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RESEARCH PAPER · Journal of Materials Chemistry C · 2018

Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 O

Hongming Liu, Xingxing Jiang, Xiaoxiao Wang, Lei Yang, Zheshuai Lin, Zhanggui Hu, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 OOriginalSynthesis, structure and nonlinear optical properties of solution-processed Bi 2 TeO 5 nanocrystals20KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer18LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution68Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 1217Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials37REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO398LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO337From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation14Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance17Volume Modulation of Nonlinear Optical Properties by Cation Substitution8Synthesis and Crystal Structure of New Iodate Na3Fe[IO3]6 of the A3M[IO3]6 Structural Family (A = Na, K, Rb, Cs, Tl; M = Ti, Fe, Ge, In, Pt)5Pb 2 TiFO(SeO 3 ) 2 Br: a new polar compound with the strongest second harmonic generation in the selenite bromide family29Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons15Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups18Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10A new I 3 O 9 3− group constructed from IO 3 − and IO 5 5− anion units in Cs 3 [Ga 2 O(I 3 O 9 )(IO 3 ) 4 (HIO 3 )]4K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations33KCs2Pb2(HCOO)2Cl5: A Lead Formate with Strong Second-Harmonic-Generation Response Obtained by an Anionic Substitution3Pressure-Induced Phase Transition and Band-Gap Decrease in Semiconducting Na3bi(Io3)68General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates15AIO3·H6TeO6 (A = NH4+, Rb+): Two telluric acid and iodate Co-crystalline compounds with second harmonic generation response4New layered nonlinear optical iodate Cs 3 Ta(IO 3 ) 8 : topology-symmetry analysis and structure prediction6Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure6Synthesis and Structure of a New Iodate Cs5[Sc2(IO3)9](IO3)2 with a Complex Framework Based on the Condensation of [Sc(IO3)6] Building Blocks4KBi(SeO4)(IO3)Cl: A mixed-anion oxychloride with three types of building units in one structure2NaMoO 3 (IO 3 )(H 2 O): water molecule introduction induces strong second harmonic generation response, widened band gap and large anisotropy8La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra4Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)64Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)60Rational Design of Novel Polar Nonlinear Optical Materials in Alkali Metal Rare Earth Iodates5Selenoborates: a latent structure resource for infrared functional crystal materials1Series of New Alkali Metal Hafnium-Based Iodates A2Hf(IO3)6 (A = K, Rb, Cs) and Isomorphic Ba2Zn(IO3)6 with Large Birefringence1La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties5Rb2HSc(IO3)6 – a new member of the iodate family with a structural unit [M(IO3)6]0Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions5Water Molecule-Driven Structural Evolution from Na2ZnCl4 to Na2ZnCl4·3H2O: A Route to Promising Deep-UV Nonlinear Optical Crystals0Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure1Solving the long-standing hygroscopicity and thermal stability issues of the nonlinear optical crystal α-LiIO 3 via homogeneous cation exchange0IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F20

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  1. Synthesis, structure and nonlinear optical properties of solution-processed Bi 2 TeO 5 nanocrystals

    Journal of Materials Chemistry C · 2018-01-01

    Bin Chen, Xingzhi Wang, Junqin Li, Qihua Xiong, Chaohua Zhang

    Read original paper ↗ ·

  2. KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer

    Dalton Transactions · 2019-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Ting Wang, Yao Guo, Xiao‐Fang Guan, Xian‐Ming Zhang

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  3. LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution

    Chemical Science · 2019-01-01

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Xiaohan Zhang, Bing‐Ping Yang, Jiang‐Gao Mao

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  4. Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 12

    CrystEngComm · 2019-01-01

    Lei Xiao, Fengguang You, Pifu Gong, Zhanggui Hu, Zheshuai Lin

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  5. Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials

    Chemistry of Materials · 2019-03-12

    Liling Cao, Yunxia Song, Guang Peng, Min Luo, Yi Jin Yang, Chensheng Lin, Dan Zhao, Feng Xu, Zheshuai Lin, Ning Ye

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  6. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie International Edition · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiao‐Han Zhang, Jiang‐Gao Mao

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  7. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiaohan Zhang, Jiang‐Gao Mao

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  8. Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties

    ChemistrySelect · 2019-08-06

    Qi Wu, Xian Liu, Siran Xu, Hongbing Pi, Yanjun Li

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  9. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie International Edition · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Minmin Liu, Xian‐Ming Zhang

