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RESEARCH PAPER · Chemistry of Materials · 2011

Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be2B2O6F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)

Hongwei Huang, Jiyong Yao, Zheshuai Lin, Xiaoyang Wang, Ran He, Wenjiao Yao, Naixia Zhai, Chuangtian Chen

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Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be2B2O6F (M═Na, M′═Ca; M═ K, M′═Ca, Sr)OriginalK6Li3Sc2B15O30: A new nonlinear optical crystal with a short absorption edge50ChemInform Abstract: Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be2B2O6F (M: Na, M′: Ca; M: K, M′: Ca, Sr).0Exploratory Investigation of New SHG Materials Based on Galloborates46LaBeB3O7: a new phase-matchable nonlinear optical crystal exclusively containing the tetrahedral XO4 (X = B and Be) anionic groups30Growth, crystal structure and optical properties of a new layered fluorine beryllium borate, Sr0.23Ca0.77Na2Be2B2O6F25Synthesis, crystal structure and optical properties of a new beryllium borate, CsBe4(BO3)313New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Sr3BeB6O13: A New Borate in the SrO/BeO/B2O3 System with Novel Tri-Six-Membered Ring (BeB6O15)10– Building Block22Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C4H4O5)27Cs2GeB4O9: a New Second-Order Nonlinear-Optical Crystal139Exploration of a new compound in the M–B–O–X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br19Bandgaps in the deep ultraviolet borate crystals: Prediction and improvement55Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O14Sr8MgB18O36: a New Alkaline-Earth Borate with a Novel Zero-Dimensional (B18O36)18– Anion Ring49New alkali-metal bidentate borate–malate NaB(DL-C4H4O5)2 and CsB(DL-C4H4O5)2⋅H2O: Effect of cations on the framework structures and macroscopic centricities10Two Novel Bi-Based Borate Photocatalysts: Crystal Structure, Electronic Structure, Photoelectrochemical Properties, and Photocatalytic Activity under Simulated Solar Light Irradiation373Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53Prospects for Fluoride Carbonate Nonlinear Optical Crystals in the UV and Deep-UV Regions116Deep-Ultraviolet Nonlinear Optical Materials: Na2Be4B4O11 and LiNa5Be12B12O33249Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response61Deep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)459Area negative thermal expansion in a beryllium borate LiBeBO 3 with edge sharing tetrahedra43Ba18F18In8S21 and Ba9F10In4S10: new kind of mixed anion compounds with the novel low-dimensional structure9Ca 3 Be 6 B 5 O 16 F: the first alkaline-earth beryllium borate with fluorine anions11Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency100A novel Bi-based phosphomolybdate photocatalyst K2Bi(PO4)(MoO4): Crystal structure, electronic structure and photocatalytic activity22SrBeB2O5: Growth, crystal structure and optical properties13ReBe2B5O11 (Re = Y, Gd): Rare-Earth Beryllium Borates as Deep-Ultraviolet Nonlinear-Optical Materials50Syntheses, characterization and nonlinear optical properties of a bismuth subcarbonate Bi2O2CO363A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation121Analysis of Deep‐UV Nonlinear Optical Borates: Approaching the End213KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups36Sr8MB18O36 (M = Zn or Cd): Design and Synthesis of Two New Borates with a Special Ratio of 8:16First-principles materials applications and design of nonlinear optical crystals259Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications462PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates43Y(IO3)3 as a Novel Photocatalyst: Synthesis, Characterization, and Highly Efficient Photocatalytic Activity44Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate ∞2[Be8B16O40F2] Layer Intrabridged by [B12O24] Groups20An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property94Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50Anomalous second-harmonic generation response in SrBPO 5 and BaBPO 541BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions36Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13Simulated pressure-induced blue-shift of phase-matching region and nonlinear optical mechanism for K3B6O10X (X = Cl, Br)167Beryllium-Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep-Ultraviolet Nonlinear Optical Crystal270Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response74First-Principles Evaluation of the Alkali and/or Alkaline Earth Beryllium