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RESEARCH PAPER · Inorganic Chemistry · 2012

Exploratory Investigation of New SHG Materials Based on Galloborates

Ting Hu, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao, Thomas C. W. Mak

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Exploratory Investigation of New SHG Materials Based on GalloboratesOriginalChemInform Abstract: Exploratory Investigation of New SHG Materials Based on Galloborates.0An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F42Growth, crystal structure and optical properties of a new layered fluorine beryllium borate, Sr0.23Ca0.77Na2Be2B2O6F25Synthesis, crystal structure and optical properties of a new beryllium borate, CsBe4(BO3)313New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene‐Like Borate Double Layer38Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C4H4O5)27Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process38Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O14New alkali-metal bidentate borate–malate NaB(DL-C4H4O5)2 and CsB(DL-C4H4O5)2⋅H2O: Effect of cations on the framework structures and macroscopic centricities10Incorporating [GaB 4 O 11 (OH)] 8− clusters to construct luminescent galloborate with open-framework layers18β-BaGa[B 4 O 8 (OH)](H 2 O) and Ba 4 Ga[B 10 O 18 (OH) 5 ](H 2 O): new barium galloborates featuring unusual [B 4 O 8 (OH)] 5− and [B 10 O 18 (OH) 5 ] 11− clusters26KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups36PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates43Recent advances on second-order NLO materials based on metal iodates328Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340The crystal design of polar one-dimensional hydrogen-bonded copper coordination complexes5N→Sn-Coordinated Stannaoxidoborates Containing a SnB4O6 Unit8NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies25Structure modulations in nonlinear optical (NLO) materials Cs2TB4O9(T= Ge, Si)14Ln2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 (Ln = Y, Sm, Eu, Gd, Dy): A Series of Lanthanide Galloborates Decorated by Acetate Anions26Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks4Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes44Molecular Group 13 Metallaborates Derived from M–O–M Cleavage Promoted by BH36Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2106Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate34Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics495Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics67Syntheses, Crystal Structures and Properties of Two Novel Mixed Anion Hybrids with Formulas of Pb 6 O 2 (BO 3 ) 2 (C 2 O 4 ) and Pb 4 (CO 3 ) 2 (C 2 O 4 )(OH) 21Second-order nonlinear optical crystals with mixed anions250Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties23Growth, Crystal Structures, and Characteristics of Li 5 ASrMB 12 O 24 (A = Zn, Mg; M = Al, Ga) with [MB 12 O 24 ] Frameworks12Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties24Synthesis, Characterization and Optical Properties of Two Metal Borates Containing Two Types of Oxoboron Clusters2A Way for Derived Carbon Materials by Thermal Etching Hybrid Borate for Electrochemical CO2 Reduction15From [B 6 O 13 ] 8− to [GaB 5 O 13 ] 8− to [Ga{B 5 O 9 (OH)}{BO(OH) 2 }] 2− : synthesis, structure and nonlinear optical properties of new metal borates10Synthesis and optical properties of N→Ga coordinated gallium boroxines6BO3 Triangle and B@Zn2O3 Cationic Layer in the Structure of the Hybrid Zinc Acetate Borate [ZnAc]·[ZnBO3]9Recent Advances in Crystalline Oxidopolyborate Complexes of d-Block or p-Block Metals: Structural Aspects, Syntheses, and Physical Properties16La2B3O4(OH)3(SO4)2: A new rare-earth borate-sulfate with second-harmonic generation response5KCs2[GaB5O10](OH): A Zeolitic Galloborate Framework with a Nonlinear Optical Property13Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8Synthesis, Characterization and Optical Properties of Two Novel Metal Borates1[H2dab][GaB5O10]: an Acentric Galloborate with a 4-Connected Uninodal Framework6

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  1. ChemInform Abstract: Exploratory Investigation of New SHG Materials Based on Galloborates.