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  10. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Min‐Min Liu, Xian‐Ming Zhang

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  11. From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation

    CrystEngComm · 2020-01-01

    Xian Liu, Can Yang, Qi Wu, Juan Sun, Fei Liang

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  12. Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance

    Inorganic Chemistry Frontiers · 2020-01-01

    Lin Lin, Longhua Li, Chao Wu, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  13. Volume Modulation of Nonlinear Optical Properties by Cation Substitution

    The Journal of Physical Chemistry C · 2020-04-15

    Jingmei Min, Hao Li, Jun Zhang

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  14. Synthesis and Crystal Structure of New Iodate Na3Fe[IO3]6 of the A3M[IO3]6 Structural Family (A = Na, K, Rb, Cs, Tl; M = Ti, Fe, Ge, In, Pt)

    Crystallography Reports · 2020-05-01

    Olga Reutova, Elena L. Belokoneva, Olga V. Dimitrova, Anatoly S. Volkov

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  15. Pb 2 TiFO(SeO 3 ) 2 Br: a new polar compound with the strongest second harmonic generation in the selenite bromide family

    Journal of Materials Chemistry C · 2021-01-01

    Lili Liu, Bingbing Zhang, P. Shiv Halasyamani, Weiguo Zhang

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  16. Pressure-dependent modifications in the optical and electronic properties of Fe(IO 3 ) 3 : the role of Fe 3d and I 5p lone–pair electrons

    Inorganic Chemistry Frontiers · 2021-01-01

    Akun Liang, Plácida Rodríguez-Hernández, Alfonso Muñoz, Saqib Rahman, Alfredo Segura, Daniel Errandonea

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  17. Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition

    Inorganic Chemistry · 2021-02-11

    Huimin Song, Dequan Jiang, Naizheng Wang, Wenhao Xing, Ruixin Guo, Zheshuai Lin, Jiyong Yao, Yonggang Wang, Heng Tu, Guochun Zhang

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  18. Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups

    Inorganic Chemistry · 2021-04-06

    Liling Cao, Shengzi Zhang, Dan Zhao, Bingxuan Li, Tao Yan, Guangsai Yang, Zheshuai Lin, Min Luo, Ning Ye

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  19. Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]

    Crystal Growth & Design · 2021-06-24

    Xiaoqing Jiang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  20. A new I 3 O 9 3− group constructed from IO 3 − and IO 5 5− anion units in Cs 3 [Ga 2 O(I 3 O 9 )(IO 3 ) 4 (HIO 3 )]

    CrystEngComm · 2021-11-11

    Dandan Wang, Xiaoqing Jiang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  21. K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations

    Chemical Science · 2021-12-06

    Jin Chen, Chun‐Li Hu, Yilin Li, Yan Chen, Qianqian Chen, Jiang‐Gao Mao

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  22. KCs2Pb2(HCOO)2Cl5: A Lead Formate with Strong Second-Harmonic-Generation Response Obtained by an Anionic Substitution

    Inorganic Chemistry · 2021-12-29

    Ziqi Zhou, Ruibiao Fu, Qirui Shui, Hong‐Xin Tang, Wen-Xiu Bao, Zuju Ma, Xintao Wu

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  23. Pressure-Induced Phase Transition and Band-Gap Decrease in Semiconducting Na3bi(Io3)6

    Results in Physics · 2022-01-01

    Robin Turnbull, Javier González‐Platas, Akun Liang, Dequan Jiang, Yonggang Wang, Cătălin Popescu, Plácida Rodríguez-Hernández, Alfonso Muñoz, Jordi Ibáñez, Daniel Errandonea

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  24. General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates

    Physical Review Materials · 2022-04-28

    Akun Liang, Robin Turnbull, Plácida Rodríguez-Hernández, Alfonso Muñoz, M. Jasmin, Lan-Ting Shi, Daniel Errandonea

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  25. AIO3·H6TeO6 (A = NH4+, Rb+): Two telluric acid and iodate Co-crystalline compounds with second harmonic generation response

    Chinese Journal of Structural Chemistry · 2023-01-01

    Shunye Yu, Yi Shui, Shuo Liu, Shuo Liu, Gan Huang, Canxiao Huang, Chunhui Geng, Hongming Liu, Lili Liu, Hongming Liu

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  26. New layered nonlinear optical iodate Cs 3 Ta(IO 3 ) 8 : topology-symmetry analysis and structure prediction