Borates in Deep Ultraviolet Nonlinear Optical Applications131Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 2018Solvothermal Synthesis and Structure of Two New Borates Containing [B7O9(OH)5]2− and [B12O18(OH)6]6− Clusters9Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340“XA 6 ” octahedra influencing the arrangement of anionic groups and optical properties in inverse-perovskite [B 6 O 10 ]XA 3 (X = Cl, Br; A = alkali metal)19Alkali metal–alkaline earth metal borate crystal LiBa 3 (OH)(B 9 O 16 )[B(OH) 4 ] as a new deep-UV nonlinear optical material34Facile growth of centimeter-order, highly crystalline ZnWO 4 single crystals by the flux evaporation technique using molten NaCl8Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates9Influence of an oxygen vacancy on the electronic structure of the asymmetric mixed borate–carbonate Pb 7 O(OH) 3 (CO 3 ) 3 (BO 3 )3K 2 Sn 2 ZnSe 6 , Na 2 Ge 2 ZnSe 6 , and Na 2 In 2 GeSe 6 : a new series of quaternary selenides with intriguing structural diversity and nonlinear optical properties32KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109M 2 Ca 3 B 16 O 28 (M = Rb, Cs): structures analogous to SBBO with three-dimensional open-framework layers10New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7Pb 2 Bi 2 GaB 3 O 11 , a new congruent-melting galloborate containing two types of asymmetric cations with a moderate birefringence5Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem256Crystal growth and optical characteristics of beryllium-free polyphosphate, KLa(PO3)4, a possible deep-ultraviolet nonlinear optical crystal101Trigonal Planar [HgSe3]4– Unit: A New Kind of Basic Functional Group in IR Nonlinear Optical Materials with Large Susceptibility and Physicochemical Stability196Deep Ultraviolet Nonlinear Optical Materials644K5Ba10(BO3)8F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure43DFT Based Theoretical Study about the Contributions of Fluorine to Nonlinear Optical Properties in Borate Fluoride Crystals27Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Deep-Ultraviolet Transparent Cs 2 LiPO 4 Exhibits an Unprecedented Second Harmonic Generation160Progress in discovery and structural design of color conversion phosphors for LEDs1095Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates31A review of recent theoretical studies in nonlinear crystals: towards the design of new materials19Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units33Beryllium-Free KBBF Family of Nonlinear-Optical Crystals: AZn2BO3X2 (A = Na, K, Rb; X = Cl, Br)71AZn2BO3X2(A = K, Rb, NH4; X = Cl, Br): New Members of KBBF Family Exhibiting Large SHG Response and the Enhancement of Layer Interaction by Modified Structures179ACaBO 3 (A = Cs, Rb): two new cubic borates with isolated BO 3 groups24LiSr 3 Be 3 B 3 O 9 F 4 : a new ultraviolet nonlinear optical crystal for fourth-harmonic generation of Nd:YAG lasers19Syntheses, crystal structures and characterization of three alkaline metal borates7The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Facile Syntheses of Ba2[B4O7(OH)2] and Na[B5O7(OH)2](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet50Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications238A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures36Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals58Chemistry-Inspired Adaptable Framework Structures368The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density14Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides21A New KBBF-Family Nonlinear Optical Material with Strong Interlayer Bonding51Structurally stable borate as a UV nonlinear optical material20Rational Design of Deep-Ultraviolet Nonlinear Optical Materials in Fluorooxoborates: Toward Optimal Planar Configuration157Structural Design of Two Fluorine–Beryllium Borates BaMBe2(BO3)2F2 (M = Mg, Ca) Containing Flexible Two-Dimensional [Be3B3O6F3]∞ Single Layers without Structural Instability Problems14Ba5Zn4(BO3)6: A Nonlinear-Optical Material with Reinforced Interlayer Connections and Large Second-Harmonic-Generation Response33Two KBBF-Type Beryllium Borates MBe2B2O6 (M = Sr, Ba) with a Three-Dimensional (Be2B2O6)∞ Network8Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O7730The Next‐Generation of Nonlinear Optical Materials: Rb3Ba3Li2Al4B6O20F—Synthesis, Characterization, and Crystal Growth88MBaYB 6 O 12 (M = Rb, Cs): two new rare-earth borates with large birefringence and short ultraviolet cutoff edges42A beryllium-free deep-UV nonlinear