    ChemInform · 2012-10-18

    Ting Hu, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao, Thomas C. W. Mak

    Read original paper ↗ ·

  2. An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }

    Dalton Transactions · 2012-11-15

    Han‐Rui Tian, Wenhua Wang, Xiaoping Zhang, Yun‐Long Feng, Jian‐Wen Cheng

    Read original paper ↗ ·

  3. Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F

    CrystEngComm · 2013-01-01

    Guohong Zou, Liyuan Zhang, Ning Ye

    Read original paper ↗ ·

  4. Growth, crystal structure and optical properties of a new layered fluorine beryllium borate, Sr0.23Ca0.77Na2Be2B2O6F2

    Journal of Alloys and Compounds · 2013-01-24

    Hongwei Huang, Wenjiao Yao, Xiaoyang Wang, Naixia Zhai, Chuangtian Chen

    Read original paper ↗ ·

  5. Synthesis, crystal structure and optical properties of a new beryllium borate, CsBe4(BO3)3

    Solid State Sciences · 2013-02-01

    Hongwei Huang, Wenjiao Yao, Ran He, Chuangtian Chen, Xiaoyang Wang, Yihe Zhang

    Read original paper ↗ ·

  6. New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F3

    Inorganic Chemistry · 2013-02-08

    T. Thao Tran, P. Shiv Halasyamani

    Read original paper ↗ ·

  7. Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene‐Like Borate Double Layer

    Chemistry - A European Journal · 2013-04-29

    Xiaoyu Dong, Hongping Wu, Yunjing Shi, Hongwei Yu, Zhihua Yang, Bingbing Zhang, Zhaohui Chen, Yun Mo Yang, Zhenjun Huang, Shilie Pan, Zhongxiang Zhou

    Read original paper ↗ ·

  8. Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C4H4O5)2

    Materials Research Bulletin · 2013-05-04

    Hongwei Huang, Wenjiao Yao, Ying He, Na Tian, Chuangtian Chen, Yihe Zhang

    Read original paper ↗ ·

  9. Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process

    Inorganic Chemistry · 2013-05-10

    Han‐Rui Tian, Wenhua Wang, Yan‐E Gao, Tingting Deng, Jiaying Wang, Yun‐Long Feng, Jian‐Wen Cheng

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  10. Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O

    Journal of Crystal Growth · 2013-06-21

    Hongwei Huang, Ran He, Wenjiao Yao, Zheshuai Lin, Chuangtian Chen, Yihe Zhang

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  11. New alkali-metal bidentate borate–malate NaB(DL-C4H4O5)2 and CsB(DL-C4H4O5)2⋅H2O: Effect of cations on the framework structures and macroscopic centricities

    Journal of Alloys and Compounds · 2013-08-21

    Hongwei Huang, Wenjiao Yao, Zheshuai Lin, Ying He, Na Tian, Chuangtian Chen, Yihe Zhang

    Read original paper ↗ ·

  12. Incorporating [GaB 4 O 11 (OH)] 8− clusters to construct luminescent galloborate with open-framework layers

    CrystEngComm · 2014-01-01

    Tingting Deng, Yan‐E Gao, Lixia Zhang, Xiang-Yu Gu, Han‐Rui Tian, Yi Liu, Yun‐Long Feng, Jian‐Wen Cheng

    Read original paper ↗ ·

  13. β-BaGa[B 4 O 8 (OH)](H 2 O) and Ba 4 Ga[B 10 O 18 (OH) 5 ](H 2 O): new barium galloborates featuring unusual [B 4 O 8 (OH)] 5− and [B 10 O 18 (OH) 5 ] 11− clusters

    RSC Advances · 2014-01-01

    Hui Yang, Chun‐Li Hu, Jun‐Ling Song, Jiang‐Gao Mao

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  14. KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups

    Inorganic Chemistry · 2014-03-25

    Chao Zhang Huang, Jian‐Han Zhang, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  15. PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates

    CrystEngComm · 2014-06-12

    Yucheng Hao, Xiang Xu, Fang Kong, Jun‐Ling Song, Jiang‐Gao Mao

    Read original paper ↗ ·

  16. Recent advances on second-order NLO materials based on metal iodates

    Coordination Chemistry Reviews · 2015-01-25

    Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  17. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

