zhao, Shao-Jie Dai, Ruijuan Zhang, Lin‐Ying Shi

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  15. Phosphogermanate Crystal: A New Ultraviolet–Infrared Nonlinear Optical Crystal with Excellent Optical Performances

    ACS Applied Materials & Interfaces · 2022-02-16

    Hongyuan Sha, Zheyao Xiong, Junxin Xu, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long, Ying Liu

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  16. A deep ultraviolet transparent birefringent monofluorophosphate: Cd2.5(NH4)2(PO3F)3Cl ⋅ 2H2O

    Zeitschrift für anorganische und allgemeine Chemie · 2022-04-01

    Xinrui Yang, Xin Liu, Ling Chen, Li‐Ming Wu

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  17. Crystallographic Insights into the Crystal Structure and Intrinsic Properties of Ca12Al14O33-Type Rb3LiZn2(MoO4)4Single Crystals

    Inorganic Chemistry · 2022-05-23

    Wenli Zhao, Lili Li, Tao Han, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  18. Two Metal Phosphate Nonlinear Optical Materials Simultaneously Exhibiting Ultraviolet Transparence and a Large Birefringence

    Chemistry of Materials · 2022-06-24

    Jiarong Lv, Yanyan Qian, Qun Jing, Xinmei Wang, Ming‐Hsien Lee, Zhaohui Chen

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  19. Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal

    Inorganic Chemistry · 2022-07-13

    Jinmiao Jiao, Fei Liang, Conggang Li, Tao Han, Wenli Zhao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  20. Growth, Structure and Optical Characterization of Rb3Ti3P5O20 Single Crystal

    Materials · 2022-08-03

    Jianfu Zhao, Pengfei Zhu, Zhenyan Wang, Li Ai, Xiulan Duan, Fapeng Yu

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  21. Synthesis, characterization and theoretical calculations of four chiral schiff base materials for second harmonic generation applications

    Journal of Molecular Structure · 2022-08-05

    Weiqiang Tan, Jiahui Gao, Jing Guan, Xuejun Bi, Yizhen Tang, Chunying Zheng, Tingliang Yan, Chenglong Zhang

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  22. Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)

    Inorganic Chemistry · 2022-09-21

    Hedi Yang, Shenghua Zhou, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  23. Single crystal growth and phase transition mechanism of KCsMoP 2 O 9 with efficient second harmonic generation via the emerging additional periodic phase technology

    Journal of Materials Chemistry C · 2023-01-01

    Mengdi Fan, Guangda Wu, Lili Li, Fapeng Yu, Chunhui Wang, Xiufeng Cheng, Xian Zhao

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  24. A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 3

    Small · 2023-02-09

    Zhiyong Bai, Jihyun Lee, Heewon Kim, Yunseung Kuk, Myung‐Ho Choi, Chun‐Li Hu, Kang Min Ok

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  25. Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response

    Chinese Journal of Structural Chemistry · 2023-02-13

    Boxuan Zhang, Zhaohui Chen

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  26. Four New Sb‐based Orthophosphates: Cation Regulation to Investigate Diversified Structural Architecture

    Chemistry - A European Journal · 2023-04-10

    Hongyu Huang, Na Li, Ruixin Zhang, Xinmei Wang, Xianmeng He, Lei Wu, Lili Liu, Qun Jing, Zhaohui Chen

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  27. Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions

    ACS Materials Letters · 2023-05-08

    Jiale Chen, Pengcheng Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  28. BaMo3O10 Polymorphs with Tunable Symmetries and Properties

    Inorganic Chemistry · 2023-06-20

    Xiangyu Long, Ran An, Yan An Lv, Xueyan Wu, Miriding Mutailipu

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  29. (NH4)3(H3O)Zn4(PO4)4: A nonlinear optical zinc orthophosphate crystal

    Journal of Solid State Chemistry · 2023-06-22

    Yueling Sun, Gang-Xiang Liu, Yi‐Lei Lv, Liang Ma, Wen‐Dong Yao, Ru‐Ling Tang

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  30. Rational Design of a Niobium Tellurite Crystal Nb2Te3O11 Exhibiting Good Overall Infrared NLO Performance by Structural Genetic Engineering

    Inorganic Chemistry · 2023-10-12

    Tinghui Zhang, Jinmiao Jiao, Wenli Zhao, Fulei Wang, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  31. Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks

    Inorganic Chemistry Frontiers · 2024-01-01

    Miao‐Bin Xu, Jin Chen, Huai‐Yu Wu, Jiajia Li, Ning Yu, Mo-Fan Zhuo, Fei‐Fei Mao, Ke‐Zhao Du