    CrystEngComm · 2023-01-01

    Elena L. Belokoneva, Olga Reutova, Olga V. Dimitrova, Anatoly S. Volkov, Sergey Yu. Stefanovich, V. V. Maltsev, Marina F. Vigasina

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  27. Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure

    Inorganic Chemistry · 2023-01-27

    Lei Geng, Wenfei Li, Baozhu Zhu, Shihua Ma, Baotong Liu, Kaiyue Jiang, Hong‐Yan Lu, Chang‐Yu Meng

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  28. Synthesis and Structure of a New Iodate Cs5[Sc2(IO3)9](IO3)2 with a Complex Framework Based on the Condensation of [Sc(IO3)6] Building Blocks

    Symmetry · 2023-09-17

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  29. KBi(SeO4)(IO3)Cl: A mixed-anion oxychloride with three types of building units in one structure

    Journal of Solid State Chemistry · 2023-10-14

    Lei Geng, Shihua Ma, Baozhu Zhu, Wenfei Li, Kaiyue Jiang, Hong‐Yan Lu, Quan Yan, Chang‐Yu Meng

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  30. NaMoO 3 (IO 3 )(H 2 O): water molecule introduction induces strong second harmonic generation response, widened band gap and large anisotropy

    Dalton Transactions · 2023-12-06

    Yi Shui, Zhengli Liang, Zhenhua Li, Jiahao Wan, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  31. La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra

    Inorganic Chemistry · 2024-07-25

    Jingxuan Hou, Jiajia Wang, Fei Liang, Shihui Ma, Hongwei Yu, Hongping Wu, Ning Ye, Zhanggui Hu, Yicheng Wu

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  32. Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)6

    Crystallography Reports · 2024-08-01

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  33. Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)6

    Кристаллография · 2024-09-25

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  34. Rational Design of Novel Polar Nonlinear Optical Materials in Alkali Metal Rare Earth Iodates

    Inorganic Chemistry · 2024-10-23

    Lijuan Liu, Haotian Tian, Mingjun Xia, Xiaoyang Wang

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  35. Selenoborates: a latent structure resource for infrared functional crystal materials

    Inorganic Chemistry Frontiers · 2025-01-01

    Yihan Yun, Abudukadi Tudi, Zhihua Yang, Guangmao Li, Shilie Pan

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  36. Series of New Alkali Metal Hafnium-Based Iodates A2Hf(IO3)6 (A = K, Rb, Cs) and Isomorphic Ba2Zn(IO3)6 with Large Birefringence

    Crystal Growth & Design · 2025-03-19

    Shuwen Zhao, Zhiyong Xue, Xin Wen, Yuchen Yan, Jindong Chen, Guang Peng, Ning Ye

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  37. La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties

    Inorganic Chemistry · 2025-06-03

    Jingxuan Hou, Dingxuan Zhao, Zifan Xu, Shihui Ma, Jiajia Wang, Hongwei Yu, Guang Peng, Ning Ye, Zhanggui Hu

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  38. Rb2HSc(IO3)6 – a new member of the iodate family with a structural unit [M(IO3)6]

    Solid State Sciences · 2025-06-25

    O. P. Grigorieva, В. А. Тафеенко, Alexey N. Kuznetsov∥, Peter S. Berdonosov, В. А. Долгих

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  39. Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions

    Inorganic Chemistry · 2025-06-30

    Lei Geng, Baozhu Zhu, You‐Zhao Lan, Chang‐Yu Meng, Qi Wu

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  40. Water Molecule-Driven Structural Evolution from Na2ZnCl4 to Na2ZnCl4·3H2O: A Route to Promising Deep-UV Nonlinear Optical Crystals

    Crystal Growth & Design · 2025-07-08

    Mengmeng Chen, Wangfei Che, Cui Chen, Qixian Ren, Juanjuan Lu, Yabo Wu

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  41. Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure

    Physical review. B./Physical review. B · 2025-12-16

    F. Bodo, E. Kraka, A. Erba

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  42. Solving the long-standing hygroscopicity and thermal stability issues of the nonlinear optical crystal α-LiIO 3 via homogeneous cation exchange

    Inorganic Chemistry Frontiers · 2026-01-01

    Jiahao Wan, Zhengli Liang, Xiuying Zhang, Hongming Liu, Le Yang, Ping Wang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Qi Wu

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  43. IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F2

    Inorganic Chemistry · 2026-08-04

    Yanhong Wang, Shuaikun Li, Haibo Li, Yun Lv, О. С. Волкова, Alexander N. Vasiliev, Zhengcai Xia, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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