    Ying Wang, Shilie Pan

    Read original paper ↗ ·

  18. The crystal design of polar one-dimensional hydrogen-bonded copper coordination complexes

    Dalton Transactions · 2016-01-01

    Kiyonori Takahashi, Norihisa Hoshino, Takashi Takeda, Koichiro Satomi, Yasutaka Suzuki, Shin‐ichiro Noro, Takayoshi Nakamura, Jun Kawamata, Tomoyuki Akutagawa

    Read original paper ↗ ·

  19. N→Sn-Coordinated Stannaoxidoborates Containing a SnB4O6 Unit

    Inorganic Chemistry · 2016-02-01

    Barbora Mairychová, Ivan V. Kityk, A. Maciąg, Filip Bureš, Milan Klikar, Aleš Růžička, Libor Dostál, Roman Jambor

    Read original paper ↗ ·

  20. NaBa4(GaB4O9)2X3 (X = Cl, Br) with NLO-Active GaO4 Tetrahedral Unit: Experimental and ab Initio Studies

    The Journal of Physical Chemistry C · 2016-02-16

    Ming Wen, Xin Su, Hongping Wu, Juanjuan Lu, Zhihua Yang, Shilie Pan

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  21. Structure modulations in nonlinear optical (NLO) materials Cs2TB4O9(T= Ge, Si)

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2016-02-29

    Zhengyang Zhou, Xiang Xu, Rao Fei, Jiang‐Gao Mao, Junliang Sun

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  22. Ln2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 (Ln = Y, Sm, Eu, Gd, Dy): A Series of Lanthanide Galloborates Decorated by Acetate Anions

    Inorganic Chemistry · 2016-06-06

    Hui Yang, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  23. Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks

    Journal of Cluster Science · 2016-12-29

    Pei-Li Xu, Congcong Jin, Tingting Deng, Er-Rong Wang, Jian‐Wen Cheng

    Read original paper ↗ ·

  24. Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes

    Chemistry - A European Journal · 2017-04-24

    Qi Wei, Shijia Sun, Jie Zhang, Guo‐Yu Yang

    Read original paper ↗ ·

  25. Molecular Group 13 Metallaborates Derived from M–O–M Cleavage Promoted by BH3

    Inorganic Chemistry · 2017-07-03

    Erandi Bernabé‐Pablo, Vojtěch Jančík, Diego Martı́nez-Otero, Joaquín Barroso‐Flores, Mónica Moya‐Cabrera

    Read original paper ↗ ·

  26. Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2

    Inorganic Chemistry · 2017-07-25

    Hongping Wu, Hongwei Yu, Shilie Pan, P. Shiv Halasyamani

    Read original paper ↗ ·

  27. Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate

    Inorganic Chemistry · 2017-10-18

    Sujuan Yu, Xiang-Yu Gu, Tingting Deng, Jianhao Huang, Jian‐Wen Cheng, Guo‐Yu Yang

    Read original paper ↗ ·

  28. Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics

    Angewandte Chemie International Edition · 2018-04-17

    Zhizhong Zhang, Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  29. Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics

    Angewandte Chemie · 2018-04-17

    Zhizhong Zhang, Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  30. Syntheses, Crystal Structures and Properties of Two Novel Mixed Anion Hybrids with Formulas of Pb 6 O 2 (BO 3 ) 2 (C 2 O 4 ) and Pb 4 (CO 3 ) 2 (C 2 O 4 )(OH) 2

    ChemistrySelect · 2018-05-22

    Hui Yang, Fei‐Fei Mao, Cuixia Xu

    Read original paper ↗ ·

  31. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

    Read original paper ↗ ·

  32. Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties

    Inorganic Chemistry · 2018-10-10

    Lin Cheng, Guo‐Yu Yang

    Read original paper ↗ ·

  33. Growth, Crystal Structures, and Characteristics of Li 5 ASrMB 12 O 24 (A = Zn, Mg; M = Al, Ga) with [MB 12 O 24 ] Frameworks