optical material CsNaMgP 2 O 7 with honeycomb-like topological layers53Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations15BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance16Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response130Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13K 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block19LiCs 2 La(BO 3 ) 2 and Li 3 K 9 La 3 (BO 3 ) 7 : new mixed alkali metal lanthanum borates with three-dimensional open frameworks and short cut-off edges10Pb 2 BO 3 Br: a novel nonlinear optical lead borate bromine with a KBBF-type structure exhibiting strong nonlinear optical response113LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge20SrB 5 O 7 F 3 Functionalized with [B 5 O 9 F 3 ] 6− Chromophores: Accelerating the Rational Design of Deep‐Ultraviolet Nonlinear Optical Materials738SrB5O7F3 Functionalized with [B5O9F3]6− Chromophores: Accelerating the Rational Design of Deep‐Ultraviolet Nonlinear Optical Materials116Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals258Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications18The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups195Electronic, bonding, linear, and nonlinear optical properties of Na2MGe2Q6 (M=Cd, Zn, Hg; Q=S, Se), Na2ZnSi2S6, and Na2ZnSn2S6 two metal-mixed chalcogenide compounds: Insights from an ab initio study21Deep‐Ultraviolet Nonlinear Optical Crystal Cs2Al2(B3O6)2O: A Benign Member of the Sr2Be2(BO3)2O Family with [Al2(B3O6)2O]2− Double Layers70A strategy for optical properties investigation in ABe 2 BO 3 F 2 (A=K, Rb, Cs) using finite field methods12Computer-Assisted Design of a Superior Be 2 BO 3 F Deep-Ultraviolet Nonlinear-Optical Material42MIMIIP3O9 (MI = Rb, MII = Cd, Mg, Ca; MI = Cs, MII = Pb, Sr; MI = K, MII = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties35Second-order nonlinear optical crystals with mixed anions250Removal of A-Site Alkali and Alkaline Earth Metal Cations in KBe2BO3F2-Type Layered Structures To Enhance the Deep-Ultraviolet Nonlinear Optical Capability47Two new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method6Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)23The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge17Na 3 B 7 O 11 F 2 : a new sodium-rich fluorooxoborate with a unique [B 14 O 24 F 4 ] ring and a short ultraviolet absorption edge27Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66An energy band engineering design to enlarge the band gap of KTiOPO 4 (KTP)-type sulfates via aliovalent substitution66Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F27Two alkali calcium borates exhibiting second harmonic generation and deep-UV cutoff edges3Triangular Rare-Earth Lattice Materials RbBaR(BO3)2 (R = Y, Gd–Yb) and Comparison to the KBaR(BO3)2 Analogs42Co-existence phenomenon of Ce3+/Ce4+ and Tb3+ in Ce/Tb co-doped Zn2(BO3)(OH)0.75F0.25 phosphor: Luminescence and energy transfer24CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure87CsSbF2SO4: An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO4 (KTP)‐type Structure432Heteroanionic Materials by Design: Progress Toward Targeted Properties237Deep-Ultraviolet Mixed-Alkali-Metal Borates with Induced Enlarged Birefringence Derived from the Structure Rearrangement of the LiB3O545β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Centrosymmetric Rb2Mg3(SO4)4 and non-centrosymmetric Cs2Mg3(SO4)4 with a phase-matching nonlinear optical response35Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20K5B19O31: A Deep‐Ultraviolet Congruent Melting Compound6Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)18Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design303Synthesis, structure and characterization of three new Mg-containing phosphates with deep-UV cut-off edges9KNiB4O6F3: A Layered Fluorooxoborate with Charge‐Oriented Ordering18PbB5O7F3: A High-Performing Short-Wavelength Nonlinear Optical Material120Two New Ferroborates with Three‐Dimensional Framework and Wide Transmittance Window2Synthesis, characterizations and theoretical analysis of a noncentrosymmetric sulfate8Hydrogen-Bond-Assisted Reinforcement of Interlayer Connections in Zn2BO3X·H2O (X = Cl, Br): Two UV Nonlinear Optical Crystals with KBBF-Type Structure9Deep-ultraviolet nonlinear optical crystals by design: A computer-aided modeling blueprint from first principles45Rational Design of the Metal‐Free KBe 2 BO 3 F 2 ⋅(KBBF) Family Member C(NH 2 ) 3 SO 3 F with Ultraviolet Optical Nonlinearity201