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  32. K 2 MgMoP 2 O 10 and K 3 Mg 2 MoP 3 O 14 : two new molybdophosphates exhibiting different optical anisotropies induced by variable dimensionality of the anion framework

    Dalton Transactions · 2024-01-01

    Zhixia Gao, Qiuyuan Feng, Juanjuan Lu, Hong Lei Du

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  33. Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer

    Inorganic Chemistry Frontiers · 2024-01-01

    Qiao Xia, Xingxing Jiang, Qi Lu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Kazuyuki Tatsumi, Chi Zhang

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  34. The effect of co-substitution of heterovalent ions Ga 3+ and Sb 5+ on nonlinear optical properties of phosphate crystals

    Materials Advances · 2024-01-01

    Yutong Zhang, Biao Wang, Xinhui Jia, Xi Chong, Jing Li, Bingbing Zhang, Jiyang Wang

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  35. Electro-elastic characteristics of KCsMoP2O9 crystal: Exploiting strong piezoelectricity for guided wave transducer applications

    Journal of Materiomics · 2024-02-09

    Mengdi Fan, Guangda Wu, Huaiyu Wu, Nicholas Garcia, Xiaoning Jiang, Shujun J. Zhang, Xian Zhao, Fapeng Yu

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  36. [C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence

    Journal of Solid State Chemistry · 2024-06-12

    Yang Zhang, Yang Zhang, Meng-Han Lv, Shu‐Fang Li, Hongbo Huang, Bingbing Zhang, Dong Yan

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  37. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  38. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

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  39. Design of true zero-order half-wave plates using KCsMoP2O9 crystal: A novel molybdophosphate material with extremely small birefringence

    Optical Materials · 2024-10-03

    Mengdi Fan, Guangda Wu, Hongkai Ren, Chunhui Wang, Fapeng Yu, Xian Zhao

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  40. Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

    Coordination Chemistry Reviews · 2024-11-27

    Fan Liu, Pifu Gong, Zheshuai Lin, Lei Kang

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  41. Deep-ultraviolet nonlinear-optical crystals LiBePO 4 and BeP 2 O 6 synthesized by ionic potential modulation towards uniform arrangement of PO 4 groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Xia Zhang, Jian‐Qiang Shen, Hong-Xiao Lv, Peng-Hui Guo, Yi-Gang Chen, Chun‐Li Hu, Xian‐Ming Zhang

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  42. Four noncentrosymmetric molybdophosphates discovered by a chemical substitution strategy

    Dalton Transactions · 2025-01-01

    Zhixia Gao, Ke Li, Hong Du, Tuohetijiang Baiheti

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  43. Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )

    Inorganic Chemistry Frontiers · 2025-01-01

    Jingdong Yan, Xiangran Kong, Shichao Cheng, Tao Liu, Hongwei Leng, Yunfei Shang, Zuotao Lei, Chunhui Yang

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  44. Three Deep-UV Phosphate Optical Materials with Interesting Structural Evolution

    Crystal Growth & Design · 2025-06-25

    Xinglong Liu, Lei Wu, Hongheng Chen, Menglin Zhu, Yi Huang, Qun Jing, Xuebin Yu, Zhaohui Chen

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  45. A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response

    Inorganic Chemistry · 2025-08-11

    Hanjing Huang, Xianghao Kong, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  46. Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal

    Crystal Growth & Design · 2025-11-26

    Feng Xu, Mengya Qin, Bin Su, Chao He, Shaohua Yu, Yu Li, Rong Guo, Chan Zheng

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  47. Ag(Te 2 O 3 )(PO 4 ): Linear and Nonlinear Optical Properties of a Noncentrosymmetric Phosphotellurite with P–O–Te Connection

    Inorganic Chemistry · 2025-12-03

    Wei Chen, Zi-Xuan Zhao, Chao He, Mengjiao Xu, Hui‐Yan Zhao, Qi Wei, Guo‐Ming Wang

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  48. K 6 Mo 8 PO 29 OH·H 2 O and K 6 Mo 5 P 2 O 23 ·7H 2 O: strongly distorted [MoO 6 ] octahedral groups effectively enhance birefringence

    Materials Chemistry Frontiers · 2025-12-09

    Jianlong Huang, Wenhu Wang, Juanjuan Lu, Feng Yu, Jian Wei Han

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  49. K 2 ZnMoP 2 O 10 : crystal growth, optical characterization, and structure–property insights into phase matching

    CrystEngComm · 2026-01-01

    Youbin Wang, Haonan Liu, Yujie Zhang, Hongping Wu, Hongping Wu, Zhanggui Hu

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  50. K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-03-12

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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