    Inorganic Chemistry · 2018-12-31

    Huimin Song, Naizheng Wang, Xingxing Jiang, Ying Fu, Yunfei Li, Wang Liu, Zheshuai Lin, Jiyong Yao, Guochun Zhang

    Read original paper ↗ ·

  34. Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties

    Inorganic Chemistry · 2019-02-13

    Qi Wei, Chao He, Bang‐Di Ge, Meng-Xin Wan, Li Wei, Guo‐Ming Wang

    Read original paper ↗ ·

  35. Synthesis, Characterization and Optical Properties of Two Metal Borates Containing Two Types of Oxoboron Clusters

    ChemistrySelect · 2019-04-02

    Hui Yang, Chun‐Li Hu, Bei Lv, Ru‐Ling Tang, Cuixia Xu

    Read original paper ↗ ·

  36. A Way for Derived Carbon Materials by Thermal Etching Hybrid Borate for Electrochemical CO2 Reduction

    Inorganic Chemistry · 2020-07-16

    Ying Liu, Kang Zhou, Hongli Chen, Yun‐Nan Gong, Chun‐Yang Pan

    Read original paper ↗ ·

  37. From [B 6 O 13 ] 8− to [GaB 5 O 13 ] 8− to [Ga{B 5 O 9 (OH)}{BO(OH) 2 }] 2− : synthesis, structure and nonlinear optical properties of new metal borates

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Guo‐Yu Yang

    Read original paper ↗ ·

  38. Synthesis and optical properties of N→Ga coordinated gallium boroxines

    Dalton Transactions · 2021-01-01

    Yaraslava Milasheuskaya, J. Schwarz, Libor Dostál, Zdeňka Růžičková, Marek Bouška, Zuzana Olmrová Zmrhalová, Tomáš Syrový, Roman Jambor

    Read original paper ↗ ·

  39. BO3 Triangle and B@Zn2O3 Cationic Layer in the Structure of the Hybrid Zinc Acetate Borate [ZnAc]·[ZnBO3]

    Inorganic Chemistry · 2021-01-08

    Wei Li, Jun-Xia Deng, Chun‐Yang Pan

    Read original paper ↗ ·

  40. Recent Advances in Crystalline Oxidopolyborate Complexes of d-Block or p-Block Metals: Structural Aspects, Syntheses, and Physical Properties

    Molecules · 2021-06-22

    Shu-Sheng Xin, Minghua Zhou, Michael A. Beckett, Chun‐Yang Pan

    Read original paper ↗ ·

  41. La2B3O4(OH)3(SO4)2: A new rare-earth borate-sulfate with second-harmonic generation response

    Journal of Solid State Chemistry · 2022-11-11

    Hui Yang, Ziyu Wang, Cuixia Xu, Yuan Hua Lin, Guoliang Liu

    Read original paper ↗ ·

  42. KCs2[GaB5O10](OH): A Zeolitic Galloborate Framework with a Nonlinear Optical Property

    Crystal Growth & Design · 2023-04-04

    Wenfang Liu, Chong‐An Chen, Xuyan Li, Guo‐Yu Yang

    Read original paper ↗ ·

  43. Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate

    Inorganic Chemistry · 2023-12-19

    Guangsheng Xu, Huimin Li, Jian Wei Han, Xueling Hou, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  44. Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives

    Dalton Transactions · 2024-01-01

    Jingyi Lu, Yangfeifei Ou, Congcong Jin, Jian‐Wen Cheng

    Read original paper ↗ ·

  45. Synthesis, Characterization and Optical Properties of Two Novel Metal Borates

    ChemistrySelect · 2024-04-11

    Menghan Zhou, Hui Yang, Zhifen Guo, Cuixia Xu, Xiaomin Gu, Yuan Hua Lin

    Read original paper ↗ ·

  46. [H2dab][GaB5O10]: an Acentric Galloborate with a 4-Connected Uninodal Framework

    Chemical Research in Chinese Universities · 2024-07-12

    Wenfang Liu, Chongan Chen, Guo‐Yu Yang

    Read original paper ↗ ·
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