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  1. K6Li3Sc2B15O30: A new nonlinear optical crystal with a short absorption edge

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  2. ChemInform Abstract: Molecular Engineering Design to Resolve the Layering Habit and Polymorphism Problems in Deep UV NLO Crystals: New Structures in MM′Be2B2O6F (M: Na, M′: Ca; M: K, M′: Ca, Sr).

    ChemInform · 2012-02-02

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  3. Exploratory Investigation of New SHG Materials Based on Galloborates

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  4. LaBeB3O7: a new phase-matchable nonlinear optical crystal exclusively containing the tetrahedral XO4 (X = B and Be) anionic groups

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  5. Growth, crystal structure and optical properties of a new layered fluorine beryllium borate, Sr0.23Ca0.77Na2Be2B2O6F2

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  6. Synthesis, crystal structure and optical properties of a new beryllium borate, CsBe4(BO3)3

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  7. New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F3

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  8. Sr3BeB6O13: A New Borate in the SrO/BeO/B2O3 System with Novel Tri-Six-Membered Ring (BeB6O15)10– Building Block

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  9. Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C4H4O5)2

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  10. Cs2GeB4O9: a New Second-Order Nonlinear-Optical Crystal

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  11. Exploration of a new compound in the M–B–O–X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br

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  12. Bandgaps in the deep ultraviolet borate crystals: Prediction and improvement

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  13. Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O

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  14. Sr8MgB18O36: a New Alkaline-Earth Borate with a Novel Zero-Dimensional (B18O36)18– Anion Ring

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  15. New alkali-metal bidentate borate–malate NaB(DL-C4H4O5)2 and CsB(DL-C4H4O5)2⋅H2O: Effect of cations on the framework structures and macroscopic centricities

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  16. Two Novel Bi-Based Borate Photocatalysts: Crystal Structure, Electronic Structure, Photoelectrochemical Properties, and Photocatalytic Activity under Simulated Solar Light Irradiation

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  17. Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block

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  18. Prospects for Fluoride Carbonate Nonlinear Optical Crystals in the UV and Deep-UV Regions

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  19. Deep-Ultraviolet Nonlinear Optical Materials: Na2Be4B4O11 and LiNa5Be12B12O33

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  20. Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response

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  21. Deep-Ultraviolet Nonlinear Optical Crystals: Ba3P3O10X (X = Cl, Br)

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  22. Area negative thermal expansion in a beryllium borate LiBeBO 3 with edge sharing tetrahedra

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  23. Ba18F18In8S21 and Ba9F10In4S10: new kind of mixed anion compounds with the novel low-dimensional structure

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  24. Ca 3 Be 6 B 5 O 16 F: the first alkaline-earth beryllium borate with fluorine anions

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  25. Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency

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  26. A novel Bi-based phosphomolybdate photocatalyst K2Bi(PO4)(MoO4): Crystal structure, electronic structure and photocatalytic activity

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  27. SrBeB2O5: Growth, crystal structure and optical properties

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  28. ReBe2B5O11 (Re = Y, Gd): Rare-Earth Beryllium Borates as Deep-Ultraviolet Nonlinear-Optical Materials

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  29. Syntheses, characterization and nonlinear optical properties of a bismuth subcarbonate Bi2O2CO3

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    Hongwei Huang, Na Tian, Shifeng Jin, Yihe Zhang, Shuobo Wang

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  30. A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation

    Inorganic Chemistry · 2014-02-10

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  31. Analysis of Deep‐UV Nonlinear Optical Borates: Approaching the End

    Advanced Optical Materials · 2014-02-28

    Wenjiao Yao, Ran He, Xiaoyang Wang, Zheshuai Lin, Chuangtian Chen

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  32. KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups

    Inorganic Chemistry · 2014-03-25

    Chao Zhang Huang, Jian‐Han Zhang, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

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  33. Sr8MB18O36 (M = Zn or Cd): Design and Synthesis of Two New Borates with a Special Ratio of 8:1

    Chemistry Letters · 2014-05-02

    Xingwen Zhang, Hongwei Yu, Hongping Wu, Shilie Pan, Lili Liu, Anqing Jiao, Chunyan Bai

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  34. First-principles materials applications and design of nonlinear optical crystals

    Journal of Physics D Applied Physics · 2014-05-23

    Zheshuai Lin, Xingxing Jiang, Lei Kang, Pifu Gong, Siyang Luo, Ming‐Hsien Lee

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  35. Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications

    Nature Communications · 2014-05-29

    Sangen Zhao, Pifu Gong, Lei Bai, Xiang Xu, Shuquan Zhang, Zhihua Sun, Zheshuai Lin, Maochun Hong, Chuangtian Chen, Junhua Luo

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  36. PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates

    CrystEngComm · 2014-06-12

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  37. Y(IO3)3 as a Novel Photocatalyst: Synthesis, Characterization, and Highly Efficient Photocatalytic Activity

    Inorganic Chemistry · 2014-07-24

    Hongwei Huang, Ying He, Ran He, Zheshuai Lin, Yihe Zhang, Shichao Wang

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  38. Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate ∞2[Be8B16O40F2] Layer Intrabridged by [B12O24] Groups

    Inorganic Chemistry · 2014-08-01

    Siyang Luo, Wenjiao Yao, Pifu Gong, Jiyong Yao, Zheshuai Lin, Chuangtian Chen

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  39. An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property

    Inorganic Chemistry · 2014-10-15

    Qi Wei, Jian‐Wen Cheng, Chao He, Guo‐Yu Yang

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  40. Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method

    Inorganic Chemistry · 2014-12-01

    Hongping Wu, Hongwei Yu, Qiang Bian, Zhihua Yang, Shujuan Han, Shilie Pan

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  41. Anomalous second-harmonic generation response in SrBPO 5 and BaBPO 5

    Journal of Materials Chemistry C · 2014-12-09

    Bing‐Hua Lei, Qun Jing, Zhihua Yang, Bingbing Zhang, Shilie Pan

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  42. BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions

    Journal of Materials Chemistry C · 2015-01-01

    Lei Geng, Qiang Li, Chang‐Yu Meng, Kai Dai, Hong‐Yan Lu, Chensheng Lin, Wen‐Dan Cheng

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  43. Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 6

    Physical Chemistry Chemical Physics · 2015-01-01

    Yun Mo Yang, Xin Su, Shilie Pan, Zhihua Yang

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  44. Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra

    RSC Advances · 2015-01-01

    Chunyan Bai, Shujuan Han, Shilie Pan, Bingbing Zhang, Yun Mo Yang, Lin Li, Zhihua Yang

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  45. Simulated pressure-induced blue-shift of phase-matching region and nonlinear optical mechanism for K3B6O10X (X = Cl, Br)

    Applied Physics Letters · 2015-01-19

    Bingbing Zhang, Ming‐Hsien Lee, Zhihua Yang, Qun Jing, Shilie Pan, Min Zhang, Hongping Wu, Xin Su, Chengshun Li

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  46. Beryllium-Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep-Ultraviolet Nonlinear Optical Crystal

    Journal of the American Chemical Society · 2015-01-30

    Sangen Zhao, Pifu Gong, Siyang Luo, Sijie Liu, Lina Li, Muhammad Adnan Asghar, Tariq Mehmood Khan, Maochun Hong, Zheshuai Lin, Junhua Luo

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  47. Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7

    Inorganic Chemistry · 2015-03-05

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  48. Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response

    Inorganic Chemistry · 2015-03-31

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  49. First-Principles Evaluation of the Alkali and/or Alkaline Earth Beryllium Borates in Deep Ultraviolet Nonlinear Optical Applications

    ACS Photonics · 2015-07-27

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  50. Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 20

    Dalton Transactions · 2015-11-09

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